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Physical and Chemical Study of Minerals and Rocks Containing Low-Z Compounds of Interest to Astrobiology and Origin of Life

Understanding the origins of Life requires a good understanding of the physics and chemistry of biogenic low-z elements H, C, N, O, P, S in terrestrial environments, on Mars, on extraterrestrial bodies such as meteorite parent bodies and comets, and in interstellar space. In this Proposal five Tasks form a coherent program aimed at elucidating various aspects of low-z element geo- and cosmochemistry with special reference to the origin of Life on Earth and to the search for life on Mars, extant or extinct. (i) Formation of organic molecules, in particular oxygenated H-C-0 molecules or precursors thereof of the composition H(x)C(y)O(z)(n-), inside the hard matrix of structurally dense magmatic minerals; (ii) Formation of organic molecules inside the soft matrix of amorphous and crystalline water ice; (iii) Preservation of organic molecules in cherts and other siliceous rocks formed in hot spring or submarine hydrothermal vent environments; (iv) The nature of the elusive Martian soil oxidant; and (v) Prototype development of an XRD instrument, using a new patented XRD camera concept that utilizes a Charge Coupled Device (CCD) as a camera and as a energy-dispersive analyzer.

Source record

The Propulsion Center at MSFC

The Propulsion Research Center at MSFC serves as a national resource for research of advanced, revolutionary propulsion technologies. Our mission is to move the nation's capabilities beyond the confines of conventional chemical propulsion into an era of aircraft like access to earth-orbit, rapid travel throughout the solar system, and exploration of interstellar space. Current efforts cover a wide range of exciting areas, including high-energy plasma thrusters, advanced fission and fusion engines, antimatter propulsion systems, beamed energy rockets and sails, and fundamental motive physics. Activities involve concept investigation, proof-of-concept demonstration, and breadboard validation of new propulsion systems. The Propulsion Research Center at MSFC provides an environment where NASA, national laboratories, universities, and industry researchers can pool their skills together to perform landmark propulsion achievements. We offer excellent educational opportunities to students and young researchers-fostering a wellspring of innovation that will revolutionize space transportation.

Gerrish, Harold

Formation of Planetary Systems

Stars are observed to be forming within cold regions of the galaxy called molecular clouds. A clump of gas and dust within a molecular cloud can collapse into a rotationally- supported disk orbiting the pre s sure -supported star. Such a disk has the same initial elemental composition as the growing star. At sufficient distances from the central star, it is cool enough for approx. 1 - 2% of this material to be in solid form, either remnant interstellar grains or condensates formed within the disk. During the infall stage, the disk is very active and probably highly turbulent. When the infall slows substantially or stops, the disk becomes more quiescent. The dust grows from micron-sized dust to kilometer-sized planetesimals by physical collisions, possibly aided by collective gravity. The dynamics of larger solid bodies within protoplanetary disks are better characterized. The primary perturbations on the orbits of kilometer-sized and larger planetesimals in protoplanetary disks are mutual gravitational interactions and physical collisions. These interactions lead to accretion (and in some cases erosion and fragmentation) of planetesimals. The most massive planets have the largest gravitationally-enhanced collision cross-sections, and accrete almost everything with which they collide. The size distribution of solid bodies becomes quite skewed, with a few large bodies growing much faster than the rest of the swarm, until they have accumulated most of the small bodies within their gravitational reach. Slower growth continues (at least for solid, earth-like planets) as the eccentricities of planetary embryos are pumped up by long-range mutual gravitational perturbations. As planetary masses increase, they become more efficient at stirring random velocities of neighboring bodies. If sufficiently massive and dense planets exist far enough from the star, they can eject material into interstellar space. In most models, giant planets begin their growth like terrestrial planets, but if they become massive enough before the protoplanetary disk dissipates, then they are able to accumulate substantial amounts of gas. Giant planet growth times predicted by current models are similar to estimates of the lifetime of the gaseous protoplanetary disk, so we don't know whether or not giant planets form in most protoplanetary disks. However, planets that become massive while a substantial amount of gas remains in the disk may migrate into the star as a consequence of their gravitational interactions with the disk.

Lissauer, Jack J.

