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At least 235 records · Page 13

CASSCF/CI calculations for first row transition metal hydrides - The TiH(4-phi), VH(5-delta), CrH(6-sigma-plus), MnH(7-sigma-plus), FeH(4,6-delta) and NiH(2-delta) states

Calculations are performed for the predicted ground states of TiH(4-phi), VH(5-delta), CrH(6-sigma-plus), MnH(7-sigma-plus), Fett(4,6-delta) and NiH(2-delta). For FeH both the 6-delta and 4-delta states are studied, since both are likely candidates for the ground state. The ground state symmetries are predicted based on a combination of atomic coupling arguments and coupling of 4s(2)3d(n) and 4s(1)3d(n+1) terms in the molecular system. Electron correlation is included by a CASSCF/CI (SD) treatment. The CASSCF includes near-degeneracy effects, while correlation of the 3d electrons in included at the CI level.

Walch, S. P.↗

Central Plasma Sheet Ion Properties as Inferred from Ionospheric Observations

A method of inferring central plasma sheet (CPS) temperature, density, and pressure from ionospheric observations is developed. The advantage of this method over in situ measurements is that the CPS can be studied in its entirely, rather than only in fragments. As a result, for the first time, comprehensive two-dimensional equatorial maps of CPS pressure, density, and temperature within the isotropic plasma sheet are produced. These particle properties are calculated from data taken by the Special Sensor for Precipitating Particles, version 4 (SSJ4) particle instruments onboard DMSP F8, F9, F10, and F11 satellites during the entire year of 1992. Ion spectra occurring in conjunction with electron acceleration events are specifically excluded. Because of the variability of magnetotail stretching, the mapping to the plasma sheet is done using a modified Tsyganenko [1989] magnetic field model (T89) adjusted to agree with the actual magnetotail stretch at observation time. The latter is inferred with a high degree of accuracy (correlation coefficient -0.9) from the latitude of the DMSP b2i boundary (equivalent to the ion isotropy boundary). The results show that temperature, pressure, and density all exhibit dawn-dusk asymmetries unresolved with previous measurements. The ion temperature peaks near the midnight meridian. This peak, which has been associated with bursty bulk flow events, widens in the Y direction with increased activity. The temperature is higher at dusk than at dawn, and this asymmetry increases with decreasing distance from the Earth. In contrast, the density is higher at dawn than at dusk, and there appears to be a density enhancement in the low-latitude boundary layer regions which increases with decreasing magnetic activity. In the near-Earth regions, the pressure is higher at dusk than at dawn, but this asymmetry weakens with increasing distance from the Earth and may even reverse so that at distances X less than approx. 10 to -12 R(sub E), depending on magnetic activity, the dawn sector has slightly higher pressure. The temperature and density asymmetries in the near-Earth region are consistent with the ion westward gradient/curvature drift as the ions ExB convect earthward. When the solar wind dynamic pressure increases, CPS density and pressure appear to increase, but the temperature remains relatively constant. Comparison with previously published work indicates good agreement between the inferred pressure, temperature, and density and those obtained from in situ data. This new method should provide a continuous mechanism to monitor the pressure, temperature, and density in the magnetotail with unprecedented comprehensiveness.

Wing, Simon↗

Thermal diffuse X-ray scattering in simple metals

Calculations are reported for the ionic structure factor and X-ray scattering cross section of sodium (at T=0 K and 90 K) and lithium (both isotopes at T=0 K) within the harmonic approximation. An evaluation of the appropriate displacement- displacement correlation function by the special point method circumvents the need for a multiphonon expansion. In the case of sodium, the structure in the one-phonon scattering was straightforwardly accounted for, and an approximate expansion was obtained for all multiphonon scattering. By treating core and conduction electrons on an equal footing, it is shown that information on the conduction electron system is present in the forward scattering component. In lithium the one-phonon cross section at small angles aids in the determination of the effective electron-ion interaction.

