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At least 235 records · Page 13

Process for improving mechanical properties of epoxy resins by addition of cobalt ions

A resin product useful as an adhesive, composite or casting resin is described as well as the process used in its preparation to improve its flexural strength mechanical property characteristics. Improved flexural strength is attained with little or no change in density, thermal stability or moisture resistance by chemically incorporating 1.2% to 10.6% by weight Co(3) ions in an epoxidized resin system.

Stoakley, D. M.↗

A comparison of radiation damage in linear ICs from Cobalt-60 gamma rays and 2.2 MeV electrons

The total ionizing dose response of fourteen IC types from eight manufacturers have been measured using Co-60 gamma rays and 2.2 MeV electrons for exposure levels of 100 to 20,000 Gy(Si). Key parameter measurements were made and compared for each device type. The data show that a Co-60 source may not be a suitable simulation source for some systems, because of the generally more damaging nature of electrons as well as the unpredictable nature of the individual device response to the two types of radiations used here.

Gauthier, M. K.↗

Nickel-cobalt systematics and their bearing on lunar origin

The earliest metal phases to crystallize from the least-fabricated low Ti mare basalts contain about 30% Ni and 2 to 7% of Co. Experimental investigations of partitioning of Ni and Co between primitive lunar basaltic magmas and metal phases are currently in progress. Preliminary results show that the metal phase crystallizing near the liquidus of Green Glass (185 ppm Ni, 70 ppm Co) would contain about 40% Ni and 2.3% Co. It seems, therefore, that if a lunar core does exist, as suggested by the results of (2), it is relatively rich in Ni (30-40%) and Co (2-7%). This composition presents a remarkable contrast to that of the Earth's core which is estimated to contain about 6% Ni and 0.3% Co. Explanations for the differing densities of Earth and Moon are imvestigated.

Ringwood, A. E.↗

Modified Cobalt Drills With Oil Passages

Oil forced through drill shanks to lubricate cutting edges. Drill bits cooled and lubricated by oil forced through drill shanks and out holes adjacent to bits. This cooling technique increases drillbit life and allows increased drill feed rates.

Hutchison, E.↗

The influence of cobalt, tantalum, and tungsten on the microstructure of single crystal nickel-base superalloys

The influence of composition on the microstructure of single crystal nickel-base superalloys was investigated. Co was replaced by Ni, and Ta was replaced by either Ni or W, according to a matrix of compositions based on MAR-M247. Substitution of Ni for Co caused an increase in gamma-prime solvus temperature, an increase in gamma-gamma-prime lattice mismatch, and the precipitation of W-rich phases in the alloys with high refractory metal levels. Substitution of Ni for Ta caused large decreases in gamma-prime solvus temperature, gamma-prime volume fraction, and gamma-gamma-prime lattice mismatch, whereas substitution of W for Ta resulted in smaller decreases in these features. For the alloys with gamma-prime particles that remained coherent, substitution of Ni for Co caused an increase in gamma-prime coarsening rate. The two alloys with the largest magnitude of lattice mismatch possessed gamma-prime particles which lost coherency during unstressed aging and exhibited anomalously low coarsening rates. Creep exposure at 1000 C resulted in the formation of gamma-prime lamellae oriented perpendicular to the applied stress axis in all alloys.

Nathal, M. V.↗

Advanced thermal barrier system bond coatings for use on nickel-, cobalt- and iron-base alloy substrates

New and improved Ni-, Co-, and Fe-base bond coatings have been identified for the ZrO2-Y2O3 thermal barrier coatings to be used on Ni-, Co-, and Fe-base alloy substrates. These bond coatings were evaluated in a cyclic furnace between 1120 and 1175 C. It was found that MCrAlYb (where M = Ni, Co, or Fe) bond coating thermal barrier systems have significantly longer lives than MCrAlY bond coating thermal barrier systems. The longest life was obtained with the FeCrAlYb thermal barrier system followed by NiCrAlYb and CoCrAlYb thermal barrier systems in that order.

