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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Multi-Mission Power Analysis Tool

Multi-Mission Power Analysis Tool (MMPAT) Version 2 simulates spacecraft power generation, use, and storage in order to support spacecraft design, mission planning, and spacecraft operations. It can simulate all major aspects of a spacecraft power subsystem. It is parametrically driven to reduce or eliminate the need for a programmer. A user-friendly GUI (graphical user interface) makes it easy to use. Multiple deployments allow use on the desktop, in batch mode, or as a callable library. It includes detailed models of solar arrays, radioisotope thermoelectric generators, nickel-hydrogen and lithium-ion batteries, and various load types. There is built-in flexibility through user-designed state models and table-driven parameters.

Broderick, Daniel↗

Investigation into the High Voltage Shutdown of the Oxygen Generator System in the International Space Station

The Oxygen Generation System (OGS) Hydrogen Dome Assembly Orbital Replacement Unit (ORU) serial number 00001 suffered a cell stack high-voltage shutdown on July 5, 2010. The Hydrogen Dome Assembly ORU was removed and replaced with the on-board spare ORU serial number 00002 to maintain OGS operation. The Hydrogen Dome Assembly ORU was returned from ISS on STS-133/ULF-5 in March 2011 with test, teardown and evaluation (TT&E) and failure analysis to follow.

Carpenter, Joyce E.↗

Production of Negative Hydrogen Ions Within the MMS Fast Plasma Investigation Due to Solar Wind Bombardment

The particle data delivered by the Fast Plasma Investigation instrument aboard National Aeronautics and Space Administration's Magnetospheric Multiscale (MMS) mission allow for exceptionally high-resolution examination of the electron and ion phase space in the near-Earth plasma environment. It is necessary to identify populations which originate from instrumental effects. Using Fast Plasma Investigation's Dual Electron Spectrometers, we isolate a high-energy (approximately kiloelectron volt) beam, present while the spacecraft are in the solar wind, which exhibits an azimuthal drift with period associated with the spacecraft spin. We show that this population is consistent with negative hydrogen ions H− generated by a double charge exchange interaction between the incident solar wind H+ ions and the metallic surfaces within the instrument. This interaction is likely to occur at the deflector plates close to the instrument aperture. The H− density is shown to be approximately 0.2-0.4% of the solar wind ion density, and the energy of the negative ion population is shown to be 70% of the incident solar wind energy. These negative ions may introduce errors in electron velocity moments on the order of 0.2-0.4% of the solar wind velocity and significantly higher errors in the electron temperature.

Magnetospheric Multiscale↗

Triple redundant hydrogen sensor with in situ calibration

To meet sensing and calibration needs, an in situ calibration technique was developed. It is based on electrolytic generation of a hydrogen/air atmosphere within a hydrogen sensor. The hydrogen is generated from water vapor in the air, and being electrical in nature, the in situ calibration can be performed completely automatically in remote locations. Triply redundant sensor elements are integrated within a single, compact housing, and digital logic provides inter-sensor comparisons to warn of and identify malfunctioning sensor elements. An evaluation of this concept is presented.

Lantz, J. B.↗

NASA NR hydrogen maser

The Johns Hopkins University, Applied Physics Laboratory, under contract to NASA/Goddard Space Flight Center, is engineering a new generation of field operable hydrogen masers (NR) based on prior NASA NP and NX designs. These units incorporate improvements in magnetic shielding, lower noise electronics, better thermal control and have a microprocessor for operation, monitoring and diagnostic functions. They are ruggedly built for transportability and ease of service anywhere in the world.

Rueger, L. J.↗

Power generation in fuel cells using liquid methanol and hydrogen peroxide

The invention is directed to an encapsulated fuel cell including a methanol source that feeds liquid methanol (CH.sub.3 OH) to an anode. The anode is electrical communication with a load that provides electrical power. The fuel cell also includes a hydrogen peroxide source that feeds liquid hydrogen peroxide (H.sub.2 O.sub.2) to the cathode. The cathode is also in communication with the electrical load. The anode and cathode are in contact with and separated by a proton-conducting polymer electrolyte membrane.

