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Los Alamos National Laboratory Laboratory Directed Research and Development Program FY24 Annual Progress Report and Report on Completed Projects

The Laboratory Directed Research and Development (LDRD) Annual Report for fiscal year 2024 (FY24) is organized as follows: Overview: A description of the LDRD program at Los Alamos National Laboratory (LANL), including the program’s structure and objectives; a summary of the program’s value; and highlights of outstanding program accomplishments.

99 GENERAL AND MISCELLANEOUS↗

An Updated Land Cover Map and Descriptions of Vegetative Communities for Los Alamos National Laboratory and Surrounding Areas (Rev. 1)

A land cover map shows the location of different vegetative communities (for example, forests, woodlands, or grasslands) and other land cover types (for example, developed areas and water) across a landscape. Land cover maps can be used to develop information useful for managing the land: for example, estimating the amount of forest wildfire fuels, modelling the growth and movement of wildfires, identifying wildlife habitat, modelling the risk of flash flooding, documenting changes in vegetative communities over time, and evaluating the environmental impacts of proposed projects. Since vegetative communities and other land cover types change over time in response to environmental conditions and human activity, land cover maps must be periodically updated. Prior to our effort, the most recent land cover map for Los Alamos National Laboratory was published in 2003, based on satellite imagery acquired in 2001. Our map is based on satellite imagery from 2014. Between 2001 and 2014, the Los Alamos region experienced drought, bark beetle outbreaks, widespread tree mortality, and a severe wildfire. These disturbances caused substantial changes in local vegetative communities over a relatively short period of time.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of the Likelihood for Thermal Runaway for Nitrate Salt Containers in Storage at Los Alamos National Laboratory

In order to handle and process the existing Los Alamos National Laboratory (LANL) Nitrate Salt drums it is necessary to quantify the risk. One of the most obvious dangers is a repeat of the original violent reaction (2015), which would endanger nearby workers, not only with radioactive contamination, but also with large amounts of heat, dangerous corrosive gases and the physical dangers associated with a bursting drum. If there still existed a high probability of violent reaction, then these drums should only be accessed remotely. The objective of the work reported herein is to determine the likelihood of a similar violent event occurring.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

US-DOE and Republic of South Africa Uranium Benchmarking: Results From Los Alamos National Laboratory (Study Report)

This report details work performed at Los Alamos National Laboratory (LANL) in support of an interlaboratory uranium (U) benchmarking collaboration between LANL, Lawrence Livermore National Laboratory (LLNL), and South African Nuclear Energy Corporation (Necsa). The goal of this interlaboratory benchmarking exercise is to compare analytical methods and data obtained on uranium reference materials CUP-2 and New Brunswick Laboratory (NBL) certified reference material (CRM) 124-2. The LANL commitments for this project include performing microwave digestion of fresh CUP-2 and CRM 124-2 powders, measuring the U isotope composition of CUP-2 and CRM 124-2 by both single-collector and multi-collector inductively coupled plasma mass spectrometry (SC-ICP-MS and MC-ICP-MS, respectively), and determining trace-element abundances in CUP-2 and CRM 124-2 by inductively coupled plasma mass spectrometry (ICP-MS). This report details the methods employed by LANL in support of these objectives and presents the data obtained during this collaborative exercise.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Final Reports of the 2021 Los Alamos National Laboratory Computational Physics Student Summer Workshop

