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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
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NASA NTRS2021

Hydrogen Abundance and Distribution on (101955) Bennu

Asteroids were likely a major source of volatiles and water to early Earth. Quantifying the hydration of asteroids is necessary to constrain models of the formation and evolution of the Solar System and the origin of Life on Earth. The OSIRIS-REx (Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer) mission showed that near-Earth asteroid (101955) Bennu contains widespread, abundant hydrated phyllosilicates, indicated by a ubiquitous absorption at ~ 2.7 μm. The objective of this work is to quantify the hydration—that is, the hydrogen content—of phyllosilicates on Bennu's surface and investigate how this hydration varies spatially. We analyse spectral parameters (normalized optical path length, NOPL; effective single-scattering albedo, ESPAT; and Gaussian modeling) computed from the hydrated phyllosilicate absorption band of spatially resolved visible–near-infrared spectra acquired by OVIRS (the OSIRIS-REx Visible and InfraRed Spectrometer). We also computed the same spectral parameters using laboratory-measured spectra of meteorites including CMs, CIs, and the ungrouped C2 Tagish Lake. We estimate the mean hydrogen content of water and hydroxyl groups in hydrated phyllosilicates on Bennu's surface to be 0.71 ± 0.16 wt%. This value is consistent with the hydration range of some aqueously altered meteorites (CMs, C2 Tagish Lake), but not the most aqueously altered group (CIs). The sample collection site of the OSIRIS-REx mission has slightly higher hydrogen content than average. Spatial variations in hydrogen content on Bennu's surface are linked to geomorphology, and may have been partially inherited from its parent body.

A. Praet↗
NASA NTRS1992

Type IA Supernovae

Spectral calculations show that a model based on the thermonuclear explosion of a degenerate carbon/oxygen white dwarf provides excellent agreement with observations of Type Ia supernovae. Identification of suitable evolutionary progenitors remains a severe problem. General problems with estimation of supernova rates are outlined and the origin of Type Ia supernovae from double degenerate systems are discussed in the context of new rates of explosion per H band luminosity, the lack of observed candidates, and the likely presence of H in the vicinity of some SN Ia events. Re-examination of the problems of triggering Type Ia by accretion of hydrogen from a companion shows that there may be an avenue involving cataclysmic variables, especially if extreme hibernation occurs. Novae may channel accreting white dwarfs to a unique locus in accretion rate/mass space. Systems that undergo secular evolution to higher mass transfer rates could lead to just the conditions necessary for a Type Ia explosion. Tests involving fluorescence or absorption in a surrounding circumstellar medium and the detection of hydrogen stripped from a companion, which should appear at low velocity inside the white dwarf ejecta, are suggested. Possible observational confirmation of the former is described.

Wheeler, J. Craig↗
NASA NTRS1994

Discovery of a new white dwarf in a binary system (EUVE 0720-317) in the Extreme Ultraviolet Explorer survey and implications for the late stages of stellar evolution

A new precataclysmic binary is identified in the Extreme Ultraviolet Explorer (EUVE) all-sky survey. The bright source EUVE 0720-317 shows a hot hydrogen-rich white dwarf optical continuum with overlying narrow Balmer-line emission. Using high signal-to-noise ratio spectroscopy in the 4100-6700 A range, we identify a late-type companion and find a 1.3d periodic modulation in the emission-line velocities and strengths. This is the signature of Feige 24-type close binary systems. We determine the components' spectral types (DAO and dM0-2), orbital velocities (K(sub DAO) = 104 +/- 12 km/s, K(sub dM) = 96 +/- 7 km/s), and systemic velocity (gamma = 15 +/- 12 km/s). A first estimate of the white dwarf gravitational redshift, gamma(sub g) = 45 +/- 20 km/s, and theoretical mass-radius relationships imply R(sub DAO) = 0.010-0.016 solar radius and M(sub DAO) = 0.55-0.90 solar mass. The orbital inclination is therefore i greater than or equal to 52 deg, consistent with the large amplitude variations found in H-alpha equivalent widths that imply i greater than or equal to 42 deg. We show that the discovery of new close WD + MS binary systems in extreme ultraviolet (EUV) sky surveys has important implications for theory of common-envelope evolution, in particular for the predicted close binary birthrate and orbital and stellar parameters.

