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NASA NTRS1989

Combined microwave science and propulsion

The combined use of high-power active science instruments and high-power electric propulsion is investigated with a view to new science opportunities and measurements on future planetary missions. An example of a comet rendezvous mission that could benefit from this combination is discussed. It was found that, with electric propulsion, the launch mass of the comet spacecraft could be reduced by 61-68 percent over the chemical propulsion baseline mission. This high-power spacecraft is also capable of delivering a significant high-power radar science payload to the comet.

Palaszewski, Bryan↗

NASA NTRS1989

Chondrules in the Sharps H3 chondrite - Evidence for intergroup compositional differences among ordinary chondrite chondrules

Bulk compositions of 19 chondrules and one matrix-rich sample from H3.4 Sharps were determined by instrumental neutron activation analysis. Samples were characterized petrographically, and mineral compositions were determined by electron microprobe analysis. There is constancy among ordinary chondrite (OC) groups in the compositional interrelationships of different chondrule types; e.g., in H3 as well as L3 and LL3 chondrites, porphyritic chondrules are more refractory than nonporphyritic chondrules. Precursor components of H3 chondrules are closely related to those of LL3 chondrules. The mean Ir/Ni, Ir/Co, and Ir/Au ratios of H3 chondrules differ from the corresponding ratios of LL3 chondrules at the 99, 90, and 79 percent confidence levels, respectively. The ratios in H3 chondrules exceed those in LL3 chondrules by amounts similar to those by which H whole-rocks exceed LL whole-rocks. These data suggest that there are primary systematic differences in bulk composition between H and LL chondrules. These differences support the inference that chondrule formation occurred after major nebular fractionation events had established the observed bulk compositional differences among OC groups.

Rubin, Alan E.↗

NASA NTRS1989

Workshop on Analysis of Returned Comet Nucleus Samples

This volume contains abstracts that were accepted by the Program Committee for presentation at the workshop on the analysis of returned comet nucleus samples held in Milpitas, California, January 16 to 18, 1989. The abstracts deal with the nature of cometary ices, cryogenic handling and sampling equipment, origin and composition of samples, and spectroscopic, thermal and chemical processing methods of cometary nuclei. Laboratory simulation experimental results on dust samples are reported. Some results obtained from Halley's comet are also included. Microanalytic techniques for examining trace elements of cometary particles, synchrotron x ray fluorescence and instrument neutron activation analysis (INAA), are presented.

Source record↗

NASA NTRS1989

The measurement of trace elements in interplanetary dust and cometary particles by ultra-high sensitivity INAA

Today the major elemental composition of interplanetary dust particles (IDPs) is routinely determined in many laboratories. These and mineralogical studies have revealed the presence of at least two major types of IDPs, chondritic and refractory. Preliminary results of a successful attempt to determine abundances of a large suite of trace elements from both chondritic and refractory IDPs are reported. The analytical procedure can be used in the grain-by-grain analysis of returned cometary samples. Chondritic and refractory IDPs are characterized by standard scanning electron microscopy and energy dispersive x ray spectroscopy (SEM-EDX) techniques. With this system, detection limits for many elements are well below picogram levels, and some approach femtogram levels. This technique is non-destructive, although some sample handling is required, so particles can be analyzed by other techniques after instrument neutron activation analysis (INAA) is completed. Data is presently being reduced from the analyses of 7 IDPs. These are U2015E10, U2015F1, W7029-A2, W7029-A3, W7013A8, LACl (all chondritic) and 705 (refractory). So far, 17 different major and trace elements were detected and measured in these particles, including rare earths and some very volatile elements (Br and Zn).

Zolensky, M. E.↗

NASA NTRS1990

Highly evolved and ultramafic lithologies from Apollo 14 soils

Eighteen 2-4-mm fragments were extracted from several Apollo 14 soil samples and examined by instrumental neutron activation analysis, and were studied petrographically. Results indicate that these rock fragments span almost the whole range of magma evolution, from ultramafic cumulates to extreme differentiates that were apparently produced by silicate liquid immiscibility. Three of the fragments are dimict granitic breccias composed of granitic clasts intruded by a ferropyroxenitic glass, and may represent an immmiscible melt pair that has been remixed by impact. Two fragments are ultramafic rocks, including a dunite with very low REE abundances and a peridotite/impact melt breccia.