Hierarchies of Models: Toward Understanding Planetary Nebulae

Stars like our sun (initial masses between 0.8 to 8 solar masses) end their lives as swollen red giants surrounded by cool extended atmospheres. The nuclear reactions in their cores create carbon, nitrogen and oxygen, which are transported by convection to the outer envelope of the stellar atmosphere. As the star finally collapses to become a white dwarf, this envelope is expelled from the star to form a planetary nebula (PN) rich in organic molecules. The physics, dynamics, and chemistry of these nebulae are poorly understood and have implications not only for our understanding of the stellar life cycle but also for organic astrochemistry and the creation of prebiotic molecules in interstellar space. We are working toward generating three-dimensional models of planetary nebulae (PNe), which include the size, orientation, shape, expansion rate and mass distribution of the nebula. Such a reconstruction of a PN is a challenging problem for several reasons. First, the data consist of images obtained over time from the Hubble Space Telescope (HST) and spectra obtained from Kitt Peak National Observatory (KPNO) and Cerro Tololo Inter-American Observatory (CTIO). These images are of course taken from a single viewpoint in space, which amounts to a very challenging tomographic reconstruction. Second, the fact that we have two disparate and orthogonal data types requires that we utilize a method that allows these data to be used together to obtain a solution. To address these first two challenges we employ Bayesian model estimation using a parameterized physical model that incorporates much prior information about the known physics of the PN. In our previous works we have found that the forward problem of the comprehensive model is extremely time consuming. To address this challenge, we explore the use of a set of hierarchical models, which allow us to estimate increasingly more detailed sets of model parameters. These hierarchical models of increasing complexity are akin to scientific theories of increasing sophistication, with each new model/theory being a refinement of a previous one by either incorporating additional prior information or by introducing a new set of parameters to model an entirely new phenomenon. We apply these models to both a simulated and a real ellipsoidal PN to initially estimate the position, angular size, and orientation of the nebula as a two-dimensional object and use these estimates to later examine its three-dimensional properties. The efficiency/accuracy tradeoffs of the techniques are studied to determine the advantages and disadvantages of employing a set of hierarchical models over a single comprehensive model.

Knuth, Kevin H.

Hierarchies of Models: Toward Understanding Planetary Nebulae

Stars like our sun (initial masses between 0.8 to 8 solar masses) end their lives as swollen red giants surrounded by cool extended atmospheres. The nuclear reactions in their cores create carbon, nitrogen and oxygen, which are transported by convection to the outer envelope of the stellar atmosphere. As the star finally collapses to become a white dwarf, this envelope is expelled from the star to form a planetary nebula (PN) rich in organic molecules. The physics, dynamics, and chemistry of these nebulae are poorly understood and have implications not only for our understanding of the stellar life cycle but also for organic astrochemistry and the creation of prebiotic molecules in interstellar space. We are working toward generating three-dimensional models of planetary nebulae (PNe), which include the size, orientation, shape, expansion rate and mass distribution of the nebula. Such a reconstruction of a PN is a challenging problem for several reasons. First, the data consist of images obtained over time from the Hubble Space Telescope (HST) and spectra obtained from Kitt Peak National Observatory (KPNO) and Cerro Tololo Inter-American Observatory (CTIO). These images are of course taken from a single viewpoint in space, which amounts to a very challenging tomographic reconstruction. Second, the fact that we have two disparate and orthogonal data types requires that we utilize a method that allows these data to be used together to obtain a solution. To address these first two challenges we employ Bayesian model estimation using a parameterized physical model that incorporates much prior information about the known physics of the PN. In our previous works we have found that the forward problem of the comprehensive model is extremely time consuming. To address this challenge, we explore the use of a set of hierarchical models, which allow us to estimate increasingly more detailed sets of model parameters. These hierarchical models of increasing complexity are akin to scientific theories of increasing sophistication, with each new model/theory being a refinement of a previous one by either incorporating additional prior information or by introducing a new set of parameters to model an entirely new phenomenon. We apply these models to both a simulated and a real ellipsoidal PN to initially estimate the position, angular size, and orientation of the nebula as a two-dimensional object and use these estimates to later examine its three-dimensional properties. The efficiency/accuracy tradeoffs of the techniques are studied to determine the advantages and disadvantages of employing a set of hierarchical models over a single comprehensive model.

Knuth, Kevin H.

New Thematic Solar System Exploration Products for Scientists and Educators

The next several years are an exciting time in the exploration of the solar system. NASA and its international partners have a veritable armada of spaceships heading out to the far reaches of the solar system. We'll send the first spacecraft beyond our solar system into interstellar space. We'll launch our first mission to Pluto and the Kuiper Belt and just our second to Mercury (the first in 30 years). We'll continue our intensive exploration of Mars and begin our detailed study of Saturn and its moons. We'll visit asteroids and comets and bring home pieces of the Sun and a comet. This is truly an unprecedented period of exploration and discovery! To facilitate access to information and to provide the thematic context for these missions NASA s Solar System Exploration Program and Solar System Exploration Education Forum have developed several products.

