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At least 217 records · Page 12

nPINNs: nonlocal Physics-Informed Neural Networks for a parametrized nonlocal universal Laplacian operator. Algorithms and Applications

Physics-informed neural networks (PINNs) are effective in solving inverse problems based on differential and integro-differential equations with sparse, noisy, unstructured, and multifidelity data. PINNs incorporate all available information, including governing equations (reflecting physical laws), initial-boundary conditions, and observations of quantities of interest, into a loss function to be minimized, thus recasting the original problem into an optimization problem. In this paper, we extend PINNs to parameter and function inference for integral equations such as nonlocal Poisson and nonlocal turbulence models, and we refer to them as nonlocal PINNs (nPINNs). The contribution of the paper is three-fold. First, we propose a unified nonlocal Laplace operator, which converges to the classical Laplacian as one of the operator parameters, the nonlocal interaction radius δ goes to zero, and to the fractional Laplacian as δ goes to infinity. This universal operator forms a super-set of classical Laplacian and fractional Laplacian operators and, thus, has the potential to fit a broad spectrum of data sets. We provide theoretical convergence rates with respect to δ and verify them via numerical experiments. Second, we use nPINNs to estimate the two parameters, δ and α, characterizing the kernel of the unified operator. The strong non-convexity of the loss function yielding multiple (good) local minima reveals the occurrence of the operator mimicking phenomenon, that is, different pairs of estimated parameters could produce multiple solutions of comparable accuracy. Third, we propose another nonlocal operator with spatially variable order α(γ), which is more suitable for modeling turbulent Couette flow. Our results show that nPINNs can jointly infer this function as well as δ. More importantly, these parameters exhibit a universal behavior with respect to the Reynolds number, a finding that contributes to our understanding of nonlocal interactions in wall-bounded turbulence.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Evaluation of Two-Dimensional to One-Dimensional Site Response for Idaho National Laboratory

We perform two-dimensional (2D) site response analyses accounting for spatial variability of soil properties and subsurface geometry of the Eastern Snake River Plane (ESRP), and quantify their effects on ground surface motion relative to one-dimensional (1D) site response analyses at the Idaho National Laboratory (INL). We first present the development of random field idealizations of the repeated basalt lava flows, heterogeneously inter-layered with sediments, from seismic velocity data collected over four decades in the ESRP. Using realizations of the stochastic fields mapped on 2D deterministic finite element models, we perform 2D viscoelastic and equivalent-linear wave propagation simulations, and quantify the mean and variance of site response aggravation factors, defined as the response spectral ratio of 2D to 1D analyses on the ground surface. Results are shown to be insensitive to the constitutive material behavior considered here, for strains induced by rock outcrop peak ground acceleration (PGA) as high as 0.7g: viscoelastic and equivalent-linear analyses predict peak mean 2D/1D aggravation factor 1.05 at period T=0.075 sec (i.e. the 2D response spectrum is 5% higher than the corresponding 1D at that period, on average), which corresponds to the wavelength of the horizontal correlation length of the random field (50m). For periods longer than the fundamental period of the site (here, T 1 =0.3125 sec), the propagating wavelengths are too long to be affected by the 1D site response and the aggravation factor becomes equal to 1. The standard deviation of the natural logarithms of the 2D/1D aggravation factors is ~0.15 for periods shorter than the fundamental period of the site, and decays thereafter at a steady rate.

58 GEOSCIENCES↗

An Investigation on the Spatial Dependence of Autoconversion and Accretion in Eastern North Atlantic Boundary Layer Clouds (Final Report)

In many climate models, small clouds over the ocean rain too often and too lightly. This affects the amount of water in the clouds and ultimately the area covered by clouds both of which must be predicted by climate models. This in turn impacts how much sunlight these clouds can reflect to space and ultimately has a significant impact on the Earth radiation balance and climate. The purpose of this project was to use cloud and precipitation data being collected by DOE to evaluate the spatial variability of boundary layer clouds and precipitation, and the relationships between them with a view towards improving the representation of the physics that control the generation of precipitation in models.

