Search NASA⌕ Search

SEARCH · Search NASA

Results for “rotational spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 217 records · Page 12

Phase resolved optical spectroscopy of the compact X-ray binary 2A1822-371

The optical, X-ray, and ultraviolet emissions of the X-ray system 2A1822-371 are modulated with a period of 5.57 hr. The 5.57 hr modulation is believed to reflect orbital motion about a mass donating companion star. The modulation at high energies is caused by the combined effects of an occultation by the companion and by a bulge on the accretion disk. The present investigation is concerned with an extension of the study of 2A1822-371, taking into account medium resolution optical spectroscopy of the system covering the 5.57 hr cycle. Broad shallow absorption lines are observed in the optical spectrum of 2A1822-371. These lines are similar to the rotationally broadened lines which are found in the spectra of disk accreting cataclysmic variables. Their presence in 2A1822-371 is, therefore, strong confirmation that it is a disk accreting star. The He II 4686 A and H-alpha emission lines have a breadth comparable to the absorption lines at all phases in the 5.57 hr cycle.

Mason, K. O.↗

Far-infrared Spectroscopy of Interstellar Gas

Research results of far-infrared spectroscopy with the Kuiper Airborne Observatory are discussed. Both high and intermediate resolution have been successfully employed in the detection of many new molecular and atomic lines including rotational transition of hydrides such as OH, H2O, NH3 and HCl; high J rotational transitions of CO; and the ground state fine structure transitions of atomic carbon, oxygen, singly ionized carbon and doubly ionized oxygen and nitrogen. These transitions have been used to study the physics and chemistry of clouds throughout the galaxy, in the galactic center region and in neighboring galaxies. This discussion is limited to spectroscopic studies of interstellar gas.

Phillips, T. G.↗

Recent advances at NASA in calculating the electronic spectra of diatomic molecules

Advanced entry vehicles, such as the proposed Aero-assisted Orbital Transfer Vehicle, provide new and challenging problems for spectroscopy. Large portions of the flow field about such vehicles will be characterized by chemical and thermal nonequilibrium. Only by considering the actual overlap of the atomic and rotational lines emitted by the species present can the impact of radiative transport within the flow field be assessed correctly. To help make such an assessment, a new computer program is described that can generate high-resolution, line-by-line spectra for any spin-allowed transitions in diatomic molecules. The program includes the matrix elements for the rotational energy and distortion to the fourth order; the spin-orbit, spin-spin, and spin-rotation interactions to first order; and the lambda splitting by a perturbation calculation. An overview of the Computational Chemistry Branch at Ames Research Center is also presented.

Whiting, Ellis E.↗

New electronic states of NH and ND observed by resonance enhanced multiphoton ionization spectroscopy

Resonance Enhanced MultiPhoton Ionization (REMPI) spectra of NH and ND, which reveal four new electronic states are presented. Transitions from NH a 1 delta to 3s and 3p Rydberg states in both NH and ND have been observed and rotationally analyzed. The transitions were observed in the wavelength range of 258 to 288 nm. The state assignments are: e 1 pi (3s sigma) at 82857/cm, f 1 pi (3p sigma) at 86378/cm, g 1 delta (3p pi) at 88141/cm and h 1 sigma (3p pi) at 89151/cm.

Johnson, Russell D., III↗

Single photon infrared emission spectroscopy: a study of IR emission from UV laser excited PAHs between 3 and 15 micrometers

Single-photon infrared emission spectroscopy (SPIRES) has been used to measure emission spectra from polycyclic aromatic hydrocarbons (PAHs). A supersonic free-jet expansion has been used to provide emission spectra of rotationally cold and vibrationally excited naphthalene and benzene. Under these conditions, the observed width of the 3.3-micrometers (C-H stretch) band resembles the bandwidths observed in experiments in which emission is observed from naphthalene with higher rotational energy. To obtain complete coverage of IR wavelengths relevant to the unidentified infrared bands (UIRs), UV laser-induced desorption was used to generate gas-phase highly excited PAHs. Lorentzian band shapes were convoluted with the monochromator-slit function in order to determine the widths of PAH emission bands under astrophysically relevant conditions. Bandwidths were also extracted from bands consisting of multiple normal modes blended together. These parameters are grouped according to the functional groups mostly involved in the vibration, and mean bandwidths are obtained. These bandwidths are larger than the widths of the corresponding UIR bands. However, when the comparison is limited to the largest PAHs studied, the bandwidths are slightly smaller than the corresponding UIR bands. These parameters can be used to model emission spectra from PAH cations and cations of larger PAHs, which are better candidate carriers of the UIRs.

