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Panel Session 36: Hot Topics in US Commercial Low-Level Waste Management

This panel focused on emerging issues in commercial LLW management in the US from the perspective of active members of the Low-Level Radioactive Waste Forum, Inc. State, compact, federal and industry officials shared their views on a variety of timely and significant topics related to low-level radioactive waste management, disposal and related issues. Session no. 36 Co-Chairs, Patricia Holahan and Daniel Shrum, introduced the panelists and provided a summary of the purpose of the session. This Panel Session focused on several current and emerging issues impacting the commercial Low-Level Radioactive Waste (LLRW) management in the US from the perspective of active members of the Low-Level Waste Forum, Inc., States, Compact, as well as Federal and nuclear industries. The panelists provided different perspectives on number of key issues such as: LLW disposal facility status and updates (e.g.; in terms of disposal capacity, plans, and waste acceptance conditions). The panelists also addressed waste disposal rates and potential impacts of ongoing regulatory developments by the NRC and the concerned States. Other timely topics pertaining to the revision of 10CFR Part 61, the Greater-than-Class C (GTCC) and Transuranic (TRU) waste, and Very Low-Level Waste (VLLW) disposal issues were also addressed at this Session. Panelists with presentations: Hot Topics in US Commercial LLW Management (Joe Weismann); Texas LLRW Compact (David Carlson); Texas Low-Level Radioactive Waste Disposal Compact Commission (John Salsman); Barnwell LLRW Disposal Facility (Benjamin Smith, Bill Carver)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Experiences with Mobile Units for Liquid RAW Management in Slovak and Czech Nuclear Power Plants - 20089

In Nuclear Power Plants VVER 440, Russian type of reactor there was designed auxiliary building where according to basic design all operational liquid radioactive waste (RAW) should be stored in large capacity tanks during the whole operational period. That's why there are in the auxiliary building several types of large storage tanks with different internal volume from 110 m{sup 3}, 460 m{sup 3} to 550 m{sup 3}. Storage tanks are usually situated in rooms with limited access and minimal handling space. Operational waste was here transported by the system of pipes from the reactor building. There is possibility to handle with the waste and set the pipeline in to the chosen storage tanks. Nobody takes care about the quality of waste in the storage tanks and waste waits for the period of decommissioning when it should be treated. The storage capacity was designed for the whole lifetime of nuclear power plant. Currently the life time of Nuclear Power Plant's (NPP) is extended and there is necessity to retrieve and treat the RAW in advance. Another reason why the stakeholder, who operates the NPPs, decides to treat the operational RAW during the operational period of NPP, is that there are still new requirements from safety point of view which need to have free available space for example because of potential accident. So treating the operational RAW during the life time of NPP is present issue. Because in basic design nobody cares how the RAW will be retrieved and treated in the future, there is usually no technology for that in existing NPP. Some of the NPPs build an additional building with suitable technologies for treatment or hire the company which offer mobile technology for retrieving the waste from the storage tanks. Wood Nuclear Slovakia PLC provides all activities within liquid RAW management projects by its own staff including management, design, construction and deployment of equipment, engineering support, as well as all RAW retrieval and solidification activities. We offer RAW management as a service without any significant changes in existing NPP's buildings and technology. It is always a technical challenge to conduct successful retrieval, pumping and treatment of RAW. The complex RAW retrieval system can be designed as tailored solution for any RAW storage according to known boundary conditions and specific needs. These systems are based on years of experience with RAW manipulation, processing and treatment and the whole RAW management knowledge by Wood Nuclear Slovakia LTD. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Energy Leaders: The Catalyst for Strategic Energy Management