Straus, D. M.↗

Instabilities excited by an energetic ion beam and electron temperature anisotropy in tandem mirrors

Tandem mirrors are magnetic confinement devices, which have the objective to prevent a leaking out of ions in a central (solenoidal) cell at the end. This is accomplished by making use of an electrostatic potential, which is maintained by a denser plasma in mirror end cells. In the Tandem Mirror Experiment (TMX), Correll et al. (1982) have successfully verified the basic concepts involved in the design of the considered device. However, it was also found that the simple tandem mirror could not be easily scaled to a reactor-size device. Approaches for solving the arising problems were studied, taking into account also the utilization of a thermal barrier. In this connection, Winske et al. (1985) studied the nonlinear development of the instability in a finite beta plasma with isotropic electrons. The present investigation is concerned with an extension of the calculations conducted by Winske et al., giving attention to the parameter regime of the TMX. It is found that three instabilities can occur.

Da Jornada, E. H.↗

A liquid xenon imaging telescope for 1-30 MeV gamma-ray astrophysics

A study of the primary scintillation light in liquid xenon excited by 241 Am alpha particles and 207 Bi internal conversion electrons are discussed. The time dependence and the intensity of the light at different field strengths have been measured with a specifically designed chamber, equipped with a CaF sub 2 light transmitting window coupled to a UV sensitive PMT. The time correlation between the fast light signal and the charge signal shows that the scintillation signals produced in liquid xenon by ionizing particles provides an ideal trigger in a Time Projection type LXe detector aiming at full imaging of complex gamma-ray events. Researchers also started Monte Carlo calculations to establish the performance of a LXe imaging telescope for high energy gamma-rays.

Aprile, Elena↗

A liquid xenon imaging telescope for 1-30 MeV gamma-ray astrophysics

A study of the primary scintillation light in liquid xenon excited by 241 Am alpha particles and 207 Bi internal conversion electrons are discussed. The time dependence and the intensity of the light at different field strengths have been measured with a specifically designed chamber, equipped with a CaF sub 2 light transmitting window coupled to a UV sensitive PMT. The time correlation between the fast light signal and the charge signal shows that the scintillation signals produced in liquid xenon by ionizing particles provides an ideal trigger in a Time Projection type LXe detector aiming at full imaging of complex gamma-ray events. Researchers also started Monte Carlo calculations to establish the performance of a LXe imaging telescope for high energy gamma-rays.

Aprile, Elena↗

Tensile and creep rupture behavior of P/M processed Nb-base alloy, WC-3009

Due to its high strength at temperatures up to 1600 K, fabrication of niobium base alloy WC-3009 (Nb30Hf9W) by traditional methods is difficult. Powder metallurgy (P/M) processing offers an attractive fabrication alternative for this high strength alloy. Spherical powders of WC-3009 produced by electron beam atomizing (EBA) process were successfully consolidated into a one inch diameter rod by vacuum hot pressing and swaging techniques. Tensile strength of the fully dense P/M material at 300-1590 K were similar to the arc-melted material. Creep rupture tests in vacuum indicated that WC-3009 exhibits a class 1 solid solution (glide controlled) creep behavior in the 1480 to 1590 K temperature range and stress range of 14 to 70 MPa. The creep behavior was correlated with temperature and stress using a power law relationship. The calculated stress exponent n, was about 3.2 and the apparent activation energy, Q, was about 270 kJ/mol. The large creep ductility exhibited by WC-3009 was attributed to its high strain rate sensitivity.

Hebsur, Mohan G.↗

Molecular hydrogen in the galaxy and galactic gamma rays

Recent surveys of 2.6 mm CO emission and 100 MeV gamma-radiation in the galactic plane reveal a striking correlation suggesting that both emissions may be primarily proportional to the line-of-sight column density of H2 in the inner galaxy. Both the gamma ray and CO data suggest a prominent ring or arm consisting of cool clouds of H2 at a galactocentric distance of approximately 5 kpc with a mean density of approximately 4 atoms/cu cm. The importance of H2 in understanding galactic gamma ray observations is also reflected in the correlation of galactic latitude distribution of gamma rays and dense dust clouds. A detailed calculation of the gamma ray flux distribution in the 0 deg to 180 deg range using the CO data to obtain the average distribution of molecular clouds in the galaxy shows that most of the enhancement in the inner galaxy is due to pion-decay radiation and the 5 kpc ring plays a major role. Detailed agreement with the gamma ray data is obtained with the additional inclusion of contributions from bremsstrahlung and Compton radiation of secondary electrons and Compton radiation from the intense radiation field near the galactic center.

