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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Quantile Vocoder

Parameters of spectral envelope obtained statistically. Algorithm for digital compression of speech signals encodes power spectral density of each short interval of speech by use of quantiles or order statistics. Purpose to reduce bit rate and bandwidth required for transmission. When fully developed, quantile vocoder - speech-encoding system based on new algorithm - expected moderately complicated compared with other speech-encoding systems and reproduce high-quality speech from code transmitted at relatively low bit rates. Speech signal treated mathematically as though amplitude spectrum stationary during short coding intervals, called "windows". Window duration of 20 or 35 ms, chosen as compromise between frequency resolution and time resolution. During each window, short-time amplitude and power spectra found by sampling at high rate (typically 10 kHz) and taking fast Fourier transforms (FFT's).

Swaminathan, Kumar↗
DOE OSTI2016

Fluorescent lighting with aluminum nitride phosphors

A fluorescent lamp includes a glass envelope; at least two electrodes connected to the glass envelope; mercury vapor and an inert gas within the glass envelope; and a phosphor within the glass envelope, wherein the phosphor blend includes aluminum nitride. The phosphor may be a wurtzite (hexagonal) crystalline structure Al.sub.(1-x)M.sub.xN phosphor, where M may be drawn from beryllium, magnesium, calcium, strontium, barium, zinc, scandium, yttrium, lanthanum, cerium, praseodymium, europium, gadolinium, terbium, ytterbium, bismuth, manganese, silicon, germanium, tin, boron, or gallium is synthesized to include dopants to control its luminescence under ultraviolet excitation. The disclosed Al.sub.(1-x)M.sub.xN:Mn phosphor provides bright orange-red emission, comparable in efficiency and spectrum to that of the standard orange-red phosphor used in fluorescent lighting, Y.sub.2O.sub.3:Eu. Furthermore, it offers excellent lumen maintenance in a fluorescent lamp, and does not utilize "critical rare earths," minimizing sensitivity to fluctuating market prices for the rare earth elements.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Modification of conventional peak shapes to accurately represent spectral asymmetry: High-Resolution X-ray photoelectron spectra of [C 4 C 1 Pyrr][NTf 2 ] and [C 8 C 1 Im][NTf 2 ] ionic liquids

X-ray photoelectron spectroscopy (XPS) is one of the most widely used techniques for surface characterization. Analysis of XPS data is challenging and requires the analyst to fit the data with synthetic line shapes to reach physically meaningful interpretations. Experimental spectral envelopes, however, are complex and display asymmetric features that are often ignored or attributed to additional chemical components. The high-resolution XPS spectra of [C 4 C 1 Pyrr][NTf 2 ] and [C 8 C 1 Im][NTf 2 ] all exhibit a degree of asymmetry which is systematically observed at the higher binding energy side of photoemission envelopes. Here, we present the development of a refined fitting procedure for XPS spectra of these ionic liquid-based systems which include (a) Shirley background offset necessary to account for the insulator-like region and (b) spectral asymmetry in C 1s and N 1s regions. Further, Shirley and trapezoid components are applied to compensate for inelastic scattering taking place during electron transitions as high as 7.8 eV above the start of the fitting region in C 1s high-resolution spectrum. To demonstrate the fitness of this model, we present an analysis of a 2:1 mixture of [C 4 C 1 Pyrr][NTf 2 ]: [C 8 C 1 Im][NTf 2 ].

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1978

A study of mass loss from the mid-ultraviolet spectrum of Alpha Cygni /A2 Ia/, Beta Orionis /B8 Ia/, and Eta Leonis /A0 Ib/

Results are presented for a study of mass loss from A and late-B supergiants based on high-resolution mid-UV spectra obtained with the echelle spectrograph of the Balloon-borne Ultraviolet Stellar Spectrometer. Spectra of Alpha Cyg, Beta Ori, Eta Leo, and Alpha Lyr are compared in selected wavelength regions; particular attention is given to previous observations of each star, the Mg II and Fe II resonance lines, lines due to other ions, and evidence for mass ejection. The results indicate that mass loss from late-B and A supergiants is variable, that a considerable fraction of envelope material is ejected in 'puffs', and that the puffs may be due to photospheric instabilities. A mass-loss rate of about 1 hundred-millionth of a solar mass per year is derived for Alpha Cyg and shown to be two orders of magnitude smaller than the value determined from the observed IR excess. This discrepancy is attributed to excess ionization in the envelope.