Vennes, Stephane↗
NASA NTRS2018

Solar Wind Implantation Into the Lunar Regolith: Monte Carlo Simulations of H Retention in a Surface With Defects and the H2 Exosphere

The solar wind implants protons into the top 20–30 nm of lunar regolith grains, and the implanted hydrogen will diffuse out of the regolith but also interact with oxygen in the regolith oxides. We apply a statistical approach to estimate the diffusion of hydrogen in the regolith hindered by forming temporary bonds with regolith oxygen atoms. A Monte Carlo simulation was used to track the temporal evolution of bound OH surface content and the H2 exosphere. The model results are consistent with the interpretation of the Chandrayaan-1 M3 observations of infrared absorption spectra by surface hydroxyls as discussed in Li and Milliken (2017). Themodel reproduced the latitudinal concentration of OH by using a Gaussian energy distribution of f(U(o) = 0.5eV, U(w) = 0.078 – 0.1 eV) to characterize the activation energy barrier to the diffusion of hydrogen in space weathered regolith. In addition, the model results of the exospheric content of H2 are consistent with observations by the Lyman Alpha Mapping Project on the Lunar Reconnaissance Orbiter. Therefore, we provide support for hydroxyl formation by chemically trapped solar wind protons.

O. J. Tucker↗
NASA NTRS1985

An evaluation of oxygen-hydrogen propulsion systems for the Space Station

Conceptual designs for O2/H2 chemical and resistojet propulsion systems for the space station was developed and evaluated. The evolution of propulsion requirements was considered as the space station configuration and its utilization as a space transportation node change over the first decade of operation. The characteristics of candidate O2/H2 auxiliary propulsion systems are determined, and opportunities for integration with the OTV tank farm and the space station life support, power and thermal control subsystems are investigated. OTV tank farm boiloff can provide a major portion of the growth station impulse requirements and CO2 from the life support system can be a significant propellant resource, provided it is not denied by closure of that subsystem. Waste heat from the thermal control system is sufficient for many propellant conditioning requirements. It is concluded that the optimum level of subsystem integration must be based on higher level space station studies.

Klemetson, R. W.↗
NASA NTRS1986

The evolution of ultrashort period binary systems

A discussion is presented concerning the results of detailed evolutionary calculations in which a very low mass and hydrogen-depleted semiattached binary star containing a collapsed object can reach an exceptionally short orbital period while sustaining a relatively high mass transfer rate. The observed properties of such systems can be understood under the assumption that they contain moderately to severely hydrogen-defficient secondary stars that are neither fully degenerate nor burning He. It is noted that for extremely hydrogen-depleted stars, the assumption of chemical homogeneity becomes untenable. Attention is given to the binary systems 4U 1626-67, 4U 1916-05, and G61-29.

Nelson, L. A.↗
NASA NTRS2018

Solar Wind Implantation Into the Lunar Regolith: Monte Carlo Simulations of H Retention in a Surface With Defects and the H2 Exosphere

The solar wind implants protons into the top 20–30 nm of lunar regolith grains, and the implanted hydrogen will diffuse out of the regolith but also interact with oxygen in the regolith oxides. We apply a statistical approach to estimate the diffusion of hydrogen in the regolith hindered by forming temporary bonds with regolith oxygen atoms. A Monte Carlo simulation was used to track the temporal evolution of bound OH surface content and the H2 exosphere. The model results are consistent with the interpretation of the Chandrayaan‐1 M3 observations of infrared absorption spectra by surface hydroxyls as discussed in Li and Milliken (2017, https://doi.org/10.1126/sciadv.1701471). The model reproduced the latitudinal concentration of OH by using a Gaussian energy distribution of f(U0 = 0.5 eV, UW = 0.078–0.1 eV) to characterize the activation energy barrier to the diffusion of hydrogen in space weathered regolith. In addition, the model results of the exospheric content of H2 are consistent with observations by the Lyman Alpha Mapping Project on the Lunar Reconnaissance Orbiter. Therefore, we provide support for hydroxyl formation by chemically trapped solar wind protons.