Stecker, F. W.↗

Multi-Parameter Observation and Detection of Pre-Earthquake Signals in Seismically Active Areas

The recent large earthquakes (M9.0 Tohoku, 03/2011; M7.0 Haiti, 01/2010; M6.7 L Aquila, 04/2008; and M7.9 Wenchuan 05/2008) have renewed interest in pre-anomalous seismic signals associated with them. Recent workshops (DEMETER 2006, 2011 and VESTO 2009 ) have shown that there were precursory atmospheric /ionospheric signals observed in space prior to these events. Our initial results indicate that no single pre-earthquake observation (seismic, magnetic field, electric field, thermal infrared [TIR], or GPS/TEC) can provide a consistent and successful global scale early warning. This is most likely due to complexity and chaotic nature of earthquakes and the limitation in existing ground (temporal/spatial) and global satellite observations. In this study we analyze preseismic temporal and spatial variations (gas/radon counting rate, atmospheric temperature and humidity change, long-wave radiation transitions and ionospheric electron density/plasma variations) which we propose occur before the onset of major earthquakes:. We propose an Integrated Space -- Terrestrial Framework (ISTF), as a different approach for revealing pre-earthquake phenomena in seismically active areas. ISTF is a sensor web of a coordinated observation infrastructure employing multiple sensors that are distributed on one or more platforms; data from satellite sensors (Terra, Aqua, POES, DEMETER and others) and ground observations, e.g., Global Positioning System, Total Electron Content (GPS/TEC). As a theoretical guide we use the Lithosphere-Atmosphere-Ionosphere Coupling (LAIC) model to explain the generation of multiple earthquake precursors. Using our methodology, we evaluated retrospectively the signals preceding the most devastated earthquakes during 2005-2011. We observed a correlation between both atmospheric and ionospheric anomalies preceding most of these earthquakes. The second phase of our validation include systematic retrospective analysis for more than 100 major earthquakes (M>5.9) in Taiwan and Japan. We have found anomalous behavior before all of these events with no false negatives. Calculated false alarm ratio for the for the same month over the entire period of analysis (2003-2009) is less than 10% and was d as the earthquakes. The commonalities in detecting atmospheric/ionospheric anomalies show that they may exist over both land and sea in regions of maximum stress (i.e., along plate boundaries) Our results indicate that the ISTF model could provide a capability to observe pre-earthquake atmospheric/ionospheric signals by combining this information into a common framework.

Ouzounov, D.↗

Isolated Stroemgren spheres as a source of galactic H alpha emission

The isolated H alpha emission features reported by Reynolds et al. are identified with Stroemgren spheres surrounding observed O stars; the root mean square electron densities and Stroemgren radii are calculated from the observed emission measure and stellar type. The density has an average value of 2 per cu cm but increases to 3.3 per cu cm for stars within 200 pc of the galactic plane. An analysis of the Catalogue of Galactic O Stars shows that enhanced H alpha emission is observed around all known O stars. The diffuse component of H alpha emission is what one would expect from the line-of-sight overlapping of isolated Stroemgren spheres surrounding B stars and appears to correlate with features on extinction maps, as derived. There is no compelling reason to suggest any large-scale intercloud ionization from H alpha data alone.

Elmergreen, B. G.↗

Observations in interplanetary space of relativistic electrons from Jupiter

Evidence for the presence of Jovian electrons in interplanetary space as much as 1 AU inside the orbit of Jupiter is summarized. Electron flux patterns at Pioneer 10 can only rarely be correlated with solar activity. Clear variations in intensity and spectrum with a period of 10 hrs are seen at varying distances from Jupiter, consistent with similar observations inside the magnetosphere. Extrapolated electron flux maxima and minima are in good agreement with the observed phase at distances as large as 80 million km from Jupiter, indicating rapid propagation of electrons from the planet. Anisotropy is greatest during the rising phase of the 10 hr variations and in a direction consistent with the interpretation of electrons traveling toward the sun along interplanetary spiral field lines. The propagation time calculated by Chenette's derivation is much larger than that implied by the data.

