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Experimental technique used in study of damage mechanism to semiconductor pigments exposed to ultraviolet radiation can be adapted for investigations of surface chemistry and may be used analytically to determine contamination.
The basic concepts associated with the friction and wear of materials are discussed as they relate to ceramics. Properties of ceramics such as crystal structure, crystallographic orientation, mechanical deformation, and surface chemistry are reviewed as they influence friction and wear. Both adhesive and abrasive wear of ceramics are discussed. The friction and wear of ceramics are examined in contact with themselves and when in contact with metals. The influences of environmental constituents such as water and hydrocarbons on friction and wear are reviewed. Materials discussed, by way of example, include aluminum oxide, rutile, calcium fluoride, and lithium fluoride.
The basic concepts associated with the friction and wear of materials are discussed as they relate to ceramics. Properties of ceramics such as crystal structure, crystallographic orientation, mechanical deformation and surface chemistry are reviewed as they influence friction and wear. Both adhesive and abrasive wear of ceramics are discussed. The friction and wear of ceramics are examined in contact with themselves and when in contact with metals. The influences of environmental constituents such as water and hydrocarbons on friction and wear are reviewed. Materials discussed, by way of example, include aluminum oxide, rutile, calcium fluoride, and lithium fluoride.
Analysis of the effects of ejection of materials from large lunar craters, photogeologic evidence, remote measurements of surface chemistry and petrology of lunar samples are synthesized. Previous theories for emplacement of the Cayley are volcanic ash emplacement and emplacement as ejecta from multiringed basins. Calculations show that materials ejected beyond the continuous deposits of large lunar craters produce secondary impact craters that excavate and deposit masses of local material equal to multiples of the crater ejecta deposited at the same place. It is shown that the main influence of a large cratering event on terrain at distances greater than 50 km from large lunar craters is one of cratering and deposition of local material by secondary craters rather than deposition of ejecta from the large crater.
The effects of convective heating upon reusable surface insulation coatings were studied utilizing scanning electron microscopy, X-ray fluorescence, and X-ray diffraction. Samples of coated silica, mullite, and ceramic mullite fiber were cycled in an arc plasma stream up to 15 times for 15 minutes per cycle at surface temperatures simulating those on the space shuttle vehicle. The surfaces of ceramic mullite fiber and mullite coatings were roughened substantially by the convectively heated environment while the silica was significantly smoothed after testing. Scanning electron microscopy also showed surface cracking of varying degrees in all of the coatings. The surface chemistry of the coatings as examined by X-ray fluorescence revealed that significant changes in composition were occurring during cycling, particularly within the mullite coating.
The surface properties of lunar fines were investigated. Results indicate that, for the most part, these properties are independent of the chemical composition and location of the samples on the lunar surface. The leaching of channels and pores by adsorbed water vapor is a distinguishing feature of their surface chemistry. The elements of air, if adsorbed in conjunction with water vapor or liquid water, severely impedes the leaching process. In the absence of air, liquid water is more effective than water vapor in attacking the grains. The characteristics of Apollo 17 orange fines were evaluated and compared with those of other samples. The interconnecting channels produced by water vapor adsorption were found to be wider than usual for other types of fines. Damage tracks caused by heavy cosmic ray nuclei and an unusually high halogen content might provide for stronger etching conditions upon exposure to water vapor.
Various surface preparations for titanium 6-4 alloy were studied. An anodizing method was investigated, and compared with the results of other chemical treatments, namely, phosphate/fluoride, Pasa-Jell and Turco. The relative durability of the different surface treatments was assessed by monitoring changes in surface chemistry and morphology occasioned by aging at 505 K (450 F). Basic electron spectroscopic data were collected for polyimide and polyphenylquinoxaline adhesives and synthetic precursors. Fractographic studies were completed for several combinations of adherend, adhesive, and testing conditions.