Morris, R. W.↗

NASA NTRS1991

Microprobe studies of microtomed particles of white druse salts in shergottite EETA 79001

The white druse material in Antarctic shergottite EETA 79001 has attracted much attention as a possible sample fo Martian aqueous deposits. Instrumental Neutron Activation Analysis (INAA) was used to determine trace element analyses of small particles of this material obtained by handpicking of likely grains from broken surfaces of the meteorite. Electron microprobe work was attempted on grain areas as large as 150x120 microns. Backscattered electron images show considerable variations in brightness, and botryoidal structures were observed. Microprobe analyses showed considerable variability both within single particles and between different particles. Microtomed surfaces of small selected particles were shown to be very useful in obtaining information on the texture and composition of rare lithologies like the white druse of EETA 79001. This material is clearly heterogeneous on all distance scales, so a large number of further analyses will be required to characterize it.

Lindstrom, D. J.↗

NASA NTRS1991

Movement of Trace Elements During Residence in the Antarctic Ice: a Laboratory Simulation

Recent work has determined that differences in the trace element distribution between Antarctic eucrites and non-Antarctic eucrites may be due to weathering during residence in the ice, and samples that demonstrate trace element disturbances do not necessarily correspond to eucrites that appear badly weathered to the naked eye. This study constitutes a preliminary test of the idea that long-term residence in the ice is the cause of the trace element disturbances observed in the eucrites. Samples of a non-Antarctic eucrite were leached in water at room temperature conditions. Liquid samples were analyzed for rare earth element abundances using ion chromatography. The results for the short-term study showed little or no evidence that leaching had occurred. However, there were tantalizing hints that something may be happening. The residual solid samples are currently being analyzed for the unleached trace metals using instrumental neutron activation analysis and should show evidence of disturbance if the chromatography clues were real. In addition, another set of samples continues to be intermittently sampled for later analysis. The results should give us information about the movement of trace elements under our conditions and allow us to make some tentative extrapolations to what we observe in actual Antarctic eucrite samples.

Strait, Melissa M.↗

NASA NTRS1991

Paired lunar meteorites MAC88104 and MAC88105 - A new 'FAN' of lunar petrology

To determine the chemical characteristics of the MAC88104/5 meteorite six thin sections and three bulk samples were analyzed by electron microprobe and instrumental neutron activation. It is concluded that this meteorite is dominated by lithologies of the ferroan anorthosite suite and contains abundant granulitized highland clasts, devitrified glass beads of impact origin, and two small clasts of basaltic origin. It is suggested that one of these basaltic clasts, clast E, is mesostasis material, and clast G is similar to the very low-Ti or low-Ti/high-alumina mare basalts. Impact melt clasts MAC88105, 69, and 72 have major and trace element compositions similar to the bulk meteorite.

Neal, Clive R.↗

NASA NTRS1992

Classification of mafic clasts from mesosiderites - Implications for endogenous igneous processes

Results are presented from an analysis of 13 igneous pebbles from the Vaca Muerta, EET87500, and Bondoc mesosiderites, using electron microprobe and instrumental neutron activation techniques. These data, combined with literature data on compositions of 43 mesosiderite clasts were used to compile a classification scheme for the various types of mafic silicate clasts that occur in mesosiderites. These clasts were classified into five principal groups: (1) polygenic and monogenic cumulates (30 percent); (2) polygenic basalts (30 percent); (3) quench-textured rocks, comprising two compositional subgroups (those which resemble basaltic eucrites (5 percent), and those which resemble cumulate eucrites (2 percent)); (4) monogenic basalts (11 percent); and (5) ultramafic rocks, consisting mainly of large crystals of orthopyroxene (9 percent) or olivine (4 percent). The conditions under which these clasts were formed are discussed.

Rubin, Alan E.↗

NASA NTRS1992

Troctolitic anorthosite from 77115: A magnesian member of the alkalic suite

Alkalic suite pristine nonmare rocks are distinctly enriched in plagiophile elements such as Na and K, as well as generally incompatible elements, despite modes and textures more characteristic of typical crustal cumulates (most commonly anorthosites) than of the basaltic KREEP rocks that appear to account for the bulk of the lunar crust's total complement of incompatible elements. Our studies indicate that the 77115 troctolitic clasts of Winzer et al. is actually a troctolitic anorthosite (or anorthositic troctolite), probably best classified as a member of the alkalic suite. We managed to obtain a thin section with pyroxene and olivine, and analyzed a 13.4-mg chip by instrumental neutron activation analysis (INAA). The results of this analysis are briefly discussed.

