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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

The Effect of Journal Roughness and Foil Coatings on the Performance of Heavily Loaded Foil Air Bearings

Foil air bearing load capacity tests were conducted to investigate if a solid lubricant coating applied to the surface of the bearing's top foil can function as a break-in coating. Two foil coating materials, a conventional soft polymer film (polyimide) and a hard ceramic (alumina), were independently evaluated against as-ground and worn (run-in) journals coated with NASA PS304, a high-temperature solid lubricant composite coating. The foil coatings were evaluated at journal rotational speeds of 30,000 rpm and at 25 C. Tests were also performed on a foil bearing with a bare (uncoated) nickel-based superalloy top foil to establish a baseline for comparison. The test results indicate that the presence of a top foil solid lubricant coating is effective at increasing the load capacity performance of the foil bearing. Compared to the uncoated baseline, the addition of the soft polymer coating on the top foil increased the bearing load coefficient by 120% when operating against an as-ground journal surface and 85 percent against a run-in journal surface. The alumina coating increased the load coefficient by 40% against the as-ground journal but did not have any affect when the bearing was operated with the run-in journal. The results suggest that the addition of solid lubricant films provide added lubrication when the air film is marginal indicating that as the load capacity is approached foil air bearings transition from hydrodynamic to mixed and boundary lubrication.

Radil, Kevin C.↗

Enriched aluminide coatings for dispersion strengthened nickel materials

Improved aluminide/barrier coating combinations for dispersion strengthened nickel materials were investigated. The barrier materials involved alloys with refractory metal content to limit interdiffusion between the coating and the substrate, thereby minimizing void formation. Improved aluminide coatings involved the dispersion of aluminum-rich compounds. Coatings were tested in argon at 1533 K (2300 F) for 100 hours and in cyclic oxidation at 1422 K (2100 F). Two coatings on TDNiCr completed 300 hours of oxidation testing, none on TDNi. Selected coating combinations were evaluated in Mach 1 burner rig testing using JP-4 fuel and air at 1422 K (2100 F) and 1477 K (2200 F) for 350 and 100 hours, respectively. Static oxidation in 1-hour cycles was conducted at 1533 K (2300 F) for 100 hours. For comparison purposes a physical vapor deposition (PVD) NiCrAlY coating was tested concurrently. Only the NiCrA1Y coating survived the 1477 K (2200 F)/100-hour burner rig test and 275 hours of the 350-hour 1422 K (2100 F) test. Elevated temperature exposure reduced room temperature tensile properties but had little effect on elevated temperature properties.

Levinstein, M. A.↗

A comparison of ground-based and space flight data: Atomic oxygen reactions with boron nitride and silicon nitride

The effects of atomic oxygen on boron nitride (BN) and silicon nitride (Si3N4) have been studied in low Earth orbit (LEO) flight experiments and in a ground-based simulation facility at Los Alamos National Laboratory. Both the in-flight and ground-based experiments employed the materials coated over thin (approx 250 Angstrom) silver films whose electrical resistance was measured in situ to detect penetration of atomic oxygen through the BN and Si3N4 materials. In the presence of atomic oxygen, silver oxidizes to form silver oxide, which has a much higher electrical resistance than pure silver. Permeation of atomic oxygen through BN, as indicated by an increase in the electrical resistance of the silver underneath, was observed in both the in-flight and ground-based experiments. In contrast, no permeation of atomic oxygen through Si3N4 was observed in either the in-flight or ground-based experiments. The ground-based results show good qualitative correlation with the LEO flight results, thus validating the simulation fidelity of the ground-based facility in terms of reproducing LEO flight results.

Cross, J. B.↗

Predictive Failure of Cylindrical Coatings Using Weibull Analysis

Rotating, coated wiping rollers used in a high-speed printing application failed primarily from fatigue. Two coating materials were evaluated: a hard, cross-linked, plasticized polyvinyl chloride (PVC) and a softer, plasticized PVC. A total of 447 tests was conducted with these coatings in a production facility. The data were evaluated using Weibull analysis. The softer coating produced more than twice the life of the harder cross-linked coating and reduced the wiper replacement rate by two-thirds, resulting in minimum production interruption.

