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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Interplanetary dust collected in the earth's stratosphere - The question of solar flare tracks

The negative result of a transmission electron microscope (TEM) search for solar flare tracks in 10 micron interplanetary dust particles (Flynn et al., 1978) which have been collected in the earth's stratosphere with a program of sampling initiated by Brownlee et al. (1976) has been reported previously. In this paper, it is shown that silicates in the particles record laboratory iron-ion tracks which are detectable in the TEM. The absence of tracks in the silicates could be due to track annealing on atmospheric entry, and may indicate a particle emissivity below 0.3, or that many of the particles broke up on encounter with the atmosphere. Alternatively, the lifetime of 10 micron dust particles at 1 AU could be shorter than that given by previous estimates.

Fraundorf, P.↗
NASA NTRS1998

Contributions of Nimbus 7 TOMS Data to Volcanic Study and Hazard Mitigation

Nimbus TOMS data have led to advancements among many volcano-related scientific disciplines, from the initial ability to quantify SO2 clouds leading to derivations of eruptive S budgets and fluxes, to tracking of individual clouds, assessing global volcanism and atmospheric impacts. Some of the major aspects of TOMS-related research, listed below, will be reviewed and updated: (1) Measurement of volcanic SO2 clouds: Nimbus TOMS observed over 100 individual SO2 clouds during its mission lifetime; large explosive eruptions are now routinely and reliably measured by satellite. (2) Eruption processes: quantification of SO2 emissions have allowed assessments of eruption sulfur budgets, the evaluation of "excess" sulfur, and inferences of H2S emissions. (3) Detection of ash: TOMS data are now used to detect volcanic particulates in the atmosphere, providing complementary analyses to infrared methods of detection. Paired TOMS and AVHRR studies have provided invaluable information on volcanic cloud compositions and processes. (4) Cloud tracking and hazard mitigation: volcanic clouds can be considered gigantic tracers in the atmosphere, and studies of the fates of these clouds have led to new knowledge of their physical and chemical dispersion in the atmosphere for predictive models. (5) Global trends: the long term data set has provided researchers an unparalleled record of explosive volcanism, and forms a key component in assessing annual to decadal trends in global S emissions. (6) Atmospheric impacts: TOMS data have been linked to independent records of atmospheric change, in order to compare cause and effect processes following a massive injection of SO2 into the atmosphere. (7) Future TOMS instruments and applications: Nimbus TOMS has given way to new satellite platforms, with several wavelength and resolution modifications. New efforts to launch a geostationary TOMS could provide unprecedented observations of volcanic activity.

Krueger, Arlin J.↗
NASA NTRSDate not supplied

Development of Luminescence Lifetime-Based Surface Temperature Mapping for Environmental Barrier Coatings

Luminescence lifetime-based temperature mapping for thermal barrier coatings (TBCs) has been previously demonstrated up to temperatures approaching 1200 °C. Advantages of this method include insensitivities to reflected radiation and emissivity uncertainties. Because of a push towards greater efficiency turbine engine operation using higher turbine inlet temperatures, there is an ongoing movement from TBC-coated superalloy turbine engine components to SiC/SiC ceramic matrix composite components protected by environmental barrier coatings (EBCs). The useful application of luminescence lifetime-based temperature mapping to EBCs requires a significant increase in high temperature capability from below 1200 °C up into the 1300 to 1500 °C temperature range where the much higher background thermal radiation is a challenging issue. In addition, the luminescing sensing layer must exhibit thermochemical compatibility with the EBC. To meet these requirements, Er-doped Y 2 SiO 5 was selected as the luminescing sensor layer material both for its enhanced temperature sensitivity above 1300 °C and its compatibility with rare-earth disilicate EBC topcoats. Both localized spot temperature measurements as well as luminescence lifetime imaging-based temperature mapping were demonstrated up to 1560 °C for Er-doped Y 2 SiO 5 disks. In addition, temperature mapping capability was demonstrated from a 15 µm thick Er-doped Y 2 SiO 5 layer at the surface of a Sc 2 Si 2 O 7 based EBC topcoat. Both localized spot and temperature mapping by luminescence lifetime imaging were demonstrated up to 1380 °C (upper temperature limit of this slurry-based layered EBC) with excellent suppression of background thermal radiation and no degradation of the Er-doped Y 2 SiO 5 temperature sensing surface layer. The source of the novel enhanced temperature sensitivity above 1300 °C will be discussed as well as a path towards compatibility between sensing layer and EBC topcoat to higher temperatures.

