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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

r-Process Radioisotopes from Near-Earth Supernovae and Kilonovae

The astrophysical sites where r-process elements are synthesized remain mysterious: it is clear that neutron star mergers (kilonovae (KNe)) contribute, and some classes of core-collapse supernovae (SNe) are also possible sources of at least the lighter r-process species. The discovery of 60Fe on the Earth and Moon implies that one or more astrophysical explosions have occurred near the Earth within the last few million years, probably SNe. Intriguingly, 244 Pu has now been detected, mostly overlapping with 60 Fe pulses. However, the 244 Pu flux may extend to before 12 Myr ago, pointing to a different origin. Here, motivated by these observations and difficulties for r-process nucleosynthesis in SN models, we propose that ejecta from a KN enriched the giant molecular cloud that gave rise to the Local Bubble, where the Sun resides. Accelerator mass spectrometry (AMS) measurements of 244 Pu and searches for other live isotopes could probe the origins of the r-process and the history of the solar neighborhood, including triggers for mass extinctions, e.g., that at the end of the Devonian epoch, motivating the calculations of the abundances of live r-process radioisotopes produced in SNe and KNe that we present here. Given the presence of 244 Pu, other r-process species such as 93 Zr, 107 Pd, 129 I, 135 Cs, 182 Hf, 236 U, 237 Np, and 247 Cm should be present. Their abundances and well-resolved time histories could distinguish between the SN and KN scenarios, and we discuss prospects for their detection in deep-ocean deposits and the lunar regolith. We show that AMS 129 I measurements in Fe–Mn crusts already constrain a possible nearby KN scenario.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1998

Numerical Simulation of Combustion and Extinction of a Solid Cylinder in Low-Speed Cross Flow

The combustion and extinction behavior of a diffusion flame around a solid fuel cylinder (PMMA) in low-speed forced flow in zero gravity was studied numerically using a quasi-steady gas phase model. This model includes two-dimensional continuity, full Navier Stokes' momentum, energy, and species equations with a one-step overall chemical reaction and second-order finite-rate Arrhenius kinetics. Surface radiation and Arrhenius pyrolysis kinetics are included on the solid fuel surface description and a parameter Phi, representing the percentage of gas-phase conductive heat flux going into the solid, is introduced into the interfacial energy balance boundary condition to complete the description for the quasi-steady gas-phase system. The model was solved numerically using a body-fitted coordinate transformation and the SIMPLE algorithm. The effects of varying freestream velocity and Phi were studied. These parameters have a significant effect on the flame structure and extinction limits. Two flame modes were identified: envelope flame and wake flame. Two kinds of flammability limits were found: quenching at low-flow speeds due to radiative loss and blow-off at high flow speeds due to insufficient gas residence time. A flammability map was constructed showing the existence of maximum Phi above which the solid is not flammable at any freestream velocity.

Tien, J. S.↗
NASA NTRS1989

Diffuse interstellar clouds as a chemical laboratory - The chemistry of diatomic carbon species

The chemistry of C2, CH, and CO in diffuse interstellar clouds is analyzed and compared to absorption line measurements toward background stars. Analytical expressions in terms of column densities are derived for the rate equations. The results indicate that in clouds with 4 mag of visual extinction, the abundance of C+ has to decrease by a factor of about 15 from the value traditionally used for clouds with 1 mag of extinction. The rate coefficients for the reactions C+ + CH - C2+ + H and C+ + H2 - CH2+ + h-nu need to be reduced from previous estimates. Chemical arguments are presented for the revised rate coefficients.

