Flash photolysis of ketene and diazomethane - The production and reaction kinetics of triplet and singlet methylene
Ketene and diazomethane flash photolytic measurement of reaction rates of singlet-triplet methylene deactivation
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Ketene and diazomethane flash photolytic measurement of reaction rates of singlet-triplet methylene deactivation
Single to triplet transitions of water vapor as function of scattering angle in electron impact detection
Self consistent field /SCF/ calculations of dipyridine glyoxal and bianthrone photoproduct molecules with triplet ground state, using unrestricted Hartree-Fock theory
Calculated spectral line profiles (intensity distributions) of the helium triplet diffuse series were obtained using the quasi-static approximation for ions and electrons. In these calculations, Doppler broadening, although negligible in most of the cases, was included as a device to avoid singularities. Plots and tabulations of the calculated profiles are presented, in addition to a discussion of the computational procedure and the validity of the calculations.
Double pass photoelectric observations are presented of five CaII lines (H, K, 8498 A, 8542 A, and 8662 A) in a number of solar plages of different degrees of activity, quiet regions, and a sunspot. The data are compared with previous work. All five lines show increasing emission together in plages, and the least opaque of the infrared triplet lines appears to exhibit core emission prior to the more opaque members of the multiplet. The question of source function equality is considered and the differences and similarities among plage profiles and between plage and quiet profiles are shown qualitatively and quantitatively.
The results of the configuration calculations of six singlet electronic states and one triplet electronic state of CO are presented. The potential energy curves, spectroscopic constants, and electron transition moments are calculated, along with electronic dipole moment functions for three states. The self consistent field and configuration calculations used to obtain the electronic wave functions are described. The theoretical results are found to be in good agreement with the experimental measurements, and in the case of the dipole moment function calculations, preferable to them.
Previous work in this area is surveyed and the mathematics involved in determining the quantitative intensity measurements in triplet bands is presented. Explicit expressions for the intensity distribution in the branches of the 3 Sigma-3 Pi and 1 Sigma-3Pi bands valid for all values of the coupling constant Y of the 3 Pi terms are given. The intensity distribution calculated according to the formulas given is compared with measurements of PH, 3 Pi-3 Sigma. Good quantitative agreement is obtained.
The vinylidene radical (H2C = C) is proposed as an intermediate in the combination reaction of triplet methylene. The conclusion is based upon the distribution of isotopic acetylenes produced from a 1:1 mixture of CD2 and CH2. The path of the reaction and the energetics of the intermediate species are discussed.
A new series of vibrational bands is predicted which arises from transitions between the lowest electron states of the triplet and singlet states of homonuclear C2. The predictions are useful for C2 identifications and for disentangling congested low resolution spectra that characterize new observations. Predictions are also made for Mulliken, Phillips, and Ballik-Ramsay band sequences, and all calculations are made with the assumed molecular constants and computational methods of KSO-II.
Profile variations from center to limb, as well as at different heights above the quiet solar limb, are illustrated by profile observations of the solar O I resonant triplet at 1302, 1304, and 1306 A that were obtained with the Skylab S082-B spectrograph. Since these lines share a common upper energy level, source function equality should exist for them when the lower states are populated according to their statistical weights. Profile congruency and profile inversion calculations comparisons show, however, that this is not the case, suggesting either errors in the fine structure collision rates, or the H I Ly-beta flux preferentially depopulating the 1302 A lower level, or two-dimensional transfer effects.
Resonance fluorescence theory was used to calculate the population distribution in the energy states of the C2 molecule in comets. Ten electronic states, each with 14 vibrational states, were used in the calculations. These new calculations differ from earlier work in terms of additional electronic levels and the role of singlet-triplet transitions between the b and X levels. Since transition moments are not known, calculations are made of observable flux ratios for an array of possible values. Comparison with existing observations indicates that the a-X transition is very important, and there is marginal indication that the b-X transition is present. Swan band sequence flux ratios at large heliocentric distance are needed, as are accurate Mulliken/Swan and Phillips/Ballik-Ramsay (1963) observations.
