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At least 235 records · Page 13

Two-Pendulum Model of Propellant Slosh in Europa Clipper PMD Tank

The objective of this fluids analysis is to model propellant slosh for the Europa Clipper mission using a two-pendulum model, such that controls engineers can predict slosh behavior during the mission. Propellant slosh causes shifts in center of mass and exerts forces and torques on the spacecraft which, if not adequately controlled, can lead to mission failure. The two-pendulum model provides a computationally simple model that can be used to predict slosh for the Europa Clipper tank geometry. The Europa Clipper tank is cylindrical with a domed top and bottom and includes a propellant management device (PMD). Due to the lack of experimental data in low gravity environments, computational fluid dynamics (CFD) simulation results were used as 'real' slosh behavior for two propellants at three fill fractions. Key pendulum parameters were derived that allow the pendulum model's center of mass, forces, and moments to closely match the CFD data. The parameter trends were examined as a function of tank fill fraction and compared with solutions to analytic equations that describe the frequency of slosh in tanks with simple geometries. The trends were monotonic as expected, and parameters resembled analytical predictions; any differences could be explained by the specific differences in the geometry of the tank. This paper summarizes the new method developed at Goddard Space Flight Center (GSFC) for deriving pendulum parameters for two-pendulum equivalent sloshing models. It presents the results of this method and discusses the validity of the results. This analysis is at a completed stage and will be applied in the immediate future to the evolving tank geometry as Europa Clipper moves past its preliminary design review (PDR) phase.

Propellant Slosh↗

Turbulence in planetary occultations. II - Effects on atmospheric profiles derived from Doppler measurements. III - Effects on atmospheric profiles derived from intensity measurements

The nature and magnitude of turbulence-induced errors in atmospheric profiles derived from Doppler measurements made during radio occultations are investigated. It is found that turbulence in planetary atmospheres induces both fluctuating and systematic errors in derived profiles, but the errors of both types are very small. Consideration of the occultation of Mariner 10 by Venus and of the Pioneer occultations by Jupiter shows that the rms fractional errors in the atmospheric profiles derived from these observations were less than 0.01 in both temperature and pressure, while the fractional systematic errors were typically of the order of 1 millionth. The extent to which atmospheric profiles derived from radio and optical intensity measurements are affected by turbulence is also examined. The results indicate that turbulence in planetary atmospheres has only a marginal effect on derived profiles in the weak-scattering limit and that the turbulence-induced errors in this case are always much larger than the corresponding errors in profiles derived from radio Doppler measurements.

Haugstad, B. S.↗

Augmented reduced order models for turbulence

The authors introduce an augmented-basis method (ABM) to stabilize reduced-order models (ROMs) of turbulent incompressible flows. The method begins with standard basis functions derived from proper orthogonal decomposition (POD) of snapshot sets taken from a full-order model. These are then augmented with divergence-free projections of a subset of the nonlinear interaction terms that constitute a significant fraction of the time-derivative of the solution. The augmenting bases, which are rich in localized high wavenumber content, are better able to dissipate turbulent kinetic energy than the standard POD bases. Several examples illustrate that the ABM significantly out-performs L 2 -, H 1 - and Leray-stabilized POD ROM approaches. The ABM yields accuracy that is comparable to constraint-based stabilization approaches yet is suitable for parametric model-order reduction in which one uses the ROM to evaluate quantities of interests at parameter values that differ from those used to generate the full-order model snapshots. Several numerical experiments point to the importance of localized high wavenumber content in the generation of stable, accurate, and efficient ROMs for turbulent flows.

Kaneko, Kento↗

An optimization-based approach to parameter learning for fractional type nonlocal models

Nonlocal operators of fractional type are a popular modeling choice for applications that do not adhere to classical diffusive behavior; however, one major challenge in nonlocal simulations is the selection of model parameters. In this study we propose an optimization-based approach to parameter identification for fractional models with an optional truncation radius. We formulate the inference problem as an optimal control problem where the objective is to minimize the discrepancy between observed data and an approximate solution of the model, and the control variables are the fractional order and the truncation length. For the numerical solution of the minimization problem we propose a gradient-based approach, where we enhance the numerical performance by an approximation of the bilinear form of the state equation and its derivative with respect to the fractional order. Several numerical tests in one and two dimensions illustrate the theoretical results and show the robustness and applicability of our method.