Lowes, Lesile

In Situ Location and Characterization of Carbon-bearing Phases in Carbonaceous Chondrites: Insights from Yamato 791198, a Weakly-altered CM2 Chondrite

Intense studies of carbonaceous chondrites have provided remarkable insights into the behavior of carbon during the earliest stages of our solar system. This research has demonstrated that carbonaceous meteorites contain a diverse array of organic compounds, whose origins are probably the result of multiple processes that occurred in different locations including interstellar space, the solar nebula and asteroidal parent bodies [1-3]. The most abundant organic carbon component in CI1 and CM2 carbonaceous chondrites is so-called macromolecular carbon, a high molecular weight material that has some affinities to terrestrial kerogen and constitutes approximately 60-70% of the organic material in these meteorites. Although recent studies e.g. [3] have radically improved our understanding of the structural and compositional characteristics of this material, a number of key questions remain to be addressed. In particular, our knowledge of where this macromolecular material is distributed at the fine-scale within carbonaceous chondrites is scant. [4] have shown that organic material is associated with phyllosilicate-rich matrix in CM chondrites, but the detailed mineralogical associations are not well-known. Over the past 2 years, we have begun to address this question by using energy filtered transmission electron microscopy (EFTEM) to locate carbon-bearing materials in situ, focusing specifically on the CM2s. To date we have reported data on the Murchison CM2 chondrite [5], a meteorite that has experienced a modest degree of aqueous alteration. To extend our observations to other CM2 chondrites, we have examined the occurrence of carbon-bearing phases in Yamato 791198. Our recent studies [5] have shown that Y-791198 is among the most weakly-altered CM chondrite currently known and hence is likely to preserve a quite primitive distribution of carbonaceous material. In this study, we present initial observations on the distribution of these materials in one fine-grained rim and compare them with our results from Murchison. Such information may provide important insights into the origins of the carbonaceous material and how it was distributed in nebular and perhaps presolar dust.

Brearley, Adrian J.

Photoevaporating Disks Around Young Stars

Ultraviolet radiation from the central star or from a nearby massive star heats the surfaces of protoplanetary disks and causes the outer, less gravitationally bound part of the disks, to photoevaporate into interstellar space. Photoevaporation is likely the most important dispersal mechanism for the outer regions of disks. We focus in this talk on disks around low-mass stars like the Sun rather than high-mass stars, which we have treated previously. Stars often form in clusters and the ultraviolet flux from the most luminous star in the cluster can have a dramatic effect on the disk orbiting a nearby low-mass star. We apply our theoretical models to the evaporating protoplanetary disks (or "proplyds") in the Trapezium cluster in Orion, to the formation of gas giant planets like Jupiter around Sun-like stars in the Galaxy, and to the formation of Kuiper belts around low mass stars. We discuss recent models of the effects of the radiation from the central low mass star including both the predicted infrared spectra from the heated disks as well as preliminary results on the photoevaporation rates.

Hollenbach, David

A priori predictions of the rotational constants for HC13N, HC15N, C5O

Ab initio molecular orbital theory is used to estimate the rotational constant for several carbon-chain molecules that are candidates for discovery in interstellar space. These estimated rotational constants can be used in laboratory or astronomical searches for the molecules. The rotational constant for HC13N is estimated to be 0.1073 +/- 0.0002 GHz and its dipole moment 5.4 D. The rotational constant for HC15N is estimated to be 0.0724 GHz, with a somewhat larger uncertainty. The rotational constant of C5O is estimated to be 1.360 +/- 2% GHz and its dipole moment 4.4. D.

NASA Discipline Exobiology

Measurement of Recoil Losses and Ranges for Spallation Products Produced in Proton Interactions with Al, Si, Mg at 200 and 500 MeV

Cosmic rays interact with extraterrestrial materials to produce a variety of spallation products. If these cosmogenic nuclides are produced within an inclusion in such material, then an important consideration is the loss of the product nuclei, which recoil out of the inclusion. Of course, at the same time, some atoms of the product nuclei under study may be knocked into the inclusion from the surrounding material, which is likely to have a different composition to that of the inclusion [1]. For example, Ne-21 would be produced in presolar grains, such as SiC, when irradiated in interstellar space. However, to calculate a presolar age, one needs to know how much 21Ne is retained in the grain. For small grains, the recoil losses might be large [2, 3] To study this effect under laboratory conditions, recoil measurements were made using protons with energies from 66 - 1600 MeV on Si, Al and Ba targets [3, 4, 5].

