Results for “surface impedance” — Page 12

DOE OSTI2023

Impedance Response Influenced by Variability in the Random Distribution of Physical Properties of Coated Materials in Two-Dimensional Space

Heterogeneous physical characteristics of a system featuring a single-layer film on a metallic surface have been explored via its impedance response. The Nyquist plot showed a distorted semicircle, indicative of the system's unique distribution characteristics. Utilizing a copula-based probability method, a two-dimensional deterministic impedance model was successfully integrated, accounting for spatial physical properties such as permittivity and electrical conductivity. This strategy enabled in-depth exploration and mechanistic quantification of a broad spectrum of properties. A quantitative understanding of impedance signal alterations, characterized by normally or log-normally correlated variables, was achieved through the variation in aspect ratio and characteristic frequency of the impedance spectra. Log-normally distributed electrical properties provided a superior representation of the distorted impedance spectra. As coefficient of variation (CV) values fluctuated, the aspect ratio and characteristic frequency showed heightened sensitivity to log-normal permittivity compared to log-normal electrical conductivity. Notably, a marked positive linear correlation between electrical properties resulted in an impedance response that approximated perfect semicircular spectra. The variability in the electrical properties' distribution was demonstrated by considering the correlation coefficient between electrical conductivity and the z-direction position. Furthermore, the highest aspect ratio of the impedance spectra was observed when the electrical conductivity was randomly distributed across the z-direction space.

36 MATERIALS SCIENCE↗

DOE OSTI2023

xLi2MnO3 (1-x)LiMeO2 and Li4Ti5O12 Cell Chemistry for Behind-the-Meter Storage Applications

Li- and Mn-rich layered oxide material (xLi2MnO3 (1-x)LiMeO2, Me = Ni, Mn, and etc., LMR-NM) is paired with Li4Ti5O12 (LTO) in a full cell and evaluated for the Behind-the-Meter Storage (BTMS) applications. The LMR-NM/LTO full cell shows very high capacities and excellent long-term cycle life. It delivers 192 mAh g-1 after 500 cycles at C/2 and 45 degrees C with a capacity retention of 75% and coulombic efficiency higher than 99.95%. It also has impressive rate capabilities. A capacity of 220 mAh g-1 is achieved at 2C which is 88 % of the initial capacity at C/10. The high cycling temperature clearly enhances electrochemical kinetics and activates more Li2MnO3 component, which gives high capacities, low cell impedance, and better rate capabilities. Moreover, it helps to form a relatively thick cathode-electrolyte interphase (CEI) film to suppress transition metal dissolution from the cathode surface. The upper cut-off voltage (UCV) of 3.0 V keeps the structural integrity of the cathode during cycling. A higher UCV of 3.2 V accelerates structural instabilities of the cathode as well as growth of the solid-electrolyte interphase (SEI) via transition metal dissolution and deposition on the anode surface. It results in higher cell impedance, worse capacity retention and faster capacity fade.

behind-the-meter storage↗

NASA NTRS2019

Carbon Nanostructures in Biological Sensors for Space and Terrestrial Applications

Biosensing devices comprised of carbon nanotubes and nanofibers have been developed for astronaut crew point-of-care. Their inherent nanometer scale, high conductivity, wide potential window, good biocompatibility and well-defined surface chemistry make them ideal candidates as biosensor electrodes. Here, we report two studies using carbon nanotube and carbon nanofiber electrodes for biomedical applications. First, a 3x3 electrode device, with each electrode containing 40,000 carbon nanofiber nanoelectrodes was fabricated on silicon using traditional microfabrication processing. The device was demonstrated as a multiplexed immunosensor for simultaneous, label-free detection of cardiac troponin-I, C-reactive protein and myoglobin. Antibodies specific to cardiac troponin-I, C-reactive protein and myoglobin were covalently bound to the CNF surface and were characterized using electrochemical impedance spectroscopy and differential pulse voltammetry. Each step of the modification process resulted in changes in resistance to charge transfer due to the changes at the electrode surface upon antibody immobilization and binding to the specific cardiac protein. The real-time label free detection of the three cardiac markers from pure components and mixtures was demonstrated with high sensitivity, down to 0.2 ng/mL, and good selectivity. Detection in human blood serum did not present false positives from non-specific protein adsorption. More recently, this detection scheme has been applied to inkjet printed carbon nanotube electrodes on Kapton and paper. Printed devices have several unique advantages including simple and inexpensive fabrication. The results demonstrate that these sensors can serve a miniaturized, low cost device for detection of proteins in complex mixtures making this platform a good candidate for early stage diagnosis of myocardial infarction. Future inkjet printed devices can be fabricated have the added advantage in their suitability to be manufactured in an in-space, microgravity environment.

