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Fracture Testing with Surface Crack Specimens

Recommendations are given for the design, preparation, and static fracture testing of surface crack specimens. The recommendations are preceded by background information including discussions of stress intensity factors, crack opening displacements, and fracture toughness values associated with surface crack specimens. Cyclic load and sustained load tests are discussed briefly.

Orange, T. W.↗

Surface ozone variability at Kislovodsk Observatory

The results of the surface ozone observations at the Observatory 'Kislovodsk', situated in the North Caucasus at the altitude 2070 m a.s.l., are given. The observatory is in the background conditions and the variations of the surface ozone are determined by the natural dynamic and photochemical processes. The mean value of the concentration and its seasonal variations are very near to those obtained at the high-mountain stations in Alps. The daily variations have the features, which remain stable during all warm period of the year (April-October). These features, including the minimum of the surface ozone at noon, are formed by the mountain-valley circulation. The significant variations of the surface ozone are connected with the unstationary lee waves.

Elansky, Nikolay F.↗

Effect of Anions on the Changes in the Structure and Adsorption Mechanism of Zirconium Species at the Muscovite (001)–Water Interface

Multivalent cations primarily exist as polynuclear hydroxo and oxyhydroxo clusters and/or nanoparticles (NPs) in aqueous environments, where their interactions with mineral surfaces can be influenced by complexing anions. In this work, we explored the distribution of tetravalent Zr adsorbed on the negatively charged basal surface of muscovite mica in four background electrolytes (0.1 M NaClO 4 , 0.1 M NaCl, 0.04 M Na 2 SO 4 , and 0.045 M Na 2 HPO 4 ) at constant pH (= 3), total Zr(IV) concentration (= 0.1 mM), and ionic strength (= 0.1 M). The results show that aqueous Zr speciation determined by reactions with anions controls the formation and structure of Zr-containing adsorbates on the mica surface. The Zr coverages measured by X-ray fluorescence (XRF) in ClO 4 - and Cl - systems were 1.3 and 2.1 Zr/A UC (where A UC = 46.72 Å 2 is the area of the unit cell of the mica (001) surface), respectively, and mostly remained unchanged during the reaction time from 6 to 50 h. In these conditions, Zr adsorption occurred both as small NPs (with an average height of ~4 nm observed by ex situ atomic force microscopy, AFM) and in a ~2 nm-thick molecular layer (observed by in situ resonant anomalous X-ray reflectivity, RAXR). In comparison, higher Zr coverages that increased with reaction time (i.e., from ~4 to ~7 Zr/A UC from 6 to 50 h reactions) were observed in the SO 4 2- system. Ex situ AFM showed that the Zr uptake in this system occurred predominantly as NPs that were ~5 to 15 nm tall and 20 to 40 nm wide, but no evidence of the interfacial molecular-layer formation was observed by RAXR. In the HPO 4 2– solution, all measurements unequivocally showed no significant Zr sorption, in stark contrast to the observations in the other solutions. Details of the Zr surface coverage and sorption modes are consistent with the known clustering of tetravalent Zr in solutions in the presence of these anions. These results reveal the critical impact of anions on the adsorption affinity and mechanism of Zr on the negatively charged mica surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Water Detection Based on Object Reflections

Water bodies are challenging terrain hazards for terrestrial unmanned ground vehicles (UGVs) for several reasons. Traversing through deep water bodies could cause costly damage to the electronics of UGVs. Additionally, a UGV that is either broken down due to water damage or becomes stuck in a water body during an autonomous operation will require rescue, potentially drawing critical resources away from the primary operation and increasing the operation cost. Thus, robust water detection is a critical perception requirement for UGV autonomous navigation. One of the properties useful for detecting still water bodies is that their surface acts as a horizontal mirror at high incidence angles. Still water bodies in wide-open areas can be detected by geometrically locating the exact pixels in the sky that are reflecting on candidate water pixels on the ground, predicting if ground pixels are water based on color similarity to the sky and local terrain features. But in cluttered areas where reflections of objects in the background dominate the appearance of the surface of still water bodies, detection based on sky reflections is of marginal value. Specifically, this software attempts to solve the problem of detecting still water bodies on cross-country terrain in cluttered areas at low cost.

