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At least 217 records · Page 12

Investigation of the Ignition and Burning of Materials in Space Cabin Atmospheres. Part 2: Ignition of a Combustible Mixture by a Hot Body with the Effects of Gravity

The ignition of a combustible gas mixture by a hot cylinder under the effect of a gravity field for steady state conditions is examined. For this purpose a horizontal cylinder is considered with gravity as a parameter together with a finite chemical reacting flow generated by free convection with the additional effect of diffusion. Both mass transfer and zero mass transfer cases are considered. By defining an ignition criterion the surface temperature and species are obtained from the analysis as a function of the gravity field. It is supposed that at the point of ignition the heat evolved in the gas is sufficiently high to attain a sustained combustion without any energy from the hot cylinder.

Lew, H. G.↗

Thermal property measurements on lunar material returned by Apollo 11 and 12 missions.

Measurement of thermal diffusivity on Apollo 11 type A and type C samples in the temperature range between 150 and 440 K under atmospheric pressure. Thermal diffusivity of type C material is lower and less temperature-dependent than type A material. Both types of samples exhibit lower thermal diffusivities than nonporous terrestrial basalt. The rate of heat generation of Apollo 11 and 12 samples was calculated from the concentrations of radioactive elements: potassium, thorium, and uranium. Apollo 11 crystalline rocks show an average rate of heat generation which is not significantly different from terrestrial basalt. The Th/U ratio does not differ greatly from chondritic and terrestrial averages.

Horai, K.-I.↗

Radiative equilibrium in a rectangular enclosure bounded by gray walls

Two-dimensional temperature and heat-flux distributions are calculated for an absorbing-emitting gray medium at radiative equilibrium in a rectangular enclosure. The bounding walls are gray and diffuse with arbitrary surface-temperature distributions, and heat generation may take place inside the medium. As a first approximation, the problem is solved for optically thick systems (differential approximation). These results are subsequently improved by the introduction of a number of geometrical parameters to yield good accuracy for all optical thicknesses. As examples, two cases are discussed in detail: (1) uniform heat generation in a black enclosure, and (2) an enclosure with one gray surface at constant temperature. Comparison with some numerical solutions generated by Hottel's /Hottel and Cohen (1958) and Einstein (1963)/ zonal method shows excellent agreement.

Modest, M. F.↗

Elemental composition of aerosols in fourteen experiments of the Cloud Condensation Nuclei Workshop

Aeosols were collected with two Ci impactors and analyzed with proton induced X-ray emission (PIXE) for chemical composition and to detect if contamination was present. One of the impactors sampled the generated aerosols; the other impactor sampled droplets from a diffusion cloud chamber. The purpose of the experiments was to test the feasibility of a study of the transfer of chemical elements from the fine particle sizes to the coarse particle sizes, after CCN are activated and cloud droplets are formed. The data indicated that sulfur-containing aerosols did exhibit the expected transfer.

Mach, W. H.↗

Electric discharge synthesis of HCN in simulated Jovian atmospheres

Corona discharge is presently considered as a possible source of the HCN detected in the Jovian atmosphere at 2.2 x 10 to the -7th moles/sq cm column density, for the cases of gas mixtures containing H2, CH4, and NH3, with H2/CH4 ratios from 4.4 to 1585. A 3:1 ratio of corona discharge to lightning energy similar to that of the earth is applied to Jupiter. Depending on the lightning energy available on Jupiter and the eddy diffusion coefficients in the synthesis region, HCN column densities generated by corona discharge could account for about 10 percent of the HCN observed.

Stribling, Roscoe↗

Hydrogen line and continuum emission in young stellar objects. II - Theoretical results and observational constraints

Theoretical results for H I emission from YSOs are compared with available observations. IR line and radio continuum properties have been gathered for 29 objects that include a number of T Tau stars, several emission-line stars with IR excesses, and many heavily obscured luminous YSOs. The present excitation model can account for the observed Brackett line and radio continuum fluxes of YSOs with luminosities of 20-100,000 solar luminosities. It is argued that the observed Br-alpha line and 6-cm free-free continuum emissions are best explained in terms of a core-halo structure. The small core (ranging from r less than about 30 AU for a 10,000-solar luminosity YSO to r less than about 0.2 AU for a 10-solar luminosity YSO) is responsible for generating the strong IR line fluxes, while the surrounding diffuse halo dominates the 6-cm emission.