carbon nanotubes↗

NASA NTRS2019

Carbon Nanomaterials for Biosensing Applications

Biosensing devices comprised of carbon nanotubes and nanofibers have been developed for astronaut crew point-of-care. Their inherent nanometer scale, high conductivity, wide potential window, good biocompatibility and well-defined surface chemistry make them ideal candidates as biosensor electrodes. Here, we report two studies using carbon nanotube and carbon nanofiber electrodes for biomedical applications. First, a 3x3 electrode device, with each electrode containing 40,000 carbon nanofiber nanoelectrodes was fabricated on silicon using traditional microfabrication processing. The device was demonstrated as a multiplexed immunosensor for simultaneous, label-free detection of cardiac troponin-I, C-reactive protein and myoglobin. Antibodies specific to cardiac troponin-I, C-reactive protein and myoglobin were covalently bound to the CNF surface and were characterized using electrochemical impedance spectroscopy and differential pulse voltammetry. Each step of the modification process resulted in changes in resistance to charge transfer due to the changes at the electrode surface upon antibody immobilization and binding to the specific cardiac protein. The real-time label free detection of the three cardiac markers from pure components and mixtures was demonstrated with high sensitivity, down to 0.2 ng/mL, and good selectivity. Detection in human blood serum did not present false positives from non-specific protein adsorption. More recently, this detection scheme has been applied to inkjet printed carbon nanotube electrodes on Kapton and paper. Printed devices have several unique advantages including simple and inexpensive fabrication. The results demonstrate that these sensors can serve a miniaturized, low cost device for detection of proteins in complex mixtures making this platform a good candidate for early stage diagnosis of myocardial infarction. Future inkjet printed devices can be fabricated have the added advantage in their suitability to be manufactured in an in-space, microgravity environment.

carbon nanotubes↗

DOE OSTI2022

Anion Effects on the Interfacial Structure and Bulk Physical Properties in Choline-Based Hydrogen-Bonded Electrolytes

Electrolytes consisting of choline (Ch) salts with acetate (Ac) and oxalate (Ox) anions were studied in mixtures with ethylene glycol (EG), in comparison to chloride (Cl)- and bis(trifluorosulfonyl)imide (TFSI)-containing systems to understand the impact of anion size and charge density on the bulk electrolyte and interfacial properties. These represent hydrogen-bonded concentrated electrolytes where the Ch salts are the H-bond acceptors (HBAs) and EG is the H-bond donor (HBD) in 1:2 and 1:4 HBA:HBD ratios. Increased H-bonding in Ch 2 Ox with EG compacts the liquid compared to ChAc, consistent with the increased dissociation energies of the HBA:HBD clusters with Ox –2 calculated by density functional theory (DFT), thus leading to denser and more viscous liquids. Electrochemical impedance spectroscopy (EIS) and surface-enhanced Raman spectroscopy (SERS) were used to investigate interfacial charge density and the electrode surface species. Differential capacitance curves demonstrate weak dependence on potential except for ChAc:EG, where Ac – is found to adsorb on the Au surface, in particular at +0.055 V vs Ag quasi-reference while no specific adsorption was observed on glassy carbon (GC). In situ SERS measurement confirms the formation of a surface layer in the ChAc:EG systems resulting from a Au–acetate interaction. Despite the structural similarities, Ox –2 did not show specific binding or any dependence of capacitance on potential as a result of strongly solvating EG molecules via H-bonds. Furthermore, this study shows that the charge density of the HBAs impacts both bulk properties and the electrical double-layer formation in concentrated H-bonded electrolytes that is relevant to electrochemical kinetics and morphology in electrodeposition processes and energy storage applications.