Narayanan, Sekharipuram R.↗

Hydrogen - Primary or supplementary fuel for automotive engines

Hydrogen, gasoline, and mixtures thereof were compared as fuels for lean-burn engines. Hydrogen for the mixed fuels tests was generated by partial oxidation of gasoline. Hydrogen combustion yielded the highest thermal efficiency at any NOx level. Gasoline yielded the second highest thermal efficiency for NOx levels greater than or approximately equal to 2 gm/mi. For lower NOx levels and high vehicle inertia weights, progressively more hydrogen supplementation was the second most efficient system. For vehicle inertia weights below 5000 lbm (2300 kg), the statutory NOx standard (0.4 gm/mi) could be met with 1 lb/hr (0.13 g/s) hydrogen supplementation.

Finegold, J. G.↗

Booster propulsion/vehicle impact study, 2

This is the final report in a study examining the impact of launch vehicles for various boost propulsion design options. These options included: differing boost phase engines using different combinations of fuels and coolants to include RP-1, methane, propane (subcooled and normal boiling point), and hydrogen; variable and high mixture ratio hydrogen engines; translating nozzles on boost phase engines; and cross feeding propellants from the booster to second stage. Vehicles examined included a fully reusable two stage cargo vehicle and a single stage to orbit vehicle. The use of subcooled propane as a fuel generated vehicles with the lowest total vehicle dry mass. Engines with hydrogen cooling generated only slight mass reductions from the reference, all-hydrogen vehicle. Cross feeding propellants generated the most significant mass reductions from the reference two stage vehicle. The use of high mixture ratio or variable mixture ratio hydrogen engines in the boost phase of flight resulted in vehicles with total dry mass 20 percent greater than the reference hydrogen vehicle. Translating nozzles for boost phase engines generated a heavier vehicle. Also examined were the design impacts on the vehicle and ground support subsystems when subcooled propane is used as a fuel. The most significant cost difference between facilities to handle normal boiling point versus subcooled propane is 5 million dollars. Vehicle cost differences were negligible. A significant technical challenge exists for properly conditioning the vehicle propellant on the ground and in flight when subcooled propane is used as fuel.

Johnson, P.↗

Electrical conductivity of condensed molecular hydrogen in the giant planets

Theoretical interpretation of several phenomena concerning Jupiter and Saturn depends upon the electrical conductivity of molecular hydrogen which, according to present models, forms the outermost layer of both planets. The layer starts at the transition pressure between the metallic and the molecular form of hydrogen, that is around 1 Mbar, and extends to the outside limits of the atmosphere. Whether at the highest pressures (and temperatures) this layer is a solid or a dense fluid is not certain. In any case, the fluid is in supercritical condition so that there is only a gradual transition from dense liquid to a gaseous form. The two theories which require specific values of the conductivity of the condensed molecular hydrogen are those pertaining to the generation of a magnetic field in the liquid hydrogen rather than in the deep metallic interior (HIDE, 1967), and those concerned with the electromagnetic coupling and exchange of angular momentum between the liquid core and the solid molecular hydrogen mantle.

Smoluchowski, R.↗

Infrared-pumped third-harmonic and sum-frequency generation in diatomic molecules

Using molecular hydrogen as a model system, we present a calculation which demonstrates the feasibility of efficient third-harmonic and sum-frequency generation of IR laser radiation by diatomic molecular gases. A conversion efficiency of 10% without phase matching is achievable with a modest laser intensity of about 20 MW/sq cm. In addition to a two-photon resonance, the efficient conversion depends on a mechanism which makes use of virtual vibronic transitions exclusively. Possible methods for phase matching are also suggested.