Lamers, H. J. G. L. M.↗
DOE OSTI2019

Multi-octave visible to long-wave IR femtosecond continuum generated in Cr:ZnS-GaSe tandem

We report a technique for generation of broad and coherent femtosecond (fs) continua that span several octaves from visible to long-wave IR parts of the spectrum (0.4–18 µm). The approach is based on simultaneous amplification of few-cycle pulses at 2.5 µm central wavelength at 80 MHz repetition rate, and augmentation of their spectrum via three-wave mixing in a tandem arrangement of polycrystalline Cr:ZnS and single crystal GaSe. The obtained average power levels include several mW in the 0.4–0.8 µm visible, 0.23 W in the 0.8–2 µm near-IR, up to 4 W in the 2–3 µm IR, and about 17 mW in the 3–18 µm long-wave IR bands, respectively. High brightness and mutual coherence of all parts of the continuum was confirmed by direct detections of the carrier envelope offset frequency of the master oscillator.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

On the Origin of SN 2016hil—A Type II Supernova in the Remote Outskirts of an Elliptical Host

Type II supernovae (SNe) stem from the core collapse of massive ($>8\ M_{\odot}$) stars. Owing to their short lifespan, we expect a very low rate of such events in elliptical host galaxies, where the star-formation rate is low, and which mostly consist of an old stellar population. SN 2016hil (iPTF16hil) is a Type II supernova located in the extreme outskirts of an elliptical galaxy at redshift $z=0.0608$ (projected distance $27.2$ kpc). It was detected near peak brightness ($M_{r} \approx -17$ mag) 9 days after the last nondetection. SN 2016hil has some potentially peculiar properties: while presenting a characteristic spectrum, the event was unusually short lived and declined by $\sim 1.5$ mag in $< 40$ days, following an apparently double-peaked light curve. Its spectra suggest a low metallicity ($Z<0.4\ Z_{\odot}$). We place a tentative upper limit on the mass of a potential faint host at $\log(M/M_{\odot}) =7.27^{+0.43}_{-0.24}$ using deep Keck optical imaging. In light of this, we discuss the possibility of the progenitor forming locally, and other more exotic formation scenarios such as a merger or common-envelope evolution causing a time-delayed explosion. Further observations of the explosion site in the ultraviolet are needed in order to distinguish between the cases. Regardless of the origin of the transient, observing a population of such seemingly hostless Type II SNe could have many uses, including an estimate the number of faint galaxies in a given volume, and tests of the prediction of a time-delayed population of core-collapse SNe in locations otherwise unfavorable for the detection of such events.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Measuring an Off-center Detonation through Infrared Line Profiles: The Peculiar Type Ia Supernova SN 2020qxp/ASASSN-20jq

In this study, we present and analyze a near-infrared (NIR) spectrum of the underluminous Type Ia supernova SN 2020qxp/ASASSN-20jq obtained with NIRES at the Keck Observatory, 191 days after B-band maximum. The spectrum is dominated by a number of broad emission features, including the [Fe ιι] at 1.644 μm, which is highly asymmetric with a tilted top and a peak redshifted by ≈2000 km s -1 . In comparison with 2D non-LTE synthetic spectra computed from 3D simulations of off-center delayed-detonation Chandrasekhar-mass (M ch ) white dwarf (WD) models, we find good agreement between the observed lines and the synthetic profiles, and are able to unravel the structure of the progenitor’s envelope. We find that the size and tilt of the [Fe ιι] 1.644 μm profile (in velocity space) is an effective way to determine the location of an off-center delayed-detonation transition (DDT) and the viewing angle, and it requires a WD with a high central density of ~4 × 10 9 g cm -3 . We also tentatively identify a stable Ni feature around 1.9 μm characterized by a “pot-belly” profile that is slightly offset with respect to the kinematic center. In the case of SN 2020qxp/ASASSN-20jq, we estimate that the location of the DDT is ~0.3M WD off center, which gives rise to an asymmetric distribution of the underlying ejecta. We also demonstrate that low-luminosity and high-density WD SN Ia progenitors exhibit a very strong overlap of Ca and 56 Ni in physical space. This results in the formation of a prevalent [Ca ιι] 0.73 μm emission feature that is sensitive to asymmetry effects. Our findings are discussed within the context of alternative scenarios, including off-center C/O detonations in He-triggered sub-M Ch WDs and the direct collision of two WDs. Snapshot programs with Gemini/Keck/Very Large Telescope (VLT)/ELT-class instruments and our spectropolarimetry program are complementary to mid-IR spectra by the James Webb Space Telescope (JWST).