Rankin, Arturo L.↗

Output of acoustical sources

Acoustic radiation from a source, here viewed as an immobile point singularity with periodic strength and a given multipolar nature, is affected by the presence of nearly structural elements (e.g., rigid or impedance surfaces) as well as that of a background flow in the medium. An alternative to the conventional manner of calculating the net source output by integrating the energy flux over a distant control surface is described; this involves a direct evaluation of the secondary wavefunction at the position of the primary source and obviates the need for a (prospectively difficult) flux integration. Various full and half-planar surface configurations with an adjacent source are analyzed in detail, and the explicit results obtained, in particular, for the power factor of a dipole brings out a substantial rise in its output as the source nears the sharp edge of a half-plane.

Levine, H.↗

Gold-Tin Solder Wetting Behavior for Package Lid Seals

This study examined the cause of nonwetted regions of the gold (Au) finish on iron-nickel (Fe–Ni) alloy lids that seal ceramic packages using the 80Au-20Sn solder (wt %, abbreviated Au–Sn) and their impact on the final lid-to-ceramic frame solder joint. The Auger electron spectroscopy (AES) surface and depth profile techniques identified surface and through-thickness contaminants in the Au metallization layer. In one case, the AES analysis identified background levels of carbon (C) contamination on the surface; however, the depth profile detected Fe and Ni contaminants that originated from the plating process. The Fe and Ni could impede the completion of wetting and spreading to the edge of the Au metallization. The Au layer of lids not exposed to a Au–Sn solder reflow step had significant surface and through-thickness C contamination. Inorganic contaminants were absent. Subsequent simulated reflow processes removed the C contamination from the Au layer without driving Ni diffusion from the underlying solderable layer. Finally, an Au metallization having negligible C contamination developed elevated C levels after exposure to a simulated reflow process due to C contamination diffusing into it from the underlying Ni layer. However, the second reflow step removed that contamination from the Au layer, thereby allowing the metallization to support the formation of lid-to-ceramic frame Au–Sn joints without risk to their mechanical strength or hermeticity.

36 MATERIALS SCIENCE↗

Vertical distribution of acetonitrile in the atmosphere

The presence of acetonitrile in the atmosphere was confirmed by results of surface and stratospheric investigations. Stratospheric measurements give mixing ratios typically decreasing with height from 3 ppt at 25 km to 0.5 ppt at 40 km. Measurements at the Earth's surface are less unanimous, although a ground level background mixing ratio of a few times 10 ppt seems realistic. Measurements are compatible with a small global surface source of acetonitrile and a small tropospheric loss. The vertical distribution of acetonitrile presented in consistent with general knowledge of its atmospheric chemistry.

Ingels, J.↗

High Layer Uniformity of Two-Dimensional Materials Demonstrated Surprisingly from Broad Features in Surface Electron Diffraction

Paradoxically, a very broad diffraction background, named the bell-shaped-component (BSC), has been established as a feature of graphene growth. Recent diffraction studies as a function of electron energy have shown that the BSC is not related to scattering interference. Here, additional experiments are carried out as a function of temperature over the range in which single-layer graphene (SLG) grows. Quantitative fitting of the profiles shows that the BSC follows the increase of the Gr(10) spot, proving directly that the BSC indicates high-quality graphene. Additional metal deposition experiments provide more information about the BSC. The BSC is insensitive to metal deposition, and it increases with metal intercalation, because a more uniform interface forms between graphene and SiC. These experiments support the conclusion that the BSC originates from electron confinement within SLG, and surprisingly, it is an excellent measure of graphene uniformity.

