Chemical, mineralogical and textural systematics of non-mare melt rocks Implications for lunar impact and volcanic processes
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A method of creating simulated agglutinate particles by applying a heat source sufficient to partially melt a raw material is provided. The raw material is preferably any lunar soil simulant, crushed mineral, mixture of crushed minerals, or similar material, and the heat source creates localized heating of the raw material.
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NASA has built a prototype oxygen production plant to process the lunar regolith using the hydrogen reduction chemical process. This plant is known as "ROxygen - making oxygen from moon rocks". The ROxygen regolith transfer team has identified the flow and transfer characteristics of lunar regolith simulant to be a concern for lunar oxygen production efforts. It is important to ISRU lunar exploration efforts to develop hardware designs that can demonstrate the ability to flow and transfer a given mass of regolith simulant to a desired vertical height under lunar gravity conditions in order to introduce it into a reactor. We will present results obtained under both 1/6-g and 1-g gravity conditions for a system that can pneumatically convey 16.5 kg of lunar regolith simulant (NU-LHT-2M, Mauna Kea Tephra, and JSC-1A) from a flat-bottom supply hopper to a simulated ISRU reactor (dual-chambered receiving hopper) where the granular material is separated from the convey gas (air) using a series of cyclone separators, one of which is an electrically enhanced cyclone separator (electrocyclone). The results of our study include (1) the mass flow rate as a function of input air pressure for lunar regolith simulants that are conveyed pneumatically as a dusty gas in a vertical direction against gravity under lunar gravity conditions (for NU-LHT-2M and Mauna Kea Tephra), and under earth gravity conditions (for NU-LHT-2M, Mauna Kea Tephra and JSC-1A), and (2) the efficiency of the cyclone/electrocyclone filtration system in separating the convey gas (air) from the granular particulates as a function of particle size.
Several experiments were performed in order to evaluate the effect of carbon on phosphate reduction in synthetic systems. It was attempted to simulate in the experiments conditions occurring during lunar impact processes, but without shock pressure. Temperature, oxygen fugacity, and bulk chemistry were evaluated separately in order to determine the conditions which are suitable for carbon reduction. It appears on the basis of the results of the reported investigation that carbon can be an effective reducing agent during reheating events such as those encountered by lunar soils and breccias. Phosphate reduction may be viewed as a two-step process in which carbon is mobilized as CO during heating and preferentially dissolved in the metal phase. It then acts as a reducing agent on cooling. Gas phase transport and diffusion of carbon in metal are sufficiently rapid to allow uniform carbon distribution both within and between metal grains. The availability of metal from meteorites and carbon from the solar wind is probably sufficient to make reduction by carbon a significant process on the lunar surface.
Experiments were conducted to determine the nature of the alteration process in lunar rocks. Mixtures of 10 wt.% Fe + 10 wt.% FeCl2 + 80 wt.% basalt (terrestrial) were pelletized and allowed to set for 48 hrs at 25 C, at 40% and at 100% relative humidity. The end products were examined by reflected-light microscopy and by X-ray diffraction. The degree of reaction appears to depend upon the amount of FeCl2, the availability of water and the Ni content of the metallic Fe. The experiments showed the extremely rapid rate at which the oxyhydration can occur in air and that the product is beta-FeOOH. The data from the FeOOH mineral in rock 66095 were compared with those obtained from synthetic beta-FeOOH and found to be identical. The 'rust' in the Apollo 16 rocks could result from oxyhydration of the samples, caused by water vapor contamination, all or part of which occurred in the Apollo spacecraft and/or upon return to earth. The akageneite (beta-FeOOH) in lunar rocks could be entirely of terrestrial origin as originally suggested by Taylor et al. (1973).
The in-space operations required to process the lunar and Mars mission vehicles foreseen in early studies for the SEI are discussed. Those studies that have examined the degree to which on-orbit operations alter as a function of the earth-to-orbit launch vehicle size, identified a common set of on-orbit vehicle processing tasks, and generated functional requirements for in-space processing nodes, are summarized. Attention is focused on the amount of time these processing operations might necessitate and how this time duration changes as a result of how the operation is executed and how the hardware is designed.
The purpose of this project was to design a method of producing a fabric material on the lunar surface from readily available glass fibers. Various methods for forming fabrics were analyzed to determine which methods were appropriate for the lunar conditions. A nonwoven process was determined to be the most suitable process for making a fabric material out of fiberglass under these conditions. Various resins were considered for adhering the fibers. A single thermoplastic resin (AURUM) was found to be the only applicable resin. The end product of the process was determined to be suitable for use as a roadway surfacing material, canopy materials, reflective material, or packaging material. A cost analysis of the lunar process versus shipping the end-product from the earth suggests that the lunar formation is highly feasible. A design for a lunar, nonwoven process was determined and included in the following document.