temperature measurement↗
NASA NTRS1982

X-ray illumination of globular cluster puzzles

Globular clusters are thought to be among the oldest objects in the Galaxy, and provide, in this connection, important clues for determining the age and process of formation of the Galaxy. The present investigation is concerned with puzzles relating to the X-ray emission of globular clusters, taking into account questions regarding the location of X-ray emitting clusters (XEGC) unusually near the galactic plane and/or galactic center. An adopted model is discussed for the nature, formation, and lifetime of X-ray sources in globular clusters. An analysis of the available data is conducted in connection with a search for correlations between binary formation time scales, central relaxation times, galactic locations, and X-ray emission. The positive correlation found between distance from galactic center and two-body binary formation time for globular clusters, explanations for this correlation, and the hypothesis that X-ray sources in globular clusters require binary star systems provide a possible explanation of the considered puzzles.

Lightman, A. P.↗
NASA NTRS2007

Arrays of Bundles of Carbon Nanotubes as Field Emitters

Experiments have shown that with suitable choices of critical dimensions, planar arrays of bundles of carbon nanotubes (see figure) can serve as high-current-density field emitter (cold-cathode) electron sources. Whereas some hot-cathode electron sources must be operated at supply potentials of thousands of volts, these cold-cathode sources generate comparable current densities when operated at tens of volts. Consequently, arrays of bundles of carbon nanotubes might prove useful as cold-cathode sources in miniature, lightweight electron-beam devices (e.g., nanoklystrons) soon to be developed. Prior to the experiments, all reported efforts to develop carbon-nanotube-based field-emission sources had yielded low current densities from a few hundred microamperes to a few hundred milliamperes per square centimeter. An electrostatic screening effect, in which taller nanotubes screen the shorter ones from participating in field emission, was conjectured to be what restricts the emission of electrons to such low levels. It was further conjectured that the screening effect could be reduced and thus emission levels increased by increasing the spacing between nanotubes to at least by a factor of one to two times the height of the nanotubes. While this change might increase the emission from individual nanotubes, it would decrease the number of nanotubes per unit area and thereby reduce the total possible emission current. Therefore, to maximize the area-averaged current density, it would be necessary to find an optimum combination of nanotube spacing and nanotube height. The present concept of using an array of bundles of nanotubes arises partly from the concept of optimizing the spacing and height of field emitters. It also arises partly from the idea that single nanotubes may have short lifetimes as field emitters, whereas bundles of nanotubes could afford redundancy so that the loss of a single nanotube would not significantly reduce the overall field emission.

Manohara, Harish↗
NASA NTRS1991

Excited state dynamics of thulium ions in yttrium aluminum garnets

The processes that take place in the excited states of a trivalent Thulium (Tm) ion in an Yttrium Aluminum Garnet (YAG) crystal, being relevant to the use of this system for laser applications, have been the object of several studies. We have reexamined this system focusing our attention on the dynamics of Tm following its excitation in the H-3(sub 4) level. Under these conditions the system relaxes through a cross-relaxation process. H-3(sub 4) yields F-3(sub 4), H-3(sub 6) yields F-3(sub 4), whose rate depends upon both the concentration of the Tm ion and the temperature of the crystal. The excitation spectrum obtained by monitoring the 1.8 micron emission of Tm (due to the F-3(sub 4) yields H-3(sub 6) transition) indicates an increase in the contribution to this emission from the H-3(sub 4) level relative to the H-3(sub 5) level as the Tm concentration increases; this shows the increased role played by the H-3(sub 4) level in pumping the infrared emission. Correspondingly, the duration of the luminescence originating in the H-3(sub 4) level is shortened as the concentration of Tm increases. The concentration quenching of this lifetime can be fit to a model which assumes that the cross-relaxation is due to a dipole-dipole interaction; from this fit, the intrinsic Tm lifetime in the absence of cross relaxation can be derived. We have used this lifetime to calculate the rate of the cross-relaxation process. We have evaluated this rate as a function of the temperature and found it to be fastest at 77 K. We have also calculated the microscopic interaction parameters for the cross-relaxation process by using two independent experimental features: (1) the time evolution of the emission from the H-3(sub 4) level; and (2) the spectral overlap between the H-3(sub 4) yields F-3(sub 4) emission and the H-3(sub 6) yields F-3(sub 4) absorption. We have also considered the migration of excitation among the Tm ions in the F-3(sub 4) level and calculated the relevant microparameter by the use of the relevant spectral overlap. The data are consistent with the model in which the Tm ions, once excited into the H-3(sub 4) level decay by cross-relaxation to the F-3(sub 4), and then transfer rapidly their energy to other Tm ions.

