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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

High Data Rate Architecture (HiDRA)

One of the greatest challenges in developing new space technology is in navigating the transition from ground based laboratory demonstration at Technology Readiness Level 6 (TRL-6) to conducting a prototype demonstration in space (TRL-7). This challenge is com- pounded by the relatively low availability of new spacecraft missions when compared with aeronautical craft to bridge this gap, leading to the general adoption of a low-risk stance by mission management to accept new, unproven technologies into the system. Also in consideration of risk, the limited selection and availability of proven space-grade components imparts a severe limitation on achieving high performance systems by current terrestrial technology standards. Finally from a space communications point of view the long duration characteristic of most missions imparts a major constraint on the entire space and ground network architecture, since any new technologies introduced into the system would have to be compliant with the duration of the currently deployed operational technologies, and in some cases may be limited by surrounding legacy capabilities. Beyond ensuring that the new technology is verified to function correctly and validated to meet the needs of the end users the formidable challenge then grows to additionally include: carefully timing the maturity path of the new technology to coincide with a feasible and accepting future mission so it flies before its relevancy has passed, utilizing a limited catalog of available components to their maximum potential to create meaningful and unprecedented new capabilities, designing and ensuring interoperability with aging space and ground infrastructures while simultaneously providing a growth path to the future. The International Space Station (ISS) is approaching 20 years of age. To keep the ISS relevant, technology upgrades are continuously taking place. Regarding communications, the state-of-the-art communication system upgrades underway include high-rate laser terminals. These must interface with the existing, aging data infrastructure. The High Data Rate Architecture (HiDRA) project is designed to provide networked store, carry, and forward capability to optimize data flow through both the existing radio frequency (RF) and new laser communications terminal. The networking capability is realized through the Delay Tolerant Networking (DTN) protocol, and is used for scheduling data movement as well as optimizing the performance of existing RF channels. HiDRA is realized as a distributed FPGA memory and interface controller that is itself controlled by a local computer running DTN software. Thus HiDRA is applicable to other arenas seeking to employ next-generation communications technologies, e.g. deep space. In this paper, we describe HiDRA and its far-reaching research implications.

DTN↗

Calorimetric metal vapor adsorption energies for characterizing industrial catalyst support materials

Many important catalysts and electro-catalysts for energy and environmental technologies involve late transition metal atoms and nanoparticles dispersed across the surface of high-surface-area support materials, for example, oxide nanoparticles. The surface reactivity and long-term stability against deactivation of these materials depends strongly on the strength of bonding of the metal atom and nanoparticles to the support surface. Here, we introduce a novel calorimetry method that implements a LiTaO 3 crystal for heat detection and extends metal adsorption calorimetry to surfaces of nanomaterials that are deposited from liquid solutions, as is typical when preparing industrial catalyst supports. This allows one to measure the strength of metal atom bonding and the adhesion energy of metal nanoparticles to clean surfaces of technologically relevant catalyst supports. We demonstrate that here by measuring the heat of Ag vapor adsorption onto the clean surfaces of high-surface-area TiO 2 anatase powdered support materials (i.e., 5-nm-diameter nanoparticles). These heats of adsorption show a pulse-to-pulse standard deviation of only 9.3 kJ/mol (3.3%) for pulses containing only 1% of a monolayer of Ag vapor, with potential for a 5-fold reduction in noise if used with another metal evaporator. The calorimeter was also proven to work well measuring heats of Ag adsorption on calcium niobate(001) nanosheets deposited as thin films from liquid solution. Here, this calorimeter opens up the possibility of using metal adsorption calorimetry to screen catalyst support materials for the strengths with which they bind metal atoms and metal nanoparticles, offering new opportunities to discover better support materials or for basic scientific study of structure / function relationships with respect to metal / support bond energies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

From the Discovery of the Giant Magnetocaloric Effect to the Development of High‐Power‐Density Systems