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Modulational instability and soliton trains in a model for two-mode fiber ring lasers

A model of orthogonally polarized two-field fiber ring laser with a linear gain is considered, with emphasis on the continuous-wave stability and the existence of soliton trains. The continuous-wave stability analysis is carried out within the framework of the modulational-instability approach, the variations of the gain spectrum with the modulation frequency and characteristic parameters of the model give rise to a rich variety of stability features including single-band and multiband stability regions. Seeking for pulse structures of the model, the two coupled cubic complex Ginzburg–Landau equations describing individual mode propagations are transformed into a set of coupled, first-order nonlinear ordinary-differential equations for the amplitudes and phases of the two modes. Numerical simulations of the last set of coupled equations indicate that in the anomalous dispersion regime, envelopes of the two fields are periodic trains of pulses the amplitudes of which are affected by the linear gain.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Surface analysis insight note: X‐ray photoelectron spectroscopy analysis of battery electrodes—Challenges with nickel–manganese–cobalt and Li examples using an Al Kα x‐ray source

X‐ray photoelectron spectroscopy (XPS) has become a highly important tool for the analysis of battery materials and components. However, both anecdotal and detailed analysis of selected parts of the literature indicate that many reports of XPS on battery electrodes have significant analysis or data flaws. In this paper, we highlight several of the common challenges that analysts face when using XPS for battery materials, pointing to recent literature that addresses many of the critical issues associated with sample preparation as well as data collection and analysis. A common error for battery materials (and other materials) involves ignoring peak overlaps and interferences. Specifically, when a “minor” peak associated with a component in relatively high concentration overlaps or contributes to the primary peak (or one recommended for quantitative analysis) from a different element in the material. Overlap issues apply to many battery electrodes composed of many elements with complex photoelectron peak structures, as well as those involving peaks with seemingly simpler spectral envelopes such as Li and F. Examples of issues associated with battery systems are highlighted by a discussion of challenges associated with XPS analysis of Li and nickel–manganese–cobalt (NMC) electrodes in battery systems. Lithium analysis has challenges associated with the preparation and an often‐unrecognized peak overlap with F. In our laboratory and in the literature, NMC electrodes are often examined and new XPS users do not always recognize interference of the Auger signal from F KLL (in or on the electrode) with Ni 2p photoelectron spectrum when generated with Al Kα X‐rays. The use of simulated spectra involving both F and NiO demonstrates the extent of F Auger contributions to the Ni 2p signal strength as a function of the F/Ni atom ratio in the material and suggests spectra information that can be used to identify how significant effects will be on the resultant spectra. Our analysis demonstrates that in many cases overlap issues are significant for real electrode materials.

25 ENERGY STORAGE↗
NASA NTRS1999

A New Method for Nonlinear and Nonstationary Time Series Analysis and Its Application to the Earthquake and Building Response Records

A new method for analyzing nonlinear and nonstationary data has been developed. The key part of the method is the Empirical Mode Decomposition method with which any complicated data set can be decomposed into a finite and often small number of Intrinsic Mode Functions (IMF). An IMF is defined as any function having the same numbers of zero-crossing and extrema, and also having symmetric envelopes defined by the local maxima and minima respectively. The IMF also admits well-behaved Hilbert transform. This decomposition method is adaptive, and, therefore, highly efficient. Since the decomposition is based on the local characteristic time scale of the data, it is applicable to nonlinear and nonstationary processes. With the Hilbert transform, the Intrinsic Mode Functions yield instantaneous frequencies as functions of time that give sharp identifications of imbedded structures. The final presentation of the results is an energy-frequency-time distribution, designated as the Hilbert Spectrum, Example of application of this method to earthquake and building response will be given. The results indicate those low frequency components, totally missed by the Fourier analysis, are clearly identified by the new method. Comparisons with Wavelet and window Fourier analysis show the new method offers much better temporal and frequency resolutions.