58 GEOSCIENCES↗

Development of Scalable Reactive Transport Framework for PFAS

Research on PFAS chemicals is extensive and covers all aspects, including analytical quantification, determination of properties, toxicology, ex situ treatment, and in situ remediation. PFAS chemicals are very stable and thus persistent/recalcitrant in the environment. Although there are many unknowns about PFAS chemicals, degradation pathways, reaction rates, etc., many different sorption, oxidation, reduction, biological, and innovative treatment approaches are being developed. Sorption with activated carbon is currently the only fully available in situ treatment technology for PFAS-impacted groundwater. Given the wide array of PFAS chemicals and transformation products, remediation may need multi-step treatment trains to fully address the PFAS contamination. The work here provides kinetic reaction modules that represent an initial cut at functionality representing PFAS migration and reaction in groundwater aquifer flow and transport models. One reaction kinetics module provides a method to model kinetically limited adsorption using a mass transfer model. The second reaction module represents biological transformation of 8:2 FTOH and daughter species, illustrating how a complex reaction pathway network can be represented. Both reaction modules allow for spatially variable parameter values so that a variety of remediation approaches (e.g., a PRB or volumetric treatment or variations in geochemical conditions) can be simulated. The intent with these PFAS reaction modules is to provide tools for practitioners to aid in the selection, design, and assessment of potential in situ PFAS remediation strategies. It is anticipated that, as PFAS remediation technologies and scientific understanding advances, these modules would be refined or replaced to match new knowledge.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessment of InSAR Seasonal Movements at Bayou Choctaw SPR Site

Ground deformation is important to monitor for the ongoing safety and stability of underground caverns. Implementing InSAR technology to monitor site-wide surface deformation at the Strategic Petroleum Reserve has revealed seasonal ground movements at Bayou Choctaw in Louisiana. The cyclic, seasonal pattern shows soil shrinkage during the spring and summer months and soil expansion during the fall and winter months. Prior to this report, no in-depth investigation was conducted to explain this seasonal phenomenon. However, the ground movement is believed to be near-surface and not geological due to the relatively insignificant movement between years. To better understand seasonality movements, soil properties, land cover, and climatic conditions are assessed to relate near-surface water and soil interactions. The soil, land, and climatic properties all contribute to seasonal ground movement, and vegetation cover and the soil's water capacity contribute to the spatial variability of InSAR seasonal measurements at Bayou Choctaw.

02 PETROLEUM↗

Characterizing Bioavailable Soil Nutrients Across Coastal Systems: Western Lake Erie and Chesapeake Bay

Terrestrial Aquatic Interfaces (TAIs), defined as where land meets water, exhibit important hydrological, biological, and biogeochemical dynamics and play a critical role in the Earth’s carbon cycle. Current Earth System Models improperly represent this role due to the complexity of these systems and the disproportionally large impact TAIs have relative to their area. To improve our predictive capacity of coastal system dynamics, a better understanding of carbon and nutrient cycling across TAI’s is needed. Coastal Observations, Mechanisms, and Predictions Across Systems and Scales (COMPASS) aims to achieve this through field observations and laboratory incubations throughout the Western Lake Erie and Chesapeake Bay regions. Here, we report on preliminary results from a soil characterization experiment across the WLE and CB regions. This experiment was conducted as part of the 2-year field, measurements, and experiments (FME) pilot study portion of COMPASS to provide initial baseline data for the sites and to characterize the spatial variability of our analytes. Soil samples were collected from three locations along the TAI transect (upland forest, transitional forest, and wetland) and analyzed for bioavailable nutrients using three types of extractions: (a) water extractions, (b) 2M KCl extractions, and (c) 1M NH4Cl extractions to analyze (a) water soluble organic carbon (WSOC), (b) ammonium and nitrate, and (c) base cations, including Ca, Mg, Na, K, and Fe. These analyses, in conjunction with other bulk physicochemical analyses, will help establish baseline understanding of these sites to drive future research and design focused experiments that will ultimately improve our predictive understanding of these freshwater and marine coastal TAIs and their response to short and long-term changes.