She, C. Y.↗

Oxygen Production from Lunar Regolith using Ionic Liquids

The objective of this work and future follow-on work is to develop a safe, efficient, and recyclable method for oxygen and/or metals extraction from lunar regolith, in support of establishing a manned lunar outpost. The approach is to solubilize the oxides that comprise lunar regolith in media consisting of ionic liquids (ILs) and/or their mixtures at temperatures at or below 300 C. Once in solution, electrolysis can either be performed in-situ to generate oxygen at the anode and hydrogen and/or metals (silicon, iron, aluminum, titanium, etc.) at the cathode. Alternatively, the water that is generated during the solubilization process can be distilled out and condensed into a separate IL and then electrolysized to produce hydrogen and oxygen. In the case of lunar regolith, this method could theoretically produce 44g oxygen per 100g of regolith. The oxygen can be used for human life support and/or as an oxidizer for rocket fuels, and the metals can be used as raw materials for construction and/or device fabrication. Moreover, the hydrogen produced can be used to re-generate the acidic medium, which can then be used to process additional regolith, thereby making the materials recyclable and limiting upmass requirements. An important advantage of IL acid systems is that they are much "greener" and safer than conventional materials used for regolith processing such as sulfuric or hydrochloric acids. They have very low vapor pressures, which means that they contain virtually no toxic and/or flammable volatile content, they are relatively non-corrosive, and they can exhibit good stability in harsh environments (extreme temperatures, hard vacuum, etc.). Furthermore, regolith processing can be achieved at lower temperatures than other processes such as molten oxide electrolysis or hydrogen reduction, thereby reducing initial power requirements. Six ILs have been synthesized and tested for their capability to dissolve lunar simulant, and for electrochemical and thermal stability. The results showed that ILs can be very efficient electrolytes; in particular IL/phosphoric-acid mixtures appear extremely promising for solubilizing lunar simulant. Results from preliminary experiments for distillation of water produced from the oxygen within the metal oxides of the simulant and the hydrogen from the acid indicates that over 75% of the oxygen from the simulant can be harvested as water at a temperature of 150 C. A method for collection of oxygen from electrolysis of the water derived from solubilizing simulant was developed by using a liquid nitrogen trap to liquefy and collect the oxygen. Although precise quantification of the liquid oxygen trapped is difficult to obtain, the amount of hydrogen and oxygen collected from electrolysis of water in this system was greater than 98%. This set-up also included a portable mass spectrometer for the identification of gases released from electrolysis cells. Regeneration of ILs through re-protonation was also demonstrated. Four sequential re-generations of an IL following solubilization of simulant showed no significant differences in amounts of simulant dissolved. Follow-on work for this project should include more studies of IL/phosphoric acid systems. Also, much more work is necessary for defining methods for electrolysis and purification of metals from regolith solubilized in ILs, and for developing a system to use the produced hydrogen to regenerate the spent IL. Finally, design and development of flight breadboard and prototype hardware is required.

Paley, Mark Steven↗

H2-O2 auxiliary power unit for Space Shuttle vehicles - A progress report.

Description of a program to establish technology readiness of hydrogen-oxygen (H2-O2) auxiliary power units for use on board the Space Shuttle orbiter vehicle. Fundamental objectives include experimentally establishing an acceptable propellant flow control method, verification of combustor stability, and adequate thermal management. An initial auxiliary power unit (APU) configuration with recycled hydrogen flow has been studied and revised toward greater simplicity and scaling ease. The selected APU is a recuperated open-cycle, turbine-driven unit. Series flow of cryogenic hydrogen removes internally-generated heat and heat from the hydraulic system. The revised configuration schematic and its calculated performance are reviewed. A weight comparison is made between the shuttle baseline hydrazine and H2-O2 APU systems, showing that hydrogen-oxygen APUs have the potential of increasing the payload of the Space Shuttle.

Joyce, J. P.↗

Hydrogen emission-line spectra in quasars and active galactic nuclei

An attempt is made to account for the observational fact that the intensity ratios of the lower Balmer lines seen in emission from QSOs, type 1 Seyfert galaxies, and other related active galaxies are not what would be expected from the conventional picture of lines generated in a recombining hydrogen plasma. Previous observations of emission-line intensities in QSOs and Seyfert galaxies are reviewed. The various processes included in the rate coefficients of the calculations are then described, viz., free-free, bound-free, and bound-bound transitions, radiative transfer, and angular-momentum mixing. The strengths of the various emission lines are calculated by using more accurate values for the transition rates, including excitation and deexcitation simultaneously, and providing for finite rates in optically forbidden transitions. Numerical results are presented for the cases of ground-state collisional excitation, reabsorption of the upper Balmer lines, and collisional deexcitation. The results are applied to construct a model for the emission-line gas in a QSO and to discuss limits on models of Seyfert galaxies.