Since 2011, the Los Alamos National Laboratory Computational Physics Student Summer Workshop has been bringing together a highly talented and diverse group of students every summer. Students work in teams of two, alongside typically two mentors, on research projects reflecting a broad range of topics within computational physics. In addition, students attend a series of lectures on topics within computational physics, facility tours, and networking events. The program lasts ten weeks, with this year’s workshop running from June 7 to August 13. At the end of the summer, students give a final presentation, along with a written report. Those reports are what make up the remaining sections of this document. Admission to the workshop is by a competitive process, with the mentors forming the selection committee. One of the important accomplishments of the workshop has been to create a student pipeline from diverse schools that sometimes are not normally tapped by LANL recruiting. Many workshop students maintain a continuing relationship with LANL, returning as student interns, post-doctoral researchers, and staff members. Additionally, workshop alumni act as ambassadors for LANL. The result is a wider awareness both of LANL as a potential employer, and of the technical work that happens at LANL. This year, the workshop was once again in an off-site, virtual format. Students worked on LANL virtual desktop systems remotely, also accessing LANL HPC resources. In order to facilitate communication, student were given accounts on both Webex, a video teleconferencing platform, and Mattermost, an online team collaboration and chat platform, similar to Slack. Daily communication between students and mentors was primarily on Mattermost, with Webex conferencing as needed. The lectures were all done on Webex. Given the difficulty of the virtual format, and a concern that students might have video teleconferencing burn-out, all lectures were optional this year. In spite of this, the attendance was generally high. Lecturers were asked to try to move to a more high-level, ”What is it?,” format. Once again, the students did a tremendous job. Over the course of ten weeks, they did important research across a staggering array of disciplines. The following pages contain the final report for each team’s research efforts. Enjoy!

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Los Alamos National Laboratory Facility Review

This series of slides depicts the Los Alamos Neutron Science Center (LANSCE). The Center's 800-MeV linac produces H + and H - beams as well as beams of moderated (cold to 1 MeV) and unmoderated (0.1 to 600 MeV) neutrons. Experimental facilities and their capabilities and characteristics are outlined. Among these are LENZ, SPIDER, and DANCE.

43 PARTICLE ACCELERATORS↗

Potential Applications of Quantum Computing at Los Alamos National Laboratory, v0.3.0

Since the scientific revolution in the 16th and 17th centuries, the process of scientific discovery has followed an iterative feedback process of observation, hypothesis development and testing with physical experiments, which is widely referred to as the scientific method. This process remained largely unchanged until the middle of the 20th century, when the emergence of digital computers empowered scientist to build and inspect detailed simulations of physical phenomena. Over the last century, computational tools have transformed modern approaches to scientific discovery by enabling fast and affordable hypothesis testing before physical experiments are conducted, shown in Figure 1-1. Some notable examples include: global climate forecasts to understand how the environment may change over decades [130]; modeling the behavior of plasma to design fusion reactors [59]; and understanding the behavior of molecules in biological processes [161, 223].

36 MATERIALS SCIENCE↗

Methodology for Safety Conscious Work Environment Self-Assessment at Los Alamos National Laboratory

As part of a DOE complex-wide requirement, Los Alamos National Laboratory must conduct a self-assessment of safety conscious work environment (SCWE) by the end of fiscal year 2013 (FY2013). This report describes the methodology used to randomly select employees and managers for focus groups and individual interviews as part of this assessment. One of the first tasks is to identify the metrics that are used to measure the LANL safety conscious work environment. DOE’s guidance document 450.4-1C provides a listing of attributes that are present in institutions with excellent SCWE. Questions used in the self-assessment surveys and interviews are designed to elicit employee feedback with respect to these attributes.

99 GENERAL AND MISCELLANEOUS↗

Commercialization at Los Alamos

This report gives some commercialization examples that have been done at Los Alamos National Laboratory.

99 GENERAL AND MISCELLANEOUS↗

Inorganic Element Concentrations in Passerine Eggs Collected at Technical Areas 36, 39, and 16 at Los Alamos National Laboratory

In 2018, nonviable avian eggs were opportunistically collected at Los Alamos National Laboratory near open detonation sites at Technical Area (TA) 36 and TA-39 and near the TA-16 burning grounds and were evaluated for inorganic elements (mostly metals). A total of eight western bluebird Sialia mexicana ) and ash-throated flycatcher ( Myiarchus cinerascens ) egg samples were collected among the three locations of interest. Due to the small sample size, statistical comparisons could not be made. However, concentrations of inorganic elements observed in this study were compared with the upper-level bounds of background concentrations (mean + three standard deviations = 99% confidence interval; regional statistical reference level [RSRL]). Several inorganic elements were not detected in avian eggs and the majority of inorganic elements detected were below the RSRL. The few elements that exceeded the RSRL were below the lowest observable adverse effect level (LOAEL), when available. These data suggest that inorganic element concentrations in eggs observed here are not of ecological concern. As these data are preliminary, more data are needed to make a robust assessment, including additional background samples.