O J Tucker↗
NASA NTRS1989

Chemical evolution of primitive solar system bodies

Observations on organic molecules and compounds containing biogenic elements in the interstellar medium and in the primitive bodies of the solar system are reviewed. The discovery of phosphorus molecular species in dense interstellar clouds, the existence of organic ions in the dust and gas phase of the comas of Comet Halley, and the presence of presolar, deuterium-hydrogen ratios in the amino acids of carbonaceous chondrites are discussed. The relationships between comets, dark asteroids, and carbonaceous chondrites are examined. Also, consideration is given to the chemical evolution of Titan, the primitive earth, and early Mars.

Oro, J.↗
NASA NTRS2018

Solar Wind Implantation Into the Lunar Regolith: Monte Carlo Simulations of H Retention in a Surface With Defects and the H2 Exosphere

The solar wind implants protons into the top 20–30 nm of lunar regolith grains, and the implanted hydrogen will diffuse out of the regolith but also interact with oxygen in the regolith oxides. We apply a statistical approach to estimate the diffusion of hydrogen in the regolith hindered by forming temporary bonds with regolith oxygen atoms. A Monte Carlo simulation was used to track the temporal evolution of bound OH surface content and the H2 exosphere. The model results are consistent with the interpretation of the Chandrayaan‐1 M3 observations of infrared absorption spectra by surface hydroxyls as discussed in Li and Milliken (2017, https://doi.org/10.1126/sciadv.1701471). The model reproduced the latitudinal concentration of OH by using a Gaussian energy distribution of f(U(sub 0) = 0.5 eV, U(sub W) = 0.078–0.1 eV) to characterize the activation energy barrier to the diffusion of hydrogen in space weathered regolith. In addition, the model results of the exospheric content of H2 are consistent with observations by the Lyman Alpha Mapping Project on the Lunar Reconnaissance Orbiter. Therefore, we provide support for hydroxyl formation by chemically trapped solar wind protons.

Tucker, O. J.↗
NASA NTRS2000

Understanding Microbial Contributions to Planetary Atmosphere

Should our search of distant, extrasolar planetary atmospheres encounter evidence of life, that evidence will most likely be the gaseous products of microorganisms. Our biosphere was exclusively microbial for over 80 percent of its history and, even today, microbes strongly influence atmospheric composition. Life's greatest environmental impact arises from its capacity for harvesting energy and creating organic matter. Microorganisms catalyze the equilibration of C, S and transition metal species at temperatures where such reactions can be very slow in the absence of life. Sunlight has been harvested through photosynthesis to create enormous energy reservoirs that exist in the form of coexisting reservoirs of reduced, organic C and S stored in Earth's crust, and highly oxidized species (oxygen, sulfate and ferric iron) stored in the crust, oceans and atmosphere. Our civilization taps that storehouse of energy by burning fossil fuels. As astrobiologists, we identify the chemical consequences of distant biospheres as expressed in the atmospheres of their planets. Our approach must recognize that planets, biospheres and atmospheres evolve and change. For example, a tectonically more active early Earth hosted a thermophilic, non-photosynthetic biosphere and a mildly reducing, carbon dioxide-rich and oxygen-poor atmosphere. Microorganisms acquired energy by consuming hydrogen and sulfide and producing a broad array of reduced C and S gases, most notably, methane. Later, diverse types of bacterial photosynthesis developed that enhanced productivity but were incapable of splitting water to produce oxygen. Later, but still prior to 2.6 billion years ago, oxygenic photosynthesis developed. We can expect to encounter distant biospheres that represent various stages of evolution and that coexist with atmospheres ranging from mildly reducing to oxidizing compositions. Accordinaly, we must be prepared to interpret a broad range of atmospheric compositions, all containing signatures of life. Remarkably little is known about the composition of our own earlier atmosphere, particularly prior to the rise of oxygen levels some 2.0 to 2.2 billion years ago. Thus, field and laboratory observations and theoretical simulations should be conducted to examine the relationships between the structure and function of microbial ecosystems and their gaseous products. Ecosystems that are analogs of our ancient biosphere (e.g., based upon chemosynthesis or non-oxygenic photosynthesis, thermophilic and subsurface communities, etc.) should be included. Because key environmental parameters such as temperature and levels of hydrogen, carbon dioxide and oxygen varied during planetary evolution, their consequences for microbial ecosystems should be explored.