Side-Looking Airborne Radar (SLAR) images, acquired by JPL and Strategic Air Command Systems, and visible and near-infrared LANDSAT imagery were applied to studies of the Quaternary alluvial and evaporite deposits in Death Valley, California. Unprocessed radar imagery revealed considerable variation in microwave backscatter, generally correlated with surface roughness. For Death Valley, LANDSAT imagery is of limited value in discriminating the Quaternary units except for alluvial units distinguishable by presence or absence of desert varnish or evaporite units whose extremely rough surfaces are strongly shadowed. In contrast, radar returns are most strongly dependent on surface roughness, a property more strongly correlated with surficial geology than is surface chemistry.
The effects of different weathering processes on the albedo of the lunar surface cover is discussed. The surface chemical composition of numerous lunar soil and pulverized rock samples was determined by auger electron spectroscopy. The optical albedo of these samples was also measured. The chemical concentration of iron and titanium is greater on the surface of soil samples than it is on the surface of crushed rock samples with similar bulk composition, whereas the albedo of soil samples is lower than that of the crushed rock samples. A correlation is presented between the surface iron + titanium content and the albedo. Results of solar wind simulation experiments show that irradiation of crushed lunar rock samples with a small dose (corresponding to 3000 years of solar wind) of 2-keV energy protons changed the surface chemistry of the rock to that of the soil. A much larger dose of protons (corresponding to 30,000 years of solar wind) was needed to darken crushed rock to the albedo of the soil of similar bulk chemical composition. The mechanism of darkening by solar wind is discussed, and its effectiveness is compared to that of other darkening processes.
A neutral mass spectrometer with a quasi-open ion source was flown on each of the Atmosphere Explorer (AE) C, D, and E satellites. The three instruments provided an opportunity to study the effects of different source insert materials on the source surface chemistry. It was found that, after a period of conditioning in space, the recombination coefficient of atomic oxygen on gold appears to be substantially lower than it is on Nichrome V. The lower recombination coefficient on gold allows the spectrometer to directly measure a significant fraction of the incident atomic oxygen, making it possible to distinguish between ambient O and O2. Equations are developed to calculate the atomic and molecular oxygen densities. Preliminary measurements of molecular oxygen densities obtained by this technique agree well with measurements taken in the fly-through mode of operation.
The surface properties of an Apollo 11 soil sample have been reinvestigated. The present study shows that the preliminary results for this sample (Fuller et al., 1971) are in error, principally because of incorrectly applied instrumental background effects. The surface properties of these Apollo 11 fines are very similar to those of fines from the other Apollo landing sites that we have examined. On the basis of results reported to date, the surface properties (specific surface area, porosity, and reactivity with water) of lunar soil samples are, to a first approximation, independent of bulk chemical composition and location on the lunar surface. Drastic alteration of the surface characteristics of lunar fines by adsorbed water continues to be the distinguishing feature of their surface chemistry.
Sliding friction experiments were conducted with aluminum and other riders rubbing on disks of various elemental metals in the presence of a thin film of zinc dialkyldithiophosphate (ZDP). Auger emission spectroscopy was used to in situ monitor the changes in surface chemistry with rubbing under various loads. The metal disks examined included iron, titanium, rhodium, tungsten, molybdenum, and copper. For equivalent films of ZDP the film is a more effective lubricant for some metals than it is for others. The important active element in the compound varies with the metal lubricated and is a function of metal chemistry. The zinc in the ZDP is susceptible to electron beam induced desorption.
Lunar radar mappings carried out in the late 1960s and 1970s have provided several valuable insights into lunar surface processes. These radar mappings used the delay-Doppler technique and needed the narrow antenna beams now available with large radio telescopes. Two-element radar interferometers have provided resolution of the delay-Doppler ambiguity at meter wavelengths and provided topographic information at centimeter wavelengths. These techniques have provided high resolution lunar radar maps at 3.8-cm, 70-cm, and 7.5-m wavelengths, a set of wavelengths which span the window available for earth-based radar mapping of the moon. These radar maps have been used along with other earth-based and Apollo orbital measurements to define surface units. The radar maps and these other data can describe physical properties such as small-scale blockiness and surface chemistry.