36 MATERIALS SCIENCE↗

Lower Urban Humidity Moderates Outdoor Heat Stress

Abstract Surface temperature is often used to examine heat exposure in multi‐city studies and for informing urban heat mitigation efforts due to scarcity of urban air temperature measurements. Cities also have lower relative humidity, traditionally not accounted for in large‐scale observational urban heat risk assessments. Here, using crowdsourced measurements from over 40,000 weather stations in ≈600 urban clusters in Europe, we show the moderating effect of this urbanization‐induced humidity reduction on outdoor heat stress during the 2019 heatwave. We demonstrate that daytime differences in heat index between urban clusters and their surroundings are weak, and associations of this urban‐rural difference with background climate, generally examined from the surface temperature perspective, are diminished due to moisture feedbacks. We also examine the spatial variability of surface temperature, air temperature, and heat index within these clusters—relevant for detecting hotspots and potential disparities in heat exposure—and find that surface temperature is a poor proxy for the intra‐urban distribution of heat index during daytime. Finally, urban vegetation shows much weaker (∼1/6th as strong) associations with heat index than with surface temperature, which has broad implications for optimizing urban heat stress mitigation strategies. These findings are valid for operational metrics of heat stress for shaded conditions (apparent temperature and humidex), thermodynamic proxies (wet‐bulb temperature), and empirical heat indices. Based on this large‐scale empirical evidence, surface temperature, used due to the lack of better alternatives, may not be suitable for accurately informing heat mitigation strategies within and across cities, necessitating more urban‐scale observations and better urban‐resolving models.

54 ENVIRONMENTAL SCIENCES↗

A Qualitative Investigation of Selected Infrared Flow Visualization Image Processing Techniques

The deployment and integration of high-sensitivity infrared cameras in a transonic wind tunnel testenvironment has resulted in a unique capability to image aerodynamic phenomena in real-time. Multi-camera infrared flow visualization data systems are now routinely utilized at the NASA Ames Unitary Plan Wind Tunnel. The small flow-induced temperature gradients on the surface of the wind tunnel test article coupled with the high bit-depth of the infrared camera sensor makes the processing of the image data critically important. An image processing routine must enhance features of interest with minimal artifacts. Additionally, the production wind tunnel test environment demands that these processed images are made available in a real-time, automatic fashion. Therefore, any image processing routine must be computationally economical and enhance the image data with minimal input from a human operator. The following seeks to qualitatively explore selected image processing techniques by assessing their effectiveness to resolve flow features on a wind tunnel test article. A multi-scale contrast enhancement technique is discussed as well as a new implementation of a multi-scale, non-interpolated adaptive histogram equalization. Finally, a novel method is introduced that demonstrates the ability to resolve flow features imaged on bare-steel test articles possessing low emissivity.This method makes use of dynamic mode decomposition and discrete-time filtering to separate the background reflections that dominate low emissivity surfaces from the aerodynamic driven surface temperature gradients.This process will be shown to resolve the onset of boundary layer transition on a bare metal wing as well as identify and resolve hidden features in the image data. While the implementation of this technique is very preliminary it demonstrates the potential to extend the application of infrared flow-visualization within the wind tunnel test environment.

Image Processeing↗

Transitioning Enhanced Land Surface Initialization and Model Verification Capabilities to the Kenya Meteorological Department (KMD)

Flooding, severe weather, and drought are key forecasting challenges for the Kenya Meteorological Department (KMD), based in Nairobi, Kenya. Atmospheric processes leading to convection, excessive precipitation and/or prolonged drought can be strongly influenced by land cover, vegetation, and soil moisture content, especially during anomalous conditions and dry/wet seasonal transitions. It is thus important to represent accurately land surface state variables (green vegetation fraction, soil moisture, and soil temperature) in Numerical Weather Prediction (NWP) models. The NASA SERVIR and the Short-term Prediction Research and Transition (SPoRT) programs in Huntsville, AL have established a working partnership with KMD to enhance its regional modeling capabilities. SPoRT and SERVIR are providing experimental land surface initialization datasets and model verification capabilities for capacity building at KMD. To support its forecasting operations, KMD is running experimental configurations of the Weather Research and Forecasting (WRF; Skamarock et al. 2008) model on a 12-km/4-km nested regional domain over eastern Africa, incorporating the land surface datasets provided by NASA SPoRT and SERVIR. SPoRT, SERVIR, and KMD participated in two training sessions in March 2014 and June 2015 to foster the collaboration and use of unique land surface datasets and model verification capabilities. Enhanced regional modeling capabilities have the potential to improve guidance in support of daily operations and high-impact weather and climate outlooks over Eastern Africa. For enhanced land-surface initialization, the NASA Land Information System (LIS) is run over Eastern Africa at ~3-km resolution, providing real-time land surface initialization data in place of interpolated global model soil moisture and temperature data available at coarser resolutions. Additionally, real-time green vegetation fraction (GVF) composites from the Suomi-NPP VIIRS instrument is being incorporated into the KMD-WRF runs, using the product generated by NOAA/NESDIS. Model verification capabilities are also being transitioned to KMD using NCAR's Model *Corresponding author address: Jonathan Case, ENSCO, Inc., 320 Sparkman Dr., Room 3008, Huntsville, AL, 35805. Email: Jonathan.Case-1@nasa.gov Evaluation Tools (MET; Brown et al. 2009) software in conjunction with a SPoRT-developed scripting package, in order to quantify and compare errors in simulated temperature, moisture and precipitation in the experimental WRF model simulations. This extended abstract and accompanying presentation summarizes the efforts and training done to date to support this unique regional modeling initiative at KMD. To honor the memory of Dr. Peter J. Lamb and his extensive efforts in bolstering weather and climate science and capacity-building in Africa, we offer this contribution to the special Peter J. Lamb symposium. The remainder of this extended abstract is organized as follows. The collaborating international organizations involved in the project are presented in Section 2. Background information on the unique land surface input datasets is presented in Section 3. The hands-on training sessions from March 2014 and June 2015 are described in Section 4. Sample experimental WRF output and verification from the June 2015 training are given in Section 5. A summary is given in Section 6, followed by Acknowledgements and References.