This study investigates the crucial role energy leaders play in driving strategic energy management (SEM) and accelerating cost savings within a manufacturing organization and consequently, the industrial sector. Whereas energy efficiency can be seen as an innovative business practice with irrefutable cost benefits, its effective implementation requires strategic leadership and a structured approach. This research analyzes data collected from 120 participants representing 71 companies attending the Energy Bootcamp events organized by the U.S. Department of Energy’s (DOE) Better Plants program. The collected data focused on the state of SEM implementation, the presence and responsibilities of energy leaders, and the formation and function of energy teams. The findings reveal a significant gap between the perceived importance of SEM and its actual adoption, highlighting the need for strong leadership to drive behavioral changes by championing energy efficiency initiatives. Results indicate that effective energy leaders possess a diverse skill set, including the ability to secure top management buy-in, foster a culture of energy consciousness, and collaborate across departments. This study emphasizes the importance of empowering energy leaders with clearly defined roles and responsibilities as well as the authority to build and lead cross-functional energy teams. Furthermore, integrating energy management into existing organizational structures and leveraging readily available resources are identified as key factors for successful implementation. This research underscores how dedicated leadership and effective SEM practices help achieve industrial energy efficiency goals, providing practical insights for organizations seeking to improve performance and contribute to a resilient future.

energy leader↗

14 Steps to Creating Value in Cost and Schedule Resources for Nuclear Waste Management - 20188

While Waste Management budgets are shrinking, DOE required cost and schedule controls are becoming increasingly stringent. At the same time, there is a scarcity of adept, qualified, and competent projects controls staff who both understand nuclear waste management and are capable of addressing today's cost and schedule challenges. In response, we have developed a systematic approach to training and mentoring project controls staff. The approach is based on the observations and lessons learned on projects, both successful and unsuccessful, over the past 20 years. During that time, we evaluated staff development and used that experience to design a program that progresses the maturity, knowledge and experience of the individual. The program is based on the unique needs of cost and schedule specialists while incorporating the best leadership and managerial applications. The system is not limited to developing individual software skills, which is a primary focus of many project controls training programs. Instead, our system develops an individual's soft and hard skill sets. The system develops the user's skill, talent, attitude, and drive to do the best job possible. It focuses on all aspects of becoming a more productive technical team while accepting responsibility for individual growth. It also enhances the project controls team by setting up checks and balances that everyone is aware of and participates in. The system is based on 14 steps of increasing complexity in knowledge and application. The system clarifies roles, responsibilities and expectations. It helps eliminate uncertainty and reduces stress on staff and managers. It contains everyday routine actions and is simple to implement. It allows the development of a consistent rhythm to staff growth and development. Mastering the steps will allow the user to achieve excellence in cost and schedule control. The 14 steps are: 1 - Key Performance Objectives, 2 - Check Lists, 3 - Desktop Guides, 4 - System Description, 5 - Procedures, 6 - Software and On the Job Training (OTJ), 7 - Traceability Checks, 8 - Surveillances, 9 - 32 Criteria, 10 - The Contract, 11 - Customer/Government Guidance, 12 - Training and Mentoring Others, 13 - Master your weekly and daily schedules, 14 - Improving your interpersonal skills. Application and mastery of this system will produce better cost and schedule control results. Your project controls staff will write better reports, analyze data better, make better use of their time, and be more valuable to decision makers. If followed rigorously, our system will produce a great project controls team, which is invaluable to the success of each project. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Phosphorus and cover crop management practices affect phosphorus speciation in soils and eroded sediments

Abstract Agricultural runoff often contains P in dissolved and sediment‐bound forms, decreasing surface water quality. No‐till and cover cropping conservation practices have been recommended for reducing erosion and nutrient loss from cropping systems. The overall aims of this study were to characterize and evaluate the effects of fertilizer (placement and source) and cover crop management on P speciation in surface runoff sediments and source soil. In 2014, a field‐scale experiment was established in a no‐till, corn (Zea maysL.)–soybean (Glycine maxL.) cropping system with two cover crop treatments (with and without a winter crop; winter wheat [Triticum aestivumL.], rapeseed [Brassica napusL.], hairy vetch [Vicia villosaRoth], winter triticale [×Triticosecale Wittm.], and cereal rye [Secale cerealeL.]) and three P fertilizer management treatments (no P, fall broadcast diammonium phosphate, and spring subsurface injected ammonium polyphosphate). Phosphorus fractionation in the source soil collected in the fall of 2019 and sediment samples collected throughout 2020 were analyzed using a modified sequential P extraction method to evaluate the cumulative effects of imposing the treatment factors over 5 years. The direct P speciation was done using X‐ray absorption near edge structure spectroscopy. The indirect P speciation (fractionation) results showed that the management practices affected the exchangeable, organic matter‐associated, and Fe‐bound P fractions in sediments and the exchangeable and residual fractions in source soil. Direct P speciation results showed a depletion of Fe‐associated P in soil and sediment from cover crop treatment, suggesting that Fe‐associated P species were affected by cover crops. Changes in soil and runoff sediment P speciation would change the proportions and forms of soluble and particulate P in runoff sediments and may influence P bioavailability in aquatic ecosystems. Developing P fertilizer and cropping system management options with an understanding of soil P transformations helps maintain environmental sustainability.