Non-NASA Center↗

The Fourier-Kelvin Stellar Interferometer (FKSI): A Discovery Class TPF/DARWIN Pathfinder Mission Concept

The Fourier-Kelvin Stellar Interferometer (FKSI) is a mission concept for an imaging and nulling interferometer for the mid-infrared spectral region (5-30 microns). FKSI is conceived as a scientific and technological pathfinder to TPF/DARWIN as well as SPIRIT, SPECS, and SAFIR. It will also be a high angular resolution system complementary to NGST. The scientific emphasis of the mission is on the evolution of protostellar systems, from just after the collapse of the precursor molecular cloud core, through the formation of the disk surrounding the protostar, the formation of planets in the disk, and eventual dispersal of the disk material. FKSI will also search for brown dwarfs and Jupiter mass and smaller planets, and could also play a very powerful role in the investigation of the structure of active galactic nuclei and extra-galactic star formation. We have been studying alternative interferometer architectures and beam combination techniques, and evaluating the relevant science and technology tradeoffs. Some of the technical challenges include the development of the cryocooler systems necessary for the telescopes and focal plane array, light and stiff but well-damped truss systems to support the telescopes, and lightweight and coolable optical telescopes. We present results of detailed design studies of the FKSI starting with a design consisting of five one meter diameter telescopes arranged along a truss structure in a linear non-redundant array, cooled to 35 K. A maximum baseline of 20 meters gives a nominal resolution of 26 mas at 5 microns. Using a Fizeau beam combination technique, a simple focal plane camera could be used to obtain both Fourier and spectral data simultaneously for a given orientation of the array. The spacecraft will be rotated to give sufficient Fourier data to reconstruct complex images of a broad range of astrophysical sources. Alternative and simpler three and two telescope designs emphasizing nulling and spectroscopy also have been investigated and will be discussed.

Danchi, W. C.↗

Techniques for Spectroscopic Measurements in an Arcjet Nozzle

A successful attempt has been made to gain optical access to the inside of an arcjet nozzle without changing internal thruster design or affecting performance characteristics. Both fiber optics and small open holes have been used for emission spectroscopy of a small, confined, high-temperature plasma source. The plasma was found to be in a highly nonequilibrium state, with electron excitation temperatures more than double the rotational or vibrational temperatures.

Zube, Dieter M.↗

A Chemical and Structural Study of the A1N-Si Interface

Samples of A1N grown on silicon [111] subtrates were examined using electron enery loss spectroscopy (EELS) and selected area diffraction (SAD) with high-resolution transmission electron microscopy (TEM) to determine the source of out-of-place tilts and in-plane rotations of the A1N crystallites at the Si interface.

silicon out-of-plane tilts in-plane rotations sili↗

Io's atmosphere detected by ground-based microwave spectroscopy

Io's corona and extended atmosphere, i.e., the plasma torus and neutral Na and K clouds, were the subject of intensive ground-based studies. E. Lellouch et al. not only detected but also fully resolved the profiles of two pure rotational lines of SO2. The lines were found in emission showing that early theoretical predictions for a thermally inverted atmospheric structure were correct.

Belton, Michael J. S.↗

Spectroscopy of emission-line nebulae in powerful radio galaxies - Interpretation

Long-slit optical spectra of the emission-line nebulae associated with 21 low-redshift (less than 0.2) radio galaxies are analyzed. Nebulae are classified kinematically into three types: rotators, calm nonrotators, and violent nonrotators; these types are characterized. It is proposed that the rotators have dynamically young disks of gas recently acquired by the radio galaxy in an interaction or merger with a gas-rich galaxy. This is consistent with the data on the morphologies, colors, and stellar dynamics of radio galaxies with strong emission lines. It is inferred from the association of the large-scale gas kinematics with the radio and optical properties of an active galaxy that the angular momentum of the gas which fuels the AGN may be an important parameter in the determinant of how activity is manifest in an AGN.