land surface modeling↗

Aeolian Processes and Features on Venus

Aeolian features on Venus include dune fields, eroded hills (yardangs), wind streaks, (miniature dunes of 10 to 30 cm wavelength). Although and possibly microdunes (in repetitive imaging by Magellan did show changes in the appearance of the surface, these changes are attributed to radar artifacts as a consequence of look direction rather than to physical changes of the surface. Nonetheless, measurements of wind speeds near the surface of Venus and wind tunnel simulations suggest that aeolian processes could be currently active on Venus. Study of radar images of terrestrial analogs shows that radar wavelength, polarization, and viewing geometry, including look direction and incidence angle, all influence the detection of dunes, yardangs, and wind streaks. For best detection, dune crests and yardangs should be oriented perpendicular to look direction. Longer wavelength systems can penetrate sand sheets a meter or more thick, rendering them invisible, especially in arid regions. For wind streaks to be visible, there must be a contrast in surface properties between the streak and the background on which it occurs. Nonetheless, more than 6000 aeolian features have been found on Magellan images of Venus, the most common of which are various wind streaks. Mapping wind streak orientations enables near-surface wind patterns to be inferred for the time of their formation. Type P streaks are associated with parabolic ejecta crater deposits and are considered to have formed in association with the impact event. Most Type P streaks are oriented westward, indicative of the upper altitude superrotation winds of Venus. Non Type P streaks have occurrences and orientations consistent with Hadley circulation. Some streaks in the southern hemisphere are oriented to the northeast, suggesting a Coriolis effect.

Greeley, Ronald↗

Comprehensive study of radon progeny attachment to surfaces

Low energy, low rate experiments, such as searches for neutrinoless double β decay and dark matter, require unprecedentedly low levels of background in order to deliver their full science potential. 210 Po driven, neutron induced background, caused by nuclear (α, n) reactions on low-Z materials, direct background contributions of the 210 Po α radiation and desorption of the 210 Pb progeny 210 Bi from surfaces into the detector medium are of particular of concern. These backgrounds depend on details of the components’ exposure to radon-loaded laboratory air and, thus, their handling history. The attachment rates of airborne radon progeny to surfaces, needed for the estimation of these background rates, are poorly understood. This article reports the results of a campaign comprising of more than 1200 attachment measurements, performed for nine different materials. Correlations of the attachment with environmental parameters such as air exchange rate, electrical surface potential, temperature, atmospheric pressure, and relative humidity have been studied and found to be significant only in case of the first two. Attachment modeling, using the Jacobi model, is compared to data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Photon-Counting Multikilohertz Microlaser Altimeters