54 ENVIRONMENTAL SCIENCES↗

Characterization of Nitrate, Nitrite, Ammonia, and Tritium in D0220 Cores

This report describes characterization of nitrogen species (nitrate, nitrite, ammonia) in aqueous and solid phases in cores taken in borehole D0220 (well 299-E25-245) under crib 216-A-37-1 at the Hanford Site in 2022 to evaluate (a) the types of nitrogen species currently in the vadose zone and (b) the migration of nitrogen species in the vadose zone. Ammonia and tritium from PUREX decladding condensate were sporadically discharged to the crib from 1977 to 1989. During discharge operations, the estimated travel time through the vadose zone to groundwater was 2.5 to 9 months. By 2003, a characterization borehole (C4106) showed residual pore water with elevated tritium and nitrate in the first 100 ft of the vadose zone, which is likely from the crib. However, there was significantly more nitrate present at the shallowest depth (15 to 22 ft), which may indicate a different source for nitrate, such as adsorbed ammonia slowly being oxidized or nitrogen species precipitates slowly dissolving. In this study, more extensive nitrogen species characterization was done on D0220 cores (drilled in 2022) at 40- and 262-ft depths, which included (a) aqueous nitrate, nitrite, and tritium; (b) adsorbed ammonia; (c) nitrogen in carbonates (or other minerals dissolved in acidic acid); (d) nitrogen in iron oxides (or other minerals dissolved in oxalic acid); and (e) nitrogen in hard-to-extract minerals (minerals dissolved in nitric acid). High pore water nitrate (226 to 331 mg/L) at 40-ft depth measured in D0220 (2022) compared to 60 mg/L at 40-ft depth in C4106 (2003) may indicate nitrate is migrating deeper. Tritium concentrations (pore water 132,000 to 148,000 pCi/L) measured in D0220 at 40-ft depth in 2022 were considerably higher than in C4106 at 40-ft depth (160 pCi/L). Additional nitrogen species mass was present in adsorbed and precipitated phases in D0220 cores. Low adsorbed ammonia was measured at 40.1- and 261.7-ft depths. Low concentrations of carbonate associated nitrogen and iron oxide-associated nitrogen were present at 40.1 and 40.6 ft depths. Nitrogen species in solid phase extractions indicate nitrogen precipitates or aqueous nitrate or ammonia trapped in sediment microfractures that are coated by precipitates. Overall, the nitrogen species and tritium characterization at two depths in D0220 showed that additional nitrogen species were present in the vadose zone. In addition, elevated pore water nitrate in D0220 at 40 ft depth from 2022 may indicate vertical migration compared to C4106 nitrate profile from 2003. Analysis of additional depths in D0220 and spatial variability of the nitrate plume along the length of the crib (from surface electrical resistivity) would be extremely useful for this comparison.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Stereo Camera Deployment in Support of TRACER (Field Campaign Report)