DesMarais, David J.↗
NASA NTRS2004

Evidence for a Wet, Reduced Martian Interior

Knowledge of the oxygen fugacity and hydrogen content of the source regions of martian meteorites is of paramount importance in constraining phase equilibria, crystallization sequences, and geodynamic processes of the martian interior, as well as models of the planet's evolution. To date, these interpretations have been hindered by the paucity in SNC meteorites of Fe-Ti oxides used in conventional oxybarometry, and by the presence of secondary alteration products that make it impossible to quantify primary hydrogen abundances in SNC minerals and melts based on whole rock samples. We present here the first transmission FTIR spectra of individual mineral grains from SNC meteorites, and interpret those results along with Mossbauer data on mineral separates from the same meteorites. Our goal is to quantify the amount of water and the oxygen fugacity present in the source regions for the rocks comprising the meteorites.

Dyar, M. D.↗
NASA NTRS1971

Some implications of a new value for the primordial solar deuterium-hydrogen ratio.

Some astrophysical implications of a primordial solar D/H ratio of 0.000015 are investigated. Perhaps the most interesting aspects of the D/H ratio concern galactic evolution and cosmology. It is shown that the initial galactic abundance of deuterium exceeds by at least a factor of 30 the abundance expected from known galactic production mechanisms. If a Friedmann cosmology is a correct description of the universe, it must be an open one unless some as yet unknown mechanism is invo ked to produce deuterium and He-3.

Black, D. C.↗
NASA NTRS1993

Cosmic evolution of extragalactic C 1, C 2, and CO luminosity

Carbon is the fourth most abundant element in the Galaxy with an abundance of approximately 4 x 10(exp -4) relative to hydrogen. Of all abundant metals it is the easiest to observe in the interstellar medium (ISM). Carbon can be found in four dominant forms: dust grains, C 2, C 1, and CO. The latter is the most abundant molecule (next to H2) in molecular clouds. All three gas-phase forms produce strong sub-mm wavelength emission lines and are the principal tracers of the warm and dense neutral phases of the ISM. We calculate the gas-phase abundances of neutral carbon (C 1), ionized carbon (C 2), and carbon monoxide (CO) as a function of cosmic time or redshift z in an idealized scenario of galactic evolution.

Bally, John↗
NASA NTRS1976

Molecular hydrogen in interstellar dark clouds

A simplified H2 formation mechanism is proposed in which small interstellar grains furnish the reaction sites. This mechanism results in a maximum value for the rate constant of about 2 by 10 to the -18th power per cu cm/sec for dark clouds at 10 K. Also, the nascent molecules are ejected in excited states, in qualitative agreement with Copernicus observations. A time-dependent treatment of the chemical evolution of a dark cloud with little or no ionizing radiation shows that the clouds require more than 10 million years to achieve chemical equilibrium. The observed residual atomic hydrogen in several dark clouds suggests that the clouds are 1 to 10 million years old. Other consequences of the temporal cloud model are in accord with astronomical observations.

Allen, M.↗
NASA NTRS1993

A two-dimensional model of the plasmasphere - Refilling time constants

A 2D model of the plasmasphere has been developed to study the temporal evolution of plasma density in the equatorial plane of the magnetosphere. This model includes the supply and loss of hydrogen ions due to ionosphere-magnetosphere coupling as well as the effects of E x B convection. A parametric model describing the required coupling fluxes has been developed which utilizes empirical models of the neutral atmosphere, the ionosphere and the saturated plasmasphere. The plasmaspheric model has been used to examine the time it takes for the plasmasphere to refill after it has been depleted by a magnetic storm. The time it takes for the plasmasphere to reach 90 percent of its equilibrium level ranges from 3 days at L = 3 during solar minimum to as high as 100 days at L = 5 during solar maximum. Refilling is also dependent on the month of the year, with refilling requiring a longer period of time at solar maximum during June than during December for L greater than 3.2.