Armagan, G.↗
NASA NTRS1988

Performance of efficient Q-switched diode-laser-pumped Nd:YAG and Ho:YLF lasers for space applications

Solid-state lasers pumped by continuous-wave diode lasers can be Q-switched to obtain high peak power output pulses. The dependence of laser-pulse energy, average output power, peak power, and pulse width on pulse-repetition frequency in Q-switched Nd:YAG and Ho:YLF lasers is determined and compared. At low pulse repetition rates, the much longer upper-stage lifetime in Ho:YLF gives a distinct advantage. At higher pulse rates, the overall laser efficiency and the stimulated emission cross section are more important parameters, leading to an advantage for Nd:YAG. The results are of significance for designing lasers for use in space optical communications and remote sensing systems.

Marshall, W. K.↗
NASA NTRS1988

Fabry-Perot ground-based observations of comets and the Jupiter plasma torus

The Wisconsin 150 mm dual etalon Fabry-Perot spectrometer is a powerful instrument for the study of diffuse emission sources such as cometary atmospheres, the Jupiter plasma torus, and various emission nebulae. Since 1985, researchers have concentrated their efforts on extensive observations of Comet Halley and the analysis of the data. Images of Comet Halley in (OI)6300 Angstrom emission were analyzed to obtain the spatial distribution of O(1D) in the cometary atmosphere. The narrow spectral bandpass of the Fabry-Perot (0.2 Angstrom) eliminated contamination from terrestrial airglow (OI)6300 and cometary NH2 lines in the nearby spectrum. The results were modelled to provide photodestruction lifetimes of cometary Water abd OH, the predominant parents of O(1D). The Fabry-Perot was also used in the scanning mode to obtain measurements of (OI)6300 and Balmer alpha emissions which were used to determine the H, O(1D) and water production rates as a function of heliocentric distance, both pre-perihelion and post-perihelion. Researchers also analyzed high resolution spectra of the NH2 (0,8,0) band in the 6300 Angstrom region to obtain preliminary values of the NH2 production rate. Assuming NH3 is the major parent of NH2, researchers found that the abundance ratio NH3/water is about (0.12 plus or minus 0.04 percent), assuming thermal equilibrium for the level populations of NH2.

Scherb, Frank↗
NASA NTRS1981

Negative ions in the ionospheres of planetary bodies without atmospheres

It is noted that negative ions may be formed in the ionospheres of Mercury, the moon, and Jupiter's satellites with densities of a few percent of the ionospheric electron density. Negative ions result from three mechanisms at the planetary surface: charge inversion during energetic proton scattering, with simultaneous secondary negative ion emission, and micrometeorite impacts. The density and distribution of negative ions around planetary bodies depends primarily on the negative ion lifetimes determined through photodetachment by solar radiation.

Wekhof, A.↗
NASA NTRS1983

Sources, sinks, and seasonal cycles of atmospheric methane

It is shown that a lifetime of approximately 8 years is most consistent with the observed latitudinal variation of atmospheric methane, requiring the current global emissions of methane to be around 550 teragrams per year. The repeating pattern of a rapid rise of CH4 concentrations in the fall in the Northern Hemisphere indicates a large fall source at latitudes above 30 deg N. The remaining observed seasonal variations are seen as consistent with the seasonal cycle of OH, which removes methane from the atmosphere. An extensive set of self-consistent measurements of methane is reported and analyzed, revealing that methane has increased during the past 3-4 years at rates of 1-1.9 percent per year all over the world at sites ranging from inside the Arctic Circle to the South Pole. The observational results are used in estimating the sources, sinks, and seasonal cycles of CH4 and the effects of human activities on its atmospheric abundance.