An improved understanding of the salient environmental controls on cloud formation, evolution, and eventual dissipation is critical to address ongoing challenges with cloud process and parameterization representations in global climate and Earth system models. One goal for the recent U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Tracking Aerosol Convection Interactions Experiment (TRACER) campaign was to collect a comprehensive data set that enabled such convective cloud process studies and key demonstrations for those controls that influenced cloud life cycle (i.e., aerosols, thermodynamics) in the Houston, Texas region. To help accomplish this, ARM instrumentation during TRACER was tasked with tracking a large number of individual, isolated convective cells – and to follow the evolution of these cells at high spatiotemporal resolution to characterize changes in cloud dynamic and microphysical properties. Since Houston experiences a range of convective clouds, it was known that the standard ARM Mobile Facility (AMF) instruments may not be sufficient to completely document initiating, transient, or dissipating low- or shallow-cloud behaviors that were also expected during this campaign (in terms of sensitivity, resolution, and/or operational availability). As one partial solution, a supplemental stereo camera deployment (this sub-campaign) was requested to augment the ARM AMF instrumentation to better address shallow and shallow-to-deep transitional types of cloud process drivers during TRACER (ARM stereo cameras for clouds [STEREOCAM]; Romps and Öktem 2018). The primary scientific focus was the relationships between cloud properties and the ambient conditions, which points to several key TRACER science questions including: ‘What is the relationship between cloud size or updraft intensity to the environmental wind shear and/or humidity?’ Overall, the ARM TRACER stereo camera deployment demonstrated unique effectiveness in observing a wide range of critical shallow, congestus, and transitioning or time-evolving cloud characteristics. The data sets from these cameras include information on the clouds' horizontal dimensions, elevations, and depths, while also enabling potential products for cloud initiation and dissipation rates, and vertical velocities. Stereo cameras simultaneously inform on cloud life cycle stage and spatial properties such as cloud fractional coverage, which should provide complementary information for ARM users when combined with TRACER cloud radars, lidar, and/or other profiling sensors. Moreover, camera products offer large-eddy simulation (LES),-scale-appropriate cloud coverage, depth, and spatial variability estimates, while opening additional avenues to challenge difficult process questions on cloud updrafts/entrainment and their covariability with environmental controls such as wind shear and humidity.

47 OTHER INSTRUMENTATION↗

Myriad World Baseline: Global Geodemographic Estimates

The LandScan Myriad World Baseline (MWB) method produces global, residential (nighttime/home-location) gridded geodemographic estimates based on 5-year age/gender cohorts—at 30-arcsecond (≈1 km) resolution. MWB is designed to fill gaps where detailed, georeferenced survey data (e.g., Demographic and Health Surveys (DHS)) are missing or outdated, and to provide a baseline that can support human security analysis, including consequence assessment, “patterns of life” modeling, and scenario-based population futures. MWB’s workflow spatializes household-level age/gender characteristics from the GLOPOP-S dataset by conflating household and gridded expected relative wealth adapted from Global Gridded Relative Deprivation Index (GRDI), then adjusts them to a target year of interest. Age/gender estimates are then applied to harmonize lowest-administrative-level statistics with LandScan residential counts, yielding final geodemographic estimates. Two validation case studies are presented: Ghana (2021) and Tokyo/Kanagawa, Japan (2020), illustrating spatial variability in demographic cohorts and comparing MWB outputs to official gridded statistics. Results show close overall alignment relative to validation criteria including population pyramids and age-dependency ratios.

Tuccillo, Joe [ORNL] (ORCID:0000000259300943)↗

Site B - NREL ASSIST (SN11) Thermodynamic Retrievals TROPoe / Derived Data

This dataset contains daily files with thermodynamic profiles retrieved with the optimal estimation physical retrieval TROPoe v0.12 (Turner and Löhnert 2014; Turner and Blumberg 2019; Turner and Löhnert 2021). The profiles are retrieved every 10 minutes from instantaneous observations from the NREL ASSIST-II (SN 11) infrared spectrometer. Observations are noise-filtered but not averaged in time to minimize errors due to non-uniform clouds. Additional input data in TROPoe are cloud base height (CBH), which is a combined data product that uses data from ceilometers at sites A1 and H and scanning lidars from ARM sites C1 and E37. The CBH is weighted inversely proportionally to the distance to the respective site to take into account the spatial variability of clouds (see https://github.com/StefanoWind/ASSIST_analysis/blob/main/awaken_processing/combine_cbh.py). The full pipeline for running the retrieval is available at https://github.com/StefanoWind/TROPoe_processor. Met data was not ingested. In addition to these temporally resolved input data, TROPoe requires an a priori dataset (prior) that provides mean climatological estimates of thermodynamic profiles and specifies how temperature and humidity covary with height as an input (for details see, e.g., Djalalova et al. 2022). The prior is a key component of the retrieval and provides a constraint on the ill-posed inversion problem. A monthly prior was computed from operational radiosonde launches at ARM SGP, OK.