97 MATHEMATICS AND COMPUTING↗

Intrinsic Ion Transport Properties of Block Copolymer Electrolytes

Knowledge of intrinsic properties is of central importance for materials design and assessing suitability for specific applications. Self-assembling block copolymer electrolytes (BCEs) are of great interest for applications in solid-state energy storage devices. A fundamental understanding of ion transport properties, however, is hindered by the difficulty in deconvoluting extrinsic factors, such as defects, from intrinsic factors, such as the presence of interfaces between the domains. Here, we quantify the intrinsic ion transport properties of a model BCE system consisting of poly(styrene-block-ethylene oxide) (SEO) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt using a generalizable strategy of depositing thin films on interdigitated electrodes and self-assembling fully connected parallel lamellar structures throughout the films. Comparison between conductivity in homopolymer poly(ethylene oxide) (PEO)-LiTFSI electrolytes and the analogous conducting material in SEO over a range of salt concentrations (r, molar ratio of lithium ion to ethylene oxide repeat units) and temperatures reveals that between 20% and 50% of the PEO in SEO is inactive. Using mean-field theory calculations of the domain structure and monomer concentration profiles at domain interfaces-both of which vary substantially with salt concentration-the fraction of inactive PEO in the SEO, as derived from conductivity measurements, can be quantitatively reconciled with the fraction of PEO that is mixed with greater than a few volume percent of polystyrene. Despite the detrimental interfacial effects for ion transport in BCEs, the intrinsic conductivity of the SEO studied here (ca. 10 -3 S/cm at 90 degrees C, r = 0.085) is an order of magnitude higher than reported values from bulk samples of similar molecular weight SEO (ca. 10 -4 S/cm at 90 degrees C, r = 0.085). Finally, this work provides motivation and methods for pursuing improved BCE chemical design, interfacial engineering, and processing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

An optimization-based approach to parameter learning for fractional type nonlocal models

Nonlocal operators of fractional type are a popular modeling choice for applications that do not adhere to classical diffusive behavior; however, one major challenge in nonlocal simulations is the selection of model parameters. In this work we propose an optimization-based approach to parameter identification for fractional models with an optional truncation radius. We formulate the inference problem as an optimal control problem where the objective is to minimize the discrepancy between observed data and an approximate solution of the model, and the control variables are the fractional order and the truncation length. For the numerical solution of the minimization problem we propose a gradient-based approach, where we enhance the numerical performance by an approximation of the bilinear form of the state equation and its derivative with respect to the fractional order. Several numerical tests in one and two dimensions illustrate the theoretical results and show the robustness and applicability of our method.

97 MATHEMATICS AND COMPUTING↗

The consanguinity of the oldest Apollo 11 mare basalts

The textural, mineralogical, and chemical relationships between three of the oldest dates lunar mare basalt samples returned by Apollo 11 (10003, 10029 and 10062) were investigated. Very strong resemblances were noted between the modal minerologies of 10003 and 10029. Significantly more modal olivine and cristobalite was observed in 10062 than in the other basalt samples. A detailed examination of mineral-chemical relationships among the samples revealed similarities between 10003 and 10062 and differences between these two rocks and 10029, the most significant of which is the presence of akaganeite in 10029, implying that lawrencite was present in the pristine sample of 10029 but not in 10003 and 10062. Results of a Wright-Doherty mixing program used to test various fractional crystallization schemes show that 10062 can be derived from a liquid with the composition of either 10003 or 10029 by removing 2-5% ilmenite and 5% olivine. By removing about 6% plagioclase, 10003 can be derived from a liquid with the bulk composition of 10062. It is concluded that 10003 and 10029 may have come from different basaltic flows, whereas it is possible that 10003 and 10062 were derived from the same parental magma by near-surface fractionation of olivine plus ilmenite or of plagioclase plus or minus olivine.