Krolik, J. H.↗

Process Research of Polycrystalline Silicon Material (PROPSM)

An investigation was begun into the usefulness of molecular hydrogen annealing on polycrystalline solar cells. No improvement was realized even after twenty hours of hydrogenation. Thus, samples were chosen on the basis of: (1) low open circuit voltage; (2) low shunt conductance; and (3) high light generated current. These cells were hydrogenated in molecular hydrogen at 300 C. The differences between the before and after hydrogenation values are so slight as to be negligible. These cells have light generated current densities that indicate long minority carrier diffusion lengths. The open circuit voltage appears to be degraded, and quasi-neutral recombination current enhanced. Therefore, molecular hydrogen is not usful for passivating electrically active defects.

Culik, J. S.↗

Survey of low-frequency electromagnetic waves stimulated by two coexisting newborn ion species

Parallel electromagnetic instabilities generated by coexisting newborn hydrogen and oxygen ions are studied for different orientations of the interplanetary magnetic field with respect to the solar wind velocity. The wave growth dependence on the densities and temperatures of the newborn species is investigated. The results indicate that in most domains of the Brillouin plane each ion beam can excite resonant instabilities without undue influence from the other newborn ion species. Although comparable resonant instabilities are more efficiently generated by the lighter newborn ions in ion-rich environments, the growth stimulated by the heavier species can withstand large beam density decreases.

Brinca, Armando L.↗

Influence of Oxygenated Compounds on Reaction Products in a Microwave Plasma Methane Pyrolysis Assembly for Post-Processing of Sabatier Methane

The state-of-the-art Carbon Dioxide Reduction Assembly (CRA) was delivered to the International Space Station (ISS) in April 2010. The system is designed to accept carbon dioxide from the Carbon Dioxide Removal Assembly and hydrogen from the Oxygen Generation Assembly. The two gases are reacted in the CRA in a Sabatier reactor to produce water and methane. Venting of methane results in an oxygen resupply requirement of about 378 lbs per crew member per year. If the oxygen is supplied as water, the total weight for resupply is about 476 lb per crew member per year. For long-term missions beyond low Earth orbit, during which resupply capabilities will be further limited, recovery of hydrogen from methane is highly desirable. For this purpose, NASA is pursuing development of a Plasma Pyrolysis Assembly (PPA) capable of recovering hydrogen from methane. Under certain conditions, water vapor and carbon dioxide (nominally intended to be separated from the CRA outlet stream) may be present in the PPA feed stream. Thus, testing was conducted in 2010 to determine the effect of these "oxygenated" compounds on PPA performance, particularly the effect of inlet carbon dioxide and water variations on the PPA product stream. This paper discusses the test set-up, analysis, and results of this testing

Mansell, J. Matthew↗

Influence of Oxygenated Compounds on Reaction Products in a Microwave Plasma Methane Pyrolysis Assembly for Post-Processing of Sabatier Methane

The state-of-the-art Carbon Dioxide Reduction Assembly (CRA) was delivered to the International Space Station (ISS) in April 2010. The system is designed to accept carbon dioxide from the Carbon Dioxide Removal Assembly and hydrogen from the Oxygen Generation Assembly. The two gases are reacted in the CRA in a Sabatier reactor to produce water and methane. Venting of methane results in an oxygen resupply requirement of about 378 lbs per crew member per year. If the oxygen is supplied as water, the total weight for resupply is about 476 lb per crew member per year. For long-term missions beyond low Earth orbit, during which resupply capabilities will be further limited, recovery of hydrogen from methane is highly desirable. For this purpose, NASA is pursuing development of a Plasma Pyrolysis Assembly (PPA) capable of recovering hydrogen from methane. Under certain conditions, water vapor and carbon dioxide (nominally intended to be separated from the CRA outlet stream) may be present in the PPA feed stream. Thus, testing was conducted in 2010 to determine the effect of these oxygenated compounds on PPA performance, particularly the effect of inlet carbon dioxide and water variations on the PPA product stream. This paper discusses the test set-up, analysis, and results of this testing.

Mansell, J. Matthew↗