17 WIND ENERGY↗

Site G - NREL ASSIST (SN10) Thermodynamic Retrievals TROPoe / Derived Data

This dataset contains daily files with thermodynamic profiles retrieved with the optimal estimation physical retrieval TROPoe v0.12 (Turner and Löhnert 2014; Turner and Blumberg 2019; Turner and Löhnert 2021). The profiles are retrieved every 10 minutes from instantaneous observations from the NREL ASSIST-II (SN 10) infrared spectrometer. Observations are noise-filtered but not averaged in time to minimize errors due to non-uniform clouds. Additional input data in TROPoe are cloud base height (CBH), which is a combined data product that uses data from ceilometers at sites A1 and H and scanning lidars from ARM sites C1 and E37. The CBH is weighted inversely proportionally to the distance to the respective site to take into account the spatial variability of clouds (see https://github.com/StefanoWind/ASSIST_analysis/blob/main/awaken_processing/combine_cbh.py). The full pipeline for running the retrieval is available at https://github.com/StefanoWind/TROPoe_processor. Met data was not ingested. In addition to these temporally resolved input data, TROPoe requires an a priori dataset (prior) that provides mean climatological estimates of thermodynamic profiles and specifies how temperature and humidity covary with height as an input (for details see, e.g., Djalalova et al. 2022). The prior is a key component of the retrieval and provides a constraint on the ill-posed inversion problem. A monthly prior was computed from operational radiosonde launches at ARM SGP, OK.

17 WIND ENERGY↗

Site C1a - NREL ASSIST (SN12) Thermodynamic Retrievals TROPoe / Derived Data

This dataset contains daily files with thermodynamic profiles retrieved with the optimal estimation physical retrieval TROPoe v0.12 (Turner and Löhnert 2014; Turner and Blumberg 2019; Turner and Löhnert 2021). The profiles are retrieved every 10 minutes from instantaneous observations from the NREL ASSIST-II (SN 12) infrared spectrometer. Observations are noise-filtered but not averaged in time to minimize errors due to non-uniform clouds. Additional input data in TROPoe are cloud base height (CBH), which is a combined data product that uses data from ceilometers at sites A1 and H and scanning lidars from ARM sites C1 and E37. The CBH is weighted inversely proportionally to the distance to the respective site to take into account the spatial variability of clouds (see https://github.com/StefanoWind/ASSIST_analysis/blob/main/awaken_processing/combine_cbh.py). The full pipeline for running the retrieval is available at https://github.com/StefanoWind/TROPoe_processor. Met data was not ingested. In addition to these temporally resolved input data, TROPoe requires an a priori dataset (prior) that provides mean climatological estimates of thermodynamic profiles and specifies how temperature and humidity covary with height as an input (for details see, e.g., Djalalova et al. 2022). The prior is a key component of the retrieval and provides a constraint on the ill-posed inversion problem. A monthly prior was computed from operational radiosonde launches at ARM SGP, OK.

17 WIND ENERGY↗

Enhanced Multi-Dimensional Inversion Through Target-Specific Inversion Parameter Bounds With an Application to Crosswell Electromagnetic for Sequestration Monitoring

In geophysical inversions, lower and upper model parameter bounds are a means of solution stabilization. Further, constraints that intend to let only geologically plausible inverse solutions pass are amenable to lower and upper bounds. Reliable prior information is paramount to construct such bound constraints. It is common practice to narrow and widen bound intervals for regions of, respectively, more and less certain prior information. Contrary to this practice, we experiment with widened bound intervals in zones that are poorly resolved by a given survey configuration but where prior information would suggest structural anomalies of interest. The purpose of enlarged parameter bounds that correlate spatially with predefined targets is to let the inversion explore a larger solution space, thus increasing the potential to resolve otherwise hidden anomalies. Application of the method is based on a carbon-sequestration baseline (pre-injection) crosswell electromagnetic (EM) field survey at the Containment and Monitoring Institute Field Research Station (Alberta, Canada), where impeded measurements led to generally reduced sensitivities for the interwell region. Synthetic-data proofs of concept use augmented bounds designed to boost the resolution of artificial plume targets, indicating an enhanced illumination compared to constant bounds. Comparative field data inversions with spatially variable bounds constructed from prior resistivity and velocity information highlight non-horizontal baseline structures.

