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NASA NTRSDate not supplied

Compositional Analysis of Titan’s Atmosphere Using Spitzer Infrared Spectrograph Data

We present, for the first time, infrared spectra from the Spitzer Space Telescope’s Infrared Spectrograph (IRS) (2004-2008) of Titan in both the short wavelength-low resolution(SL, R=60~127,5.13-14.29 μm) and short wavelength-high resolution channels (SH, R=600, 9.89-19.51 μm) showing the emissions of CH4, C2H4, C2H2, C2H6, HCN, CO2, HC3N, C3H4, C4H2, and C3H8. Spitzer IRS data has been used to measure atmospheric composition of various Solar System bodies, including Neptune [1] and Uranus [2],[3]. Although Spitzer took multiple dedicated observations of Titan, none of the results have been modeled before. We conduct our own investigation of these datasets and search for new results. We retrieve temperature and gas composition profiles and compare the results obtained for Titan to those of the Cassini Composite Infrared Spectrometer (CIRS) and the Infrared Space Observatory Short Wavelength Spectrometer [4], and comment on the effect of spectral resolution on retrieved information content. We conclude by recommending gaps in current spectroscopic knowledge of molecular bands that could be addressed by theoretical and laboratory study to aid future astronomical studies of Titan, for example the James Webb Space Telescope (JWST) and the Stratospheric Observatory for Infrared Astronomy (SOFIA) Acknowledgments: Data analyzed in this project is public available online on the Spitzer Heritage Archive (sha.ipac.caltech.edu). This research has made use of the NASA/IPAC Infrared Science Archive, which is funded by the National Aeronautics and Space Administration and operated by the California Institute of Technology.

Titan↗
NASA NTRS1984

A Far Infrared Echelle Spectrometer for the Kuiper Airborne Observatory

A liquid-helium-cooled grating spectrometer (CGS) is being developed as a facility instrument for the Kuiper Airborne Observatory (KAO), primarily to study for infrared lines originating in the interstellar medium. A maximum resolving power of approximately 6000 is achieved by means of a 45 cm long Echelle grating and is optically capable of operating in the spectral range from 25 to 300 microns. An array of detectors is used to simultaneously measure a line and the adjacent continuum from astronomical sources. Currently six detectors allow measurements in the 30 to 120 micron spectral band. The instrument, its operation, and its performance are described.

Erickson, E. F.↗
NASA NTRS2004

Comparative NIR Detector Characterization for NGST

List of publications for final perfomance report are: Detectors for the JWST Near-Infrared Spectrometer Rauscher, B.J., Strada, P., Regan, M.W., Figer, D.F., Jakobsen, P., Moseley, H.S., & Boeker, T. 2004, SPIE Detectors for the JWST Near-Infrared Spectrometer Rauscher, B.J., Strada, P., Regan, M.W., Figer, D.F., Jakobsen, P., Moseley, H.S., & Boeker, T. 2004, AAS, 203, 124.07 Independent Testing of JWST Detector Prototypes Figer, D.F., Rauscher, B. J., Regan, M. W., Morse, E., Balleza, J., Bergeron, L., & Stockman, H. S. 2003 , SPIE, 5 167 The Independent Detector Testing Laboratory and the NGST Detector Program Figer, D.F., Agronin, M., Balleza, J., Barkhouser, R., Bergeron, L., Greene, G. R., McCandliss, S. R., Rauscher, B. J., Reeves, T., Regan, M. W., Sharma, U., Stockman, H. S. 2003, SPIE, 4850,981 Intra-Pixel Sensitivity in NIR Detectors for NGST Sharma, U., Figer, D.F., Sivaramakrishnan, A., Agronin, M., Balleza, J., Barkhouser, R., Bergeron, L., Greene, G. R., McCandliss, S. R., Rauscher, B. J., Reeves, T., Regan, M. W., Stockman, H. S. 2003, SPIE, 4850,1001 NIRCAM Image Simulations for NGST Wavefiont SensinglPS A. Sivaramakrishnan, D. Figer, H. Bushouse, H. S. Stockman (STScI),C. Ohara , D. Redding (JPL), M. Im (IPAC), & J. Offenberg (Raytheon) 2003, SPIE, 4850,388 Ultra-Low Background Operation of Near-Infrared Detectors for NGS Rauscher, B. J., Figer, D. F., Agronin, M., Balleza, J., Barkhouser, R., Bergeron, L., Greene, G. R., McCandliss, S. R., Reeves, T., Regan, M. W., Sharma, U., Stockman, H. S. 2003, SPIE, 4850,962 The Independent Detector Testing Laboratory and the JWST Detector Program Figer, D.F. et a1.2003, AAS201, #131.05