Khalil, M. A. K.↗
NASA NTRS1985

On the rarity of FK Com stars

Very high-dispersion spectra (2.5 A/mm) were obtained of 31 southern late-type stars, predominantly early G giants, in an effort to find new rapidly rotating, active stars which would be FK Com-like. Measurements of linewidths and the strength of chromospheric Ca II K-line emission are presented, but no new star could be added to the class of 'rapid rotators'. Space densities and evolutionary lifetimes for FK Com stars are discussed.

Hagen, W.↗
NASA NTRS1988

Spectroscopy and diode laser-pumped operation of Tm, Ho:YAG

Spectroscopic measurements and analysis of diode laser-pumped operation of Tm, Ho:YAG at 2.1 microns at room temperature have been performed. The peak effective stimulated emission cross section is measured to be 9 x 10-21 sq cm at 2.091 microns and the upper state lifetime is 8.5 ms. Under diode laser pumping, thresholds of 4.4 mW of absorbed power and slope efficiency of 19 percent have been demonstrated. Calculations of threshold power are performed based on the spectroscopic measurements. An energy transfer upconversion process is identified which leads to a sublinear rise in upper-state population with pump power.

Fan, Tso Yee↗
NASA NTRS1993

Atmospheric methyl bromide - Trends and global mass balance

A decadal time series of global CH3Br concentrations in the earth's atmosphere is presented. It is shown that average concentrations are about 10 pptv and during the last 4 yr may be increasing at 0.3 +/- 0.1 pptv/yr. It is estimated that the atmospheric lifetime of CH3Br that is due to reaction with OH is about 2 yr, which results in a calculated global emission rate of about 100 Gg/yr. Ocean supersaturations of 140-180 percent are observed, and atmospheric concentrations over the open oceans are higher than at comparably located coastal sites. The ocean source is estimated to be about 35 Gg/yr. The remaining emissions must come from other natural sources and anthropogenic activities.

Khalil, M. A. K.↗
NASA NTRS1996

Photodissociation Cross Sections for the Production of C2 from C2H Using Laser Induced Hg Photosensitization and Tunable Ultraviolet and Visible Lasers

The principle goal of our research was to understand the formation of free radicals in comets. To do this we compared laboratory results with cometary observations in attempt to make sure that the cometary observations agree with what is known about the photochemistry of the proposed parent molecule. Initially we concentrated on the CS emission in an effort to show the parent of this molecule was CS2, consistent with cometary observations of the photochemical lifetime. We then started to look into the problem of the C2 formation in comets. We set out to see if we could measure all of the nascent distributions of the C2 products in the hope that they would be a characteristic signature of the formation process.

Jackson, William M.↗
NASA NTRS2000

Methanogenesis, Mesospheric Clouds, and Global Habitability

Hyperthermophilic methanogens can exist in a deep hot biosphere up to 110 C, or 10 km deep. Methane (CH4) itself is thermodynamically stable to depths of 300 km. Geologic (microbial plus abiogenic thermal) methane is transported upward, attested to by its association with helium, to form petroleum pools. Near or at the surface, geologic CH4 mixes with other natural and with anthropogenic CH4 yielding annual emissions into the atmosphere of 500 Tg, of which 200 Tg are natural and 300 Tg are man-made. The atmospheric lifetime of CH4, a greenhouse gas 20 times more effective than CO2 in raising global temperatures, is approximately 10 years. It is removed from the atmosphere mainly by reactions with hydroxyl radical (OH) to form CO2, but also by dry soil and by conversion to H2O in the stratosphere and middle atmosphere. A sudden rise in atmospheric temperatures by 9-12 C some 55 million years ago has been explained by the release in a few thousand years of three trillion tons of CH4 out of 15 trillion tons that had formed beneath the sea floor. What prevented this CH4-induced greenhouse effect from running away? An analog to the CH4-burp of 55 million years ago is the CH4-doubling over the past century which resulted in a increase in upper level H2O from 4.3 ppmv to 6 ppmv. This 30% increase in H2O vapor yielded a tenfold increase in brightness of polar mesospheric clouds because of a strong dependence of the ice particle nucleation rate on the water saturation ratios. Models show that at a given temperature the optical depth of mesospheric clouds scales as [H2O]beta with beta varying between 4 and 8. Radiative transfer tools applied to mesospheric particles suggest that an optical depth of approximately one, or 1000 times the current mesospheric cloud optical depth, would result in tropospheric cooling of about 10 K. Assuming beta=6, a thousandfold increase in optical thickness would require a three-fold increase of H2O, or a 20-fold increase of CH4. At the current rate of anthropogenic emissions this is expected to occur within the next 1000 years. This timescale is also commensurate with what has been assumed for the CH4- burp 55 million years ago.