54 ENVIRONMENTAL SCIENCES↗

Proposal for a Fusion Prototype Neutron Source at the Los Alamos Neutron Science Center

This study evaluates a target station at the Los Alamos Neutron Science Center dedicated to the mission of irradiating structural materials in an environment that is nearly prototypic of the radiation environment experienced by the first wall of a magnetically-confined fusion reactor burning D-T fuel. Such a station could be located in the existing Area A experimental hall and be driven by an 800-MeV, 1-MW proton beam delivered by the LANSCE accelerator. A neutronics assessment of a target concept shows it satisfies all of the key parameter guidelines stated in the Summary Report on the Fusion Prototypic Neutron Source Workshop.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Start your career at Los Alamos National Laboratory in the Associate Laboratory Directorate for Weapons Production [Slides]

Los Alamos National Laboratory (LANL) is the place for early-career professionals to join our crucial mission in support of national security. In the Associate Laboratory Directorate for Weapons Production (ALDWP) you will find a diverse workplace with roles of all kinds and endless upward momentum for a long-lasting and ever-changing career!

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Global aspects of the Los Alamos general circulation model hydrologic cycle

The global hydrologic cycle in the Los Alamos general circulation model (GCM) is compared to available global observations. Global observations of the water vapor, water-vapor flux and water-vapor flux divergence are derived from the National Meteorological Center's final analysis for the period 1986-1989. The new precipitation data set of Legates and Willmott (1990) is used for the global precipitation observations. Global evaporation is derived as a residual of the precipitation and water-vapor flux divergence. There are a number of similarities as well as discrepancies between the GCM and observations. The large-scale nondivergent and divergent GCM circulations are remarkably similar to the observed circulations; the large-scale GCM precipitation and evaporation patterns are also qualitatively similar to observations. Discrepancies are mainly quantitative and small-scale in nature: the GCM atmosphere is relatively dry which results in a slightly greater evaporation and precipitation rate than is observed; the GCM South Pacific convergence zone is displaced too far to the northwest.

Roads, J. O.↗

Performance of the Los Alamos National Laboratory spallation-driven solid-deuterium ultra-cold neutron source

In this paper, we describe the performance of the Los Alamos spallation-driven solid-deuterium ultra-cold neutron (UCN) source. Measurements of the cold neutron flux, the very low energy neutron production rate, and the UCN rates and density at the exit from the biological shield are presented and compared to Monte Carlo predictions. The cold neutron rates compare well with predictions from the Monte Carlo code MCNPX and the UCN rates agree with our custom UCN Monte Carlo code. The source is shown to perform as modeled. The maximum delivered UCN density at the exit from the biological shield is 52(9) UCN/cc with a solid deuterium volume of {approx}1500 cm{sup 3}.

43 PARTICLE ACCELERATORS↗

Invasive Plant Species Management Plan for Los Alamos National Laboratory (Rev.3)