Caloric cooling and heating promise an efficient and reliable alternative to ubiquitous vapor-compression technology. In 1976, the very first near-room-temperature caloric system is developed, but it took another 20 years for this technology to fully bloom and gain global attention. The discovery of the giant magnetocaloric effect in Gd 5 Si 2 Ge 2 and the advance of the first long-operating magnetic refrigerator, both in 1997, due to the Ames National Laboratory and Astronautics Corporation of America cooperation, are two milestones that sparked ongoing interest in caloric research, which continues to thrive to this day. This review presents a brief history of caloric heat pumping, from the discovery of the magnetocaloric effect to the most recent developments in materials and systems. The contributions of Ames National Laboratory of the U.S. Department of Energy are highlighted, celebrating its 30-year anniversary in caloric research and paying tribute to two outstanding scientists, Vitalij K. Pecharsky and Karl A. Gschneidner, Jr., who inspired the caloric community for decades. The paper concludes with insights into remaining research and development challenges that must be addressed to enable the market transition of caloric technology and its widespread adoption.

caloric materials↗

Evaluation of coal-associated sediments, wastes, and AMD sludge in the Southern Appalachian Basin as feedstock materials for REE and Li recovery

Critical minerals (CM) such as rare earth elements (REE+) and Lithium (Li) are essential to technological innovation, energy transitions, global economic and defense security, necessitating the search for unconventional resources and efficient recovery methods to avert supply chain disruptions. Here, this study evaluates coal-associated sediments (underclay and roof rock) and wastes from the Pennsylvanian Pottsville Formation of the Southern Appalachian Basin (SAB) as potential feedstocks for CM recovery. A total of 34 samples (15 underclays, 12 roof rocks, 5 Acid Mine Drainage (AMD) sludges, and 2 coal mining wastes) were characterized using XRD, XRF, ICP-MS, and μ-XRF analytical methods. The REE+ and Li concentrations of these materials ranged from 46.8 to 334.4 ppm and from 11.1 to 519 ppm, respectively, with one underclay sample (Hendrix 3456) yielding the highest values for both. Bulk mineralogy for all samples was dominated by aluminosilicate clay phases, particularly illite and kaolinite. All samples exhibited REY def, rel% values >26% and C outl indices that ranged from 0.69 to 0.94, classifying their REE ore potential as Category II (Promising) as defined by Seredin and Dai (2012). Extractability tests (EPA method 3051 A) yielded low REE+ and Li recoveries, with maximum values of 3.3% and 3.6%, respectively, suggesting associations with resistant minerals like clay and phosphates. Elemental mapping indicates that REE+ is associated with phosphate, whereas statistical analysis suggests that REE+ are associated with aluminosilicates, suggesting heterogeneous associations or minimal phosphate contribution. Li also correlated positively with Al 2 O 3 , indicating an aluminosilicate host. This study highlights the potential of coal-associated sediments in the SAB.

Clay minerals↗

Bridging the gap between academic research and industrial development in advanced all-solid-state lithium–sulfur batteries

The energy storage and vehicle industries are heavily investing in advancing all-solid-state batteries to overcome critical limitations in existing liquid electrolyte-based lithium-ion batteries, specifically focusing on mitigating fire hazards and improving energy density. All-solid-state lithium–sulfur batteries (ASSLSBs), featuring earth-abundant sulfur cathodes, high-capacity metallic lithium anodes, and non-flammable solid electrolytes, hold significant promise. Despite these appealing advantages, persistent challenges like sluggish sulfur redox kinetics, lithium metal failure, solid electrolyte degradation, and manufacturing complexities hinder their practical use. Further, to facilitate the transition of these technologies to an industrial scale, bridging the gap between fundamental scientific research and applied R&D activities is crucial. Our review will address the inherent challenges in cell chemistries within ASSLSBs, explore advanced characterization techniques, and delve into innovative cell structure designs. Furthermore, we will provide an overview of the recent trends in R&D and investment activities from both academia and industry. Building on the fundamental understandings and significant progress that has been made thus far, our objective is to motivate the battery community to advance ASSLSBs in a practical direction and propel the industrialized process.