Gamble, R. P.↗

BOREAS TE-23 Canopy Architecture and Spectral Data from Hemispherical Photographs

The Boreal Ecosystem-Atmospheric Study (BOREAS) TE-23 (Terrestrial Ecology) team collected hemispherical photographs in support of its efforts to characterize and interpret information on estimates of canopy architecture and radiative transfer properties for most BOREAS study sites. Various Old Aspen (OA), Old Black Spruce (OBS), Old Jack Pine (OJP), Young Jack Pine (YJP), and Young Aspen (YA) sites in the boreal forest were measured from May to August 1994. The hemispherical photographs were used to derive values of leaf area index (LAI), leaf angle, gap fraction, and clumping index. This documentation describes these derived values. The derived data are stored in tabular ASCII files. The hemispherical photographs are stored in the original set of 42 CD-ROMs that were supplied by TE-23. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Rich, Paul M.↗

Thermal remote sensing of surface soil water content with partial vegetation cover for incorporation into climate models

This study outlines a method for the estimation of regional patterns of surface moisture availability (M(sub 0)) and fractional vegetation (Fr) in the presence of spatially variable vegetation cover. The method requires relating variations in satellite-derived (NOAA, Advanced Very High Resolution Radiometer (AVHRR)) surface radiant temperature to a vegetation index (computed from satellite visible and near-infrared data) while coupling this association to an inverse modeling scheme. More than merely furnishing surface soil moisture values, the method constitues a new conceptual and practical approach for combining thermal infrared and vegetation index measurements for incorporating the derived values of M(sub 0) into hydrologic and atmospheric prediction models. Application of the technique is demonstrated for a region in and around the city of Newcastle upon Tyne situated in the northeast of England. A regional estimate of M(sub 0) is derived and is probabbly good for fractional vegetation cover up to 80% before errors in the estimated soil water content become unacceptably large. Moreover, a normalization scheme is suggested from which a nomogram, `universal triangle,' is constructed and is seen to fit the observed data well. The universal triangle also simplifies the inclusion of remotely derived M(sub 0) in hydrology and meteorological models and is perhaps a practicable step toward integrating derived data from satellite measurements in weather forecasting.

Gillies, Robert R.↗

Investigation of Three Analytical Hypothesis for Determining Material Creep Behavior under Varied Loads, with an Application to 2024-T3 Aluminum-Alloy Sheet in Tension at 400 F

Three existing hypotheses are formulated mathematically to estimate tensile creep strain under varied loads and constant temperature from creep data obtained under constant load and constant temperature. hypotheses investigated include the time-hardening, strain-hardening, and life-fraction rules. Predicted creep behavior is compared with data obtained from tensile creep tests of 2024-T3 aluminum-alloy sheet at 400 F under cyclic-load conditions. creep strain under varied loads is presented on the basis of an equivalent stress, derived from the life-fraction rule, which reduces the varied-load case to a constant-load problem. Creep strain in the region of interest for structural design and rupture times, determined from the hypotheses investigated, are in fair agreement with data in most cases, although calculated values of creep strain are generally greater than the experimental values because creep recovery is neglected in the calculations.

Berkovits, Avraham↗

Calculator for Agricultural Water Use Fractions in California

Improved quantification of agricultural water use efficiency is a primary focus of California's Water Conservation Act. The California Department of Water Resources (CDWR), after extensive stakeholder consultation, has published methods and indicators to help identify opportunities for improved efficiency of irrigation management at various spatial scales. Additional 2017 legislation directs water suppliers to quantify water use efficiency using the CDWR metrics to support preparation of agricultural water management plans. The IrriQuest calculator derives the Crop Consumptive Use Fraction (CCUF), a foundational metric relating seasonal crop evapotranspiration (ET) to total applied water. Satellite normalized difference vegetation index (NDVI) data are used to develop fractional canopy cover timeseries. Additional key inputs include daily reference ET, irrigation volume, irrigation method, precipitation, soil texture and crop type. IrriQuest estimates of seasonal crop ET show less than 10% mean absolute error compared to ground-based measurements of several annual and perennial crops monitored by sensor deployment in commercial fields. Two additional indicators build on CCUF. The Agronomic Water Use Fraction adds consideration of water applied for beneficial purposes such as pre-plant soil preparation, soil salinity management, and climate control. Total Water Use Fraction additionally accounts for water applied for environmental purposes such as maintenance of wetland and riparian habitat. A convenient on-line portal is under development for CCUF estimation and a standalone spreadsheet is available for computation of all three use fractions.