Alonso-Costa, Jose L.↗

The effect of Na vapor on the Na content of chondrules

Chondrules contain higher concentrations of volatiles (Na) than expected for melt droplets in the solar nebula. Recent studies have proposed that chondrules may have formed under non-canonical nebular conditions such as in particle/gas-rich clumps. Such chondrule formation areas may have contained significant Na vapor. To test the hypothesis of whether a Na-rich vapor would minimize Na volatilization reaction rates in a chondrule analog and maintain the Na value of the melt, experiments were designed where a Na-rich vapor could be maintained around the sample. A starting material with a melting point lower that typical chondrules was required to keep the logistics of working with Na volatilization from NaCl within the realm of feasibility. The Knippa basalt, a MgO-rich alkali olivine basalt with a melting temperature of 1325 +/- 5 C and a Na2O content of 3.05 wt%, was used as the chondrule analog. Experiments were conducted in a 1 atm, gas-mixing furnace with the fO2 controlled by a CO/CO2 gas mixture and fixed at the I-W buffer curve. To determine the extent of Na loss from the sample, initial experiments were conducted at high temperatures (1300 C - 1350 C) for duration of up to 72 h without a Na-rich vapor present. Almost all (up to 98%) Na was volatilized in runs of 72 h. Subsequent trials were conducted at 1330 C for 16 h in the presence of a Na-rich vapor, supplied by a NaCl-filled crucible placed in the bottom of the furnace. Succeeding Knudsen cell weight-loss mass-spectrometry analysis of NaCl determined the P(sub Na) for these experimental conditions to be in the 10(exp -6) atm range. This value is considered high for nebula conditions but is still plausible for non-canonical environments. In these trials the Na2O content of the glass was maintained or in some cases increased; Na2O values ranged from 2.62% wt to 4.37% wt. The Na content of chondrules may be controlled by the Na vapor pressure in the chondrule formation region. Most heating events capable of producing chondrules are sufficient to volatile Na. Sodium volatilization reaction rates will be reduced to varying degrees from melt droplets, depending on the magnitude of the P(sub Na) generated. A combination of Na vapor during, and Na diffusion back into chondrules after, formation could maintain and/or enrich Na concentrations in chondrules.

Lewis, R. Dean↗

Polycrystalline or amorphous semiconductor photovoltaic device having improved collection efficiency

A body of semiconductor material having a first surface and a second surface spaced from the first surface includes a first layer along the first surface, a second layer along the second surface, a third layer between and contiguous to the first and second layers. The third layer is of a conductivity type opposite that of the first and second layers so as to form first and second P-N junctions respectively therebetween. The thickness of the third layer is at least twice the minority carrier diffusion length of the semiconductor material, so that carriers generated within the third layer have a high probability of being collected by one of the P-N junctions. The body includes means for electrically connecting the first and second P-N junctions and means for transferring the carriers collected at the first P-N junction to a portion of the first surface.

Kressel, Henry↗

The Foggy EUV Corona and Coronal Heating by MHD Waves from Explosive Reconnection Events