Chenette, D. L.↗

Rotational modulation and flares on RS Canum Venaticorum and BY Draconis stars. 18: Coordinated VLA, ROSAT, and IUE observations of RS CVn binaries

As part of a coordinated program of multi-wavelength observations of RS CVn close binary systems, we observed 15 systems with the Very Large Array (VLA) and 10 systems with IUE, simultaneously or nearly simultaneously with the ROSAT All Sky Survey observations of these stars. Of the 22 systems observed with ROSAT, three were observed both by IUE and the VLA. Radio observations were made at 3.6, 6 and 20 cm. Of the 15 observed RS CVn systems, we detected 11 with greater than 4 sigma confidence at one or more wavelengths. The IUE observations were made within the RIASS (ROSAT-IUE All Sky Survey) program. We present the results of the VLA observations, along with the corresponding subsets of the ROSAT Position Sensitive Proportional Counter (PSPC) X-ray and Wide Field Camera (WFC) XUV survey, and RIASS IUE observations. We obtained an extended VLA/IUE/ROSAT simultaneous coverage of one system, TY Pyx, covering more than one orbital period. These observations reveal that the quiescent radio flux of TY Pyx is relatively constant over time scales of up to 7 hours, but that it did change by a factor of 3 over 24 hours, probably due to a flare on 1990 Nov. 12. The UV, XUV and X-ray fluxes do not show large day-to-day or phase-related variability. The observation of the decay phase of a radio flare on EI Eri, with no accompanying X-ray or XUV flare, suggests that the lack of a strong correlation between X-ray and radio flares previously noted for dMe flare stars holds for RS CVn systems as well. We suggest that the radio flare may have been due to a coherent emission process such as electron cyclotron emission. The simultaneous measurements presented here provide a unique test of the general correlation between radio and soft X-ray luminosities, L(sub radio) approximately L(sub x exp m) (Drake et al. 1989) with a power-law slope close to unity, which was previously derived using data obtained years apart. Our derived slopes are consistent with and thus support the general correlations between coronal and chromospheric/transition region emissions previously derived from nonsimultaneous measurements of a much larger sample of these variable sources. However, the importance of simultaneous measurements for accurate energy balance calculations is stressed.

Fox, David C.↗

Correlation of electron and proton irradiation-induced damage in InP solar cells

When determining the best solar cell technology for a particular space flight mission, accurate prediction of solar cell performance in a space radiation environment is essential. The current methodology used to make such predictions requires extensive experimental data measured under both electron and proton irradiation. Due to the rising cost of accelerators and irradiation facilities, such extensive data sets are expensive to obtain. Moreover, with the rapid development of novel cell designs, the necessary data are often not available. Therefore, a method for predicting cell degradation based on limited data is needed. Such a method has been developed at the Naval Research Laboratory based on damage correlation using 'displacement damage dose' which is the product of the non-ionizing energy loss (NIEL) and the particle fluence. Displacement damage dose is a direct analog of the ionization dose used to correlate the effects of ionizing radiations. In this method, the performance of a solar cell in a complex radiation environment can be predicted from data on a single proton energy and two electron energies, or one proton energy, one electron energy, and Co(exp 60) gammas. This method has been used to accurately predict the extensive data set measured by Anspaugh on GaAs/Ge solar cells under a wide range of electron and proton energies. In this paper, the method is applied to InP solar cells using data measured under 1 MeV electron and 3 MeV proton irradiations, and the calculations are shown to agree well with the measured data. In addition to providing accurate damage predictions, this method also provides a basis for quantitative comparisons of the performance of different cell technologies. The performance of the present InP cells is compared to that published for GaAs/Ge cells. The results show InP to be inherently more resistant to displacement energy deposition than GaAs/Ge.

Walters, Robert J.↗

Theoretical study of CO chemisorption on nickel and copper surfaces

A comparative study of the chemisorption of CO on Ni(001) and Cu(001) surfaces has been performed. The study is based on an analysis of the electronic structure of (M)5CO clusters obtained from self-consistent field X alpha scattered-wave calculations. The electron orbital formed principally by the 5 sigma orbital on CO was found to be mainly responsible for the bonding of the CO molecule to the metal surface for both the CO/Ni and CO/Cu systems. The different occupation of the antibonding 7 a sub 1 orbital in the two clusters is believed to be the major reason for the large difference observed in the measured heats of adsorption of CO on Ni and Cu surfaces. It was found also that metal atoms transfer electronic charge to the antibonding pi(asterisk)-like orbital of CO. A possible correlation between the amount of the charge transfered and the relative ease of dissociation of CO molecules on metal surfaces is discussed.