25 ENERGY STORAGE↗

Leveraging chiral induced spin selectivity to improve the efficiency and selectivity of electrocatalytic reduction

Energy production is a fundamental pillar of modern society, but it remains heavily reliant on fossil fuel combustion, which leads to environmental degradation and resource depletion. Electrocatalytic reduction reactions (ERRs) offer a cleaner alternative by functioning under mild conditions, eliminating the need for high temperatures or pressures. However, their widespread adoption is hindered by challenges such as low efficiency, inadequate selectivity, and sluggish kinetics. Here, the introduction of chiral-induced spin selectivity (CISS) offers a promising strategy to address these limitations by reducing energy barriers in reactions involving spin-sensitive intermediates or transition states. By leveraging CISS, ERR pathways can be manipulated to favor desired reactions, enhance product yield, and suppress unwanted byproducts, improving selectivity. Beyond reducing the impact of competing side reactions, CISS also enhances the kinetics of ERRs by accelerating reaction rates and lowering the energy barriers associated with multi-electron transfer steps. Thanks to its straightforward and versatile application, CISS shows significant potential in optimizing well-studied ERRs, such as the hydrogen evolution reaction (HER) and carbon dioxide reduction reaction (CO2RR), facilitating the future transition of these technologies from research laboratories to commercial energy plants worldwide.

14 SOLAR ENERGY↗

Phase comparison and equation of state for Ta 2 O 5

Abstract Tantalum pentoxide (Ta 2 O 5 ) is among the most technologically useful heavy transition metal oxides. Unfortunately, its crystal structure is the subject of long-standing and unresolved disagreement. Among other consequences, this uncertainty has made it impossible to formulate a robust high pressure equation of state for Ta 2 O 5 . Here, we report the results of high pressure x-ray diffraction experiments indexed against a comprehensive list of proposed Ta 2 O 5 phases. Five of the proposed phases produce good matches to experimental observations, and the compressibility parameters for these phases are all consistent within uncertainty. This means that regardless of the particular phase chosen, the Ta 2 O 5 equation of state can be described with bulk modulus K 0 = 138 ± 3.68 GPa and pressure derivative K 0 ′ = 1.82 ± 0.45 . Combining these experimental results with new density-functional theory calculations allows us to identify the λ phase as the best structural model of Ta 2 O 5 at ambient conditions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Testing GFM and GFL Inverters Operating With Synchronous Condensers

Inverter-based resources (IBRs) are quickly evolving into a source of reliability services to the electric grid. Penetration levels of variable generation are rapidly increasing, ranging from 60% -70% in some systems. To go further, a fundamental shift is required to address challenges associated with grid stability. Synchronous condensers (SCs) are considered an important complementary technology in such transitions. This paper provides one-of-a-kind insights into real experimental results from operating a real MW-scale system consisting of a 2.2-MVA grid-forming (GFM) and grid-following (GFL) battery energy storage system, 2.5-MVA SCs, and a 3-MVA load bank operating as a small, islanded grid. Challenges that are expected in larger systems were mimicked in this small but real system to demonstrate seamless transitions from one mode to another as well as stable operation with different combinations of GFM and GFM resources, including a "loss of last synchronous generator" case. The experimental results presented in this paper are a valuable resource to everyone involved in developing and validating models or developing controls of power systems consisting of inverters and synchronous condensers.

grid-following converter↗

CMOS-fabricated ultraviolet light modulator using low-loss alumina piezo-optomechanical photonics

Ultra-violet (UV) and near-UV wavelengths are necessary for many important optical transitions for quantum technologies and various sensing mechanisms for biological and chemical detection. However, all well-known photonic platforms have excessively high losses in the UV, which has prevented photonic integrated circuits (PICs) being used to address these and other important application spaces. Photonic waveguides using low-loss alumina cores and silicon dioxide cladding have emerged as a promising solution because of alumina’s large optical bandgap and the high quality of films enabled by atomic layer deposition. These properties allow passive, low-loss waveguide operation down to at least 266 nm using multimode widths. However, to the best of our knowledge, active alumina PICs have only been realized using thermo-optic tuning, which precludes switching speeds shorter than approximately 100 microseconds, high circuit densities, and cryogenically compatible operation. Here, we introduce a CMOS-fabricated, piezo-optomechanical PIC platform using alumina waveguides and piezoelectric aluminum nitride strain actuators. The platform allows for sub-microsecond switching times, high circuit densities, and cryogenic operation which is desired in many UV PIC applications. We demonstrate a high-performance, reconfigurable optical filter operating at wavelengths as low as 320 nm. The filter has a 6-nanosecond switching time, a loaded linewidth of 3.3 GHz, tuning rate of 28 V/linewidth, and a hold power of less than 20 nW at one linewidth detuning. This work establishes the foundations for a new class of CMOS-fabricated, rapidly reconfigurable, and low-power UV photonic circuits compatible with wavelengths as low as 225 nm.