Rasmussen, Craig E.↗
NASA NTRS1993

Centrifugally driven winds from protostellar disks. I - Wind model and thermal structure

The thermal structure of a wind that is centrifugally driven from the surface of a protostellar disk is studied. A generalized version of the Blandford and Payne self-similar wind model is introduced, and the temperature and ionization distributions in the outflow are investigated. For the evolution of atomic winds, the heat equation and the rate equations that describe the ionization and excitation state of hydrogen are solved self-consistently. Ambipolar diffusion is found to be a robust mechanism for heating the gas. In the more powerful outflows, molecular hydrogen is collisionally dissociated close to the disk surface, and hydrogen is mainly atomic within a few astronomical units from the central source. It is also demonstrated that these outflows have enough momentum to lift dust grains from the disk surface.

Safier, Pedro N.↗
NASA NTRSDate not supplied

Quantative Measurements of Trace Elements and Three-Dimensional Atomic Scale Characterisation of Presolar O-rich Oxides and Silicates: An Atom Probe Tomography Approach

Presolar grains are recordsof a single moment in stellar evolution which have survived nebula and parent body processingwithin our Solar System. These grains condensed within a range of stellar envi-ronments including asymptotic giant branch stars, red giant branch stars, nova, supernova (SN) and hydrogen burning electron capture supernova(ECSN)[1,2]. Iso-topic and chemical compositions can be used to unravel details about environmental conditions at the time of their condensation and physical and chemical processes occurring at the time. For example,nucleosynthesis, stellar evolution, physical properties of stellar atmos-pheres, mixing from inner core to outer envelope, galac-tic chemical evolution, interstellar medium and parent body processing.NanoSIMS enables detailed characterisation of iso-topic compositions and rapid in situidentification of O-rich presolar oxides and silicates using their character-istic 17O/16O and 18O/16O isotopic ratios.Spectroscopic techniques e.g., auger spectroscopyand transmission electron microscopy, have provided additional details on major and minor chemical signatures. However, due tospatial resolution limitations,interaction volumes and interferencesfrom surrounding grains for in situtech-niques, attaining quantative characterisation of trace el-ements,hasproved challenging[1,3]. As the most sensitive geochemical tracers of envi-ronmental changes, trace elements are essential to un-ravelling the geochemical record of their parent stellar environments and evolutionary pathways[4].We car-ried out correlated in situisotopic and chemical analyses of 13 presolar grains to better understand stellar evolu-tion. In this work, we achieved this using a custom ap-proach, coordinating NanoSIMS, Scanning Electron Microscopy Energy Dispersive X-Ray Spectroscopy (SEM-EDX)and Atom Probe Tomography(APT).Our objective was to develop an approach which could ena-ble precise targeting of presolar grains for atom probe tomography and successfully execute atomic scale anal-yses of presolar oxides and silicates, to achieve quantative analysis of their trace elements for the first time.We also aimed to test the capability for Atom Probe tomography to measure isotopic compositions and stoichiometries of presolar oxide and silicate grains.

N D Nevill↗
NASA NTRSDate not supplied

Validation of a Two-Phase CFD Model for Autogenous Pressurization and Expulsion

This paper presents a two-phase computational fluid dynamics (CFD) model for simulating autogenous pressurization and expulsion in a cryogenic liquid hydrogen storage tank, utilizing a volume-of-fluid (VOF) approach combined with the kinetics-based Schrage equation to accurately capture the phase boundary and interfacial heat, mass, and momentum transfer between liquid and vapor phases. The model is validated against experimental data from NASA's K-site tank facility, specifically experimental case 225, which involved pressurization and controlled expulsion of liquid hydrogen. Various turbulence models are evaluated to assess their influence on model accuracy. The CFD simulations successfully replicate key thermodynamic behaviors observed during the experiments, including pressure evolution, temperature profiles, and phase-change dynamics at the vapor-liquid interface. The predicted tank pressures, temperatures, and pressurant requirements agree with experimental data, with pressurant mass predictions within 16\% of observed values. This study highlights the importance of selecting appropriate turbulence models to accurately simulate complex flow and heat transfer phenomena during tank pressurization and expulsion. By enhancing the accuracy and reliability of CFD models for liquid hydrogen under cryogenic conditions, this research contributes to developing efficient cryogenic propellant management strategies for future space missions.

Computational Fluid Dynamics↗