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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Empirical Determination of Radiolytic Products in Simulated Europan Ices

The chemical composition of Europa's surface is strongly influenced by energetic charge particle bombardment from Jupiter's magnetosphere. Here we report on progress in experimental work designed to address: 1) The production of radiolytic products in thermodynamic disequilibrium that could be utilized by known terrestrial microorganisms, and 2) The modification of complex organic molecules and degradation of biological material by the simulated Europan surface radiation environment.

Hand, P.↗

Investigating and Analyzing Applied Loads Higher Than Limit Loads

The results of the analysis for Balance 1621 indicate that the stresses are high near sharp corners. It is important to increase the size of the fillets to relieve some of the high stresses for the balances that will be designed. For the existing balances, the stresses are high and do not satisfy the established criteria. Two options are considered here. One is a possible modification of the existing balances, and two is to consider other load options. Redesigning a balance can be done in order to enhance the structural integrity of the balance. Because an existing balance needs to be modified, it is not possible to increase the fillet sizes without some further modifications to the balance. It is required that some materials be extracted from the balance in order to have larger fillet sizes. Researchers are interested in being able to apply some components of the load on the balance above the limit loads assigned. Is it possible to enhance the load on the same balance and maintain the factor of safety required? Some loads were increased above their limit loads and analyzed here.

Karkehabadi, R.↗

Performance Expectations of Closed-Brayton-Cycle Heat Exchangers in 100-kWe Nuclear Space Power Systems

Performance expectations of closed-Brayton-cycle heat exchangers to be used in 100-k We nuclear space power systems were forecast. Proposed cycle state points for a system supporting a mission to three of Jupiter's moons required effectiveness values for the heat-source exchanger, recuperator and rejection exchanger (gas cooler) of 0.98, 0.95, and 0.97, respectively. Performance parameters such as number of thermal units (Ntu), equivalent thermal conductance (UA), and entropy generation numbers (Ns) varied from 11 to 19, 23 to 39 kW/K, and 0.019 to 0.023 for some standard heat exchanger configurations. Pressure-loss contributions to entropy generation were significant; the largest frictional contribution was 114% of the heat transfer irreversibility. Using conventional recuperator designs, the 0.95 effectiveness proved difficult to achieve without exceeding other performance targets; a metallic, plate-fin counterflow solution called for 15% more mass and 33% higher pressure-loss than the target values. Two types of gas-coolers showed promise. Single-pass counterflow and multipass cross-counterflow arrangements both met the 0.97 effectiveness requirement. Potential reliability-related advantages of the cross-counterflow design were noted. Cycle modifications, enhanced heat transfer techniques and incorporation of advanced materials were suggested options to reduce system development risk. Carbon-carbon sheeting or foam proved an attractive option to improve overall performance.

Barrett, Michael J.↗

The Interaction of Impact Melt, Impact-Derived Sediment, and Volatiles at Crater Tooting, Mars

We are producing a 1:200K geologic map of Tooting crater, Mars. This work has shown that an incredible amount of information can be gleaned from mapping at even larger scales (1:10K 1:25K) using CTX and HiRISE data. We have produced two new science papers (Morris et al., 2010; Mouginis-Mark and Boyce, 2010) from this mapping, and additional science questions continue to arise from our on-going analysis of Tooting crater: 1) What was the interplay of impact melt and volatile-rich sediments that, presumably, were created during the impact? Kieffer and Simonds [1980] predicted that melt would have been destroyed during impacts on Mars because of the volatiles present within the target we seek to understand if this is indeed the case at Tooting crater. We have identified pitted and fractured terrain that formed during crater modification, but the timing of the formation of these materials in different parts of the crater remains to be resolved. Stratigraphic relationships between these units and the central peak may reveal deformation features as well as overlapping relationships. 2) Morris et al. [2010] identified several lobate flows on the inner and outer walls of Tooting crater. It is not yet clear what the physical characteristics of the source areas of these flows really are; e.g., what are the sizes of the source areas, what elevations are they located at relative to the floor of the crater, are they interconnected, and are they on horizontal or tilted surfaces? 3) What were the details of dewatering of the inner wall of Tooting crater (Fig. 1)? We find evidence within Tooting crater of channels carved by water release, and the remobilization of sediment (which is inferred to have formed during the impact event). Sapping can be identified along the crest of unit 8 near the floor of the crater (Fig. 2a, 2b). This unit displays amphitheater-headed canyons that elsewhere on Mars are typically attributed to water leaking from the substrate [Laity and Malin, 1985; Malin and Edgett, 2000].