Calculator↗

The distribution of neutral hydrogen in the interstellar medium. 1: The data

We compile, from the existing literature, the largest sample to date (842 data points) of hydrogen column density measurements, N(H I), of the gas in the interstellar medium. We include only results obtained from absorption measurements toward individual stars (594 in our sample) in an effort to construct a three-dimensional picture of the interstellar gas. We derive hydrogen column densities toward a fraction of the stars in the sample from published column density measurements of metal ions. A three-dimensional physical model derived from this data set will be presented in a companion paper. The observed stars span distances from a few parsecs to a few thousand parsecs, and more than half of the sample serves to describe the local interstellar medium within a few hundred parsecs of the Sun. Hydrogen column densities range from 10(exp 17) to 10(exp 22)/sq cm. We describe here the various observational methods used to estimate the hydrogen column densities and present the table with the stellar and hydrogen column density data. The provided table is intended as a global reference work, not to introduce new results.

Fruscione, Antonella↗

Equilibrium and fractional crystallization of a primitive Shergottite composition

The shergottites are a subset of the Shergottites Nakhlites Chassignites (SNC) meteorites, which are believed to have come from Mars. Petrologic studies of these basaltic meteorites suggest that the most primitive shergottite composition is the groundmass of EETA79001 (a lithology). This inference is based on (1) its high Mg relative to the other shergottites; (2) it normative olivine; and (3) its lack of the cumulate crystals found in most other SNC meteorites. However, the relationship between this primitive composition and the compositions of the other, more evolved shergottites cannot be discovered through petrologic investigations alone. Therefore, liquidus phase relations were experimentally determined for a synthetic EETA79001A groundmass composition at 1 bar and QFM in order to find whether the bulk compositions of other shergottites could be derived by simple equilibrium or fractional crystallization of the EETA79001A groundmass composition.

Wasylenki, L. E.↗

Using Landsat, MODIS, and a Biophysical Model to Evaluate LST in Urban Centers

In this paper, we assessed and compared land surface temperature (LST) in urban centers using data from Landsat, MODIS, and the Simple Biosphere model (SiB2). We also evaluated the sensitivity of the models LST to different land cover types, fractions (percentages), and emissivities compared to reference points derived from Landsat thermal data. This was demonstrated in three climatologically- and morphologically-different cities of Atlanta, GA, New York, NY, and Washington, DC. Our results showed that in these cities SiB2 was sensitive to both the emissivity and the land cover type and fraction, but much more sensitive to the latter. The practical implications of these results are rather significant since they imply that the SiB2 model can be used to run different scenarios for evaluating urban heat island (UHI) mitigation strategies. This study also showed that using detailed emissivities per land cover type and fractions from Landsat-derived data caused a convergence of the model results towards the Landsat-derived LST for most of the studied cases. This study also showed that SiB2 LSTs are closer in magnitude to Landsat-derived LSTs than MODIS-derived LSTs. It is important, however, to emphasize that both Landsat and MODIS LSTs are not direct observations and, as such, do not represent a ground truth. More studies will be needed to compare these results to in situ LST data and provide further validation.

Al-Hamdan, Mohammad Z.↗

Utilization of Airborne Observations to Assess Model Parametrizations of Critical RH Profiles in the Arctic Ocean

Observational paucity is a reality in the Arctic Ocean. This is especially true for near-surface variables such as temperature, moisture, heat fluxes and BL clouds. As a result, modeling has become one of the major avenues for understanding current and future Arctic trends. Reanalyses are frequently used to force global ocean circulation and sea-ice models. But in northern high latitudes, model integrations and reanalyses are known to have large uncertainties in temperature and humidity profiles, and in boundary layer cloudiness. These are common sources of error in the surface radiative budget terms.An important way to diagnose these biases spatially and temporally is by using satellite remote sensing data. However, remotely-sensed observations also have large uncertainties, especially in near-surface temperature and relative humidity profiles.In situ observational studies are important in bridging our knowledge gap in regions such as the Arctic Ocean. Here, we utilize airborne and ship observations from the ARISE, ACME-IV, and ASCOS campaigns to construct critical relative humidity (RH) profiles over the Beaufort Sea. Such profiles are used as parameterization inputs in the NASA GOES global model to derive the total water condensate in a model grid-box, which determines the cloud fraction. Currently, the critical RH profiles are derived by global AIRS data, relaying mostly on mid-latitude regions, which are not necessarily relevant to the Arctic.We derive campaign-wide mean, standard deviation, and critical RH values, for grid size of 50x50 km and altitude bins between 50 to 400 m, covering both open-ocean and sea-ice covered regions. We compare profiles over open ocean and sea-ice, and look at correlations between the observed critical RH values and water condensate (by cloud number concentration) from observations versus the modeled ones. We then input our calculated values of minimal critical RH values into a set of GEOS single column model (SCM) simulations over the ARISE and ASCOS regions and compare the differences between the predicted values of cloud liquid water path (LWP), ice water path (IWP) and surface fluxes with the observed ones under the range of input parameterizations. Finally, we discuss the implications on surface radiative budget predictions in this region.