The purpose of this project was to design a method of producing a fabric material on the lunar surface from readily available glass fibers. Various methods for forming fabrics were analyzed to determine which methods were appropriate for the lunar conditions. A nonwoven process was determined to be the most suitable process for making a fabric material out of fiberglass under these conditions. Various resins were considered for adhering the fibers. A single thermoplastic resin (AURUM) was found to be the only applicable resin. The end product of the process was determined to be suitable for use as a roadway surfacing material, canopy material, reflective material, or packaging material. A cost analysis of the lunar process versus shipping the end-product from the Earth suggests that the lunar formation is highly feasible. A design for a lunar, nonwoven process was determined and is included.
Underground excavation and construction techniques have been well developed terrestrially and provide an attractive option for lunar mining and habitat construction. The lunar mine, processing facilities and habitats could be located beneath the lunar surface in basaltic rock that would protect the crew and equipment from the hazardous surface environment. A terrestrial-like atmosphere would be created within the underground structures allowing more conventional technologies to be utilized. In addition, the basalt would likely contain higher quality mineral deposits than the regolith (lunar soil) since the minerals in the regolith have been degraded by meteorite bombardment. The conditions that would affect the design of an underground lunar mine are described and a lunar rock mass rated to assess its quality using terrestrial rock mass classification systems. Design criteria are established and a construction scenario proposed. Parameters having the greatest effect on stability are identified based on distinct element computer modeling and terrestrial experience.
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The nature of the impact process has been inferred through the study of the geology of a wide variety of impact crater types and sizes. Some of the largest craters known are the multiring basins found in ancient terrains of the terrestrial planets. Of these features, those found on the Moon possess the most extensive and diverse data coverage, including morphological, geochemical, geophysical, and sample data. The study of the geology of lunar basins over the past 10 years has given us a rudimentary understanding of how these large structures have formed and evolved. The topics covered include basin morphology, basin ejecta, basin excavation, and basin ring formation.
This paper describes how the Orion program is incorporating improvements in the heat shield design and manufacturing processes reducing programmatic risk and ensuring crew safety in support of NASA’s Exploration Missions. The Orion program successfully completed the EFT-1 flight test in 2014 and is currently developing the EM-1 spacecraft to meet the test objectives of an orbital mission to the moon and return to earth in 2019. Lessons learned from the EFT-1 manufacturing and flight test experience are being incorporated into a wide variety of vehicle systems and manufacturing processes to reduce risk to the Orion missions and flight crew. A critical contributor to crew safety is the heat shield that protects the crew capsule during re-entry through the earth’s atmosphere for return from deep space. The first flight test vehicle, EFT-1, was manufactured and tested in the Neil Armstrong Operations and Checkout (O&C) facility at KSC to demonstrate early risk reduction including the functionality of the Thermal Protection Systems (TPS) for capsule safe return to earth. The approach for the EFT-1 heat shield utilized a low risk approach using Apollo heritage design and manufacturing processes using an Avcoat TPS ablator with a honeycomb substrate to provide a one piece heat shield to meet the mission re-entry heating environments. The manufacturing processes used honeycomb cell injection guns which were redeveloped from the Apollo Lunar Program processes to build the EFT-1 heat shield. The completed heat shield was transported across the country by aircraft to the O&C at KSC for installation onto the capsule. The EFT-1 heat shield successfully performed its mission and experienced ~80% of the re-entry velocity (50% heating rate) for a lunar return for an Exploration Mission. The second flight test vehicle is the EM-1 mission which will have additional flight systems installed to fly to the moon and return. Heat shield design and producibility improvements have been incorporated in the EM-1 vehicle to meet deep space mission and programmatic requirements. The design continues to use the Avcoat material, but in a “block” configuration to enable improvements in the application processes as well as additional improvements in the carrier structure design and manufacturing operations. Incorporating flight test results and producibility improvements from EFT-1 for the heat shield system design and processes have improved the thermal protection capability, improved the producibility, and cost for EM-1 flight test.