Mouginis-Mark, P.↗

Nanolayered Features of Collagen-like Peptides

We have been investigating collagen-like model oligopeptides as molecular bases for complex ordered biomimetic materials. The collagen-like molecules incorporate aspects of native collagen sequence and secondary structure. Designed modifications to native primary and secondary structure have been incorporated to control the nanostructure and microstructure of the collagen-like materials produced. We find that the collagen-like molecules form a number of lyotropic rod liquid crystalline phases, which because of their strong temperature dependence in the liquid state can also be viewed as solvent intercalated thermotropic liquid crystals. The liquid crystalline phases formed by the molecules can be captured in the solid state by drying off solvent, resulting in solid nanopatterned (chemically and physically) thermally stable (to greater than 100 C) materials. Designed sequences which stabilize smectic phases have allowed a variety of nanoscale multilayered biopolymeric materials to be developed. Preliminary investigations suggest that chemical patterns running perpendicular to the smectic layer plane can be functionalized and used to localize a variety of organic, inorganic, and organometallic moieties in very simple multilayered nanocomposites. The phase behavior of collagen-like oligopeptide materials is described, emphasizing the correlation between mesophase, molecular orientation, and chemical patterning at the microscale and nanoscale. In many cases, the textures observed for smectic and hexatic phase collagens are remarkably similar to the complex (and not fully understood) helicoids observed in biological collagen-based tissues. Comparisons between biological morphologies and collagen model liquid crystalline (and solidified materials) textures may help us understand the molecular features which impart order and function to the extracellular matrix and to collagen-based mineralized tissues. Initial studies have utilized synthetic collagen-like peptides while future work will also focus on similar sequences generated via genetic engineering methods.

Valluzzi, Regina↗

Cryogenic mechanical properties of low density superplastically formable Al-Li alloys

The aerospace industry is considering the use of low density, superplastically formable (SPF) materials, such as Al-Li alloys in cryogenic tankage. SPF modifications of alloys 8090, 2090, and 2090+In were tested for strength and Kahn tear toughness. The results were compared to those of similar tests of 2219-T87, an alloy currently used in cryogenic tankage, and 2090-T81, a recently studied Al-Li alloy with exceptional cryogenic properties (1-9). With decreasing temperature, all materials showed an increase in strength, while most materials showed an increase in elongation and decrease in Kahn toughness. The indium addition to 2090 increased alloy strength, but did not improve the strength-toughness combination. The fracture mode was predominantly intergranular along small, recrystallized grains, with some transgranular fracture, some ductile rupture, and some delamination on large, unrecrystallized grains.

Verzasconi, S. L.↗

Modified Composite Materials Workshop

The reduction or elimination of the hazard which results from accidental release of graphite fibers from composite materials was studied at a workshop. At the workshop, groups were organized to consider six topics: epoxy modifications, epoxy replacement, fiber modifications, fiber coatings and new fibers, hybrids, and fiber release testing. Because of the time required to develop a new material and acquire a design data base, most of the workers concluded that a modified composite material would require about four to five years of development and testing before it could be applied to aircraft structures. The hybrid working group considered that some hybrid composites which reduce the risk of accidental fiber release might be put into service over the near term. The fiber release testing working group recommended a coordinated effort to define a suitable laboratory test.