Sisterson, J. M.

Star Passages Through the Oort Cloud

Stars passing through the Oort cloud eject comets to interstellar space and initiate showers of comets into the planetary region.

Oort cloud comets cometary orbits shower comets

The Whole Heliosphere Interval: Campaign Summaries and Early Results

The Whole Heliosphere Interval (WHI) is an internationally coordinated observing and modeling effort to characterize the 3-dimensional interconnected solar-heliospheric-planetary system - a.k.a. the "heliophysical" system. The heart of the WHI campaign is the study of the interconnected 3-D heliophysical domain, from the interior of the Sun, to the Earth, outer planets, and into interstellar space. WHI observing campaigns began with the 3-0 solar structure from solar Carrington Rotation 2068, which ran from March 20 - April 16, 2008. Observations and models of the outer heliosphere and planetary impacts extended beyond those dates as necessary; for example, the solar wind transit time to outer planets can take months. WHI occurs during solar minimum, which optimizes our ability to characterize the 3-D heliosphere and trace the structure to the outer limits of the heliosphere. A summary of some of the key results from the WHI first workshop in August 2008 will be given.

Thompson, Barbara J.

The Rotation Temperature of Methanol in Comet 103P/Hartley 2

Considered to be relics from Solar System formation, comets may provide the vital information connecting Solar Nebula and its parent molecular cloud. Study of chemical and physical properties of comets is thus important for our better understanding of the formation of Solar System. In addition, observing organic molecules in comets may provide clues fundamental to our knowledge on the formation of prebiotically important organic molecules in interstellar space, hence, may shed light on the origin of life on the early Earth. Comet 103PIHartley 2 was fIrst discovered in 1986 and had gone through apparitions in 1991, 1997, and 2004 with an orbital period of about 6 years, before its latest return in 2010. 2010 was also a special year for Comet 103PIHartley 2 because of the NASA EPOXI comet-flyby mission.

Chuang, Yo-Ling

Voyagers 1 and 2 in a Shrunken and Squashed Heliosphere

We have extended our earlier calculations of the distance to the heliospheric termination shock (HTS), which covered the period from the launch of V1 and V2 in 1977 to 2005, to the period from 2006 to 2011. During this latter period, the solar wind speed, ram pressure, and magnetic field decreased to the lowest levels in recent history, related to the sunspot minimum in 2008-2009. The HTS distance has decreased correspondingly so that V1, which was crossed by the HTS at 94 AU in late 2004, would now, in early 2011, be expected to reach the HTS at a distance of approx 80 AU, when the HTS distance would be expected to be at its minimum. Similarly, V2, which was crossed by the HTS at 84 AU in mid-2007, would, in early 2011, reach the HTS at a distance of only 74 AU. These distances, in early 2011, are approx 15% less than those at which V1 and V2 initially reached the HTS. The distance to the heliopause (HP) is more uncertain, but recent calculations place its equilibrium distance at between 1.4 and 1.6 times the HTS distance. Allowing for an additional 1 year for the HP to reach its equilibrium minimum distance relative to the HTS would mean that, assuming this distance remains a constant fraction larger than the HTS distance, the HP distance would be at its minimum distance of (1.4-1.6) X 80 AU = 112-128 AU in the direction of V1 in early 2012. At this time, V1 will be at a distance of approx 120 AU so that there is a possibility that V1 could cross the HP and enter interstellar space at the time 2012.0 +/- 1 year. If the crossing does not happen during this time period, then it is unlikely that V1 will reach this defining boundary before about 2016 because of the expected outward motion of the HTS and the HP toward their more normal distances of 85-96 and approx 120-140 AU, coincident with the maximum of the new sunspot cycle.

Webber, W. R.

Carbon in the Universe

Over the past few decades, NASA missions have revealed that we live in a Universe that is not a hydrogen-dominated, physicist's paradise, but in a molecular Universe with complex molecules directly interwoven into its fabric. These missions have shown that molecules are an abundant and important component of astronomical objects at all stages of their evolution and that they play a key role in many processes that dominate the structure and evolution of galaxies. Closer to home in our galaxy, the Milky Way, they have revealed a unique and complex organic inventory of regions of star and planet formation that may well represent some of the prebiotic roots to life. Astrobiology emerges from the great interest in understanding astrochemical evolution from simple to complex molecules, especially those with biogenic potential and the roles they may play as primordial seeds in the origin of life on habitable worlds. The first part of this talk will highlight how infrared spectroscopic studies of interstellar space, combined with dedicated laboratory simulations, have revealed the widespread presence of complex organics across deep space. The remainder of the presentation will focus on the evolution of these materials and astrobiology.

