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At least 235 records · Page 13

Observation of a periodic array of flux-closure quadrants in strained ferroelectric PbTiO 3 films

Nanoscale ferroelectrics are expected to exhibit various exotic domain configurations, such as the full flux-closure pattern that is well known in ferromagnetic materials. Here we observe not only the atomic morphology of the flux-closure quadrant but also a periodic array of flux closures in ferroelectric PbTiO 3 films, mediated by tensile strain on a GdScO 3 substrate. Using aberration-corrected scanning transmission electron microscopy, we directly visualize an alternating array of clockwise and counterclockwise flux closures, whose periodicity depends on the PbTiO 3 film thickness. In the vicinity of the core, the strain is sufficient to rupture the lattice, with strain gradients up to 10 9 per meter. We found engineering strain at the nanoscale may facilitate the development of nanoscale ferroelectric devices.

36 MATERIALS SCIENCE↗

Role of superexchange interactions in the ferromagnetism of manganites

Compound La{sub 0.7}Sr{sub 0.3}Mn{sub 0.85}Nb{sub 0.15}O{sub 3}, in which manganese ions are in an oxidation state close to 3+, are studied by neutron diffraction and magnetic measurements. This compound is shown to be a ferromagnet with T{sub C} = 145 K and a magnetic moment of 3.1 μ{sub B}/Mn at T = 10 K. No signs of cooperative orbital ordering are detected. When Mg{sup 2+} ions substitute for some Nb{sup 5+} ions, Mn{sup 4+} ions appear but ferromagnetism is not enhanced. An increase in the structural distortions leads to a decrease in the ferromagnetic component. The ferromagnetic state is assumed to be caused by substantial hybridization of the e{sub g} orbitals of manganese and oxygen, which increases the positive part of the superexchange interactions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Structure, Ferroelectric, and Magnetoelectric Properties of Bulk PZT–NiFe{sub 1.9}Co{sub 0.02}O{sub 4–δ} Composites

The phase composition, microstructure, and dielectric, ferroelectric, magnetic, and magnetoelectric properties of bulk ceramic (1 – x)PZT–xNiFe{sub 1.9}Co{sub 0.02}O{sub 4–δ} composites with 3–0 connectivity have been studied. Using X-ray diffraction and electron microscopy, it has been established that the ferrimagnetic (spinel- like) and ferroelectric (tetragonal perovskite-like) phases separately exist in the composites of all compositions. The simultaneous existence of ferroelectric and ferrimagnetic properties in the composites is confirmed by measuring their P(E) and σ(B) hysteresis loops and studying the temperature dependences of dielectric and magnetic properties. The synthesized composites have high magnetoelectric characteristics: their voltage coefficient at x = 0.4 is 215 mV/A at a frequency of 1 kHz and 130 V/A at an electromechanical resonance frequency of 380 kHz.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A shortcut to gradient-corrected magnon dispersion: exchange-only case

Ab initio calculations of the magnon dispersion in ferromagnetic materials typically rely on the adiabatic local density approximation (ALDA) in which the effective exchange-correlation field is everywhere parallel to the magnetization. These calculations, however, tend to overestimate the “magnon stiffness”, defined as the curvature of the magnon frequency vs. wave vector relation evaluated at zero wave vector. Here we suggest a simple procedure to improve the magnon dispersion by taking into account gradient corrections to the ALDA at the exchange-only level. We find that this gradient correction always reduces the magnon stiffness. The surprisingly large size of these corrections (~30%) greatly improves the agreement between the calculated and the observed magnon stiffness for cobalt and nickel, which are known to be overestimated within the ALDA.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Massive Gas Injection Valve Development for NSTX-U

NSTX-U research will offer new insight by studying gas assimilation efficiencies for MGI injection from different poloidal locations using identical gas injection systems. In support of this activity, an electromagnetic MGI valve has been built and tested. The valve operates by repelling two conductive disks due to eddy currents induced on them by a rapidly changing magnetic field created by a pancake disk solenoid positioned beneath the circular disk attached to a piston. The current is driven in opposite directions in the two solenoids, which creates a cancelling torque when the valve is operated in an ambient magnetic field, as would be required in a tokamak installation. The valve does not use ferromagnetic materials. Results from the operation of the valve, including tests conducted in 1 T external magnetic fields, are described. The pressure rise in the test chamber is measured directly using a fast time response baratron gauge. At a plenum pressure of just 1.38 MPa (~200 psig), the valve injects 27 Pa.m^3 (~200 Torr.L) of nitrogen with a pressure rise time of 3 ms.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Theoretical development and first-principles analysis of strongly correlated systems

A variety of quantum many-body methods have been developed for studying the strongly correlated electron systems. We have also proposed a computationally efficient and accurate approach, named the correlation matrix renormalization (CMR) method, to address the challenges. The initial implementation of the CMR method is designed for molecules which have theoretical advantages, including small size of system, manifest mechanism and strongly correlation effect such as bond breaking process. The theoretic development and benchmark tests of the CMR method are included in this thesis. Meanwhile, ground state total energy is the most important property of electronic calculations. We also investigated an alternative approach to calculate the total energy, and extended this method for magnetic anisotropy energy (MAE) of ferromagnetic materials. In addition, another theoretical tool, dynamical mean- field theory (DMFT) on top of the DFT , has also been used in electronic structure calculations for an Iridium oxide to study the phase transition, which results from an interplay of the d electrons' internal degrees of freedom.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A transient solution for domain wall motion

An analytic solution of transient wall motion in a bulk ferromagnetic material is obtained from the dynamic torque equations with a Gilbert damping term. The steady state solution reduces to previously obtained, well known solutions.