Castillo, Zachary A. [Sandia National Laboratories↗

Formulation via Resonant Acoustic Mixing at LANL

Discussions in the middle of 2014 led researchers at LANL to seek an alternate formulation method for making PBX based explosives. We began looking into the use of Resonant Acoustic Mixers (RAM) to formulate explosives and mocks. Acoustic mixing had been used in pharmaceutical plants for mixing medicines and coating materials, so we envisioned transitioning that same technology to the energetics world. Up until this time only the wet slurry formulation method that had been used was from the 1940’s. This wet slurry method had been and still was the standard for all explosive formulations. The possibility of an alternate method needed to be looked at to advance the process by expanding solvent choices, substrates, and reducing costs. Acoustic mixing had been shown to mix powders, slurries, pastes or even liquids. A Resodyn LabRAM was purchased in late 2014 to explore these possible applications to energetics. This LabRAM was in a remote configuration that met our need for explosive operations.

36 MATERIALS SCIENCE↗

Quantum Random Number Generator (QRNG)

The Los Alamos QRNG is a hardware-based high-performance Random Number Generator capable of generating 200 Mbit/s or more of true random numbers. The device harvests entropy from fluctuations in an optical source that arise from quantum mechanical properties of light. These quantum effects are irreducibly random; the resulting numbers are unpredictable and beyond the influence of any adversary. Qrypt, Inc., launched in 2017, has amassed multiple quantum entropy sources to create high-quality random keys at scale. The company is engaging with Los Alamos through license and a Cooperative Research and Development Agreement to facilitate the transition of QRNG technology and deploy the technology into the marketplace.

97 MATHEMATICS AND COMPUTING↗

Electricity demand in South Asia – data gaps and pathways for research and modeling

South Asia is one of the fastest growing regions - economically and energy-wise in the world. However, there are significant uncertainties in how the energy demand would grow given the rapidly rising incomes, urbanization, industrialization, access to energy, warming climate and technological change. The transition to clean energy in the region is a priority and is critical to limiting emissions in the region and increasing regional energy security. The power sector will play an important role in decarbonization of energy systems, lowering emissions in other sectors through electrification. However, as existing end uses are scaled up more and new end uses are electrified, the temporal and spatial patterns of electricity consumption could change. These changes have implications for the magnitude, shape, and timing of peak demand, which in turn affects the power sector’s investments and operations, and ability to provide reliable power. In this report, we outline key uncertainties in demand growth that South Asian countries would face in the near to medium term, along with summarizing insights from stakeholder consultations we held over the past 6 months.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

CyclusJS: A Distributed Web-based Fuel Cycle Visual Analytics. Research Performance (Final Report)

The overall aim of the CyclusJS project has been to design novel approaches that support fuel cycle simulations and empower decision-makers and researchers with better tools to compare and contrast results from multiple simulations to understand the landscape of potential outcomes better. In particular, nuclear fuel cycle simulations focus on modeling the nuclear industry and ecosystem at a macroscopic level, and the analysis tools connect such simulations with decision support systems. As a demonstration of the novelty and effectiveness of the proposed approach, we study scenarios for transitioning from one technology, Light Water Reactors (LWR), to a newer Sodium-cooled Fast breeder Reactor (SFR) technology.

60 APPLIED LIFE SCIENCES↗

New Mexico Clean Energy and Resilience Growth (NM CERG) Cluster

The New Mexico Clean Energy Resilience and Growth (NM CERG) project was designed to foster a clean energy cluster in New Mexico by providing a robust pipeline of support for clean-energy technology startups. By leveraging the expertise and resources of national laboratories, universities, and regional partners, the project contributed to a deeper understanding of how public-private partnerships can enhance the commercialization of innovative clean energy technologies. The project explored the key challenges faced by startups, such as securing capital, rapid prototyping, technology validation, and transitioning from research to market-ready products.