Spaceborne laser altimeters in planetary orbit typically use high energy (approximately 100 mJ) solid state lasers, large telescopes (50 to 100 cm), and high detection thresholds to achieve unambiguous surface returns with few or no ifalse alarmsi resulting from solar background noise. As a result of this conservative design philosophy, spacecraft prime power weight, or size constraints typically restrict operations to modest repetition rates on the order of a few tens of Hz which, at a typical ground velocity of 7 Km/sec, limits along-track spatial sampling to one sample every few hundred meters. The surface return rate of an Earth-orbiting altimeter can be increased by up to two orders of magnitude for a given laser output power by emitting the available photons in a high frequency (few KHz) train of low energy (< 1 mJ) pulses, as produced by passively Q-switched solid state "microlasers", and using single photon detection. while simultaneously using much smaller telescope diameters on the order of 10 cm. Simple onboard software algorithms, based on post-detection Poisson filtering techniques, can be employed to identify and extract the surface data from solar background noise prior to onboard data storage or transmission to a ground station. Under NASAis Instrument Incubator Program, we have begun the design and construction of a scanning airborne instrument to demonstrate the potential advantages of the technique for future space missions.

Degnan, John J.↗

EVA Swab Kit: Tools and Techniques for Collecting Aseptic Samples from Crewed Space Missions