Stecura, S.↗

Abundances of cobalt, nickel, and volatiles in the silicate portion of the moon

The trace abundances of Ni have been determined in 20 high-Mg magmas produced by partial melting of the lunar mantle. Associated with the eruption of the high-Mg magmas was the release of indigenous volatile elements. Data suggest that these volatiles were derived from primordial blocks of debris from the outer solar system that became entrained in the circumterrestrial accretion disk. The survival of these reservoirs within the lunar interior places constraints on the moon's thermal history.

Delano, John W.↗

The nature of the meteoritic components of Apollo 16 soil, as inferred from correlations of iron, cobalt, iridium, and gold with nickel

The Apollo 16 soil concentrations of Ni, Fe, Co, Ir, and Au were studied to determine the correlations with Ni. The correlations obtained indicate that the variation in the siderophile element concentrations in Apollo 16 soils result from the variation in the concentration of a Fe-Ni metal (with the mean composition of 5.6 pct Ni and 0.36 pct Co) that contributes about 0.4-0.5 pct to a typical soil from Apollo 16. It is shown that the siderophile elements of the 'ancient meteorite component' of Anders et al. (1973) and Hertogen et al. (1977) are located in the grains of Fe-Ni metal that in turn are contained in noritic impact melt breccias produced about 3.9 Ga ago. The ancient Fe-Ni is different from the metal of ordinary chondrites by having lower Ni/Co, Ir/Ni, and Ir/Au ratios. It is shown that Ni in the Apollo 16 soil is contributed approximately equally by the 'ancient meteorite component' and the 'micrometeorite component' (dominated by carbonaceous chondrites); however, most of the variation in Ni concentration results from the variation of the ancient Fe-Ni metal among samples of Apollo 16 soil.

Korotev, Randy L.↗

Nickel, argon and cobalt in the infrared spectrum of SN1987A - The core becomes visible

Infrared spectra of supernova 1987A taken in April and November 1987 are presented, showing two distinctly different stages in the evolution of the expanding gas shell. The optical and infrared spectrum in April originated from the hydrogen envelope and show weak hydrogen lines rising above a 5,000-K photospheric continuum. The November spectrum was dominated by strong emission lines from heavy elements as well as many lines from highly excited levels of hydrogen, with peak flux levels in the lines at or slightly above the level of the continuum in April. It is concluded that the inner regions of the supernova were just becoming visible in early 1988. It is expected that these regions contain heavy elements produced by advanced nuclear burning stages in the progenitor star and in the shock wave that ejected all material external to the iron core.

Rank, D. M.↗

Mechanical properties of modified low cobalt powder metallurgy Udimet 700 type alloys

Eight superalloys derived from Udimet 700 were prepared by powder metallurgy, hot isostatically pressed, heat treated and their tensile and creep rupture properties determined. Several of these alloys displayed properties superior to those of Udimet 700 similarly prepared, in one case exceeding the creep rupture life tenfold. Filter clogging by extracted gamma prime, its measurement and significance are discussed in an appendix.

Harf, Fredric H.↗

Effects of Cobalt Concentration on the Relative Resistance to Octahedral and Cube Slip in Nickel-Base Superalloys

Compression yielding tests were performed at 760 C on crystals of the Ni base superalloys Rene 150 and a modified MAR-M247, both having two different Co concentrations. For both alloy bases, increasing Co concentration was shown to decrease the critical resolved shear stress for octahedral slip, but to have little effect on that for cube slip. The results suggest that decreasing complex stacking fault energy in the gamma-prime with increasing Co could account for the observed effects.

Bobeck, Gene E.↗

Comparison of the degradation effects of heavy ion, electron, and cobalt-60 irradiation in an advanced bipolar process

Experimental measurements are reported of the degradation effects of high-energy particles (heavy Br ions and electrons) and Co-60 gamma-rays on the current gain of minimum-geometry bipolar transistors made from an advanced process. The data clearly illustrate the total-ionizing-dose vs particle-fluence behavior of this bipolar transistor produced by an advanced process. In particular, bulk damage from Co-60 gamma rays in bipolar transistors (base transport factor degradation) and surface damage in bipolar transistors from ionizing radiation (emitter-efficiency degradation) have been observed. The true equivalence between various types of radiation for this process technology has been determined on the basis of damage from the log K1 intercepts.