In the last few years NASA has set new priorities for research and development of technologies necessary to enable long-term presence on the Moon and Mars. Among these key technologies is what is known as in situ resource utilization, which defines all conceivable usage of mineral, liquid, gaseous, or biological resources on a visited planet. In response to this challenge, we have been focusing on developing and demonstrating the manufacturing of a specific product using Lunar and Martian soil simulants (i.e., a mold for the casting of metal and alloy parts) which will be an indispensable tool for the survival of outposts on the Moon and Mars. In addition, our purpose is to demonstrate the feasibility of using mesoporous materials such as aerogels to serve as efficient casting molds for high quality components in propulsion and other aerospace applications. The first part of the project consists of producing aerogels from the in situ resources available in Martian and Lunar soil. The approach we are investigating is to use chemical processes to solubilize silicates using organic reagents at low temperatures and then use these as precursors in the formation of aerogels for the fabrication of metal casting molds. One set of experiments consists of dissolving silica sources in basic ethylene glycol solution to form silicon glycolates. When ground silica aerogel was used as source material, a clear solution of silicon glycolate was obtained and reacted to form a gel thus proving the feasibility of this approach. The application of this process to Lunar and Martian simulants did not result in the formation of a gel; further study is in progress. In the second method acidified alcohol is reacted with the simulants to form silicate esters. Preliminary results indicate the presence of silicon alkoxide in the product distillation. However, no gel has been obtained so further characterization is ongoing. In the second part of the project, the focus has been on developing a series of aerogel plates suitable for thin plate metal casting and ingot metal castings. The influence of aerogels on thin wall metal castings was studied by placing aerogel plates into the cavities of thin sections of resin bonded sand molds. An 1 based commercial alloy ( 356) containing 7 percent Si was poured into these molds. Post-solidification studies provide evidence that aerogel inserts significantly reduce the cooling rate during solidification. The advantage of a lower rate using aerogel inserts was reflected in the reduction of casting defects such as shrinkage porosity. Quantitative results support the hypothesis that using aerogels as a mold material can offer definite advantages when used as casting thin sections. As a separate effort, silica aerogel with cylindrical cavities have been prepared and will be evaluated for casting commercial alloys.
Accommodation of the new Human Exploration Initiative being developed by NASA requires Space Station Freedom to serve three major roles: first, as a facility for precursory technology development and life sciences research for both transportation systems and lunar/Mars outpost systems; second, as a transportation node capable of processing both lunar- and Mars-class transportation vehicles and their accompanying payloads. This processing includes all required initial vehicle assembly, mating, servicing, refurbishment, and repair. In addition, some amount of mission propellant may be stored and transferred on Freedom. Third, Freedom provides an ideal test bed for developing operational techniques that are applicable to the Human Exploration Initiative missions. The work performed under this task and presented in this briefing serves to define and prepare Space Station Freedom evolution in keeping with the mission needs stated above by: defining Freedom transportation node evolution configurations consistent with user requirements and program constraints; defining and incorporating baseline design accommodations (hardware 'scars' and software 'hooks') to satisfy evolution requirements; and identifying advanced technology that will enhance Freedom's capabilities and enables its evolution.
Rare earth elements (REE) are an extremely useful tool in modeling lunar magmatic processes. Here we present the first experimentally derived plagioclase/melt partition coefficients in lunar compositions covering the entire suite of REE. Positive europium anomalies are ubiquitous in the plagioclase-rich rocks of the lunar highlands, and complementary negative Eu anomalies are found in most lunar basalts. These features are taken as evidence of a large-scale differentiation event, with crystallization of a global-scale lunar magma ocean (LMO) resulting in a plagioclase flotation crust and a mafic lunar interior from which mare basalts were subsequently derived. However, the extent of the Eu anomaly in lunar rocks is variable. Fagan and Neal [1] reported highly anorthitic plagioclase grains in lunar impact melt rock 60635,19 that displayed negative Eu anomalies as well as the more usual positive anomalies. Indeed some grains in the sample are reported to display both positive and negative anomalies. Judging from cathodoluminescence images, these anomalies do not appear to be associated with crystal overgrowths or zones.
The Space Exploration Initiative (SEI) includes space resource utilization as one of the four architectures to achieve U.S. goals in space. Space resource utilization will make use of lunar resources to support long term activities on the lunar surface. Lunar ilmenite and regolith are two of the materials that can be mined and processed for lunar oxygen production. During this investigation, several sources were reviewed to assess terrestrial exploration methods used for locating ilmenite resources. These sources included published reports on terrestrial ilmenite exploration methods, analytical methods, case histories, chemical and physical properties, and associations with other minerals. Using a terrestrial analog and considering the differences between terrestrial and lunar environmental conditions, rocks, and minerals, exploration methods and analytical instruments can be recommended for a lunar orbiter and lander for assessing lunar resources. Twelve terrestrial case histories were reviewed to gain insight into ilmenite exploration on the Moon. All exploration case histories follow the same pattern. They begin with a model, use remote geophysical techniques, define regional sampling sites from the model and geophysics, narrow down the area of exploration based on the preceding work, collect more samples and cores, and perform laboratory analyses of samples. An important part of this process is the collection of samples to determine the correctness of the model. Surface and core samples are collected in areas expected to contain both high and low concentration of the commodity to test the model. After samples are analyzed and the area of mineralization is defined, reserves are calculated to determine the cost/benefit ratio, the necessary capacity of the processing plant, and the life of the mine. The exploration methods used for locating terrestrial ilmenite resources are reviewed with respect to the petrology, chemistry, and mineral associations of the terrestrial and lunar environments.