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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Rate processes in gas phase

Reaction-rate theory and experiment are given a critical review from the engineers' point of view. Rates of heavy-particle, collision-induced reaction in gas phase are formulated in terms of the cross sections and activation energies for reaction. The effect of cross section function shape and of excited state contributions to reaction both cause the slope of Arrhenius plots to differ from the true activation energy, except at low temperature. The master equations for chemically reacting gases are introduced, and dissociation and ionization reactions are shown to proceed primarily from excited states about kT from the dissociation or ionization limit. Collision-induced vibration, vibration-rotation, and pure rotation transitions are treated, including three-dimensional effects and conservation of energy, which have usually been ignored. The quantum theory of transitions at potential surface crossing is derived, and results are found to be in fair agreement with experiment in spite of some questionable approximations involved.

Hansen, C. F.↗
NASA NTRS1982

New theoretical and experimental methods for pressure broadened linewidths and their interpretation

A review of recent progress in the theory of collisional line broadening, particularly the impact of recent advances in collision dynamics calculations is presented. Some new approaches to the interpretation of experimentally measured linewidths and their impact on planetary atmosphere research are discussed. Experimental techniques which may have some advantage in providing pressure broadening data at very low temperatures are also mentioned.

Gelfand, J. J.↗
NASA NTRS1983

A thermal oscillating two-stream instability

A theory for the oscillating two-stream instability, in which the Ohmic heating of the electrons constitutes the nonlinearity, is developed for an inhomogeneous and magnetized plasma. Its possible role in explaining short-scale, field-aligned irregularities observed in ionospheric heating experiments is emphasized. The theory predicts that the initial growth of such irregularities is centered around the level of upper hybrid resonance. Furthermore, plane disturbances nearly parallel to the magnetic meridian plane have the largest growth rates. Expressions for threshold, growth rate, and transverse scale of maximum growth are obtained. Special attention is paid to the transport theory, since the physical picture depends heavily on the kind of electron collisions which dominate. This is due to the velocity dependence of collision frequencies, which gives rise to the thermal forces

Dysthe, K. B.↗
NASA NTRS1985

Pressure broadening of rotational bands. I - A statistical theory

Absorption of electromagnetic waves by rotational transitions of molecules is formulated for the case in which the wave frequency is displaced from resonance by an amount large compared to the reciprocal duration of a typical binary collision, and also large compared to the differences between frequencies of the strong resonances of the gas. In this far-wing limit, Fano's relaxation operator is reduced to a scalar parameter which depends on the frequency displacement. This relaxation parameter is not symmetric with respect to reflection about resonance, but becomes symmetric when multiplied by the factor exp (h/2pi) (omega sub d)/2kT where omega sub d is the frequency displacement. The theory applies to dipolar molecules of any shape, in collisions with either dipolar or quadrupolar molecules.

Rosenkranz, P. W.↗
NASA NTRS1982

Test of Sigmund scaling for low collision energies

A scaling law that describes the most probable vibrorotational excitation in ion-molecule collisions has recently been extended by Sigmund (1981) to cover polyatomic targets. The predictions of this scaling law are examined for collisions of Cl(-) and K(+) with the targets O2, N2, CO, CO2, and CH4 in the energy range 50-200 eV. The experimental results do not all scale according to the theory. The study does demonstrate the usefulness of the scaling variables when examining the most probable vibrorotational excitation in ion-molecule collisions. A collection of isoelectronic scattering results is presented.

Vedder, M.↗
NASA NTRS1988

Origin of the solar system

The current status of the classical model of solar-system formation is surveyed, reviewing the results of recent observational and theoretical investigations. Topics addressed include interstellar clouds, the collapse of interstellar gas, the primitive solar nebula, the formation of the sun, planetesimal accumulation, planetary accumulation, major planetary collisions, the development of planetary atmospheres, and comets. The relative merits of conflicting theories on many key problems are indicated, with reference to more detailed reviews in the literature.

Cameron, A. G. W.↗
NASA NTRS1995

Heavy ion track-structure calculations for radial dose in arbitrary materials

The delta-ray theory of track structure is compared with experimental data for the radial dose from heavy ion irradiation. The effects of electron transmission and the angular dependence of secondary electron ejection are included in the calculations. Several empirical formulas for electron range and energy are compared in a wide variety of materials in order to extend the application of the track-structure theory. The model of Rudd for the secondary electron-spectrum in proton collisions, which is based on a modified classical kinematics binary encounter model at high energies and a molecular promotion model at low energies, is employed. For heavier projectiles, the secondary electron spectrum is found by scaling the effective charge. Radial dose calculations for carbon, water, silicon, and gold are discussed. The theoretical data agreed well with the experimental data.