Greenhouse, Matthew↗
NASA NTRS1986

A faint object spectrometer for the infrared

A cryogenic astronomical spectrometer for the NASA Infrared Telescope Facility is described. This spectrometer will employ an array of at least 20 detectors and provide a resolving power of 100 to 1500 at 1-5 microns. The resolving power will be adjustable by changing gratings.

Tokunaga, A. T.↗
NASA NTRS2006

Cassini Thermal Observations of Saturn's Main Rings: Implications for Particle Rotation and Vertical Mixing

In late 2004 and 2005 the Cassini composite infrared spectrometer (CIRS) obtained spatially resolved thermal infrared radial scans of Saturn's main rings (A, B and C, and Cassini Division) that show ring temperatures decreasing with increasing solar phase angle, (alpha), on both the lit and unlit faces of the ring plane. These temperature differences suggest that Saturn's main rings include a population of ring particles that spin slowly, with a spin period greater than 3.6 h, given their low thermal inertia. The A ring shows the smallest temperature variation with (alpha), and this variation decreases with distance from the planet. This suggests an increasing number of smaller, and/or more rapidly rotating ring particles with more uniform temperatures, resulting perhaps from stirring by the density waves in the outer A ring and/or self-gravity wakes. The temperatures of the A and B rings are correlated with their optical depth, (tau), when viewed from the lit face, and anti-correlated when viewed from the unlit face. On the unlit face of the B ring, not only do the lowest temperatures correlate with the largest (tau), these temperatures are also the same at both low and high a, suggesting that little sunlight is penetrating these regions. The temperature differential from the lit to the unlit side of the rings is a strong, nearly linear, function of optical depth. This is consistent with the expectation that little sunlight penetrates to the dark side of the densest rings, but also suggests that little vertical mixing of ring particles is taking place in the A and B rings.

Cassini composite infrared spectrometer (CIRS)↗
NASA NTRSDate not supplied

Integrated laboratory, modeling and observational investigations of the condensation of benzene on Titan's stratospheric aerosols

Aerosols in Titan’s atmosphere play an important role in determining its thermal structure and can act as condensation nuclei for the formation of clouds. The global circulation of Titan’s atmosphere reversed within the two years following the northern spring equinox in August 2009, increasing the mixing ratios of benzene (C6H6) and other species at the South pole. A simultaneous strong cooling above the south pole (dropping temperatures below 120 K) resulted in conditions where molecules could condense at unusually high altitudes (>250 km). C6H6 and HCN ices have been detected by the Composite Infrared Spectrometer (CIRS) and the Visible and Infrared Mapping Spectrometer (VIMS), respectively, in the South polar cloud system, but the existing laboratory data is insufficient to allow models to reproduce the formation of the observed cloud system. We will present the preliminary results and the overall scope of a newly funded NASA SMD Cassini Data Analysis Program (CDAP) project which proposes to combine laboratory, modeling and observational studies to investigate the condensation of benzene on Titan’s aerosol as an important component of the cloud system that appeared during the autumn at 300 km above Titan’s South pole.

E. Sciamma-O’Brien↗
NASA NTRS1990

Fiber-coupled high resolution infrared array spectrometer for the Kuiper Airborne Observatory

A novel cryogenic grating spectrometer (FCAS) is being designed for observations of volatiles in cometary and planetary atmospheres, and in newly forming planetary systems. The instrument features two-dimensional detector arrays coupled to a high-dispersion echelle by infrared fibers, and will achieve a spectral resolving power of about 40,000. The primary observational platform for this instrument will be the Kuiper Airborne Observatory, but it will also be configured for use at ground-based observatories. Initially, the spectrometer will use a 58 x 62, 1- to 5-micron InSb array. Larger-format IR arrays and arrays of different composition, will later be incorporated as they become available. The instrument will be used in two modes. The first uses a large format IR array in the spectral image plane for the customary one-dimensional spectral-one-dimensional spatial coverage. In the second mode, a massive, coherent bundle of infrared transmitting ZrF4 fibers will be installed after the dispersive element, to reformat the two-dimensional array into an elongated one-dimensional array for wide spectral coverage, allowing multiple lines to be measured in a single integration with high sensitivity. The overall instrument design is discussed, and the system sensitivity is estimated.