Federman, S. R.↗
NASA NTRS1996

Paleobiology, community ecology, and scales of ecological pattern

The fossil record provides a wealth of data on the role of regional processes and historical events in shaping biological communities over a variety of time scales. The Quaternary record with its evidence of repeated climatic change shows that both terrestrial and marine species shifted independently rather than as cohesive assemblages over scales of thousands of years. Larger scale patterns also show a strong individualistic component to taxon dynamics; assemblage stability, when it occurs, is difficult to separate from shared responses to low rates of environmental change. Nevertheless, the fossil record does suggest that some biotic interactions influence large-scale ecological and evolutionary patterns, albeit in more diffuse and protracted fashions than those generally studied by community ecologists. These include: (1) the resistance by incumbents to the establishment of new or invading taxa, with episodes of explosive diversification often appearing contingent on the removal of incumbents at extinction events; (2) steady states of within-habitat and global diversity at longer time scales (10(7)-l0(8) yr), despite enormous turnover of taxa; and (3) morphological and biogeographic responses to increased intensities of predation and substratum disturbance over similarly long time scales. The behavior of species and communities over the array of temporal and spatial scales in the fossil record takes on additional significance for framing conservation strategies, and for understanding recovery of species, lineages, and communities from environmental changes.

NASA Discipline Exobiology↗
NASA NTRS1993

Tropospheric gas composition and cloud structure of the Jovian North Equatorial Belt

Voyager IRIS observations of the NEB reveal longitudinal variability of 5-micron brightness temperatures of order 100 C. An anisotropic multiple scattering radiative transfer model is used to calculate synthetic spectra for comparison with the IRIS observations. Mie theory is used to model the spectral dependence of cloud extinction from 180 to 2300/cm. Cloud base locations within the model vary with assumed gas abundances according to thermochemical equilibrium. It is found that spatial variations in the abundance profiles of the condensible species, parahydrogen profiles and cloud optical depths can be used as tracers of the local and large-scale dynamics. The variation of cloud opacity is strongly correlated with the variation of relative humidity, which suggests that dynamic depletion of water vapor above the cloud forming level is the most plausible model to explain the spatial variation in the water profile within the NEB.

Carlson, Barbara E.↗
NASA NTRS1986

Lidar method of measurement of atmospheric extinction and ozone profiles

A description of a method of measurement of atmospheric extinction and of ozone profiles by use of the backscatter signal from a monostatic lidar is given. The central feature of the procedure involves a measurement of the ratio of the Raman backscatter returns of both the oxygen and nitrogen atmospheric content. Because the ratio of the number density of both species is known to high accuracy, the measurement itself becomes a measure of the ratio of two transmissions to altitude along with a ratio of the two system constants. The calibration measurement for determining the value of the ratio of the two system constants or electro-optical conversion constants is accomplished by a lidar measurement of identical atmospheric targets while at the same time interchanging the two optical filters in the two optical channels of the receiver. More details of the procedure are discussed. Factoring this calibrated value into the measured O2/N2 profile ratio provides a measured value of the ratio of the two transmissions. Or equivalently, it provides a measurement of the difference of the two extinction coefficients at the O2 and N2 Raman wavelengths as a function of the height.

Cooney, J. A.↗
NASA NTRS1999

Computational and Experimental Study of Energetic Material in a Counterflow Microgravity Environment

Ground based (normal gravity) combustion studies can provide important information on the processes by which monopropellants and composite systems burn. The effects of gravitational forces, however, can often complicate the interpretation of the models and the implementation of experiments designed to help elucidate complex issues. We propose to utilize a combined computational/experimental approach in a microgravity environment to understand the interaction of oxidizer-binder diffusion flames in composite propellants. By operating under microgravity conditions we will be able to increase the length scales and suppress the gravitational forces on melting binders such that increased resolution of both major and minor species will be possible thus reducing the demands placed on both the computational and diagnostic tools. Results of a detailed transport/finite rate chemistry model will be compared with nonintrusive optical diagnostic measurements of the structure and extinction of diffusion flames in which oxidizers such as ammonium perchlorate (AP) and ammonium dinitramide (ADN) are counterflowed against realistic binders such as hydroxyl-terminated polybutadiene (HTPB) and 3,3-bis(azidomethyl)oxetane (BAMO). The work proposed herein represents a collaborative effort among the research groups at Yale University, Princeton University and the Combustion Diagnostics Laboratory at the Naval Air Warfare Center in China Lake, CA.