Dicus, D. L.↗

Layered Electrode Architectures Enabled by Holey Graphene Hosts

Battery electrodes are typically prepared using a slurry-based method, where high boiling point organic solvents are typically used with a polymer binder to disperse active electrode materials and conductive carbon additives followed by casting into current collector sheets. In this process, the use of organic solvents are environmentally hazardous, energy intensive, and time-consuming, while polymeric binders add weight and can undergo parasitic reactions during battery cycling. Here we discuss the use of a unique conductive carbon nanomaterial, namely holey graphene, as a multifunctional host that can be processed via a facile, solvent-free, binder-free, cold pressing method to prepare electrodes with unique architectures. This approach can accommodate a broad range of battery chemistries, such as lithium oxygen/carbon dioxide (Li-O2/CO2), lithium sulfur/selenium (Li-S/Se), and various lithium ion chemistries. The successful use of dry, cold compression allows the convenient modification of electrode mass loading with unique architectures containing active materials randomly mixed or layered with single or multiple layers of one or more active materials. In the conventional slurry-based electrode fabrication method, it is difficult, if not impossible, to achieve such layered architectures. In particular, the layered electrode architectures from the dry, cold press approach are easy to fabricate without significantly sacrificing device performance, and are amenable to continuous roll-to-roll dry processing. In addition, these architectures offer unprecedented perspectives on the battery material loading vs. utilization efficiency, as well as enabling unique characterization opportunities to advance mechanistic understanding of various battery chemistries. Potential applications of this unique electrode fabrication approach for solid-state batteries will also be discussed.

holey graphene, batteries, electrode architecture,↗

A photoelastic investigation of asymmetric four point bend shear test for composite materials

The shear stress fringe value of orthotropic birefringent model materials is presently used in an asymmetric four-point bend test that employs a notched specimen and is a modification of the Iosipescu test (1967). While in the case of a unidirectionally reinforced glass-polyester model material, shear stress fringe values obtained from 90- and 120-deg (sharp and radiused) notches are reasonably close to the values obtained for an off-axis tensile specimen, no conclusions can be drawn on the influence of the notch parameters, due to the peculiarities of the photoelastic response of the inhomogeneous orthotropic model material. The failure modes nevertheless indicate that a notch radius, and the 120-deg notch angle, reduce the stress concentration. Comparisons are made with finite element results.

Prabhakaran, R.↗

High-temperature behavior of advanced spacecraft TPS

The objective of this work has been to develop more efficient, lighter weight, and higher temperature thermal protection systems (TPS) for future reentry space vehicles. The research carried out during this funding period involved the design, analysis, testing, fabrication, and characterization of thermal protection materials to be used on future hypersonic vehicles. This work is important for the prediction of material performance at high temperature and aids in the design of thermal protection systems for a number of programs including programs such as the National Aerospace Plane (NASP), Pegasus and Pegasus/SWERVE, the Comet Rendezvous and Flyby Vehicle (CRAF), and the Mars mission entry vehicles. Research has been performed in two main areas including development and testing of thermal protection systems (TPS) and computational research. A variety of TPS materials and coatings have been developed during this funding period. Ceramic coatings were developed for flexible insulations as well as for low density ceramic insulators. Chemical vapor deposition processes were established for the fabrication of ceramic matrix composites. Experimental testing and characterization of these materials has been carried out in the NASA Ames Research Center Thermophysics Facilities and in the Ames time-of-flight mass spectrometer facility. By means of computation, we have been better able to understand the flow structure and properties of the TPS components and to estimate the aerothermal heating, stress, ablation rate, thermal response, and shape change on the surfaces of TPS. In addition, work for the computational surface thermochemistry project has included modification of existing computer codes and creating new codes to model material response and shape change on atmospheric entry vehicles in a variety of environments (e.g., earth and Mars atmospheres).

Pallix, Joan↗

A Module Experimental Process System Development Unit (MEPSDU)

Restructuring research objectives from a technical readiness demonstration program to an investigation of high risk, high payoff activities associated with producing photovoltaic modules using non-CZ sheet material is reported. Deletion of the module frame in favor of a frameless design, and modification in cell series parallel electrical interconnect configuration are reviewed. A baseline process sequence was identified for the fabrication of modules using the selected dendritic web sheet material, and economic evaluations of the sequence were completed.

Source record↗

Aging Mechanisms and Control: Specialists' Meeting on Life Management Techniques for Aging Air Vehicles

The costs of maintaining ageing aircraft are draining the existing budgets. The Specialist Meeting provided guidance on strategies for the development and implementation of technologies and logistic management processes to reduce this economic burden. The emphasis was on military aircraft, but many of the principles could be applied to other defence systems. The papers covered the entire range of ageing problems including structural integrity, corrosion, avionics, mechanical subsystems, structures and wiring as well as the role of information management. Forty-two papers addressed the safety and economic implications such as fatigue cracking, corrosion, wear and material degradation. Key technologies were discussed, including non-destructive inspection, repair, modifications, prevention analysis, and health management. The shortcomings of current were highlighted and the investment required was identified. The need for research and development was clearly identified.