Glenar, D. A.↗
NASA NTRS1993

Stratospheric OH measurements with a far-infrared limb observing spectrometer

The Far-Infrared Limb Observing Spectrometer (FILOS) is an instrument designed to measure the hydroxyl radical (OH) and other chemical species in the upper atmosphere using limb emission in the far-infrared region of the spectrum. FILOS uses three Fabry-Perot etalons in series to obtain high spectral resolution near 101/cm and 118/cm. The instrument concept, calibration, and atmospheric measurements are discussed.

Pickett, H. M.↗
NASA NTRS1991

InSb linear multiplexed FPAs for the CRAF/Cassini visible and infrared mapping spectrometer

This paper provides a review of a custom multiplexer circuit designed for use with a 256 element InSb linear array in the CRAF/Cassini VIMS instruments. The requirements, operation noise model and test results from a prototype 1 x 64 array are discussed. The infrared focal plane array (FPA) preliminary design and the impact of the new multiplexer on the instruments' predicted performance will be discussed. Emphasis will be placed on the multiplexer that was designed for the CRAF/Cassini missions. The FPA assembly combines electronic and optical components into a single hermetically sealed hybrid package. The detector configuration is that of a linear dual-multiplexed indium antimonide array with 256 elements, each 103 x 200 on 123-micron centers.

Niblack, Curtiss↗
NASA NTRS2012

Portable Fourier Transform Spectroscopy for Analysis of Surface Contamination and Quality Control

Progress has been made into adapting and enhancing a commercially available infrared spectrometer for the development of a handheld device for in-field measurements of the chemical composition of various samples of materials. The intent is to duplicate the functionality of a benchtop Fourier transform infrared spectrometer (FTIR) within the compactness of a handheld instrument with significantly improved spectral responsivity. Existing commercial technology, like the deuterated L-alanine triglycine sulfide detectors (DLATGS), is capable of sensitive in-field chemical analysis. This proposed approach compares several subsystem elements of the FTIR inside of the commercial, non-benchtop system to the commercial benchtop systems. These subsystem elements are the detector, the preamplifier and associated electronics of the detector, the interferometer, associated readout parameters, and cooling. This effort will examine these different detector subsystem elements to look for limitations in each. These limitations will be explored collaboratively with the commercial provider, and will be prioritized to meet the deliverable objectives. The tool design will be that of a handheld gun containing the IR filament source and associated optics. It will operate in a point-and-shoot manner, pointing the source and optics at the sample under test and capturing the reflected response of the material in the same handheld gun. Data will be captured via the gun and ported to a laptop.

Pugel, Diane↗
NASA NTRS1993

Planetary Instrument Definition and Development Program (PIDDP). Instrument for future planetary flight missions: A visible-infrared imaging spectrometer for planetary missions

The objective of this project is to develop and prove a small, light-weight, efficient imaging spectrometer design to cover the VIS/NIR spectral range for applications particularly but not exclusively to NASA inner solar system space missions. A design and a brassboard prototype will be developed and tested. Progress over the first year of this project includes design specification, optical design layout, grating specifications, infrared detector selection, and mechanical design. Mechanical and grating manufacturing drawings were begun. We developed an agreement in principle to cooperate with the German space group, DLR, to apply some of their electronics microminiaturization technology to this imaging spectrometer project, mostly or entirely at their expense. Funds from NASA for the second year of this effort have been received and the effort is on track. Release of funds for the third year of this award will be requested later this year in order to accelerate this work and bring it to a conclusion in time for new NASA missions considerations as well as to make effective use of the DLR contributions.