Introduction: When we send humans to search for life on other planets, we'll need to know what we brought with us versus what may already be there. To ensure our crewed spacecraft meet planetary protection requirements—and to protect our science from human contamination—we'll need to assess and verify whether micro-organisms may be leaking/venting from our spacesuits. This requires collecting samples under Extravehicular Activity (EVA) conditions. Detailed, systematic research on forward contamination from robotic spacecraft has been steadily progressing since the Viking missions, but systematic studies of contamination from space suits has not been conducted in many years. The modern EMU (Extravehicular Mobility Unit) suit used by NASA is designed to leak at rates as high as 100 cc/min. Before humans land on Mars there is a critical need to understand the types and quantities of microbes that could be introduced via space suits. The Human Forward Contamination Assessment team at NASA’s Johnson Space Center (JSC) has developed a prototype EVA swab tool [1,2,3,4] designed for use in space to sample cleaned and uncleaned space suits to determine the present day microbial load and eventually the rate of leakage. The ability to assess microbial leakage early in advanced space suit and life support system design cycles will help avoid costly hardware redesign later. Test Objectives: The primary objective of EMU testing was to characterize the type of micro-organisms typically found on or near selected suit pressure joints under suit differential pressure conditions. Most human-borne microbes can fit through a 0.5 to 1.0 µm gap. Knowing which joints are more likely to leak will inform hardware design decisions. Knowing which types of micro-organisms may leak from EVA suits provides a basis for subsequent studies to characterize the viability of those organisms under destination conditions, as well as how far they might spread through natural or human-influenced processes. That data, in turn, will inform exploration mission operations and hardware design. The secondary objective of testing was to evaluate the interface between a fully suited test subject and the EVA swab tool at vacuum. Bulky EVA suits can restrict movement and limit visibility through the helmet visor. Fully suited testing is important for identifying tool design issues prior to flight. At exploration destinations, such as Mars, suited crew may be required to periodically sample their suits as part of an environmental monitoring protocol. Suit Microbial Sampling Results: This report details results of microbial swabs collected from current flight suit configurations worn by crew members assigned to upcoming ISS expedition missions as well as swabs collected from prototype suits intended for use on the Orion spacecraft. These tests were intended to characterize the types of contaminants found on flight suits under current, typical handling conditions. No attempt was made to change suit handling procedures, provide additional sterilization, or to limit typical potential contaminant sources. Using culture based techniques, we cultivated 235 CFU (colony forming units) comprised of 26 bacterial species and one fungal species on the outside of the suits. The fungal species and 14 of the bacterial species were unique to the suit surfaces and were not detected in any of the background samples collected within the chambers. We sequenced 755,434 ribosomal fragments on all of the suit surfaces from swab samples. 557,016 of these sequences represent DNA that survived at least 4 hours at vacuum. These sequences formed 2,464 OTU's (Operational Taxonomic Units, 97% similarity) showing low diversity in the samples. The most abundant sequences that survived vacuum belong to the genera Staphyloccocus, Ralstona, Bacillus and Rhodobacter all of which are common to the human microbiome. [5] See Danko et al., (2021) for more complete details of these first analyses. Further analysis of EVA suit materials with respect to the efficacy of various cleaning protocols and engineered containment solutions is planned to inform suit design for NASA’s Artemis Moon to Mars program crew testing. Swab Tool Function Results: The kit was demonstrated for fit and function in suited subject vacuum tests to determine how well the tool worked as an aseptic microbial sampling device as well as to identify any design elements that could be upgraded for EVA task specific improvement. It was found that sample acquisition efficacy could be enhanced by redesign of the sample canister to end-effector interface. Several modifications of the sample caddy assemblies to optimize EVA safety and functionality were also identified. Consequently, fabrication of the redesigned sample canister to end-effector assembly interfaces and and the sample caddy assemblies are required. Fabrication of sixteen flight sample canister assemblies (8 per each of two EVA Swab Kits) and two sample caddy assemblies are in process to be followed by hardware testing and certification to produce two flight-certified EVA Swab Kits for transport to ISS no earlier than summer of 2022. Sampling Strategy: The International Space Station is an ideal testbed for systematic studies of contamination from crewed vehicles since it has been continuously occupied for 20 years and exposed to non-terrestrial conditions. We will sample the exterior of the ISS during EVA using a purpose-built swab tool capable of maintaining sterility while undergoing temperature changes from -151 to +121°C under hard vacuum. Prior to each EVA, the project team will work with ISS mission managers to identify precise sampling locations, which will vary by EVA based on the translation paths and worksites scheduled for that particular EVA. Ideally, translation path handrails and areas near ECLSS (Environmental Control and Life Support System) external vent openings on a spacecraft would be assessed. There are currently more than a dozen ECLSS external vents on the ISS. Some are connected to systems that vent waste products, while others are intended to equalize cabin pressure. As EVA opportunity allows, microbial samples from any of these external vents would provide a valuable data point, though some will be more useful than others. Four criteria have been identified to help prioritize sampling sites near vents: • EVA Accessibility: To minimize cost, it is desired to piggy-back onto a planned EVA. Therefore, the sampling location must be readily accessible by an EVA crew • Type of Vented Products: Vent products that have been in direct contact with crew, such as cabin air, are more likely to contain microorganisms than vent products associated with isolated systems, such as experiment module combustion products. • Mass of Vented Products: Higher-flow vents are more likely to contain detectible levels of microbial contaminants than lower-flow vents. • Local Environment: Sample locations with relatively benign local conditions, such as warm surfaces shielded from direct ultraviolet (UV) radiation exposure, may be more likely to support microbial growth than locations with harsher local environmental conditions. Because EVA accessibility is the most important criteria, the proposal team worked with an astronaut and flight controllers using the Dynamic Onboard Ubiquitous Graphics (DOUG) tool. The DOUG virtual environment allows an operator to “fly” around the current ISS vehicle configuration to assess EVA translation paths, attach points, and keep-out zones. While analysis on station or rapid return to Earth would be preferable, samples collected from the exterior of the ISS have already been exposed to temperature variations between -157 and +121 °C as well as hard vacuum. Therefore, they should be fairly stable and robust. We hypothesize that samples collected from the ISS exterior could be stored for up to 6 months at -80°C without degradation. Sample canisters will be returned to Earth while frozen at -80°C for analysis, and sterilized canisters can be re-flown back to ISS to support additional sampling opportunities Relevance to NASA Exploration Objectives: These data will allow us to identify new or improved methods, technologies, and procedures for spacecraft sterilization and leakage mitigation to minimize the amount of contamination introduced to the environment by human explorers. This work is funded by NASA research grant: NNH18ZDA001N-PPR References: [1] Bell, M.S. et al. (2015) LPS XLVI, Abst. #1832 [2] Rucker et al. (2018) 42nd COSPAR (PPP.3) [3] Bell, M.S. et al. (2019) Mars Extant Life Conference, Abst. #5096.[4] Bell, M.S. et al., (2020) 43rd COSPAR (BO.2).[5] Danko D, et.al.,(2021)Front.Microbiol.12:608478.