25 ENERGY STORAGE↗

DOE OSTI2019

Electroanalytical Investigation of the Electrode–Electrolyte Interface of Quaternary Ammonium Ionic Liquids: Impact of Alkyl Chain Length and Ether Functionality

The influence of ionic associations and potential-dependent interactions on the electrode–electrolyte interfacial structure of ionic liquids (ILs) is studied by electrochemical impedance spectroscopy (EIS) and surface-enhanced Raman spectroscopy (SERS) for a variety of asymmetric quaternary ammonium ILs. Specifically, the impact of cation alkyl chain length (C = 4, 8 and 16) and ether functionality on the interfacial structuring of ILs at the glassy carbon electrode surface is examined. Ammonium cations with alkyl chain length of 8 and 16 carbons are found to stabilize the formation of the bis(trifluorosulfonyl)imide, [TFSI], anion dense Stern layer at positive electrode potentials leading to larger capacitances. The longer alkyl chain of the cation is believed to screen the ion–ion repulsion among the anions by intruding into the interfacial anion layer. SERS suggests the presence of carbon-containing rings at the interface at both positive and negative electrode potentials, which can be explained by the buckling of the long alkyl chains. Inclusion of an ether functionality allowed for more symmetry in the camel-shaped potential-dependent differential capacitance curves, suggesting similar excess ion density at both positive and negative potentials. This work contributes to understanding and predicting the interfacial electrode capacitance in ILs by understanding the balance of ionic interactions and the associated repulsions at electrode–electrolyte interfaces that are pertinent to electrochemical energy storage, electrocatalysis, and electrochemical sensors.

25 ENERGY STORAGE↗

DOE OSTI2021

Electric field reversals resulting from voltage waveform tailoring in Ar/O 2 capacitively coupled plasmas sustained in asymmetric systems

The etching of nanometer scale high-aspect-ratio (HAR) features into dielectric materials in low pressure radio frequency excited plasmas is often accompanied by charge accumulation inside the features which can slow etching rates and produce distortions such as twisting. The intra feature charging is at least partially produced by differences in electron and ion energy and angular distributions (EADs). Positive ions, accelerated to high energies having narrow angular spreads by the sheath electric field, can penetrate deeply into HAR features. Electrons typically arrive at the wafer with nearly thermal and isotropic distributions and do not penetrate deeply into HAR features. These disparities lead to differential charging of the inside of the feature, which can lead to reductions in etch rate and feature distortion due to ion deflection. With in-creasing aspect ratio of features, charging challenges are expected to continue for the foreseeable future. In this work, the use of tailored voltage waveforms in geometrically asymmetric capacitively coupled plasmas sustained in Ar/O 2 at 40 mTorr was computationally investigated with the goal of shaping the EAD of electrons incident onto the substrate to address differential charging. The tailored waveform consisted of a sinusoidal wave and its higher harmonics with a fundamental frequency of 1 MHz. Further, we found that electric field reversals in the sheath and presheath can occur during the anodic portion of the cycle. The electric field reversal increases the energy and decreases the angular spread of electrons incident onto the substrate. The magnitude of the electric field reversal can be controlled by the phase angle of the even harmonics and the gas composition. Due to its electronegative nature, increasing mole fractions of O 2 impedes electron transport to the surface which further increases the electric field reversal.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2021

Mitigating CO 2 Corrosion of Natural Gas Steel Pipelines by Thermal Spray Aluminum Coatings