Mccord, Thomas B.↗
NASA NTRS1992

Vertical resolution and accuracy of atmospheric infrared sounding spectrometers

A theoretical analysis is performed to evaluate the accuracy and vertical resolution of atmospheric profiles obtained with the HIRS/2, GOES I/M, and HIS instruments. In addition, a linear simultaneous retrieval algorithm is used with aircraft observations to validate the theoretical predictions. Both theoretical and observational results clearly indicate that the accuracy and vertical resolution of the retrieval profile would be improved by high spectral resolution and broad spectral coverage of infrared radiance measurements. The HIS is found to possess the equivalent of 11 pieces of temperature- and 9 pieces of water vapor-independent precise measurements. The characteristics for temperature include a vertical resolution of 1-6 km with an accuracy of 1 K and for water vapor a vertical resolution of 0.5-3.0 km with an accuracy of 3 K in dewpoint temperature. The HIS is a factor of 2-3 times better in vertical resolution and a factor of 2 times better in accuracy than the GOES I/M and HIRS/2 filter radiometers.

Huang, Hung-Lung↗
NASA NTRS1993

NASA airborne satellite instrumentation calibrator (NASIC) technical reference

The NASA Satellite Instrumentation Calibrator (NASIC) is a visible and near-infrared spectrometer used to calibrate various satellite instruments by underflying those instruments in a NASA ER-2 aircraft. The calibration instrument's hardware and software are documented. The design, operation, and function of an Ebert-Fastie monochronomator, which by means of a moveable diffraction grating, becomes a visible and near-infrared spectrometer used to calibrate satellite-borne instruments by high altitude underflights in the NASA ER-2.

Ward, John L.↗
NASA NTRS2015

RESOLVE (Regolith & Environmental Science Oxygen & Lunar Volatile Extraction) Project

The RESOLVE Project is a lunar prospecting mission whose primary goal is to characterize water and other volatiles in lunar regolith. The Lunar Advanced Volatiles Analysis (LAVA) subsystem is comprised of a fluid subsystem that transports flow to the gas chromatograph - mass spectrometer (GC-MS) instruments that characterize volatiles and the Water Droplet Demonstration (WDD) that will capture and display water condensation in the gas stream. The LAVA Engineering Test Unit (ETU) is undergoing risk reduction testing this summer and fall within a vacuum chamber to understand and characterize component and integrated system performance. Testing of line heaters, printed circuit heaters, pressure transducers, temperature sensors, regulators, and valves in atmospheric and vacuum environments was done. Test procedures were developed to guide experimental tests and test reports to analyze and draw conclusions from the data. In addition, knowledge and experience was gained with preparing a vacuum chamber with fluid and electrical connections. Further testing will include integrated testing of the fluid subsystem with the gas supply system, near-infrared spectrometer for the Surge Tank (NIRST), WDD, Sample Delivery System, and GC-MS in the vacuum chamber. Since LAVA is a scientific subsystem, the near infrared spectrometer and GC-MS instruments will be tested during the ETU testing phase.

LAVA↗
NASA NTRS2013

RESOLVE Project

The RESOLVE project is a lunar prospecting mission whose primary goal is to characterize water and other volatiles in lunar regolith. The Lunar Advanced Volatiles Analysis (LAVA) subsystem is comprised of a fluid subsystem that transports flow to the gas chromatograph - mass spectrometer (GC-MS) instruments that characterize volatiles and the Water Droplet Demonstration (WDD) that will capture and display water condensation in the gas stream. The LAVA Engineering Test Unit (ETU) is undergoing risk reduction testing this summer and fall within a vacuum chamber to understand and characterize component and integrated system performance. Testing of line heaters, printed circuit heaters, pressure transducers, temperature sensors, regulators, and valves in atmospheric and vacuum environments was done. Test procedures were developed to guide experimental tests and test reports to analyze and draw conclusions from the data. In addition, knowledge and experience was gained with preparing a vacuum chamber with fluid and electrical connections. Further testing will include integrated testing of the fluid subsystem with the gas supply system, near-infrared spectrometer, WDD, Sample Delivery System, and GC-MS in the vacuum chamber. This testing will provide hands-on exposure to a flight forward spaceflight subsystem, the processes associated with testing equipment in a vacuum chamber, and experience working in a laboratory setting. Examples of specific analysis conducted include: pneumatic analysis to calculate the WDD's efficiency at extracting water vapor from the gas stream to form condensation; thermal analysis of the conduction and radiation along a line connecting two thermal masses; and proportional-integral-derivative (PID) heater control analysis. Since LAVA is a scientific subsystem, the near-infrared spectrometer and GC-MS instruments will be tested during the ETU testing phase.

Parker, Ray↗