Vlcek, Brian L.↗

Furnace Cyclic Oxidation Behavior of Multi-Component Low Conductivity Thermal Barrier Coatings

Ceramic thermal barrier coatings will play an increasingly important role in advanced gas turbine engines because of their ability to further increase engine operating temperatures and reduce cooling, thus helping achieve future engine low emission, high efficiency and improved reliability goals. Advanced multi-component zirconia-based thermal barrier coatings are being developed using an oxide defect clustering design approach to achieve the required coating low thermal conductivity and high temperature stability. Although the new composition coatings were not yet optimized for cyclic durability, an initial durability screening of the candidate coating materials was conducted using conventional furnace cyclic oxidation tests. In this paper, furnace cyclic oxidation behavior of plasma-sprayed zirconia-based defect cluster thermal barrier coatings was investigated at 1163 C using 45 min hot cycles. The ceramic coating failure mechanisms were studied using scanning electron microscopy (SEM) combined with X-ray diffraction (XRD) phase analysis after the furnace tests. The coating cyclic lifetime is also discussed in relation to coating processing, phase structures, dopant concentration, and other thermo-physical properties.

Zhu, Dong-Ming↗

Testbed for Lunar Extreme Environment Wear Tolerant Applications

The abrasive dust from lunar regolith poses significant long-term durability and performance challenges to materials, vehicles, mechanisms and structures that will be used for the next generation of lunar exploration. The development of advanced materials, coatings and device technologies that can withstand these abrasive particles and extreme environmental conditions is critical. However, the lack of standardized and accessible methods for evaluating such materials and devices in a facsimile of the harsh lunar environment hinders progress in dust-tolerant technologies. To address this challenge, NASA Langley Research Center is creating an extreme environment testbed. This reconfigurable testbed will allow rapid, repeatable wear testing of material and candidate mechanisms under vacuum conditions, facilitating the development of critical materials technologies for lunar exploration. Preliminary results from exposing an actuating mechanism similar to a pin joint to lunar regolith simulant under high vacuum are reported.

lunar dust↗

Testbed for Lunar Extreme Environment Wear Tolerant Applications

The abrasive dust from lunar regolith poses significant long-term durability and performance challenges to materials, vehicles, mechanisms and structures that will be used for the next generation of lunar exploration. The development of advanced materials, coatings and device technologies that can withstand these abrasive particles and extreme environmental conditions is critical. However, the lack of standardized and accessible methods for evaluating such materials and devices in a facsimile of the harsh lunar environment hinders progress in dust-tolerant technologies. To address this challenge, NASA Langley Research Center is creating an extreme environment testbed. This reconfigurable testbed will allow rapid, repeatable wear testing of material and candidate mechanisms under vacuum conditions, facilitating the development of critical materials technologies for lunar exploration. Preliminary results from exposing an actuating mechanism similar to a pin joint to lunar regolith simulant under high vacuum are reported.

lunar dust↗

Testbed for Lunar Extreme Environment Wear Tolerant Applications

The abrasive dust from lunar regolith poses significant long-term durability and performance challenges to materials, vehicles, mechanisms and structures that will be used for the next generation of lunar exploration. The development of advanced materials, coatings and device technologies that can withstand these abrasive particles and extreme environmental conditions is critical. However, the lack of standardized and accessible methods for evaluating such materials and devices in a facsimile of the harsh lunar environment hinders progress in dust-tolerant technologies. To address this challenge, NASA Langley Research Center is creating an extreme environment testbed. This reconfigurable testbed will allow rapid, repeatable wear testing of material and candidate mechanisms under vacuum conditions, facilitating the development of critical materials technologies for lunar exploration. Preliminary results from exposing an actuating mechanism similar to a pin joint to lunar regolith simulant under high vacuum are reported.