Smooke, Mitchell D.↗
NASA NTRS1985

A search for evidence of large body Earth impacts associated with biological crisis zones in the fossil record

The natural history of the Earth, how the present plant and animal species developed, how others completely died out, etc., was studied. The rock strata sampled and studied were at the time of deposition at sea bottom. It was found that, exactly at the stratigraphic level corresponding to the extinction, a thin clay layer was greatly enriched in the the rare element iridium. It was hypothesized that the excess irridium at the boundary came from a large steroid like object that hit the earth, and that the impact of this object threw up a dust cloud dense enough and long lasting enough to bring about the extinction of a wide variety of plants and animals, producing the unique break in in the fossil record, the cretaceous-tertiary boundary. The same iridium and platinum metals enrichement are found in a thin clay layer that corresponds with the boundary as difined by sudden radical changes in plant populations. The irridium enrichement is confirmed at other fresh water origin rites in the Raton Basin.

Orth, C. J.↗
NASA NTRS1988

Photochemical modeling of the Antarctic stratosphere: Observational constraints from the airborne Antarctic ozone experiment and implications for ozone behavior

The rapid decrease in O3 column densities observed during Antarctic spring has been attributed to several chemical mechanisms involving nitrogen, bromine, or chlorine species, to dynamical mechanisms, or to a combination of the above. Chlorine-related theories, in particular, predict greatly elevated concentrations of ClO and OClO and suppressed abundances of NO2 below 22 km. The heterogeneous reactions and phase transitions proposed by these theories could also impact the concentrations of HCl, ClNO3 and HNO3 in this region. Observations of the above species have been carried out from the ground by the National Ozone Expedition (NOZE-I, 1986, and NOZE-II, 1987), and from aircrafts by the Airborne Antarctic Ozone Experiment (AAOE) during the austral spring of 1987. Observations of aerosol concentrations, size distribution and backscattering ratio from AAOE, and of aerosol extinction coefficients from the SAM-II satellite can also be used to deduce the altitude and temporal behavior of surfaces which catalyze heterogeneous mechanisms. All these observations provide important constraints on the photochemical processes suggested for the spring Antarctic stratosphere. Results are presented for the concentrations and time development of key trace gases in the Antarctic stratosphere, utilizing the AER photochemical model. This model includes complete gas-phase photochemistry, as well as heterogeneous reactions. Heterogeneous chemistry is parameterized in terms of surface concentrations of aerosols, collision frequencies between gas molecules and aerosol surfaces, concentrations of HCl/H2O in the frozen particles, and probability of reaction per collision (gamma). Values of gamma are taken from the latest laboratory measurements. The heterogeneous chemistry and phase transitions are assumed to occur between 12 and 22 km. The behavior of trace species at higher altitudes is calculated by the AER 2-D model without heterogeneous chemistry. Calculations are performed for solar illumination conditions typical of 60, 70, and 80 S, from July 15 to October 31.

Rodriguez, Jose M.↗
NASA NTRS2005

Effects of Aerosol on Atmospheric Dynamics and Hydrologic Processes during Boreal Spring and Summer

Global and regional climate impacts of present-day aerosol loading during boreal spring are investigated using the NASA finite volume General Circulation Model (fvGCM). Three-dimensional distributions of loadings of five species of tropospheric aerosols, i.e., sulfate, black carbon, organic carbon, soil dust, and sea salt are prescribed from outputs of the Goddard Ozone Chemistry Aerosol Radiation and Transport model (GOCART). The aerosol loadings are used to calculate the extinction coefficient, single scattering albedo, and asymmetric factor at eleven spectral wavelengths in the radiative transfer code. We find that aerosol-radiative forcing during boreal spring excites a wavetrain-like pattern in tropospheric temperature and geopotential height that emanates from Northern Africa, through Eurasia, to northeastern Pacific. Associated with the teleconnection is strong surface cooling over regions with large aerosol loading, i.e., China, India, and Africa. Low-to-mid tropospheric heating due to shortwave absorption is found in regions with large loading of dust (Northern Africa, and central East Asia), and black carbon (South and East Asia). In addition pronounced surface cooling is found over the Caspian Sea and warming over Eurasian and northeastern Asia, where aerosol loadings are relatively low. These warming and cooling are components of teleconnection pattern produced primarily by atmospheric heating from absorbing aerosols, i.e., dust from North Africa and.black carbon from South and East Asia. Effects of aerosols on atmospheric hydrologic cycle in the Asian monsoon region are also investigated. Results show that absorbing aerosols, i.e., black carbon and dust, induce large-scale upper-level heating anomaly over the Tibetan Plateau in April and May, ushering in an early onset of the Indian summer monsoon. Absorbing aerosols also enhance lower-level heating and anomalous ascent over northern India, intensifying the Indian monsoon. Overall, the aerosol-induced large-scale surface temperature cooling leads to a reduction of monsoon rainfall over the East Asia continent, and adjacent oceanic regions.