Bourne, H. C., Jr.↗

Magnetic heat pumping near room temperature

It is shown that magnetic heat pumping can be made practical at room temperature by using a ferromagnetic material with a Curie point at or near operating temperature and an appropriate regenerative thermodynamic cycle. Measurements are performed which show that gadolinium is a resonable working material and it is found that the application of a 7-T magnetic field to gadolinium at the Curie point (293 K) causes a heat release of 4 kJ/kg under isothermal conditions or a temperature rise of 14 K under adiabatic conditions. A regeneration technique can be used to lift the load of the lattice and electronic heat capacities off the magnetic system in order to span a reasonable temperature difference and to pump as much entropy per cycle as possible

Brown, G. V.↗

Theory of global thermoremanent magnetization of planetary lithospheres in dipole fields of internal origin

A model is presented for the global thermoremanent magnetization of spherical lithospheres which cool in the presence of central dipole fields. Reversals and intensity variations of the field are incorporated in this model, which is applicable to bodies whose interiors have remained above the Curie point throughout their evolution. The model demonstrates that even considering Runcorn's (1975) magnetostatics theorems for spherical shells, a nonzero magnetic permeability and a finite cooling rate in the lithosphere permit the acquisition of a sizable global remanent dipole moment, which would be detectable by external measurements after the magnetizing field has disappeared. Preliminary application of this model to Mercury, Venus, and Mars suggests that only the combination of a nonreversing ancient source field with a surface value near 1 Oe plus a sizable concentration (about 1% by volume) of ferromagnetic material in their crusts could produce remanent planetary dipole fields as large as those measured by spacecraft. On the other hand, if ancient reversing dynamos existed in these planets, it is unlikely that large planetary-scale fields like those observed at Mercury could be due to remanence in their crusts, irrespective of their composition.

Srnka, L. J.↗

Optimum dimensions of power solenoids for magnetic suspension

Design optimization of power solenoids for controllable and stabilizable magnetic suspensions with force compensation in a wind tunnel is shown. It is assumed that the model of a levitating body is a sphere of ferromagnetic material with constant magnetic permeability. This sphere, with a radius much smaller than its distance from the solenoid above, is to be maintained in position on the solenoid axis by balance of the vertical electromagnetic force and the force of gravitation. The necessary vertical (axial) force generated by the solenoid is expressed as a function of relevant system dimensions, solenoid design parameters, and physical properties of the body. Three families of curves are obtained which depict the solenoid power for a given force as a function of the solenoid length with either outside radius or inside radius as a variable parameter and as a function of the outside radius with inside radius as a variable parameter. The curves indicate the optimum solenoid length and outside radius, for minimum power, corresponding to a given outside radius and inside radius, respectively.

Kaznacheyev, B. A.↗

Residual stress characterization with an ultrasonic/magnetic technique

A potentially useful new technique for residual stress characterization in ferromagnetic material is described. The unique feature of this technique is the measurement of small changes in ultrasonic wave velocity by the application of external dc magnetic field in the material under various stress conditions. It was found, in steel, that the fractional change in the natural velocity Delta W/W of waves propagating along the external field direction is affected by the uniaxial stress applied in the same axis. External compression lowers the slope of the Delta W/W curve in the low field region, while external tension generally does the opposite. For most cases, the slope in this region falls below zero under external compression. The result of measurements in specimens with residual stress shows exactly the same tendency.

Namkung, M.↗

Temperature dependence of the time decay of the magnetization in particulate media

The time decay of magnetization in commercial CrO2, gamma-Fe2O3, and Co-doped gamma-Fe2O3 tapes is investigated experimentally at temperatures 6, 50, 100, 200, 250, and 300 K. The decay is found to be linearly dependent on temperature in all four tapes tested, but when the curves are extrapolated to 0 K, there is a large finite intercept - in contrast to similar measurements on ferromagnetic materials and rocks.

Oseroff, S. B.↗

Fast Magnetoresistive Random-Access Memory

Magnetoresistive binary digital memories of proposed new type expected to feature high speed, nonvolatility, ability to withstand ionizing radiation, high density, and low power. In memory cell, magnetoresistive effect exploited more efficiently by use of ferromagnetic material to store datum and adjacent magnetoresistive material to sense datum for readout. Because relative change in sensed resistance between "zero" and "one" states greater, shorter sampling and readout access times achievable.

Wu, Jiin-Chuan↗

Magnetic particle inspection

The purpose of this experiment is to familiarize the student with magnetic particle inspection and relate it to classification of various defects. Magnetic particle inspection is a method of detecting the presence of cracks, laps, tears, inclusions, and similar discontinuities in ferromagnetic materials such as iron and steel. This method will most clearly show defects that are perpendicular to the magnetic field. The Magnaglo method uses a liquid which is sprayed on the workpiece to be inspected, and the part is magnetized at the same time. The workpiece is then viewed under a black light, and the presence of discontinuity is shown by the formation of a bright indication formed by the magnetic particles over the discontinuity. The equipment and experimental procedures are described.

Sastri, Sankar↗