We report internal pipeline corrosion due to carbon dioxide (CO 2 ) is a major challenge facing the oil and gas industry. The objective of this study was to investigate the corrosion behavior of aluminum (Al)-based alloys as sacrificial coatings to protect pipelines in a CO 2 -saturated aqueous electrolyte (3.5 wt% NaCl) at 4 bar CO 2 partial pressure (3 bar) and 40°C. The corrosion resistance of Al-based alloys and thermal spray coatings was evaluated in an electrochemical reaction autoclave using electrochemical methods (potentiodynamic polarization, linear polarization resistance, and electrochemical impedance spectroscopy). Post-corrosion surface characterization was performed by scanning electron microscopy equipped with energy-dispersive x-ray spectroscopy. The obtained data show Al-based alloys demonstrated promising protection against CO 2 corrosion with no breakaway degradation issues.

36 MATERIALS SCIENCE↗

NASA NTRS1975

Kinetics of boron deposition by the hydrogen reduction of boron trichloride

The chemical vapor deposition of boron filament is generally considered to be limited by the diffusion of the reactive species to the hot substrate. From concentration gradient considerations and from experimental measurements it is concluded that the product species (HCl) is more likely to be involved in limiting the deposition rate. Comparison of theoretically calculated and experimentally measured deposition rates show that the rate is generally partially limited by diffusion and partially by the surface reaction rate (desorption) of HCl. The relative amounts of surface reaction or diffusion rate impedance were determined as a function of temperature and gas velocity. The temperature coefficient for the desorption of HCl was found to be 52 Kcal/mole.

Mehalso, R. M.↗

NASA NTRS1983

Acoustic Ground-Impedance Meter

Helmoltz resonator used in compact, portable meter measures acoustic impedance of ground or other surfaces. Earth's surface is subject of increasing acoustical investigations because of its importance in aircraft noise prediction and measurment. Meter offers several advantages. Is compact and portable and set up at any test site, irrespective of landscape features, weather or other environmental condition.

Zuckerwar, A. J.↗

NASA NTRS1992

Influence of aerodynamic roughness length on aeolian processes: Earth, Mars, Venus

The aerodynamic roughness length (z sub 0) is the height at which a wind profile assumes a zero velocity. The lower part of the atmospheric boundary layer will be impeded by friction with the surface. An increase in surface roughness will also increase the shear stress required to initiate particle entrainment by the wind. Bagnold (1941) estimated z sub 0 as being 1/30 of the mean particle size. In Nature, surface roughness is composed of nonerodible elements as well as sand-size erodible particles. To assess z sub 0 values as a function of terrain, field experiments were conducted to obtain wind profiles monitored over natural surfaces at 15 sites in the Mojave Desert, Death Valley, and Nye County, Nevada. These sites span a variety of arid-land terrains, including smooth playas, alluvial fans, and lava flows; z sub 0 values ranged from 0.0001 cm to 1 cm. These values were incorporated in a threshold model and a flux model to assess transport efficiency over such terrains in three planetary environments (Venus, Earth, and Mars), and for particle sizes ranging from 60-500 micron. Threshold and flux are a function of planetary environment, particle density and size (Dp), and z sub 0, and the shear velocity of 1.2 x U sub *t (for Dp = 250 micron and z sub 0 = 0.84). Results show that flux on Mars is approximately 14 g/(cm x s), on Earth it is approximately 3 g/(cm x s), and on Venus 0.5 g/(cm x s). Under all planetary environments, the results also show a dramatic decrease in the flux for particles greater than 200 microns when z sub 0 increases above 0.0085 cm (corresponding to sites consisting of alluvium). When z sub 0 approaches 0.03 cm (corresponding to a mantled pahoehoe lava), the flux diminishes.

