Identification and Quantification of Carbon Phases in Conversion Fuel for the Transient Reactor Test Facility
As part of an overall effort to convert US research reactors to low-enriched uranium (LEU) fuel, a LEU conversion fuel is being designed for the Transient Reactor Test Facility (TREAT) at the Idaho National Laboratory. TREAT fuel compacts are comprised of UO{sub 2} fuel particles in a graphitic matrix material. In order to refine heat transfer modeling, as well as determine other physical and nuclear characteristics of the fuel, the amount and type of graphite and non-graphite phases within the fuel matrix must be known. In this study, we performed a series of complementary analyses, designed to allow detailed characterization of the graphite and phenolic resin based fuel matrix. Methods included Scanning Electron Microscopy, Raman spectroscopy, and X-ray Diffraction. Our results indicate that no single characterization technique will yield all of the desired information; however, through the use of statistical and empirical data analysis, such as curve fitting, partial least squares regression, volume extrapolation and spectra peak ratios, a degree of certainty for the quantity of each phase can potentially be obtained. Although no one type of analysis has provided a complete determination of the quantities and identities of all carbon phases present in the fuel matrix, additional information has been gathered and is being used to refine future analysis methods. From the three types of quantification performed, results have been within 1% (92.8%, 93.02% and 93.6% for BSE image analysis, XRD and Raman spectroscopy, respectively). More work remains to identify any trace crystalline carbonaceous phases that may be present, quantify any traces that are identified, and develop and use further complementary bulk phase quantification techniques. (authors)