Astrobiology

The Origin of the Local 1/4-KeV X-Ray Flux in Both Charge Exhange and a Hot Bubble

The solar neighbourhood is the closest and most easily studied sample of the Galactic interstellar medium, an understanding of which is essential for models of star formation and galaxy evolution. Observations of an unexpectedly intense diffuse flux of easily absorbed 1/4-kiloelectronvolt X-rays coupled with the discovery that interstellar space within about a hundred parsecs of the Sun is almost completely devoid of cool absorbing gas, led to a picture of a 'local cavity' filled with X-ray-emitting hot gas, dubbed the local hot bubble. This model was recently challenged by suggestions that the emission could instead be readily produced within the Solar System by heavy solar-wind ions exchanging electrons with neutral H and He in interplanetary space, potentially removing the major piece of evidence for the local existence of million-degree gas within the Galactic disk. Here we report observations showing that the total solar wind charge-exchange contribution is approximately 40 percent of the 1/4-keV flux in the Galactic plane. The fact that the measured flux is not dominated by charge exchange supports the notion of a million-degree hot bubble extending about a hundred parsecs from the Sun.

Charge exhange and a hot bubble

Conceptual Design of an Electric Sail Technology Demonstration Mission Spacecraft

There is great interest in examining the outer planets of our solar system and Heliopause region (edge of Solar System) and beyond regions of interstellar space by both the Planetary and Heliophysics communities. These needs are well docu-mented in the recent National Academy of Sciences Decadal Surveys. There is significant interest in developing revolutionary propulsion techniques that will enable such Heliopause scientific missions to be completed within 10 to15 years of the launch date. One such enabling propulsion technique commonly known as Electric Sail (E-Sail) propulsion employs positively charged bare wire tethers that extend radially outward from a rotating spacecraft spinning at a rate of one revolution per hour. Around the positively charged bare-wire tethers, a Debye Sheath is created once positive voltage is applied. This sheath stands off of the bare wire tether at a sheath diameter that is proportional to the voltage in the wire coupled with the flux density of solar wind ions within the solar system (or the location of spacecraft in the solar system. The protons that are expended from the sun (solar wind) at 400 to 800 km/sec are electrostatically repelled away from these positively charged Debye sheaths and propulsive thrust is produced via the resulting momentum transfer. The amount of thrust produced is directly proportional to the total wire length. The Marshall Space Flight Center (MSFC) Electric Sail team is currently funded via a two year Phase II NASA Innovative Advanced Concepts (NIAC) awarded in July 2015. The team's current activities are: 1) Developing a Particle in Cell (PIC) numeric engineering model from the experimental data collected at MSFC's Solar Wind Facility on the interaction between simulated solar wind interaction with a charged bare wire that can be applied to a variety of missions, 2) The development of the necessary tether deployers and tethers to enable successful de-ployment of multiple, multi km length bare tethers, 3) Controllability of the space-craft via a voltage bias to steer itself through the solar system to destinations of discovery. These activities once demonstrated analytically, will require a technology demonstration mission (TDM) around the year2020 to demonstrate that all systems work together seamlessly before a Heliophysics Electrostatic Rapid Transit System (HERTS) mission could be initiated. A notional TDM spacecraft that meets the requirements of such a mission will be showcased in this paper.

Wiegmann, Bruce M.

Spaceport Command and Control System Automated Verification Software Development

For as long as we have walked the Earth, humans have always been explorers. We have visited our nearest celestial body and sent Voyager 1 beyond our solar system1 out into interstellar space. Now it is finally time for us to step beyond our home and onto another planet. The Spaceport Command and Control System (SCCS) is being developed along with the Space Launch System (SLS) to take us on a journey further than ever attempted. Within SCCS are separate subsystems and system level software, each of which have to be tested and verified. Testing is a long and tedious process, so automating it will be much more efficient and also helps to remove the possibility of human error from mission operations. I was part of a team of interns and full-time engineers who automated tests for the requirements on SCCS, and with that was able to help verify that the software systems are performing as expected.

Automation