Warren, Paul H.↗

NASA NTRS1992

Geochemistry and petrology of primitive achondrite meteorites LEW 88280, MAC 88177, ALHA 81187, EET 84302, and LEW 88663

Primitive achondrites are meteorites that have mineral and bulk chemical compositions similar to the most primitive meteorites (chondrites) but have textures similar to more evolved meteorites (achondrites). The unique geochemistry and texture of the primitive achondrites suggest these meteorites may be genetic intermediates between chondrites and achondrites and may preserve evidence of processes occurring in the early solar system. Five primitive achondrites LEW 88280, MAC 88177, ALHA 81187, EET 84302, and LEW 88663 were examined in this study in order to classify the meteorites and to determine processes that have affected them. Bulk chemical analyses of Nap, K2O, CaO, FeO, Cr, Co, Ni, Sc, Ir, Au, As, Sb, Se, Br, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, and Lu were determined for each meteorite by Instrumental Neutron Activation Analysis (INAA). Concentrations of Hf, U, and Th were determined for some meteorites. Polished thin sections of the five meteorites were examined in transmitted and reflected light microscopy to identify minerals and examine petrographic relationships. Minerals found in the meteorites include olivine, orthopyroxene, clinopyroxene, plagioclase, Cr-spinel, phosphates, troilite, kamecite, and taenite along with other minor phases. Mineral compositions were determined with an electron microprobe. The initial study suggests that the meteorites have been altered by metamorphic processes although igneous processes may also have played a role in the evolution of these rocks. Further studies of isotope and bulk chemistry are planned for these meteorites.

Field, Stephen W.↗

NASA NTRS1992

Apollo 15 green glass - Compositional distribution and petrogenesis

We have characterized a comprehensive suite of individual green-glass beads from Apollo 15 soil to determine interelement behavior and to constrain petrogenetic relationships. We analyzed 365 particles for trace elements by instrumental neutron activation analysis and analyzed 52 of them, selected to cover the compositional ranges observed for trace elements, for major elements by electron microprobe analysis. We confirm the observation of Delano (1979) that the beads comprise discrete compositional groups, although two of the groups he defined are further split on the basis of trace-element compositions. Each of the resulting seven groups has distinct average rare-earth abundances. The coherence between major- and trace-element data was masked in previous studies by imprecision, correlated error, and nonrepresentative sampling of the different groups. Most of the compositional characteristics of the green glasses can be explained by a model for batch equilibrium melting of a nearly homogeneous, ultramafic source region, when the complicating effects of high pressure and low oxygen fugacity are taken into account. The previously puzzling behavior of Ni and Co as apparently incompatible elements may arise from partial reduction of those elements to the zero oxidation state, resulting in low mineral/melt partition coefficients. The model also offers explanations for why the green glasses form boomerang-shaped trends on many two-element variation diagrams and why certain compositions (Groups A and D) are more abundant than glasses with other compositions.

Steele, Alison M.↗

NASA NTRS1991

SIRTF focal plane technologies

The Space Infrared Telescope Facility (SIRTF) will have three science instruments, the Infrared Array Camera (IRAC) which will obtain multispectral images between 1.8 micron and 26 microns, the Infrared Spectrometer (IRS) which is a set of two dispersive spectrometers covering the wavelength range between 2.5 and 200 microns, and the Multiband Imaging Photometer for SIRTF (MIPS) which is a general-purpose photometric instrument which operates between 30 and 1,200 microns. Taken together, the full wavelength range of these instruments extends from 1.8 micron to 1,200 microns, equivalent to nearly a factor of 700 in photon energy and diffraction limited image size. In addition to supporting this unprecedented spectral and optical coupling requirement, the SIRTF detectors must operate at lower temperatures than previously demonstrated and be optimized for new levels of performance in order to achieve the goals of the science mission. Thus, development of the detector arrays for the SIRTF instruments is one of the most challenging aspects of the instrument development activities.