3-D electrical resistivity imaging↗

Hyperspectral segmentation of plants in fabricated ecosystems

Hyperspectral imaging provides a powerful tool for analyzing above-ground plant characteristics in fabricated ecosystems, offering rich spectral information across diverse wavelengths. This study presents an efficient workflow for hyperspectral data segmentation and subsequent data analytics, minimizing the need for user annotation through the use of ensembles of sparse mixed scale convolution neural networks. The segmentation process leverages the diversity of ensembles to achieve high accuracy with minimal labeled data, reducing labor-intensive annotation efforts. To further enhance robustness, we incorporate image alignment techniques to address spatial variability in the dataset. Downstream analysis focuses on using the segmented data for processing spectral data, enabling monitoring of plant health. This approach provides a scalable solution for spectral segmentation, and facilitates actionable insights into plant conditions in complex, controlled environments. Our results demonstrate the utility of combining advanced machine learning techniques with hyperspectral analytics for high-throughput plant monitoring.

Zwart, Petrus H.↗

Temporal, Spatial, and Temperature Controls on Organic Carbon Mineralization and Methanogenesis in Arctic High-Centered Polygon Soils

Warming temperatures in continuous permafrost zones of the Arctic will alter both hydrological and geochemical soil conditions, which are strongly linked with heterotrophic microbial carbon (C) cycling. Heterogeneous permafrost landscapes are often dominated by polygonal features formed by expanding ice wedges: water accumulates in low centered polygons (LCPs), and water drains outward to surrounding troughs in high centered polygons (HCPs). These geospatial differences in hydrology cause gradients in biogeochemistry, soil C storage potential, and thermal properties. Presently, data quantifying carbon dioxide (CO 2 ) and methane (CH 4 ) release from HCP soils are needed to support modeling and evaluation of warming-induced CO 2 and CH 4 fluxes from tundra soils. This study quantifies the distribution of microbial CO 2 and CH 4 release in HCPs over a range of temperatures and draws comparisons to previous LCP studies. Arctic tundra soils were initially characterized for geochemical and hydraulic properties. Laboratory incubations at −2, +4, and +8°C were used to quantify temporal trends in CO 2 and CH 4 production from homogenized active layer organic and mineral soils in HCP centers and troughs, and methanogen abundance was estimated from mcrA gene measurements. Results showed that soil water availability, organic C, and redox conditions influence temporal dynamics and magnitude of gas production from HCP active layer soils during warming. At early incubation times (2–9 days), higher CO 2 emissions were observed from HCP trough soils than from HCP center soils, but increased CO 2 production occurred in center soils at later times (>20 days). HCP center soils did not support methanogenesis, but CH 4 -producing trough soils did indicate methanogen presence. Consistent with previous LCP studies, HCP organic soils showed increased CO 2 and CH 4 production with elevated water content, but HCP trough mineral soils produced more CH 4 than LCP mineral soils. HCP mineral soils also released substantial CO 2 but did not show a strong trend in CO 2 and CH 4 release with water content. Knowledge of temporal and spatial variability in microbial C mineralization rates of Arctic soils in response to warming are key to constraining uncertainties in predictive climate models.