Blumberg, Dan G.↗

NASA NTRS2019

An Investigation of Bifurcation Acoustic Treatment Effects on Aft-Fan Engine Nacelle Noise

Increasing air traffic and more stringent aircraft noise regulations continue to expand requirements on aircraft noise reduction capabilities for conventional and unconventional aircraft configurations. A major component of the overall aircraft noise is the sound associated with the propulsion system mounted in the engine nacelle. Acoustic liners mounted in the aircraft engine nacelles provide a significant portion of the current fan noise reduction. However, they must be further optimized if challenging noise reduction goals are to be achieved. One area within the aft bypass duct that may be an excellent candidate for increased attention is the acoustic treatment on the engine bifurcations (i.e., engine pylon and lower bifurcation). This paper describes a fundamental study of the effects of bifurcation treatment on simulated aft fan noise, as well as the validation of numerical tools to predict such effects. Five bifurcation configurations (four treated and one hardwall) were fabricated and tested in the NASA Langley Curved Duct Test Rig. Results show that mode scattering may occur due to both the presence of the bifurcation, as well as variable impedance distributions on the bifurcation surface. Future work will also include optimization of bifurcation treatments for testing in the Curved Duct Test Rig. These initial results are promising and this work provides valuable information for further study and improvement of the performance of bifurcation acoustic treatments.

Nark, Douglas M.↗

NASA NTRSDate not supplied

Structural Health Monitoring of Vertical Lift Structures Operating in an Urban Environment

Verifying the structural integrity of aeronautical vehicles is of critical importance for the safety of passengers and crew. When operating in a densely populated urban area, pedestrian safety and collateral damage to buildings and other infrastructure also become important concerns. Damage modes, including fatigue from an increased frequency of take-off and landing cycles and a higher probability of impacts from bird strikes, also pose different failure risks as compared to commercial long-haul aircraft and thus require a change in structural health monitoring philosophy. This presentation will review the state of the art in structural health monitoring with an eye toward applications for vertical lift systems operated in the urban environment. Structural health monitoring methods including eddy current, fiber optic, ultrasonic plate wave, surface acoustic wave and electrical impedance tomography will be explored for use in on-board monitoring of impact and overstrain events as well as damage detection and characterization. Infusion of the data into an early warning system to help ensure damage will not propagate to failure during flight will also be discussed.

Russell A Wincheski↗

NASA NTRSDate not supplied

A Fundamental Study of Bifurcation Acoustic Treatment Effects on Aft-Fan Engine Noise

Increasing air traffic and more stringent aircraft noise regulations continue to expand requirements on aircraft noise levels for conventional and unconventional aircraft configurations. A major component of the overall aircraft noise is the sound associated with the propulsion system mounted in the engine nacelle. Acoustic liners mounted in the aircraft engine nacelles provide a significant portion of the current fan noise reduction. However, they must be further optimized if challenging noise reduction goals are to be achieved. One location within the aft bypass duct that may be an excellent candidate for increased attention is the acoustic treatment on the engine bifurcations (i.e., engine pylon and lower bifurcation). This paper presents the continuation of a fundamental study of the effects of bifurcation treatment on simulated aft fan noise and the validation of numerical tools to predict such effects. Five bifurcation configurations (four treated and one hardwall) were fabricated and tested in the NASA Langley Curved Duct Test Rig. Results show that mode scattering may occur due to both the presence of the bifurcation, as well as variable impedance distributions on the bifurcation surface. Future work will also include optimization of bifurcation treatments for testing in the Curved Duct Test Rig. These initial results are promising and this work provides valuable information for further study and improvement of the performance of bifurcation acoustic treatments.

bifurcation effects↗

NASA NTRSDate not supplied

A Fundamental Study of Bifurcation Acoustic Treatment Effects on Aft-Fan Engine Noise