Segal-Rozenhaimer, Michal↗

Differential credibility assessment for statistical downscaling

Climate science is increasingly using (i) ensembles of climate projections from multiple models derived using different assumptions and/or scenarios and (ii) process-oriented diagnostics of model fidelity. Efforts to assign differential credibility to projections and/or models are also rapidly advancing. A framework to quantify and depict the credibility of statistically downscaled model output is presented and demonstrated. Here, the approach employs transfer functions in the form of robust and resilient generalized linear models applied to downscale daily minimum and maximum temperature anomalies at 10 locations using predictors drawn from ERA-Interim reanalysis and two global climate models (GCM; GFDL-ESM2M and MPI-ESM-LR). The downscaled time series are used to derive several impact relevant CLIMDEX temperature indices that are assigned credibility based on (1) the reproduction of relevant large-scale predictors by the GCMs (i.e. fraction of regression beta-weights derived from predictors that are well-reproduced) and (2) the degree of variance in the observations reproduced in the downscaled series following application of a new variance inflation technique. Credibility of the downscaled predictands varies across locations, between the two GCM and is generally higher for minimum temperature than maximum temperature. The differential credibility assessment framework demonstrated here is easy to use and flexible. It can be applied as is to inform decision makers regarding projection confidence, and/or extended to include other components of the transfer functions, and/or used to weight members of a statistically downscaled ensemble.

54 ENVIRONMENTAL SCIENCES↗

Isotopic discrimination of natural and anthropogenic perchlorate sources in groundwater in a semi-arid region of northeastern Oregon (USA)

Perchlorate (ClO 4 - ) has synthetic and natural sources. Synthetic ClO 4 - is released to the environment from its use as an oxidant in military and aerospace applications, and from its presence in a variety of common commercial products, such as safety flares, chlorate herbicides, and fireworks. Natural sources of ClO 4 - in the environment include imported nitrate fertilizers derived from salt deposits in the Atacama Desert of Chile and indigenous natural ClO 4 - that accumulates in unsaturated soils and groundwaters in other arid and semi-arid environments, largely from atmospheric deposition. The stable isotope ratios of chlorine ( 37 Cl/ 35 Cl) and oxygen ( 18 O/ 16 O, 17 O/ 16 O) and the isotopic abundance of radioactive 36 Cl in ClO 4 - can be used to discriminate these different sources. Perchlorate was previously detected at relatively high concentrations (3.8–34.7 μg/L) in groundwater from many wells in the Boardman-Umatilla area near the Columbia River in northeastern Oregon, which is a semi-arid, highly agricultural, heavily irrigated area that includes several past and current military installations. Eight representative groundwater wells were sampled throughout this region and isotopic characteristics of ClO 4 - collected from each well were measured along with other chemical and isotopic parameters including tritium and other groundwater age indicators. We report isotopic data indicate that indigenous natural ClO 4 - was present in groundwater from all sampled wells and was the predominant source in five of the wells. Synthetic ClO 4 - was present in the three remaining wells with natural ClO 4 - , and a minor fraction of Atacama-fertilizer-derived ClO4- was indicated in one of the wells. Data from this study expand the geographic area of the USA in which indigenous natural ClO 4 - has been detected to include the semi-arid northwest. This study also illustrates the role of irrigation recharge as a mechanism for producing relatively high concentrations of indigenous natural ClO 4 - in groundwater by flushing accumulated salts from the unsaturated zone.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pilot study and evaluation of a SMMR-derived sea ice data base

Data derived from the Nimbus 7 scanning multichannel microwave radiometer (SMMR) are discussed and the types of problems users have with satellite data are documented. The development of software for assessing the SMMR data is mentioned. Two case studies were conducted to verify the SMMR-derived sea ice concentrations and multi-year ice fractions. The results of a survey of potential users of SMMR data are presented, along with SMMR-derived sea ice concentration and multiyear ice fraction maps. The interaction of the Arctic atmosphere with the ice was studied using the Nimbus 7 SMMR. In addition, the characteristics of ice in the Arctic ocean were determined from SMMR data.

Barry, R. G.↗