59 BASIC BIOLOGICAL SCIENCES↗

Investigating a Renewable-Resource-Targeting Mobile Aquaculture System Using Route Optimization Based on Optimal Foraging Theory

Aquaculture systems require careful consideration of location, which determines water conditions, pollution impacts, and hazardous conditions. Mobility may be able to address these factors while also supporting the targeting of renewable energy sources such as wind, wave, and solar power throughout the year. In this paper, a purpose-built mobile aquaculture ship is identified and modeled with a combination of renewable energy harvesting capabilities as a case study with the objective of assessing the potential benefits of targeting high renewable energy potentials to power aquaculture operations. A route optimization algorithm is created and tuned to simulate the mobility of the aquaculture platform and cost-basis comparisons are made to a stationary system. The small spatial variability in renewable energy potential when combining multiple resources significantly limits the benefits of a mobile, renewable-targeting aquaculture system. On the other hand, the consistent energy harvest from a blend of renewable energy types (13 kW installed wind capacity, 661 m 2 installed solar, and 1 m characteristic width wave-energy converter) suggests that the potential benefits of a mobile platform for offshore aquaculture (mitigation of environmental and social concerns, any potential positive impact on yields, hazard avoidance, etc.) can likely be pursued without significant increases in energy harvester costs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

How Austenitic Is a Martensitic Steel Produced by Laser Powder Bed Fusion? A Cautionary Tale

Accurate phase fraction analysis is an essential element of the microstructural characterization of alloys and often serves as a basis to quantify effects such as heat treatment or mechanical deformation. Additive manufacturing (AM) of metals, due to the intrinsic nonequilibrium solidification and spatial variability, creates additional challenges for the proper quantification of phase fraction. Such challenges are exacerbated when the alloy itself is prone to deformation-induced phase transformation. Using commonly available in-house X-ray diffraction (XRD) and electron backscatter diffraction (EBSD) and less commonly used synchrotron-based high-energy X-ray diffraction, we characterized nitrogen-atomized 17-4 precipitation-hardening martensitic stainless steel, a class of AM alloy that has received broad attention within the AM research community. On the same build, our measurements recovered the entire range of reported values on the austenite phase fractions of as-built AM 17-4 in literature, from ≈100% martensite to ≈100% austenite. Aided by Calphad simulation, our experimental findings established that our as-built AM 17-4 is almost fully austenitic and that in-house XRD and EBSD measurements are subject to significant uncertainties created by the specimen’s surface finish. Hence, measurements made using these techniques must be understood in their correct context. Our results carry significant implications, not only to AM 17-4 but also to AM alloys that are susceptible to deformation-induced structure transformation and suggest that characterizations with less accessible but bulk sensitive techniques such as synchrotron-based high energy X-ray diffraction or neutron diffraction may be required for proper understanding of these materials.

17-4 steel↗

Classification of Wetland Vegetation Based on NDVI Time Series from the HLS Dataset

Natural wetlands are intrinsically heterogeneous and typically composed of a mosaic of ecosystem patches with different vegetation types. Hydrological and biogeochemical processes in wetlands vary strongly among these ecosystem patches. To date, most remote sensing classification approaches for wetland vegetation either rely on coarse images that cannot capture the spatial variability of wetland vegetation or rely on very-high-resolution multi-spectral images that are detailed but very sporadic in time (less than once per year). This study aimed to use NDVI time series, generated from NASA’s HLS dataset, to classify vegetation patches. We demonstrate our approach at a temperate, coastal lake, estuarine marsh. To classify vegetation patches, a standard time series library of the four land-cover patch types was built from referencing specific locations that were identified as “pure” pixels. These were identified using a single-time high-resolution image. We calculated the distance between the HLS-NDVI time series at each pixel and the “pure”-pixel standards for each land-cover type. The resulting true-positive classified rate was >73% for all patch types other than water lily. The classification accuracy was higher in pixels of a more uniform composition. A set of vegetation maps was created for the years 2016 to 2020 at our research site to identify the vegetation changes at the site as it is affected by rapid water elevation increases in Lake Erie. Our results reveal how changes in water elevation have changed the patch distribution in significant ways, leading to the local extinction of cattail by 2019 and a continuous increase in the area cover of water lily patches.

54 ENVIRONMENTAL SCIENCES↗