Lau, William K. M.↗
NASA NTRS2005

Effects of Aerosol on Atmospheric Dynamics and Hydrologic Processes During Boreal Spring and Summer

Global and regional climate impacts of present-day aerosol loading during boreal spring are investigated using the NASA finite volume General Circulation Model (fvGCM). Three-dimensional distributions of loadings of five species of tropospheric aerosols, i.e., sulfate, black carbon, organic carbon, soil dust, and sea salt are prescribed from outputs of the Goddard Ozone Chemistry Aerosol Radiation and Transport model (GOCART). The aerosol loadings are used to calculate the extinction coefficient, single scattering albedo, and asymmetric factor at eleven spectral wavelengths in the radiative transfer code. We find that aerosol-radiative forcing during boreal spring excites a wavetrain-like pattern in tropospheric temperature and geopotential height that emanates from Northern Africa, through Eurasia, to northeastern Pacific. Associated with the teleconnection is strong surface cooling over regions with large aerosol loading, i.e., China, India, and Africa. Low-to-mid tropospheric heating due to shortwave absorption is found in regions with large loading of dust (Northern Africa, and central East Asia), and black carbon (South and East Asia). In addition pronounced surface cooling is found over the Caspian Sea and warming over Eurasian and northeastern Asia, where aerosol loadings are relatively low. These warming and cooling are components of teleconnection pattern produced primarily by atmospheric heating from absorbing aerosols, i.e., dust from North Africa and black carbon from South and East Asia. Effects of aerosols on atmospheric hydrologic cycle in the Asian monsoon region are also investigated. Results show that absorbing aerosols, i.e., black carbon and dust, induce large-scale upper-level heating anomaly over the Tibetan Plateau in April and May, ushering in an early onset of the Indian summer monsoon. Absorbing aerosols also enhance lower-level heating and anomalous ascent over northern India, intensifying the Indian monsoon. Overall, the aerosol-induced large-scale surface tempera- cooling leads to a reduction of monsoon rainfall over the East Asia continent, and adjacent oceanic regions.

Lau, William K. M.↗
NASA NTRS1992

A comparison of lidar inversion methods for cirrus applications

Several methods for inverting the lidar equation are suggested as means to derive the cirrus optical properties (beta backscatter, alpha extinction coefficients, and delta optical depth) at one wavelength. The lidar equation can be inverted in a linear or logarithmic form; either solution assumes a linear relationship: beta = kappa(alpha), where kappa is the lidar ratio. A number of problems prevent us from calculating alpha (or beta) with a good accuracy. Some of these are as follows: (1) the multiple scattering effect (most authors neglect it); (2) an absolute calibration of the lidar system (difficult and sometimes not possible); (3) lack of accuracy on the lidar ratio k (taken as constant, but in fact it varies with range and cloud species); and (4) the determination of boundary condition for logarithmic solution which depends on signal to noise ration (SNR) at cloud top. An inversion in a linear form needs an absolute calibration of the system. In practice one uses molecular backscattering below the cloud to calibrate the system. This method is not permanent because the lower atmosphere turbidity is variable. For a logarithmic solution, a reference extinction coefficient (alpha(sub f)) at cloud top is required. Several methods to determine alpha(sub f) were suggested. We tested these methods at low SNR. This led us to propose two new methods referenced as S1 and S2.