Dual polarization L-band (lambda = 25 cm) radar imagery and Landsat multispectral scanner (MSS) data from central Death Valley have been computer processed and combined digitally in order to utilize the complementary information contained in multisensor data sets. Physically, like-polarized radar data gives roughness information on a scale proportional to radar wavelength. Cross-polarized data adds information on the overall roughness, particle shape, and packing density. Visible and near IR reflectivities pertain to surface chemistry. Surficial geologic units in Death Valley are defined on the basis of compositional and textural differences: optical and microwave scattering properties encoded in the multisensor image are sufficient to discriminate most of the units. This synergistic effect is most pronounced for the alluvial fans. Using radar scattering data and measured sun angle, passively-sensed (passive microwave, visible, near IR) images can be corrected for shadowing effects.
An overview of the Viking Mars probe is presented. The Viking spacecraft is described and a brief history of the earlier observations and exploration of Mars is provided. A number of the Viking photographs of the Martian surface are presented and a discussion of the experiments Viking performed including a confirmation of the general theory of relativity are reported. Martian surface chemistry is discussed and experiments to study the weather on Mars are reported.
Future possibilities for the further study of the asteroids are reviewed, with particular attention paid to space missions for their direct exploration. The role of traditional ground-based and earth orbiting techniques is examined briefly, and it is concluded that although astronomical techniques are presently at their peak, and despite the opportunities provided by the Infrared Astronomical satellite, the Space Telescope and Spacelab Infrared Telescope Facility, the next major step will require direct exploration by space probes to obtain information on asteroid surface chemistry, geology and bulk properties. Various mission modes and propulsion systems for a first multi-target asteroid mission are discussed, including flyby, rendezvous, landing and sample return, and ion-drive propulsion systems. Science payloads for a basic rendezvous mission are considered, and target selection for multi-asteroid flyby tours and rendezvous tours is discussed. Consideration is also given to sample return missions for the evaluation of the asteroid as potential resources.
Alkylation or carbon Vulcan XC-72, the support carbon, was shown to provide the most stable bond type for linking cobalt dehydrodibenzo tetraazannulene (CoTAA) to the surface of the carbon; this result is based on data obtained by cyclic voltammetry, pulse voltammetry and by release of 14C from bonded CoTAA. Half-cell tests at 100 C in 85% phosphoric acid showed that CoTAA bonded to the surface of carbon (Vulcan XC-72) via an alkylation procedure is a more active catalyst than is platinum based on a factor of two improvement in Tafel slope; dimeric CoTAA had catalytic activity equal to platinum. Half-cell tests also showed that bonded CoTAA catalysts do not suffer a loss in potential when air is used as a fuel rather than oxygen. Commercially available polytetrafluroethylene (PTFE) was shown to be unstable in the fuel cell environment with degradation occurring in 2000 hours or less. The PTFE was stressed at 200 C in concentrated phosphoric acid as well as electrochemically stressed in 150 C concentrated phosphoric acid; the surface chemistry of PTFE was observed to change significantly. Radiolabeled PTFE was prepared and used to verify that such chemical changes also occur in the primary fuel cell environment.
Impulsive versus steady jet impingement of spherical glass bead particles on metal surfaces was studied using a gas gun facility and a commercial sand blasting apparatus. Crushed glass particles were also used in the sand blasting apparatus as well as glass beads. Comparisons of the different types of erosion patterns were made. Scanning electron microscopy, surface profilometry and energy dispersive X-ray spectroscopy analysis were used to characterize erosion patterns. The nature of the wear can be divided into cutting and deformation, each with its own characteristic features. Surface chemistry analysis indicates the possibility of complex chemical and/or mechanical interactions between erodants and target materials.