Huang, Norden E.↗
NASA NTRS2001

Applications of the Hilbert-Huang Transform

A new method, the Hilbert-Huang Transform, has been developed for analyzing nonlinear and nonstationary data. The key part of the method is the Empirical Mode Decomposition with which any complicated data set can be decomposed into a finite and often small number of Intrinsic Mode Functions (IMF). An M is defined as any function having the same numbers of zero-crossing and extrema, and also having symmetric envelopes defined by the local maxima and minima respectively. The IMF also admits well-behaved Hilbert transform. This decomposition method is adaptive, and, therefore, highly efficient. Since the decomposition is based on the local characteristic time scale of the data, it is applicable to nonlinear and nonstationary processes. With the Hilbert transform, the Intrinsic Mode Functions yield instantaneous frequencies'as functions of time that give sharp identifications of imbedded structures. The final presentation of the results is an energy-frequency-time distribution, designated as the Hilbert Spectrum. With this technique we can examine the detailed dynamics characteristics of a nonlinear system through the instantaneous frequency rather than harmonics. Thus it constitutes a new view of the nonlinear dynamics. Examples of classic nonlinear equations and other nonlinear and nonstationary data sets will be used as examples to illustrate the advantage of the application of this new data analysis method.

Huang, Norden E.↗
NASA NTRS2001

A New Method for Nonlinear and Nonstationary Time Series Analysis: The Empirical Mode Decomposition Method

A new method for analyzing nonlinear and nonstationary data has been developed. The key part of the method is the Empirical Mode Decomposition method with which any complicated data set can be decomposed into a finite and often small number of Intrinsic Mode Functions (IMF). An IMF is defined as any function having the same numbers of zero-crossing and extrema, and also having symmetric envelopes defined by the local maxima and minima respectively. The IMF also admits well-behaved Hilbert transform. This decomposition method is adaptive, and, therefore, highly efficient. Since the decomposition is based on the local characteristic time scale of the data, it is applicable to nonlinear and nonstationary processes. With the Hilbert transform, the Intrinsic Mode Functions yield instantaneous frequencies as functions of time that give sharp identifications of imbedded structures. The final presentation of the results is an energy-frequency-time distribution, designated as the Hilbert Spectrum. Classical nonlinear system models are used to illustrate the roles played by the nonlinear and nonstationary effects in the energy-frequency-time distribution.

Huang, Norden E.↗
NASA NTRS2000

Estimating Cosmic Ray Spectral Parameters From Simulated Detector Responses With Detector Design Implications

A simple power law model consisting of a single spectral index alpha (sub 1), is believed to be an adequate description of the galactic cosmic ray (GCR) proton flux at energies below 10(exp 13) eV, with a transition at knee energy E(sub k) to a steeper spectral index alpha(sub 2) greater than alpha(sub 1) above E(sub k). The maximum likelihood procedure is developed for estimating these three spectral parameters of the broken power law energy spectrum from simulated detector responses. These estimates and their surrounding statistical uncertainty are being used to derive the requirements in energy resolution, calorimeter size, and energy response of a proposed sampling calorimeter for the Advanced Cosmic ray Composition Experiment for the Space Station (ACCESS). This study thereby permits instrument developers to make important trade studies in design parameters as a function of the science objectives, which is particularly important for space-based detectors where physical parameters, such as dimension and weight, impose rigorous practical limits to the design envelope.