Mary Suzanne Bell↗

Simulating the density of organic species in the atmosphere of Titan with a coupled ion-neutral photochemical model

We introduce a one-dimensional coupled ion-neutral photochemical kinetics and diffusion model to study the atmospheric composition of Titan in light of new theoretical kinetics calculations and scientific findings from the Cassini–Huygens mission. The model extends from the surface to the exobase. The atmospheric background, boundary conditions, vertical transport and aerosol opacity are all constrained by the Cassini–Huygens observations. The chemical network includes reactions between hydrocarbons, nitrogen and oxygen bearing species. It takes into account neutrals and both positive and negative ions with masses extending up to 116 and 74 u, respectively. We incorporate high-resolution isotopic photoabsorption and photodissociation cross sections for N 2 as well as new photodissociation branching ratios for CH 4 and C 2 H 2 . Ab initio transition state theory calculations are performed in order to estimate the rate coefficients and products for critical reactions. Critical reactions of production and loss for neutrals and ions are quantitatively assessed and thoroughly discussed. The vertical distributions of neutrals and ions predicted by the model generally reproduce observational data, suggesting that for the small species most chemical processes in Titan’s atmosphere and ionosphere are adequately described and understood; some differences are highlighted. Notable remaining issues include (i) the total positive ion density (essentially HCNH + ) in the upper ionosphere, (ii) the low mass negative ion densities (CN - , C 3 N - /C4H - ) in the upper atmosphere, and (iii) the minor oxygen-bearing species (CO 2 , H 2 O) density in the stratosphere. Pathways towards complex molecules and the impact of aerosols (UV shielding, atomic and molecular hydrogen budget, nitriles heterogeneous chemistry and condensation) are evaluated in the model, along with lifetimes and solar cycle variations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The stellar halo of isolated central galaxies in the Hyper Suprime-Cam imaging survey

We study the faint stellar halo of isolated central galaxies, by stacking galaxy images in the HSC survey and accounting for the residual sky background sampled with random points. The surface brightness profiles in HSC r band are measured for a wide range of galaxy stellar masses (9.2 < log 10 M * /M ⊙ < 11.4) and out to 120 kpc. Failing to account for the stellar halo below the noise level of individual images will lead to underestimates of the total luminosity by ≤15%. Splitting galaxies according to the concentration parameter of their light distributions, we find that the surface brightness profiles of low-concentration galaxies drop faster between 20 and 100 kpc than those of high-concentration galaxies. Albeit the large galaxy-to-galaxy scatter, we find a strong self-similarity of the stellar halo profiles. They show unified forms once the projected distance is scaled by the halo virial radius. The colour of galaxies is redder in the centre and bluer outside, with high-concentration galaxies having redder and more flattened colour profiles. There are indications of a colour minimum, beyond which the colour of the outer stellar halo turns red again. This colour minimum, however, is very sensitive to the completeness in masking satellite galaxies. We also examine the effect of the extended PSF in the measurement of the stellar halo, which is particularly important for low-mass or low-concentration galaxies. The PSF-corrected surface brightness profile can be measured down to ~31 magarcsec -2 at 3σ significance. PSF also slightly flattens the measured colour profiles.

79 ASTRONOMY AND ASTROPHYSICS↗

Dark Energy Survey year 1 results: the relationship between mass and light around cosmic voids

What are the mass and galaxy profiles of cosmic voids? In this paper, we use two methods to extract voids in the Dark Energy Survey (DES) Year 1 redMaGiC galaxy sample to address this question. We use either 2D slices in projection, or the 3D distribution of galaxies based on photometric redshifts to identify voids. For the mass profile, we measure the tangential shear profiles of background galaxies to infer the excess surface mass density. The signal-to-noise ratio for our lensing measurement ranges between 10.7 and 14.0 for the two void samples. We infer their 3D density profiles by fitting models based on N-body simulations and find good agreement for void radii in the range 15–85 Mpc. Comparison with their galaxy profiles then allows us to test the relation between mass and light at the 10 per cent level, the most stringent test to date. We find very similar shapes for the two profiles, consistent with a linear relationship between mass and light both within and outside the void radius. We validate our analysis with the help of simulated mock catalogues and estimate the impact of photometric redshift uncertainties on the measurement. Our methodology can be used for cosmological applications, including tests of gravity with voids. Finally, this is especially promising when the lensing profiles are combined with spectroscopic measurements of void dynamics via redshift-space distortions.

79 ASTRONOMY AND ASTROPHYSICS↗