Increasing air traffic and more stringent aircraft noise regulations continue to expand requirements on aircraft noise levels for conventional and unconventional aircraft configurations. A major component of the overall aircraft noise is the sound associated with the propulsion system mounted in the engine nacelle. Acoustic liners mounted in the aircraft engine nacelles provide a significant portion of the current fan noise reduction. However, they must be further optimized if challenging noise reduction goals are to be achieved. One location within the aft bypass duct that may be an excellent candidate for increased attention is the acoustic treatment on the engine bifurcations (i.e., engine pylon and lower bifurcation). This paper presents the continuation of a fundamental study of the effects of bifurcation treatment on simulated aft fan noise and the validation of numerical tools to predict such effects. Five bifurcation configurations (four treated and one hardwall) were fabricated and tested in the NASA Langley Curved Duct Test Rig. Results show that mode scattering may occur due to both the presence of the bifurcation, as well as variable impedance distributions on the bifurcation surface. Future work will also include optimization of bifurcation treatments for testing in the Curved Duct Test Rig. These initial results are promising and this work provides valuable information for further study and improvement of the performance of bifurcation acoustic treatments.

bifurcation effects↗

NASA NTRSDate not supplied

A Fundamental Study of Bifurcation Acoustic Treatment Effects on Aft-Fan Engine Noise

Increasing air traffic and more stringent aircraft noise regulations continue to expand requirements on aircraft noise levels for conventional and unconventional aircraft configurations. A major component of the overall aircraft noise is the sound associated with the propulsion system mounted in the engine nacelle. Acoustic liners mounted in the aircraft engine nacelles provide a significant portion of the current fan noise reduction. However, they must be further optimized if challenging noise reduction goals are to be achieved. One location within the aft bypass duct that may be an excellent candidate for increased attention is the acoustic treatment on the engine bifurcations (i.e., engine pylon and lower bifurcation). This paper presents the continuation of a fundamental study of the effects of bifurcation treatment on simulated aft fan noise and the validation of numerical tools to predict such effects. Five bifurcation configurations (four treated and one hardwall) were fabricated and tested in the NASA Langley Curved Duct Test Rig. Results show that mode scattering may occur due to both the presence of the bifurcation, as well as variable impedance distributions on the bifurcation surface. Future work will also include optimization of bifurcation treatments for testing in the Curved Duct Test Rig. These initial results are promising and this work provides valuable information for further study and improvement of the performance of bifurcation acoustic treatments.

bifurcation effects↗

NASA NTRS1981

Moderate temperature detector development

P-side backside reflecting constant, photodiode characterization, and photodiode diffusion and G-R currents were investigated in an effort to develop an 8 m to 12 m infrared quantum detector using mercury cadmium telluride. Anodization, phosphorus implantation, and the graded band gap concept were approaches considered for backside formation. Variable thickness diodes were fabricated with a back surface anodic oxide to investigate the effect of this surface preparation on the diffusion limited zero bias impedance. A modeling technique was refined to thoroughly model diode characteristics. Values for the surface recombination velocity in the depletion region were obtained. These values were improved by implementing better surface damage removal techniques.

Marciniec, J. W.↗

DOE OSTI2024

Trace Fe activates perovskite nickelate OER catalysts in alkaline media via redox-active surface Ni species formed during electrocatalysis

The accurate description of activity trends among perovskite-oxide oxygen-evolution-reaction (OER) catalysts using electronic-structure descriptors requires that the bulk structure of the catalyst is comparable to that of the surface. Few studies have addressed the dynamic nature of the catalyst's structure during the OER and the consequential implications for understanding activity. Here, we use a combination of electrochemical and materials-characterization techniques to study the surface reconstruction and the associated formation of a new redox-active phase on LaNiO 3 particles, LaNiO 3 epitaxial films, and an analogous Ruddlesden-Popper phase, La 2 NiO 4 . Small, but characteristic, redox features corresponding to Ni redox in nominally amorphous NiO x H y are observed during cyclic voltammetry of these initially fully crystalline materials. The size of these redox features grows with prolonged cycling and contributes to an increased surface area as determined from electrochemical impedance spectroscopy (EIS). Here we find the OER activity is strongly dependent on soluble Fe species in the electrolyte, common impurities in alkaline media. These observations are consistent with the reconstruction of the crystalline surface to form NiO x H y species and subsequent activation by adsorption of Fe forming the well-known and extremely active NiFeO x H y OER catalyst.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