Howell, L. W.↗
NASA NTRS2000

Estimating Cosmic Ray Spectral Parameters from Simulated Detector Responses

A simple power law model consisting of a single spectral index al is believed to be an adequate description of the galactic cosmic ray (GCR) proton flux at energies below 100 TeV, with a transition at kink energy Ek to a steeper spectral index a2>al above Ek. The maximum likelihood procedure is developed for estimating these three spectral parameters of the broken power law energy spectrum from simulated detector responses. These estimates and their surrounding statistical uncertainty are being used to derive the requirements in energy resolution, calorimeter size, and energy response of a proposed sampling calorimeter for the Advanced Cosmic-ray Composition Experiment for the Space Station (ACCESS). This study thereby permits instrument developers to make important trade studies in design parameters as a function of the science objectives, which is particularly important for space-based detectors where physical parameters, such as dimension and weight, impose rigorous practical limits to the design envelope.

Howell, Leonard↗
NASA NTRS2001

Estimating Cosmic-Ray Spectral Parameters from Simulated Detector Responses with Detector Design Implications

A simple power law model consisting of a single spectral index (alpha-1) is believed to be an adequate description of the galactic cosmic-ray (GCR) proton flux at energies below 10(exp 13) eV, with a transition at knee energy (E(sub k)) to a steeper spectral index alpha-2 > alpha-1 above E(sub k). The maximum likelihood procedure is developed for estimating these three spectral parameters of the broken power law energy spectrum from simulated detector responses. These estimates and their surrounding statistical uncertainty are being used to derive the requirements in energy resolution, calorimeter size, and energy response of a proposed sampling calorimeter for the Advanced Cosmic-ray Composition Experiment for the Space Station (ACCESS). This study thereby permits instrument developers to make important trade studies in design parameters as a function of the science objectives, which is particularly important for space-based detectors where physical parameters, such as dimension and weight, impose rigorous practical limits to the design envelope.

Howell, L. W.↗
NASA NTRS1994

Dynamo generation of magnetic field in the white dwarf GD 358

On the basis of Whole Earth Telescope observations of the g-mode oscillation spectrum of the white dwarf GD 358, Winget et al. find evidence for significant differential rotation and for a time-varying magnetic field concentrated in the surface layers of this star. Here we argue on theoretical grounds that this magnetic field is produced by an alpha omega dynamo operating in the lower part of a surface convection zone in GD 358. Our argument is based on numerical solutions of the nonlinear, local dynamo equations of Robinson & Durney, with specific parameters based on our detailed models of white-dwarf convective envelopes, and universal constants determined by a calibration with the the Sun's dynamo. The calculations suggest a dynamo cycle period of about 6 years for the fundamental mode, and periods as short as 1 year for the higher-order modes that are expected to dominate in view of the large dynamo number we estimate for GD 358. These dynamo periods are consistent with the changes in the magnetic field of GD 358 over the span of 1 month inferred by Winget et. al. from their observations. Our calculations also suggest a peak dynamo magnetic field strength at the base of the surface convection zone of about 1800 G, which is consistent with the field strength inferred from the observations.

Markiel, J. Andrew↗
NASA NTRS1994

Global oscillation amplitudes excited by the Jupiter-comet collision

The energy released during the collision of fragments of comet Shoemaker-Levy 9 with Jupiter in 1994 July may excite a spectrum of global oscillation modes. We estimate the maximum amplitudes to which the p-modes, discontinuity modes, inertial modes, and r-modes can be excited by assuming that the full kinetic energy of the fragment, which we take to be 10(exp 30) ergs, is converted into the energy of each individual mode. We have used two realistics Jovian models as the basis for our estimates: one with and one without the predicted 'plasma phase transition' (PPT) of hydrogen. A density discontinuity in the planet's hydrogen-helium envelope is associated with the PPT. We find that high-frequency p-modes, with periods approximately less than 15 minutes, may be excited to sufficiently large amplitudes to be observable as Doppler shifts (velocity amplitudes approximately greater than serveral m/s) or temperature variations (delta(T) approximately greater than 0.01 K) at the planetary surface. Inertial modes may also be observable. If the PPT exists in Jupiter, inertial modes with periods approximately 8 hr or approximately 2.2 days trapped in the surface region of the planet, above the PPT, may be detectable as temperature fluctuations of order delta(T) approximately 0.01 K. Inertial modes with periods of order 8-8.5 hr appear to be particularly strongly excited if the PPT exists. If the PPT does not exist in Jupiter, intertial modes with periods approximately 8-8.5 hr have much lower amplitudes. In this case, inertial modes with periods longer than approximately 18 hr may produce temperature fluctuations of order delta(T) approximately 0.01 K. Discontinuity modes associated with the PPT and r-modes unfortunately may not reach observable amplitudes.