Elouragini, Salem↗
DOE OSTI2021

Increasing temperature weakens the positive effect of genetic diversity on population growth

Abstract Genetic diversity and temperature increases associated with global climate change are known to independently influence population growth and extinction risk. Whether increasing temperature may influence the effect of genetic diversity on population growth, however, is not known. We address this issue in the model protist system Tetrahymena thermophila . We test the hypothesis that at temperatures closer to the species’ thermal optimum (i.e., the temperature at which population growth is maximal, or T opt ), genetic diversity should have a weaker effect on population growth compared to temperatures away from the thermal optimum. To do so, we grew populations of T . thermophila with varying levels of genetic diversity at increasingly warmer temperatures and quantified their intrinsic population growth rate, r . We found that genetic diversity increases population growth at cooler temperatures, but that as temperature increases, this effect weakens. We also show that a combination of changes in the amount of expressed genetic diversity (G) in r , plastic changes in population growth across temperatures (E), and strong G × E interactions underlie this temperature effect. Our results uncover important but largely overlooked temperature effects that have implications for the management of small populations with depauperate genetic stocks in an increasingly warming world.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1994

Nebular properties from far-infrared spectrosopy

We describe a semiempirical methodology-based on measurements of far-infrared (FIR) lines-that yields information on electron densities in regions where various ionic species exist, effective temperatures (T(sub eff)) for stars ionizing H II regions, and gas-phase heavy element abundances. Although this capability has long been available via optical data, the special features of FIR lines-relative insensitivity to extinction and electron temperature variations-extend the analysis ability. Several line ratios serve as diagnostics of electron density, N(sub e), probing different ionization conditions and different density regimes. The more N(sub e)-diagnostic observations made, the more reliable will be the deciphering of the actual variation in density throughout a nebula. A method to estimate T(sub eff) from the FIR (N III)/(N II) line ratio requires that the nebula be ionization bounded and that substantially all of the flux from the revevant lines be observed. However, to estimate T(sub eff) by a second method that uses the ratio of FIR (S III)/(O III) lines, an ionization-bounded nebula is a sufficient, but not necessary, condition. These restrictions are unnecessary for estimating densities and heavy element abundances. We show that a fairly general determination of metallicity, via the S/H ratio, may be made for H II regions with observations of just two lines-(S III) 19 micron and a hydrogen recombination line (or appropriate substitute). These techniques are applied to recent FIR data for the G333.6-0.2 H II region, including application to the recently measured (N II) 122 and 205 micron lines.

Rubin, Robert H.↗
NASA NTRS1998

Silicate Mineralogy of the Dust in the Inner Coma of Comet C/1995 01 (Hale-Bopp) Pre- and Post-Perihelion

We present 7.6 - 13.3 microns infrared (IR) spectrophotometry (R approx. = 180 - 350) of the 10 microns silicate emission from dust in the inner coma (i.e., within a diameter of 3in.) of comet C/1995 O1 (Hale-Bopp) at four temporal epochs from 1996 October through 1997 June during Hale-Bopp s approach to, arrival at, and recession from perihelion. The HIFOGS spectra at large heliocentric distances exhibit strong emission peaks from 9.9 - 10.1 microns and at 11.2 microns. The HIFOGS spectra of Hale-Bopp taken 1996 October 07 - 14 UT are identical in shape to the ISO SWS spectrum at 2.8 AU obtained on 1996 October 06 UT. Magnesium-rich olivine was unambiguously identified due to presence of the expected 11.2 microns peak along with the matching far-IR 18 microns, 23 microns, and 33 microns peaks in the ISO SWS spectrum. In contrast, to large heliocentric distances, we find that the silicate feature at small heliocentric distances (tau(sub lambda) less than or = 1.7 AU) exhibits strong peaks at 9.3 microns, 9.9 - 10.1 microns, and 11.2 microns, and weak at 10.5 microns and 11.8 microns. We will show that the dramatic increase of the 9.3 microns and 10.0 microns peaks close to perihelion leads to the hypothesis that there are two crystalline grain components with significantly different temperatures. The hotter mineral species (including olivines) radiate over a large range of heliocentric distances at detectable leve!s. The cooler mineral species (pyroxenes) radiate on the Wien side of the blackbody, too faint to detect in the mid-infrared spectra, until close to the sun when this species radiates on the Reyleigh-Jeans tail and becomes apparent. Decomposition of the observed silicate emission features into mineral components through comparison of the height and shape of the silicate feature ("Flux/cont") derived from the cometary spectra, to optical extinctions (Qext) derived from laboratory measurements of terrestrial silicate minerals and interplanetary dust particles (IDPs) is successful for a combination of warm grains (consisting of olivines, amorphous olivines, amorphous pyroxenes, and layer-lattice silicates) and cool grains (crystalline pyroxenes).