Environmental Sciences & Ecology↗

Decision-making Framework to Support the End-of-Life Management of High-Activity Radioactive Sources

Sealed radioactive sources are used for an extremely wide range of purposes, including as radiation sources in various nuclear facilities, universities, hospitals, biomedical and industrial applications, as well as for geological prospecting and exploration. The proper management of these sealed radioactive sources once they have reached their end-of-life is still a global challenge. Very few field-tested Mobile Hot Cells (MHC) exist in the world to support the end-of-life management of disused high-activity radioactive sources. One of the critical challenges that a source recovery team encounters on each site is to find adequate space, and access to that space to complete the staging and recapture process with a MHC; this process is tedious, uncertain, and time-consuming. Therefore, it is essential to understand the planning and management of the MHC setup and takedown. Currently, there isn't an single capable planning tool that will provide an effective medium to plan, inform, educate, and communicate knowledge about the environment where the MHC will be deployed. We present a novel approach for the planning and management of the deployment of the MHC to several different sites that relies on technology. Furthermore, this planning tool will support collaboration, promote information sharing, and foster better decision making processes, resulting in a more efficient, and reliable setup and source recovery with the MHC.

61 RADIATION PROTECTION AND DOSIMETRY↗

Rice husk and charred husk amendments increase porewater and plant Si but water management determines grain As and Cd concentration

Abstract Purpose Rice is a staple crop worldwide and a silicon (Si) hyperaccumulator with Si levels reaching 5–10% of its mass; this can result in desilication and Si-deficiency if plant residues are not managed correctly. Rice is also uniquely subject to arsenic (As) and cadmium (Cd) contamination depending on soil conditions. Our goal is to quantify the effects of rice husk (a Si-rich milling byproduct) amendments and different water management strategies on rice uptake of Si, As, and Cd. Methods We employed 4 husk amendment treatments: Control (no husk), Husk (untreated husk), Biochar (husk pyrolyzed at 450 °C), and CharSil (husk combusted at > 1000 °C). Each of these amendments was studied under nonflooded, alternate wetting and drying (AWD), and flooded water management in a pot study. Porewater chemistry and mature plant elemental composition were measured. Results Husk and Biochar treatments, along with flooding, increased porewater and plant Si. Vegetative tissue As decreased with increasing porewater Si, but grain As and plant Cd were primarily controlled by water management. Grain As and Cd were inversely correlated and are simultaneously minimized in a redox potential (Eh) range of 225–275 mV in the studied soil. Ferrihydrite in root iron plaque decreased As translocation from porewater to grain, but amendments were not able to increase plaque ferrihydrite content. Conclusion We conclude moderate husk amendment rates (i.e., 4 years’ worth) with minimal pretreatment strongly increases rice Si content but may not be sufficient to decrease grain As in low Si and As soil.

36 MATERIALS SCIENCE↗

Reduced soil diazotroph diversity decreases nitrogen fixation rates, but depends on land management