Baum, S. A.↗

NGC 4550 - A laboratory for testing galaxy formation

The kinematic and photometric structure of the two components of the E7/S0 galaxy NGC 4550 are evaluated quantitatively to determine the system's morphology. Attention is given to whether the data indicate a rotating bulge with a counterrotating disk or a pair of counterstreaming disks, and formation scenarios are discussed in the light of the findings. The data examined include long-slit spectroscopy with evidence of bimodality in the line-of-sight velocity distribution. Two photometrically inseparable counterstreaming disk components are identified and their velocities given. The structure and the formation scenarios given point to the feasibility of absorption of external material by galaxy disks without extreme heating. The possibility of detecting stellar counterrotation in S0 disks is discussed based on the study of NGC 4550.

Rix, Hans-Walter↗

The Near-Earth Encounter of Asteroid 308635 (2005 YU55): Thermal IR Observations

The near-Earth approach (0.00217 AU, or 0.845 lunar distances) of the C-type asteroid 308635 (2005 YU55) in November 2011 presented a rare opportunity for detailed observations of a low-albedo NEA in this size range. As part of a multi-telescope campaign to measure visible and infrared spectra and photometry, we obtained mid-infrared (approx. 8 to 22 micron) photometry and spectroscopy of 2005 YU55 using Michelle on the Gemini North telescope on UT November 9 and 10,2011. An extensive radar campaign together with optical light-curves established the rotation state of YU55. In addition, the radar imaging resulted in a shape model for the asteroid, detection of numerous boulders on its surface, and a preliminary estimate of its equatorial diameter at 380 +/- 20 m. In a preliminary analysis, applying the radar and lightcurve-derived parameters to a rough-surface thermophysical model fit to the Gemini/Michelle thermal emission photometry results in a thermal inertia range of approximately 500 to 1500 J/sq m/0.5s/K, with the low-thermal-inertia solution corresponding to the small end of the radar size range and vice versa. Updates to these results will be presented and modeling of the thermal contribution to the measured near-infrared spectra from Palomar/Triplespec and IRTF/SpeX will also be discussed.

Lim, Lucy F.↗

High-resolution Fourier transform spectroscopy of the Meinel system of OH

The infrared spectrum of the hydroxyl radical OH, between 1850 and 9000/cm has been measured with a Fourier transform spectrometer. The source, a hydrogen-ozone diffusion flame, was designed to study the excitation of rotation-vibration levels of the OH Meinel bands under conditions similar to those in the upper atmosphere which produce the nighttime OH airglow emission. Twenty-three bands were observed: nine bands in the Delta upsilon = 1 sequence, nine bands in the Delta upsilon = 2 sequence, and five bands in the Delta upsilon = 3 sequence. A global nonlinear least-squares fit of 1696 lines yielded molecular parameters with a standard deviation of 0.003/cm. Term values are computed, and transition frequencies in the Delta upsilon = 3, 4, 5, 6 sequences in the near-infrared are predicted.

Abrams, Mark C.↗

On the accuracy of CO line positions for high resolution IR stellar spectroscopy

The paper demonstrates the high accuracy of line positions derived from improved sets of Dunham coefficients for the four more abundant isotopic species of carbon monoxide - (C-12)(O-16), (C-13)(O-16), (C-12)(O-18), and (C-12)(O-17) - which are present in the sun and in cool stellar atmospheres. These new spectroscopic constants make it possible to predict very accurate positions of CO lines at any J-values, especially at very high rotational excitation (up to J around 135). Earlier proposed identifications of CO lines at large J-values are checked, and some incorrect identifications in sunspot spectra are found. The present accurate line positions are also compared with predictions from other available sets of molecular constants. It is concluded that the present improved sets of molecular constants are the most appropriate to all problems of high-resolution stellar and solar spectroscopy at any J- and v-values, particularly for synthetic spectra of cool stars.

Sauval, A. J.↗