In 0.5 arcsec/pixel TRACE coronal EUV images, the corona rooted in active regions that are at the limb and are not flaring is seen to consist of (1) a complex array of discrete loops and plumes embedded in (2) a diffuse ambient component that shows no fine structure and gradually fades with height. For each of two not-flaring active regions, found that the diffuse component is (1) approximately isothermal and hydrostatic and (2) emits well over half of the total EUV luminosity of the active-region corona. Here, from a TRACE Fe XII coronal image of another not-flaring active region, the large sunspot active region AR 10652 when it was at the west limb on 30 July 2004, we separate the diffuse component from the discrete loop component by spatial filtering, and find that the diffuse component has about 60% of the total luminosity. If under much higher spatial resolution than that of TRACE (e. g., the 0.1 arcsec/pixel resolution of the Hi-C sounding-rocket experiment proposed by J. W. Cirtain et al), most of the diffuse component remains diffuse rather being resolved into very narrow loops and plumes, this will raise the possibility that the EUV corona in active regions consists of two basically different but comparably luminous components: one being the set of discrete bright loops and plumes and the other being a truly diffuse component filling the space between the discrete loops and plumes. This dichotomy would imply that there are two different but comparably powerful coronal heating mechanisms operating in active regions, one for the distinct loops and plumes and another for the diffuse component. We present a scenario in which (1) each discrete bright loop or plume is a flux tube that was recently reconnected in a burst of reconnection, and (2) the diffuse component is heated by MHD waves that are generated by these reconnection events and by other fine-scale explosive reconnection events, most of which occur in and below the base of the corona where they are seen as UV explosive events, EUV blinkers, and type II spicules. These MHD waves propagate across field lines and dissipate, heating the plasma in the field between the bright loops and plumes.

Moore, Ron L.↗

Precipitation Model Validation in 3rd Generation Aeroturbine Disc Alloys

In support of application of the DARPA-AIM methodology to the accelerated hybrid thermal process optimization of 3rd generation aeroturbine disc alloys with quantified uncertainty, equilibrium and diffusion couple experiments have identified available fundamental thermodynamic and mobility databases of sufficient accuracy. Using coherent interfacial energies quantified by Single-Sensor DTA nucleation undercooling measurements, PrecipiCalc(TM) simulations of nonisothermal precipitation in both supersolvus and subsolvus treated samples show good agreement with measured gamma particle sizes and compositions. Observed longterm isothermal coarsening behavior defines requirements for further refinement of elastic misfit energy and treatment of the parallel evolution of incoherent precipitation at grain boundaries.

Olson, G. B.↗

Influence of the structure of inlet free-stream turbulence on diffuser performance

The pressure recovery coefficient of a two-dimensional diffuser (Cp) was found to be significantly affected by the intensity and structure of the inlet free-stream turbulence. Significantly larger values of Cp occurred for the case of highly anisotropic inlet free-stream turbulence with the plane of rotation of the eddies parallel to the free-stream flow and perpendicular to the diverging walls of the diffuser, as compared to the values of Cp for the case of grid-generated near-isotropic inlet conditions. The relatively high values of Cp for the case of the highly anisotropic inlet free-stream turbulence conditions can be attributed to highly effective mixing, where the plane of rotation of the eddies facilitates a direct transport of momentum from the free-stream to the boundary layers along the diverging walls of the diffuser, as compared to the mixing that occurs with grid-generated highly unorganized eddies.

Hoffmann, Jon A.↗

Electrocatalysis for oxygen electrodes in fuel cells and water electrolyzers for space applications

The lead ruthenate pyrochlore Pb2Ru2O6.5, in both high- and low-area forms, has been characterized using thermogravimetric analysis, X-ray photoelectron spectroscopy, X-ray diffraction, cyclic voltammetry, and O2 reduction and generation kinetic-mechanistic studies. Mechanisms are proposed. Compounds in which part of the Ru is substituted with Ir have also been prepared. They exhibit somewhat better performance for O2 reduction in porous, gas-fed electrodes than the unsubstituted compound. The anodic corrosion resistance of pyrochlore-based porous electrodes was improved by using two different anionically conducting polymer overlayers, which slow down the diffusion of ruthenate and plumbate out of the electrode. The O2 generation performance was improved with both types of electrodes. With a hydrogel overlayer, the O2 reduction performance was also improved.