Capps, Richard W.↗

NASA NTRS1993

Refractory inclusions from the Leoville, Efremovka, and Vigarano C3V chondrites - Major element differences between Types A and B, and extraordinary refractory siderophile element compositions

Instrumental neutron activation analysis is used to measure the bulk chemical compositions of ten Ca-, Al-rich inclusions (CAIs) from three C3V chondrites of the reduced subgroup, five from Leoville, three from Efremovka, and two from Vigarano. Six of the inclusions are found to possess very large fractionations between refractory siderophile elements, and four of the six have remarkably high concentrations of these siderophiles, as compared with CAIs analyzed previously. Most of the inclusions analyzed here have lower concentrations of Na, Au, Fe, Zn, and Mn than their Allende counterparts, consistent with the idea that they have experienced secondary alteration at a higher temperature or for a shorter time than did Allende inclusions.

Sylvester, Paul J.↗

NASA NTRS1993

Evaluation of two January - June 1992 ERS-1 AMI wind vector data sets

A Jan. - Jun. 1992 10 m height wind vector field was computed with the CMOD2 model function. Freilich and Dunbar used ESA measurements of AMI (Active Microwave Instrument) sigma-naught to derive a refined model function and to produce an alternate Jan. - Jun. 1992 10 m height wind vector field, named FD data. The ESA and FD model functions and algorithms were substantially different. The FD wind vectors were in better agreement with the climatological mean wind field and with moored buoy wind measurements. The average correlation coefficients between monthly mean and daily averaged FD and moored buoy matchups of the Cartesian wind components were 0.84 and 0.74, respectively. The average root mean square differences between the monthly mean and daily averaged FD and moored buoy matchups of the Cartesian wind components were 1.25 and 3.0 m/s, respectively.

Halpern, D.↗

NASA NTRS1993

Techniques and Applications of SAR interferometry for ERS-1: Topographic Mapping, Change Detection, and Slope Measurement

SAR (Synthetic Aperture Radar) interferometry allows the measurement of high resolution topography of terrain from repeat orbit SAR data sets obtained by the ERS-1 AMI (Active Microwave Instrument). The system parameters which affect the accuracy of the topographic maps are errors in determination of the interferometric baseline, non parallel orbit tracks, decorrelation caused by baseline length, thermal noise, and surface change. Surface change can be observed in the interferograms either through decorrelation of the interferometric phase, or coherent phase shifts caused by locally uniform surface displacements. Phase gradient maps can be derived directly from the complex interferograms and can be transformed into surface slopes mapped onto a geometrically corrected grid.

Charles L Werner↗

NASA NTRS1993

Trace-element composition of Chicxulub crater melt rock, K/T tektites and Yucatan basement

The Cretaceous/Tertiary (K/T) boundary Chicxulub impact is the best preserved large impact in the geologic record. The Chicxulub crater has been buried with no apparent erosion of its intracrater deposits, and its ejecta blanket is known and is well preserved at hundreds of localities globally. Although most of the molten material ejected from the crater has been largely altered, a few localities still preserve tektite glass. Availability of intra- and extracrater impact products as well as plausible matches to the targeted rocks allows the comparison of compositions of the different classes of impact products to those of the impacted lithologies. Determination of trace-element compositions of the K/T tektites, Chicxulub melt rock, and the targeted Yucatan silicate basement and carbonate/evaporite lithologies have been made using instrumental neutron activation analysis (INAA) and inductively coupled plasma mass spectrometry (ICP-MS). Some sample splits were studied with both techniques to ensure that inter-laboratory variation was not significant or could be corrected. The concentration of a few major and minor elements was also checked against microprobe results. Radiochemical neutron activation analysis (RNAA) was used to determine Ir abundances in some samples.

Hildebrand, A. R.↗

NASA NTRS1993

INAA of CAIs from the Maralinga CK4 chondrite: Effects of parent body thermal metamorphism

Maralinga is an anomalous CK4 carbonaceous chondrite which contains numerous Ca-, Al-rich inclusions (CAI's) unlike the other members of the CK group. These CAI's are characterized by abundant green hercynitic spinel intergrown with plagioclase and high-Ca clinopyroxene, and a total lack of melilite. Instrumental Neutron Activation Analysis (INAA) was used to further characterize the meteorite, with special focus on the CAI's. High sensitivity INAA was done on eight sample disks about 100-150 microns in diameter obtained from a normal 30 micron thin section with a diamond microcoring device. The CAI's are enriched by 60-70X bulk meteorite values in Zn, suggesting that the substantial exchange of Fe for Mg that made the spinel in the CAI's hercynitic also allowed efficient scavenging of Zn from the rest of the meteorite during parent body thermal metamorphism. Less mobile elements appear to have maintained their initial heterogeneity.

Lindstrom, D. J.↗