02 PETROLEUM↗

Rare earth element enrichment in coal and coal-adjacent strata of the Uinta Region, Utah and Colorado

This study aims to quantify rare earth element enrichment within coal and coal-adjacent strata in the Uinta Region of central Utah and western Colorado. Rare earth elements are a subset of critical minerals as defined by the U.S. Geological Survey. These elements are used for a wide variety of applications, including renewable energy technology in the transition toward carbon-neutral energy. While rare earth element enrichment has been associated with Appalachian coals, there has been a more limited evaluation of western U.S. coals. Here, samples from six active mines, four idle/historical mines, four mine waste piles, and seven stratigraphically complete cores within the Uinta Region were geochemically evaluated using portable X-ray fluorescence ( n = 3,113) and inductively coupled plasma-mass spectrometry ( n = 145) elemental analytical methods. Results suggest that 24%–45% of stratigraphically coal-adjacent carbonaceous shale and siltstone units show rare earth element enrichment (>200 ppm), as do 100% of sampled igneous material. A small subset (5%–8%) of coal samples display rare earth element enrichment, specifically in cases containing volcanic ash. This study proposes two multi-step depositional and diagenetic models to explain the enrichment process, requiring the emplacement and mobilization of rare earth element source material due to hydrothermal and other external influences. Historical geochemical evaluations of Uinta Region coal and coal-adjacent data are sparse, emphasizing the statistical significance of this research. These results support the utilization of active mines and coal processing waste piles for the future of domestic rare earth element extraction, offering economic and environmental solutions to pressing global demands.

Coe, Haley H.↗

Intelligent systems/software engineering methodology - A process to manage cost and risk

A systems development methodology is discussed that has been successfully applied to the construction of a number of intelligent systems. This methodology is a refinement of both evolutionary and spiral development methodologies. It is appropriate for development of intelligent systems. The application of advanced engineering methodology to the development of software products and intelligent systems is an important step toward supporting the transition of AI technology into aerospace applications. A description of the methodology and the process model from which it derives is given. Associated documents and tools are described which are used to manage the development process and record and report the emerging design.

Friedlander, Carl↗

An Assessment of IMPAC - Integrated Methodology for Propulsion and Airframe Controls

This report documents the work done under a NASA sponsored contract to transition to industry technologies developed under the NASA Lewis Research Center IMPAC (Integrated Methodology for Propulsion and Airframe Control) program. The critical steps in IMPAC are exercised on an example integrated flight/propulsion control design for linear airframe/engine models of a conceptual STOVL (Short Take-Off and Vertical Landing) aircraft, and MATRIXX (TM) executive files to implement each step are developed. The results from the example study are analyzed and lessons learned are listed along with recommendations that will improve the application of each design step. The end product of this research is a set of software requirements for developing a user-friendly control design tool which will automate the steps in the IMPAC methodology. Prototypes for a graphical user interface (GUI) are sketched to specify how the tool will interact with the user, and it is recommended to build the tool around existing computer aided control design software packages.

Walker, G. P.↗

First Results From the GeoSAR Mapping Instrument

Geosynchronous Synthetic Aperture Radar (GeoSAR) is a consortium project consisting of The Jet Propulsion Laboratory (JPL), Calgis (a small GIS company based in Fresno, CA) and the California Department of Conservation with funding provided by Defense Research Projects Agency (DARPA) started in November 1996. The two main objectives of the GeoSAR Program are: 1) To develop a state of the art dual frequency interferometric radar mapping instrument capable of mapping the true ground surface height beneath the vegetation canopy; and 2) To transition this mapping technology to a commercial company, Calgis. JPL, the technical lead, has the following program deliverables at program completion in November 1999 include radar design and radar hardware for X-band (3 cm) and P-band (83 cm) radars, processor software, hardware and documentation, and calibrated X-band radar.

Hensley, Scott↗