aging tests (materials)↗

The modification stage of basin formation - Conditions of ring formation

The impact cratering process may be divided into three stages, including a short high pressure phase of initial contact between the projectile and target, a longer cratering flow phase during which material is both ejected and displaced to form the transient crater, and a still longer modification phase during which the transient crater is modified into the final observed form. The present investigation is concerned with the nature of the modification stage as constrained by the initial boundary condition which comprises the transient crater and its surroundings, and the final boundary condition which comprises the structure of observed craters and basins. A brief description is provided of an interpretation of basin ring structure based on geophysical, geological, and dimensional analysis of craters and basins on the moon, Mercury, and Mars, on structural observations of terrestrial impact and explosion craters, and on an empirical crater restoration model. A scenario of basin formation is constructed, and relations of this scenario to observed morphology are discussed.

Croft, S. K.↗

Ion beam sputter modification of the surface morphology of biological implants

The surface chemistry and texture of materials used for biological implants may significantly influence their performance and biocompatibility. Recent interest in the microscopic control of implant surface texture has led to the evaluation of ion beam sputtering as a potentially useful surface roughening technique. Ion sources, similar to electron bombardment ion thrusters designed for propulsive applications, are used to roughen the surfaces of various biocompatible alloys or polymer materials. These materials are typically used for dental implants, orthopedic prostheses, vascular prostheses, and artificial heart components. Masking techniques and resulting surface textures are described along with progress concerning evaluation of the biological response to the ion beam sputtered surfaces.

Weigand, A. J.↗

Ion-beam-sputter modification of the surface morphology of biological implants

The surface chemistry and texture of materials used for biological implants may significantly influence their performance and biocompatibility. Recent interest in the microscopic control of implant surface texture has led to the evaluation of ion-beam sputtering as a potentially useful surface roughening technique. Ion sources, similar to electron-bombardment ion thrusters designed for propulsive applications, are used to roughen the surfaces of various biocompatible alloys or polymer materials. These materials are typically used for dental implants, orthopedic prostheses, vascular prostheses, and artificial heart components. Masking techniques and resulting surface textures are described along with progress concerning evaluation of the biological response to the ion-beam-sputtered surfaces.

Weigand, A. J.↗

Assessment and Requirements of Nuclear Reaction Databases for GCR Transport in the Atmosphere and Structures

The transport properties of galactic cosmic rays (GCR) in the atmosphere, material structures, and human body (self-shielding) am of interest in risk assessment for supersonic and subsonic aircraft and for space travel in low-Earth orbit and on interplanetary missions. Nuclear reactions, such as knockout and fragmentation, present large modifications of particle type and energies of the galactic cosmic rays in penetrating materials. We make an assessment of the current nuclear reaction models and improvements in these model for developing required transport code data bases. A new fragmentation data base (QMSFRG) based on microscopic models is compared to the NUCFRG2 model and implications for shield assessment made using the HZETRN radiation transport code. For deep penetration problems, the build-up of light particles, such as nucleons, light clusters and mesons from nuclear reactions in conjunction with the absorption of the heavy ions, leads to the dominance of the charge Z = 0, 1, and 2 hadrons in the exposures at large penetration depths. Light particles are produced through nuclear or cluster knockout and in evaporation events with characteristically distinct spectra which play unique roles in the build-up of secondary radiation's in shielding. We describe models of light particle production in nucleon and heavy ion induced reactions and make an assessment of the importance of light particle multiplicity and spectral parameters in these exposures.

Cucinotta, F. A.↗

Chemical vapor deposition growth

The chemical vapor deposition (CVD) method for the growth of Si sheet on inexpensive substrate materials is investigated. The objective is to develop CVD techniques for producing large areas of Si sheet on inexpensive substrate materials, with sheet properties suitable for fabricating solar cells meeting the technical goals of the Low Cost Silicon Solar Array Project. Specific areas covered include: (1) modification and test of existing CVD reactor system; (2) identification and/or development of suitable inexpensive substrate materials; (3) experimental investigation of CVD process parameters using various candidate substrate materials; (4) preparation of Si sheet samples for various special studies, including solar cell fabrication; (5) evaluation of the properties of the Si sheet material produced by the CVD process; and (6) fabrication and evaluation of experimental solar cell structures, using standard and near-standard processing techniques.

Ruth, R. P.↗