Cucinotta, Francis A.↗
NASA NTRS1988

Energy branching in the Io plasma torus - The failure of neutral cloud theory

Model calculations are used to explore the energy source characteristics of the energy branching of the hot Io plasma torus. It is assumed that the energy is derived from the kinetic energy acquired by ions created in the rotating planetary magnetic field, and that Coulomb collisions with the electron gas control the flow of energy to the ionizing and radiative processes. The results show that neutral cloud theory is qualitatively inadequate. It is shown that neutral cloud theory can only support a dominantly singly ionized system (at the measured electron densities in the plasma torus) and that it fails to predict observed plasma properties relative to variations in number density.

Shemansky, D. E.↗
NASA NTRS1991

Aspects of reheating in first-order inflation

Studied here is reheating in theories where inflation is completed by a first-order phase transition. In the scenarios, the Universe decays from its false vacuum state by bubble nucleation. In the first stage of reheating, vacuum energy is converted into kinetic energy for the bubble walls. To help understand this phase, researchers derive a simple expression for the equation of state of a universe filled with expanding bubbles. Eventually, the bubble walls collide. Researchers present numerical simulations of two-bubble collisions clarifying and extending previous work by Hawking, Moss, and Stewart. The researchers' results indicate that wall energy is efficiently converted into coherent scalar waves. Also discussed is particle production due to quantum effects. These effects lead to the decay of the coherent scalar waves. They also lead to direct particle production during bubble-wall collisions. Researchers calculate particle production for colliding walls in both sine-Gordon and theta (4) theories and show that it is far more efficient in the theta (4) case. The relevance of this work for recently proposed models of first order inflation is discussed.

Watkins, Richard↗
NASA NTRS1978

The coupled states approximation for scattering of two diatoms

The paper presents a detailed development of the coupled-states approximation for the general case of two colliding diatomic molecules. The high-energy limit of the exact Lippman-Schwinger equation is applied, and the analysis follows the Shimoni and Kouri (1977) treatment of atom-diatom collisions where the coupled rotor angular momentum and projection replace the single diatom angular momentum and projection. Parallels to the expression for the differential scattering amplitude, the opacity function, and the nondiagonality of the T matrix are reported. Symmetrized expressions and symmetrized coupled equations are derived. The present correctly labeled coupled-states theory is tested by comparing its calculated results with other computed results for three cases: H2-H2 collisions, ortho-para H2-H2 scattering, and H2-HCl.

Heil, T. G.↗
NASA NTRS1993

Asteroid collisions: Target size effects and resultant velocity distributions

To study the dynamic fragmentation of rock to simulate asteroid collisions, we use a 2-D, continuum damage numerical hydrocode which models two-body impacts. This hydrocode monitors stress wave propagation and interaction within the target body, and includes a physical model for the formation and growth of cracks in rock. With this algorithm we have successfully reproduced fragment size distributions and mean ejecta speeds from laboratory impact experiments using basalt, and weak and strong mortar as target materials. Using the hydrocode, we have determined that the energy needed to fracture a body has a much stronger dependence on target size than predicted from most scaling theories. In addition, velocity distributions obtained indicate that mean ejecta speeds resulting from large-body collisions do not exceed escape velocities.

Ryan, Eileen V.↗
NASA NTRS1979

Resonant charge transfer in He/+/-He collisions studied with the merging-beams technique

Absolute cross sections are reported for the resonant charge-transfer reaction He(+) + He yields He + He(+) at collision energies between 0.1 and 187 eV. The results, obtained using a new merging-beam apparatus are in agreement both with theory and with measurements made using other experimental techniques. The experimentally determined cross sections between 0.5 and 187 eV fall about a line given by sigma exp 1/2(sq-A) = 5.09-2.99 lnW, where W is the collision energy in eV. Considerable attention is paid to the configuration and operation of the apparatus. Tests and calculations which confirm the interpretation of the experimental data in a merging-beam experiment are discussed.

Rundel, R. D.↗
NASA NTRS1977

Charge exchange in a planetary corona - Its effect on the distribution and escape of hydrogen

The theory for a spherical collisionless planetary corona is extended to include charge-exchange collisions between H(+) and H, which are assumed to constitute intermingled gases with different kinetic temperatures. The treatment is based on the conventional concept of a critical level (or exobase) above which the only collisions considered in the Boltzmann equation are those that resonantly exchange charge. Although the geometry treated is an oversimplification for a real planet, numerical examples are given for an idealized earth and Venus. For earth, an ion temperature of 4 times the neutral temperature, an ion density at the exobase of 14,000 per cu cm, and a plasmapause at 1.5 earth radii will raise the escape flux of H by a factor of 6. The total H above the exobase is changed by less than 1%. For Venus, conditions are examined that would account for the peculiar H distribution observed from Mariner 5. The plasma conditions required are not obviously outrageous by terrestrial standards, but the Mariner 5 ionosphere measurements did not show a high plasmapause at, say, 1.25 or 1.5 planetary radii, a fact that might argue against a charge-exchange model.

Chamberlain, J. W.↗