Pueschel, Rudolf F.↗
NASA NTRS2018

Femtosecond Laser Tagging in 1,1,1,2-Tetrauoroethane with Trace Quantities of Air

Femtosecond laser tagging is demonstrated for the first time in R134a gas, and in mixtures of R134a with small quantities of air. A systematic study of this tagging method is explored through the adjustment of gas pressure, mixture ratio and laser properties. It is found that the signal strength and lifetime are greatest at low pressures for excitation at both the 400 nm and 800 nm laser wavelengths. The relative intensities of two spectral peaks in the near-UV emission change as a function of gas pressure and can potentially be used for local pressure measurements. Single shot precision in pure R134a and R134a with 5% air is demonstrated at the exit of a subsonic pipe flow. The parameter space of these results are chosen to mimic conditions used in the NASA Langley Research Center's Transonic Dynamics Tunnel. The precision and signal lifetime demonstrate the feasibility of using this technique for measuring flowfields that induce airfoil utter.

Zhang, Yibin↗
NASA NTRS2019

Early Calibration and Performance Assessments of NOAA-20 VIIRS Thermal Emissive Bands

The Visible Infrared Imaging Radiometer Suite (VIIRS) sensor aboard the NOAA-20 (previously JPSS-1) spacecraft has successfully operated since its launch in November, 2017. Similar to the first VIIRS instrument on the Suomi-NPP spacecraft, data is collected in 22 spectral bands that are calibrated by a set of onboard calibrators. This paper provides an overview of the NOAA-20 VIIRS on-orbit operation and calibration, with a particular focus on the thermal emissive bands (TEBs). Results presented in this paper include the on-orbit changes in the TEB spectral band responses, detector noise characterization, and key calibration parameters, such as the non-linear coefficients derived from the blackbody warm-up cool-down cycle. Other issues, such as the early mission long-wave infrared (LWIR) response degradation due to icing on the dewar window, and their impact on sensor calibration are also discussed. Since launch, the VIIRS instrument temperature has been stable to within ± 0.8K and the cold focal plane temperatures are well controlled with variations less than 40 mK. With the exception of the early degradation observed in the LWIR bands, the TEB gains have been stable to within 0.04% (except I5 at 0.07%). Based on the current performance, VIIRS is expected to meet its calibration requirements throughout its design lifetime.

NEdT↗
NASA NTRS2000

On the Spatial Distribution of High Velocity Al-26 Near the Galactic Center

We present results of simulations of the distribution of 1809 keV radiation from the decay of Al-26 in the Galaxy. Recent observations of this emission line using the Gamma Ray Imaging Spectrometer (GRIS) have indicated that the bulk of the AL-26 must have a velocity of approx. 500 km/ s. We have previously shown that a velocity this large could be maintained over the 10(exp 6) year lifetime of the Al-26 if it is trapped in dust grains that are reaccelerated periodically in the ISM. Here we investigate whether a dust grain velocity of approx. 500 km/ s will produce a distribution of 1809 keV emission in latitude that is consistent with the narrow distribution seen by COMPTEL. We find that dust grain velocities in the range 275 - 1000 km/ s are able to reproduce the COMPTEL 1809 keV emission maps reconstructed using the Richardson-Lucy and Maximum Entropy image reconstruction methods while the emission map reconstructed using the Multiresolution Regularized Expectation Maximization algorithm is not well fit by any of our models. The Al-26 production rate that is needed to reproduce the observed 1809 keV intensity yields in a Galactic mass of Al-26 of approx. 1.5 - 2 solar mass which is in good agreement with both other observations and theoretical production rates.

Sturner, Steven J.↗