Planar light scattering has been used to investigate the turbulent mixing in a multi-element triplet injector at mixture ratio conditions typical of liquid rocket engine gas generators. Experiments were conducted at atmospheric pressure using air seeded with smoke particles to simulate the oxidizer flow and unseeded air to simulate the fuel. Data sets of 200 images (containing 122,000 simultaneous measurements each) of the instantaneous distribution of the scattered light were acquired at several positions throughout the flow. These images have been processed digitally to produce local distributions of the average and rms fluctuation of the mixture fraction. In addition, the spatial autocorrelation of the images has been calculated and analyzed to determine a mean length scale related to the large scale structures in the flow.
Estimates were made of the full-disk line profiles of the solar O I resonant triplet at 1304 A, using data from the SMM and the Orbiting Solar Observatory 8 for the time period 1975-1985. The observed line profiles are parameterized using a nonlinear least squares fit of the data by a simple empirical representation of the general line shape. The derived full-disk line shape parameters may be used, in combination with an appropriate value for the line-integrated full-disk solar flux, in the analysis of planetary or cometary O I 1304-A observations under any solar conditions.
An accurate effective core potential (ECP), including frozen 3s, 3p orbitals and a single-zeta contracted 3d orbital, has been developed for germanium. The ECP with associated valence basis set reproduces the corresponding all-electron results for the atomic excitations and the geometry and excitation energies of GeH2. At the SCF, CAS SCF and CI levels the maximum difference from the all-electron results is 0.5 kcal/mol in the (sup 1)A(sub 1) - (sup 3)B(sub 1) excitation energy. Finally, the ECP description is used with an extended valence basis set and large-scale CAS SCF and multi-reference CI wavefunctions to compute the singlet-triplet separation; the final CI result including the Davidson correction is 22.5 kcal/mol.
The stars observed by onboard star trackers must be identified in order for the star tracker information to be used for attitude determination. Star identification associates the observed stars in the body frame with catalog stars, the positions of which in an inertial frame are well known. If the attitude is approximately known (from less accurate sensors) identification is relatively simple, but if there is no prior attitude knowledge (the Lost in Space problem) star identification is quite difficult. A new, reliable, and accurate star identification algorithm has been developed for use in a batch, ground-based attitude determination system. The identification algorithm uses input from one or more star trackers, each of which can observe three or more stars simultaneously. If observations are available at different times, rate data is used to relate them. The algorithm includes the following steps that are automatically performed: 1) Observations are examined to determine the optimal set of simultaneous star observations in a single tracker. 2) The selected optimal observations are identified using a triplet match. 3) The identified stars in the selected tracker at the selected time are used to compute an attitude at that time. 4) The rate data is refined by determination of biases that minimize the dispersion of repeated observations of the same stars. 5) The refined rate data is used to propagate the attitude to the times of each star observation. 6) The attitude at each time is used to associate all stars observed at that time, in each tracker, with catalog stars. The overall algorithm is very dependable at producing accurate star identification with no initial attitude input.
In the present work (this paper), we have measured the photoabsorption cross section of 0(sub 2) at the OI triplet lines (1302.17, 1304.86, 1306.03u at temperatures 295, 373, 473, and 573K.
Detonation combustion devices such as rotating detonation rocket engines (RDREs) have been proposed as an alternative to traditional deflagration engines as detonative combustion has a higher theoretical thermodynamic efficiency. Improved performance of an RDRE depends heavily on the propellant injection and mixing. Impingement type injectors have been shown to achieve higher characteristic velocity or combustion efficiency for both detonative and deflagrative engines. This work is exploratory in nature and focuses on unlike triplet impinging injectors to study how the flow area of the injector affects the mixing of propellants and recovery under the transient, high-peak pressure conditions unique to RDREs. A ratio of fuel flow area to oxidizer flow area is set to achieve a given mass flow rate and thus propellant mixture ratio. Four different fluid flow areas are studies while keeping the fuel/oxidizer ratio constant. This work has found that, while maintaining a fixed ratio fuel to oxidizer flow area, the injectors with smaller orifice areas show better resistance to backflow in steady state tests and have shorter recovery times in backflow experiments. Even with the shorter recovery times, it is found that the shortest recovery time is still an order of magnitude slower than the frequency of a single detonation wave traversing a 3” RDRE.
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