Wooden, Diane H.↗
NASA NTRS2004

Mars chronology: assessing techniques for quantifying surficial processes

Currently, the absolute chronology of Martian rocks, deposits and events is based mainly on crater counting and remains highly imprecise with epoch boundary uncertainties in excess of 2 billion years. Answers to key questions concerning the comparative origin and evolution of Mars and Earth will not be forthcoming without a rigid Martian chronology, enabling the construction of a time scale comparable to Earth's. Priorities for exploration include calibration of the cratering rate, dating major volcanic and fluvial events and establishing chronology of the polar layered deposits. If extinct andor extant life is discovered, the chronology of the biosphere will be of paramount importance. Many radiometric and cosmogenic techniques applicable on Earth and the Moon will apply to Mars after certain baselines (e.g. composition of the atmosphere, trace species, chemical and physical characteristics of Martian dust) are established. The high radiation regime may pose a problem for dosimetry-based techniques (e.g. luminescence). The unique isotopic composition of nitrogen in the Martian atmosphere may permit a Mars-specific chronometer for tracing the time-evolution of the atmosphere and of lithic phases with trapped atmospheric gases. Other Mars-specific chronometers include measurement of gas fluxes and accumulation of platinum group elements (PGE) in the regolith. Putting collected samples into geologic context is deemed essential, as is using multiple techniques on multiple samples. If in situ measurements are restricted to a single technique it must be shown to give consistent results on multiple samples, but in all cases, using two or more techniques (e.g. on the same lander) will reduce error. While there is no question that returned samples will yield the best ages, in situ techniques have the potential to be flown on multiple missions providing a larger data set and broader context in which to place the more accurate dates.

Doran, Peter T.↗
DOE OSTI2023

Experimental and numerical investigation of ester droplet combustion: Application to butyl acetate

This paper presents an experimental and numerical study of the combustion of isolated n–butyl acetate droplets in the standard atmosphere. Numerical simulations are reported using a model that incorporates unsteady gas and liquid transport, variable properties, and radiation. Three skeletal mechanisms of n-butyl acetate, derived from a large detailed mechanism comprised of 819 species and 52,698 reactions, were used in the numerical simulations to evaluate the influence of the kinetic mechanism on burning. The reduced mechanisms comprised 212 species and 5413 reactions, 157 species and 3089 reactions, and 105 species and 1035 reactions. The numerical model did not include soot formation, though qualitatively mild sooting was noted only for droplets larger than 0.7 mm. The numerical predictions were in good agreement with experimental measurements of droplet and flame diameters. Flame extinction was numerically predicted which was attributed to a decrease of the characteristic diffusion time relative to the chemical time as droplet burned. Effects of initial droplet diameter on the evolution of maximum gas temperature (T max ) and peak mole fractions of CO 2 and CO are also examined numerically.

09 BIOMASS FUELS↗
DOE OSTI2022

On the combustion of n-butyl acetate droplets

This paper presents an experimental and numerical study of the combustion of isolated n‑butyl acetate droplets in the standard atmosphere. Numerical simulations are reported using a model that incorporates unsteady gas and liquid transport, variable properties, and radiation. Three skeletal mechanisms of n‑butyl acetate, derived from a large detailed mechanism comprised of 819 species and 52,698 reactions, were used in the numerical simulations to evaluate the influence of the kinetic mechanism on burning. The reduced mechanisms comprised 212 species and 5413 reactions, 157 species and 3089 reactions, and 105 species and 1035 reactions. The numerical model did not include soot formation, though qualitatively mild sooting was noted only for droplets larger than 0.7 mm. The numerical predictions were in good agreement with experimental measurements of droplet and flame diameters. Flame extinction was numerically predicted which was attributed to a decrease of the characteristic diffusion time relative to the chemical time as droplet burned. Effects of initial droplet diameter on the evolution of maximum gas temperature (Tmax) and peak mole fractions of CO2 and CO are also examined numerically.

09 BIOMASS FUELS↗