Prakash, Jai↗

Gamma-ray constraints on Na-22 yields in nova explosions

The longitudinal distribution of diffuse 1.275 MeV emission produced by the decay of interstellar Na-22 generated by a limited class of energetic novae-accreting ONeMg white dwarfs is modeled. The probability distributions for the locations of disk novae are derived as functions of Galactocentric cylindrical coordinates. The occurrence rate for novae of all classes in the Galactic disk is about 30/yr. An occurrence rate of about 16/yr is found for spheroid novae of all classes. By comparing these simulation results with HEAO 3 upper limits on diffuse 1.275 MeV emission, upper limits of (3-5.6) x 10 to the -7th solar mass are determined for the mean Na-22 yield for energetic novae generated by accreting ONeMg white dwarfs. These Na-22 limits constrain future models of explosive nucleosynthesis in energetic nova explosions.

Higdon, J. C.↗

Practical method for diffusion welding of steel plate in air.

Description of a simple and easily applied method of diffusion welding steel plate in air which does not require a vacuum furnace or hot press. The novel feature of the proposed welding method is that diffusion welds are made in air with deadweight loading. In addition, the use of an autogenous (self-generated) surface-cleaning principle (termed 'auto-vac cleaning') to reduce the effects of surface oxides that normally hinder diffusion welding is examined. A series of nine butt joints were diffusion welded in thick sections of AISI 1020 steel plate. Diffusion welds were attempted at three welding temperatures (1200, 1090, and 980 C) using a deadweight pressure of 34,500 N/sq m (5 psi) and a two-hour hold time at temperature. Auto-vac cleaning operations prior to welding were also studied for the same three temperatures. Results indicate that sound welds were produced at the two higher temperatures when the joints were previously fusion seal welded completely around the periphery. Also, auto-vac cleaning at 1200 C for 2-1/2 hours prior to diffusion welding was highly beneficial, particularly when subsequent welding was accomplished at 1090 C.

Moore, T. J.↗

Numerical Simulations of Vortex Generator Vanes and Jets on a Flat Plate

Numerical simulations of a single low-profile vortex generator vane, which is only a small fraction of the boundary-layer thickness, and a vortex generating jet have been performed for flows over a flat plate. The numerical simulations were computed by solving the steady-state solution to the Reynolds-averaged Navier-Stokes equations. The vortex generating vane results were evaluated by comparing the strength and trajectory of the streamwise vortex to experimental particle image velocimetry measurements. From the numerical simulations of the vane case, it was observed that the Shear-Stress Transport (SST) turbulence model resulted in a better prediction of the streamwise peak vorticity and trajectory when compared to the Spalart-Allmaras (SA) turbulence model. It is shown in this investigation that the estimation of the turbulent eddy viscosity near the vortex core, for both the vane and jet simulations, was higher for the SA model when compared to the SST model. Even though the numerical simulations of the vortex generating vane were able to predict the trajectory of the stream-wise vortex, the initial magnitude and decay of the peak streamwise vorticity were significantly under predicted. A comparison of the positive circulation associated with the streamwise vortex showed that while the numerical simulations produced a more diffused vortex, the vortex strength compared very well to the experimental observations. A grid resolution study for the vortex generating vane was also performed showing that the diffusion of the vortex was not a result of insufficient grid resolution. Comparisons were also made between a fully modeled trapezoidal vane with finite thickness to a simply modeled rectangular thin vane. The comparisons showed that the simply modeled rectangular vane produced a streamwise vortex which had a strength and trajectory very similar to the fully modeled trapezoidal vane.

Allan, Brian G.↗

Diffusion length measurements using the scanning electron microscope

A measurement technique employing the scanning electron microscope is described in which values of the true bulk diffusion length are obtained. It is shown that surface recombination effects can be eliminated through the application of highly doped surface field layers. The influence of high injection level effects and low-high junction current generation on the resulting measurement was investigated. Close agreement is found between the diffusion lengths measured by this method and those obtained using a penetrating radiation technique.

Weizer, V. G.↗

Measuring Diffusion and Recombination in Polycrystalline Silicon

Light-beam-induced currents yield information about solar cell material. Apparatus measures short-circuit current generated when spot of concentrated light is scanned across grains and grain boundaries in material under test. Technique used to evaluate SOC samples for diffusion and recombination effects of cell processing and chemical and structural defects.

Zook, J. D.↗