Zoutendyk, John A.↗

Deformation behavior of NiAl-based alloys containing iron, cobalt, and hafnium

The effects of alloying additions on the mechanical properties of the B2 intermetallic NiAl have been investigated in both the melt-spun ribbon and consolidated, bulk form. The study is based on a matrix of NiAl-based alloys with up to 20 at. pct Co and Fe additions and with reduced Al levels in the range of 30-40 at. pct. Characterization of the melt-spun ribbon by optical and scanning electron microscopy indicates a range of microstructures, including single-phase beta, gamma-prime necklace phase surrounding either martensitic or beta grains, and a mixture of equiaxed martensitic and gamma-prime grains. Bend ductility is present in melt-spun and annealed ribbons exhibiting the gamma-prime necklace structure and in a single-phase beta material containing 20 at. pct Fe. The analysis of compressive flow behavior on consolidated, bulk specimens indicates that the single-phase beta alloys exhibit a continuous decrease in yield stress with increasing temperature and profuse microcracking at grain boundaries. In contrast, multiphase (gamma-prime + either martensite or beta) alloys tend to display a peak in flow stress between 600 and 800 K, with little or no signs of microcracking. In general, heat treatments which convert the martensitic grains to beta + gamma-prime result in improved strength at temperatures above 600 K and better resistance to crack initiation.

Pank, D. R.↗

Cobalt and nickel concentrations in the 'komatiite component' of Apollo 16 polymict samples

Some estimates for the concentrations of Co and Ni in the primitive mafic component of Apollo 16 breccias and soils are large, comparable to concentrations in terrestrial komatiites. These estimates may be erroneously high because the contribution from meteoritic contamination of the samples has been underestimated. However, even if the correction for meteoritic Co and Ni is valid and the calculated residual Ni is not of meteoritic origin, the Ni is presently carried by Fe-Ni metal while the Fe and Mg are carried by mafic silicates. If any large-scale separation of metal and silicate phases has occurred, the concentration ratio of Ni to Fe + Mg in the mafic silicates of the ancient crust in the vicinity of the Apollo 16 site has not been preserved by Apollo 16 rocks. Apollo 16 polymict breccias and soils contain much higher concentrations of siderophile elements and Fe-Ni metal than other nonmare samples from the Moon. Thus, it is likely that the Ni/(Mg + Fe) ratio estimated for the komatiite component from Apollo 16 samples is high compared to the actual ratio for the lunar crust.

Korotev, Randy L.↗

Growing Cobalt Silicide Columns In Silicon

Codeposition by molecular-beam epitaxy yields variety of structures. Proposed fabrication process produces three-dimensional nanometer-sized structures on silicon wafers. Enables control of dimensions of metal and semiconductor epitaxial layers in three dimensions instead of usual single dimension (perpendicular to the plane of the substrate). Process used to make arrays of highly efficient infrared sensors, high-speed transistors, and quantum wires. For fabrication of electronic devices, both shapes and locations of columns controlled. One possible technique for doing this electron-beam lithography, see "Making Submicron CoSi2 Structures on Silicon Substrates" (NPO-17736).

Fathauer, Obert W.↗

Use of cobalt sulfide (black dye) anodize for thermal control of the Space Station Freedom airlock

This paper presents six thermal design options of the Space Station Freedom (SSF) airlock and shows the important role that exterior coatings had in minimizing heater power. Options included using anodized coatings separately or in combination, employing fans to circulate interior air, and using a solar shade that eliminates the adverse effect of degrading optical properties. The design that is most efficient, in terms of cost and minimum heater power, and that meets all temperature requirements, has a black anodized exterior finish and uses a maximum of 410 watts of heater power.

Saiz, John↗