Lee, U.↗
NASA NTRS1999

Envelope structure of deeply embedded young stellar objects in the Serpens Molecular Cloud

Aperture-synthesis and single-dish (sub-) millimeter molecular-line and continuum observations reveal in great detail the envelope structure of deeply embedded young stellar objects (SMM 1 = FIRS 1, SMM 2, SMM 3, SMM 4) in the densely star-forming Serpens Molecular Cloud. SMM 1, 3, and 4 show partially resolved (>2" = 800 AU) continuum emission in the beam of the Owens Valley Millimeter Array at lambda = 3.4-1.4 mm. The continuum visibilities accurately constrain the density structure in the envelopes, which can be described by a radial power law with slope -2.0 +/- 0.5 on scales of 300 to 8000 AU. Inferred envelope masses within a radius of 8000 AU are 8.7, 3.0, and 5.3 Msolar for SMM 1, 3, and 4, respectively. A point source with 20%-30% of the total flux at 1.1 mm is required to fit the observations on long baselines, corresponding to warm envelope material within approximately 100 AU or a circumstellar disk. No continuum emission is detected interferometrically toward SMM 2, corresponding to an upper limit of 0.2 Msolar assuming Td = 24 K. The lack of any compact dust emission suggests that the SMM 2 core does not contain a central protostar. Aperture-synthesis observations of the 13CO, C18O, HCO+, H13CO+, HCN, H13CN, N2H+ 1-0, SiO 2-1, and SO 2(2)-1(1) transitions reveal compact emission toward SMM 1, 3, and 4. SMM 2 shows only a number of clumps scattered throughout the primary field of view, supporting the conclusion that this core does not contain a central star. The compact molecular emission around SMM 1, 3, and 4 traces 5"-10" (2000-4000 AU) diameter cores that correspond to the densest regions of the envelopes, as well as material directly associated with the molecular outflow. Especially prominent are the optically thick HCN and HCO+ lines that show up brightly along the walls of the outflow cavities. SO and SiO trace shocked material, where their abundances may be enhanced by 1-2 orders of magnitude over dark-cloud values. A total of 31 molecular transitions have been observed with the James Clerk Maxwell and Caltech Submillimeter telescopes in the 230, 345, 490, and 690 GHz atmospheric windows toward all four sources, containing, among others, lines of CO, HCO+, HCN, H2CO, SiO, SO, and their isotopomers. These lines show 20-30 km s-1 wide line wings, deep and narrow (1-2 km s-1) self-absorption, and 2-3 km s-1 FWHM line cores. The presence of highly excited lines like 12CO 4-3 and 6-5, 13CO 6-5, and several H2CO transitions indicates the presence of material with temperatures > or approximately 100 K. Monte Carlo calculations of the molecular excitation and line transfer show that the envelope model derived from the dust emission can successfully reproduce the observed line intensities. The depletion of CO in the cold gas is modest compared to values inferred in objects like NGC 1333 IRAS 4, suggesting that the phase of large depletions through the entire envelope is short lived and may be influenced by the local star formation density. Emission in high-excitation lines of CO and H2CO requires the presence of a small amount of approximately 100 K material, comprising less than 1% of the total envelope mass and probably associated with the outflow or the innermost region of the envelope. The derived molecular abundances in the warm (Tkin > 20 K) envelope are similar to those found toward other class 0 YSOs like IRAS 16293-2422, though some species appear enhanced toward SMM 1. Taken together, the presented observations and analysis provide the first comprehensive view of the physical and chemical structure of the envelopes of deeply embedded young stellar objects in a clustered environment on scales between 1000 and 10,000 AU.

NASA Discipline Exobiology↗