lunar dust↗

Properties of plasma sprayed bond coats

Increasing bond coat oxidation resistance has been clearly linked to increasing durability of the ceramic layer of TBC's. However, recent studies have shown that significant differences in TBC life can be achieved for different bond coats that have little or no difference in oxidation behavior. These results suggest bond coat properties other than oxidation resistance can also influence TBC life. A determination of which properties affect TBC life and an understanding of how these properties affect TBC life could be valuable in designing new, more durable TBC's. Unfortunately, there is little existing information on the physical and mechanical properties of bond coat materials and there are fewer comparative studies that can be used to determine which properties are important to TBC life. This paper compares the properties of three bond coat compositions that have similar oxidation behavior but different TBC lives. Analysis of the properties indicates that the coefficient of thermal expansion and stress relaxation (creep) behavior of the three alloys are strongly correlated to the observed differences in TBC life.

Brindley, W. J.↗

Furnace Cyclic Behavior of Plasma-Sprayed Zirconia-Yttria and Multi-Component Rare Earth Oxide Doped Thermal Barrier Coatings

Ceramic thermal barrier coatings will play an increasingly important role in advanced gas turbine engines because of their ability to enable further increases in engine temperatures. However, the coating performance and durability become a major concern under the increasingly harsh thermal cycling conditions. Advanced zirconia- and hafnia-based cluster oxide thermal barrier coatings with lower thermal conductivity and improved thermal stability are being developed using a high-heat-flux laser-rig based test approach. Although the new composition coatings were not yet optimized for cyclic durability, an initial durability screening of numerous candidate coating materials was carried out using conventional furnace cyclic tests. In this paper, furnace thermal cyclic behavior of the advanced plasma-sprayed zirconia-yttria-based thermal barrier coatings that were co-doped with multi-component rare earth oxides was investigated at 1163 C using 45 min hot cycles. The ceramic coating failure mechanisms were studied by using scanning electron microscopy combined with X-ray diffraction phase analysis after the furnace tests. The coating cyclic lifetime will be discussed in relation to coating phase structures, total dopant concentrations, and other properties.

Zhu, Dongming↗

Polyimides comprising substituted benzidines

A new class of polyimides and copolyimides made from substituted benzidines and aromatic dianhydrides and other aromatic diamines. The polyimides obtained with said diamines are distinguished by excellent thermal, excellent solubility, excellent electrical properties such as very low dielectric constants, excellent clarity and mechanical properties making the polyimides ideally suited as coating materials for microelectronic apparatii, as membranes for selective molecular or gas separation, as fibers in molecular composites, as high tensile strength, high compression strength fibers, as film castable coatings, or as fabric components.

Harris, Frank W.↗

Improved Mo-Re VPS Alloys for High-Temperature Uses

Dispersion-strengthened molybdenum- rhenium alloys for vacuum plasma spraying (VPS) fabrication of high-temperature-resistant components are undergoing development. In comparison with otherwise equivalent non-dispersion-strengthened Mo-Re alloys, these alloys have improved high-temperature properties. Examples of VPS-fabricated high-temperature-resistant components for which these alloys are expected to be suitable include parts of aircraft and spacecraft engines, furnaces, and nuclear power plants; wear coatings; sputtering targets; x-ray targets; heat pipes in which liquid metals are used as working fluids; and heat exchangers in general. These alloys could also be useful as coating materials in some biomedical applications. The alloys consist of 60 weight percent Mo with 40 weight percent Re made from (1) blends of elemental Mo and Re powders or (2) Re-coated Mo particles that have been subjected to a proprietary powder-alloying-and-spheroidization process. For most of the dispersion- strengthening experiments performed thus far in this development effort, 0.4 volume percent of transition-metal ceramic dispersoids were mixed into the feedstock powders. For one experiment, the proportion of dispersoid was 1 volume percent. In each case, the dispersoid consisted of either ZrN particles having sizes <45 m, ZrO2 particles having sizes of about 1 m, HfO2 particles having sizes <45 m, or HfN particles having sizes <1 m. These materials were chosen for evaluation on the basis of previously published thermodynamic stability data. For comparison, Mo-Re feedstock powders without dispersoids were also prepared.