Yu, H. L.↗

An interpretation of Jupiter's decametric radiation and the terrestrial kilometric radiation as direct amplified gyroemission

Direct amplified gyroemission due to an anisotropic distribution of suprathermal electrons is proposed as the most plausible emission mechanism for Jupiter's decametric radiation (DAM) and the terrestrial auroral kilometric radiation (AKR). It is suggested that the required electron distribution could be produced by electrons, initially with small pitch angles, precipitating from the magnetosphere. A quasi-linear treatment of the proposed mechanism is outlined, including satisfaction of the Doppler condition, calculation of the growth rate, conditions for quasi-linear relaxation, and generation of the anisotropy. The mechanism is applied to the Jovian DAM, emphasizing the growth rate, the power radiated, and the elliptical polarization of the radiation. It is found that the theory can account for the gross features of the DAM, provided the number density in the precipitating electron streams exceeds 20 per cu cm. Application of the theory to the AKR shows that the requirements concerning the properties of the precipitating electrons appear to be satisfied by the observed properties of those inverted V events which correlate with the emission of AKR.

Melrose, D. B.↗

Accretion-disk modeling of the UV spectrum of quasars

The thin accretion disk spectrum, including the effect of electron scattering, is calculated for a grid of the accretion parameters. It is shown that the luminosity and spectral slope in the UV and optical bands are uniquely determined by these parameters and depend only weakly on the viscosity parameter. When the model calculations are compared with observations of a sample of QSOs and Seyfert 1 nuclei, the black hole mass is in the range 10 to the 8th to 10 to the 9.5 solar for the QSOs and 10 to the 7.5 to 10 to the 8.5 solar for the Seyferts and for low-luminosity objects. The correlation between the spectral slope and luminosity of QSOs in the UV can be explained by evolution along curves of constant black hole mass and decreasing accretion rate. The relation between the spectrum and the accretion parameters can be used to constrain the cosmological evolution of the objects and imposes severe constraints on the pure luminosity evolution interpretation function for QSOs and Seyferts.

Wandel, Amri↗

Solar Ultraviolet Magnetograph Investigation (SUMI) Component Responses to Payload Vibration Testing

Vibration testing of SUMI was performed at both the experiment and payload levels. No accelerometers were installed inside the experiment during testing, but it is certain that component responses were very high. The environments experienced by optical and electronic components in these tests is an area of ongoing concern. The analysis supporting this presentation included a detailed finite element model of the SUMI experiment section, the dynamic response of which, correlated well with accelerometer measurements from the testing of the experimental section at Marshall Space Flight Center. The relatively short timeframe available to complete the task and the limited design information available was a limitation on the level of detail possible for the non-experiment portion of the model. However, since the locations of interest are buried in the experimental section of the model, the calculated responses should be enlightening both for the development of test criteria and for guidance in design.

Hunt, Ronald A.↗

Examination of Scanning Electron Microscope and Computed Tomography Images of PICA

Micrographs of PICA (Phenolic Impregnated Carbon Ablator) taken using a Scanning Electron Microscope (SEM) and 3D images taken with a Computed Tomography (CT) system are examined. PICA is a carbon fiber based composite (Fiberform ) with a phenolic polymer matrix. The micrographs are taken at different surface depths and at different magnifications in a sample after arc jet testing and show different levels of oxidative removal of the charred matrix (Figs 1 though 13). CT scans, courtesy of Xradia, Inc. of Concord CA, were captured for samples of virgin PICA, charred PICA and raw Fiberform (Fig. 14). We use these images to calculate the thermal conductivity (TC) of these materials using correlation function (CF) methods. CF methods give a mathematical description of how one material is embedded in another and is thus ideally suited for modeling composites like PICA. We will evaluate how the TC of the materials changes as a function of surface depth. This work is in collaboration with ETH-Zurich, which has expertise in high temperature materials and TC modeling (including CF methods).

Lawson, John W.↗