Native species are plants and animals that continually occupy a natural range without direct or indirect introduction and/or care by humans. They are adapted to the environmental conditions and processes of the ecosystem in which they reside. A species introduced into a novel ecosystem can either exploit that ecosystem and thrive or be unable to survive in that ecosystem (Hobbs et al. 2006). Alien or non-native species are species that are intentionally or accidentally introduced into a novel ecosystem and are capable of living and propagating within the physical parameters of that ecosystem. Invasive species is a species that is non-native (or alien) to the ecosystem under consideration and a noxious species are those whose introduction causes or is likely to cause economic or environmental harm. The term invasive species is applicable to plants and animals alike; however, this invasive species management plan currently focuses on invasive vegetation. Invasive plant species are usually capable of rapid colonization of disturbed ground, such as after a change in wildfire regime intensity and frequency (Reilly et al. 2020) or anthropogenic ground disturbance (Burke and Grime 1996; Hobbs and Huenneke 1992). Climate change facilitates the spread and establishment of many alien species and creates new opportunities for them to become invasive (Turbelin and Catford 2021). As climate change impacts increase in the coming decades, we may see in an increase in invasive species establishment. See a list of definitions of terms pertinent to this document in Appendix A: Definitions. Los Alamos National Laboratory (LANL) hosts populations of non-native and invasive species all typical of the northern New Mexico region (Martin 2004; NMDA 2020). By implementing an invasive species management plan, LANL will have readily accessible management strategies for invasive species that are found on-site. The benefits of managing invasive species include a decrease in wildland fire risks, an increase in soil productivity, an increase in (productive or beneficial) wildlife habitat, an increase in water quantity and quality, and the restoration of impacted areas (Burke and Grime 1996; Hobbs and Huenneke 1992; D’Antonio and Hobbie 2005; MacDougall et al. 2013; Reilly et al. 2020). The aforementioned benefits from invasive species management directly enable the LANL mission by ensuring compliance requirements are met and site-wide programs, such as the Vulnerability Assessment and Resilience Plan, are supported for a mutually beneficial outcome. An example for the LANL site specifically, controlling non-native annual plant species, for example, could reduce the costs associated with stabilizing soils during the stormwater pollution prevention compliance process. Roadway and utility right-of-way areas are another place where an integrated vegetation management strategy would promote low growing perennial plants in a way that is mutually beneficial to habitat and the institution through lowered maintenance costs. There is also an economic benefit to managing invasive species. In one nationwide study, invasive plants had an estimated impact cost of $190.45 billion (Fantel-Lepczyk et al. 2022). Investing in preventative measures and surveillance could help to offset future control and management costs of invasive species that have the potential to become established. The State of New Mexico has developed plant species lists and recommendations through the New Mexico Department of Agriculture’s Noxious Weeds Management Act, Article 7D (NM Statute § 76-7D-4 2021); however, effective invasive species management must rely on local knowledge of the site and region. Los Alamos County (LAC) has already compiled a target invasive plant species list and species-specific management objectives (Martin 2004). Therefore, the New Mexico Noxious Weed List and the LAC invasive plant species list, as well as management objectives from those documents, are integrated into LANL’s invasive plant species management plan.

54 ENVIRONMENTAL SCIENCES↗

NGEE Arctic Rainfall Simulator Validation Data from Los Alamos National Laboratory, New Mexico, Summer 2022

Experiments evaluating the uniformity and intensity of rainfall produced by the NGEE Arctic Rainfall Simulator (NARS) were conducted at Los Alamos National Laboratory, New Mexico, over summer 2022. Petri dishes were placed in a grid within the NARS plot. Simulated rainfall was collected in each petri dish and the intensity and uniformity of the simulator was subsequently calculated. This data package contains two .csv files, one that summarizes the rainfall intensity and uniformity for each experiment, the other that contains individual petri dish water volume and intensity for each plot location and experiment. The Python scripts to control NARS are also included. The NGEE Arctic Rainfall Simulator (NARS) is a variable intensity rainfall simulator (RFS) with a frame design based on the Humphry et al. (2002) RFS and a water delivery system based on the Walnut Gulch (Paige et al., 2004) RFS. The NARS uses an aluminum frame that is fully deconstructable for transportation to field locations and a water system that enables variable rain intensity. Rain intensity control and data collection are automated using a Raspberry Pi microcomputer. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a 15-year research effort (2012-2027) to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