Hickman, Robert↗

Phenylated polyimides prepared from 3,6-diarylpyromellitic dianhydride and aromatic diamines

A new class of soluble phenylated polyimides made from 3,6-diarypyromellitic dianhydride and process for the manufacture of the 3,6-diarypyromellitic dianhydride starting material. The polyimides obtained with said dianhydride are readily soluble in appropriate organic solvents and are distinguished by excellent thermal, electrical and/or mechanical properties making the polyimides ideally suited as coating materials for microelectronic apparatii, as membranes for selective molecular separation or permeation or selective gas separation or permeation, or as reinforcing fibers in molecular composites, or as high modulus, high tensile strength fibers.

Harris, Frank W.↗

Coated silicon comprising material for protection against environmental corrosion

In accordance with an embodiment of the invention, an article is disclosed. The article comprises a gas turbine engine component substrate comprising a silicon material; and an environmental barrier coating overlying the substrate, wherein the environmental barrier coating comprises cerium oxide, and the cerium oxide reduces formation of silicate glass on the substrate upon exposure to corrodant sulfates.

Hazel, Brian Thomas↗

Plasma Spray-Physical Vapor Deposition (PS-PVD) of Ceramics for Protective Coatings

In order to generate advanced multilayer thermal and environmental protection systems, a new deposition process is needed to bridge the gap between conventional plasma spray, which produces relatively thick coatings on the order of 125-250 microns, and conventional vapor phase processes such as electron beam physical vapor deposition (EB-PVD) which are limited by relatively slow deposition rates, high investment costs, and coating material vapor pressure requirements. The use of Plasma Spray - Physical Vapor Deposition (PS-PVD) processing fills this gap and allows thin (< 10 microns) single layers to be deposited and multilayer coatings of less than 100 microns to be generated with the flexibility to tailor microstructures by changing processing conditions. Coatings of yttria-stabilized zirconia (YSZ) were applied to NiCrAlY bond coated superalloy substrates using the PS-PVD coater at NASA Glenn Research Center. A design-of-experiments was used to examine the effects of process variables (Ar/He plasma gas ratio, the total plasma gas flow, and the torch current) on chamber pressure and torch power. Coating thickness, phase and microstructure were evaluated for each set of deposition conditions. Low chamber pressures and high power were shown to increase coating thickness and create columnar-like structures. Likewise, high chamber pressures and low power had lower growth rates, but resulted in flatter, more homogeneous layers

Harder, Bryan J.↗

UV blocking filters for polymeric films

The concept of incorporating UV screening agents in silicone resins as a means of protecting underlying solar cell covers and adhesives from UV degradation is presented. A silicone hard-coat resin incorporating a UV screening agent was selected as a suitable coating material for PFA Teflon solar cell covers. Consideration is given to fabrication procedures and techniques for introduction of the UV screening agents into silicone resins and application of these UV-inhibited coatings to the Teflons. Some preliminary environmental tests, such as thermal shock and temperature humidity, were conducted.

Rayl, G. J.↗

Internal Radiation Effects in Zirconia Thermal Barrier Coatings

Using thermal barrier coatings on combustor liners, turbine vanes, and rotating blades is important for reducing metal temperatures in current and advanced aircraft engines. Zirconia is a common coating material, and it is partially transparent to thermal radiation. Radiation becomes more significant as temperatures are raised for higher efficiency in advanced engines. Calculations are often made with radiation effects neglected inside the coating. The effect of radiation is illustrated here, where an analytical procedure is provided by using the two-flux method for the radiative contribution. A detailed study was made of ceramic thermal barrier coatings for diesel engines, and a two-flux analysis was developed for radiation in semitransparent multilayer composites. These efforts provide the basis for the present analysis where illustrative solutions are obtained for typical conditions in an aircraft engine. The formulation and solution of the exact spectral radiative transfer equations including large scattering, as is characteristic of zirconia, are rather complicated. The two-flux method is used here to provide a simplified method.

Siegel, Robert↗