Soil diazotrophs convert atmospheric nitrogen into plant-available ammonium through free-living nitrogen fixation (FLNF). This sustainable nitrogen source can reduce our dependence on synthetic fertilizer inputs in conventional agricultural systems. However, we know little about the effect of diazotroph diversity on FLNF, especially given that FLNF is intermediate within the broad-narrow functional spectrum. Here, we determined how management-mediated shifts in diazotroph diversity would impact their ecosystem function (FLNF) by quantifying diazotroph diversity across a long-term management gradient during and after the growing season. In addition to field observations, we leveraged the same management gradient to manipulate diversity in soil microcosms via chloroform fumigation exposure. In the field, diazotroph diversity was significantly higher after the growing season, and the biologically-based annual cropping system harbored the highest diazotroph diversity. However, perennial cropping systems maintained the highest FLNF despite lower diazotroph diversity, and both soil moisture and temperature were stronger predictors of FLNF. Based on these results, integrating diverse perennial crops into agricultural landscape could result in greater N from FLNF, particularly at the end of the growing season. When we reduced biodiversity in a manipulation experiment, the diversity-FLNF association was stronger than in the field experiment, suggesting that FLNF communities are not as functionally redundant as taxonomically ‘broad’ ecosystem functions. Here, the strength of diversity-FLNF correlation varied by previous land management. Diazotroph diversity better predicted FLNF in annual and forest soil microcosms, and microbial biomass carbon better predicted FLNF in perennial soil microcosms. Taken together, our results show that while diazotroph diversity influences FLNF, especially under extreme environmental disturbances, abiotic factors like soil moisture and temperature are stronger constraints on FLNF in the field.

60 APPLIED LIFE SCIENCES↗

Management opportunities for soil carbon sequestration following agricultural land abandonment

The widespread historical and ongoing abandonment of agricultural lands worldwide presents important opportunities for promoting climate change mitigation through carbon sequestration. The default management outcome of abandonment is natural regeneration through ecological succession. However, several different management strategies and new land uses for abandoned agricultural lands have been recommended by the scientific community in recent years. This paper reviews the foremost proposed strategies and compares their soil carbon sequestration potentials. Six major categories have been proposed globally. Each proposal has positive and negative outcomes depending on site-specific factors and management objectives. Accordingly, no single strategy is ideal in all scenarios and a combination of strategies addresses multiple rural development goals concurrently. A combination of passive and active management techniques is the most effective approach for maximizing soil carbon sequestration over large geographic scales, while other strategies can be designed to also promote low-carbon land use practices and fossil fuel substitution. The implications of each proposal highlighted here demonstrates the positive role that abandoned agricultural lands can serve in climate change mitigation efforts, supporting policymakers tasked with planning the future of regions undergoing abandonment.

54 ENVIRONMENTAL SCIENCES↗

Dirty dishes or dirty laundry? Comparing two methods for quantifying American consumers' preferences for load management in a smart home

One challenge of transitioning to renewable energy is that household electricity use and renewable generation are often misaligned. Smart home energy management systems hold promise for shifting usage to match generation, but these systems need to be designed with the occupants’ preferences in mind. The purpose of the present research is to compare two approaches for collecting and modeling consumers’ load management preferences, both of which are amenable to use in a home energy management system. Specifically, we examine the performance of Simple Multi-Attribute Rating Technique Exploiting Ranks (SMARTER) and Analytic Hierarchy Process (AHP) in quantifying consumers’ preferences regarding air temperature (air conditioning and heating), water heating, dishwashing, clothes washing and drying, monetary costs, environmental impacts, and comfort/convenience. Two studies are presented: Study 1 examines the SMARTER approach, and Study 2 focuses on the AHP approach. In both studies, online surveys (N SMARTER = 956 and N AHP = 1023) were conducted to elicit preferences from participants across the United States. The preferences modeled by both approaches were validated based on (a) their ability to predict participants’ choices in a Discrete Choice Experiment and (b) their convergence with previous research on load-shifting behavior. The validation procedure suggests that the SMARTER approach is superior in modeling consumers’ preferences for load management. Overall, this research lays the groundwork for designing a smart home interface capable of collecting occupants’ preferences and using those preferences to deliver improved occupant comfort, lower operating costs, reduced environmental impact, and more significant demand response than exists today.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Soil carbon change in intensive agriculture after 25 years of conservation management

Changes in soil organic carbon (SOC) and nitrogen (SON) are strongly affected by land management but few long-term comparative studies have surveyed changes throughout the whole soil profile. We quantified 25-year SOC and SON changes to 1 m in 10 replicate ecosystems at an Upper Midwest, USA site. We compared four annual cropping systems in maize (Zea mays)-soybean (Glycine max)-winter wheat (Triticum aestivum) rotations, each managed differently (Conventional, No-till, Reduced input, and Biologically based); in three managed perennial systems (hybrid Poplar (Populus × euramericana), Alfalfa (Medicago sativa), and Conifer (Pinus spp.); and in three successional systems (Early, Mid- and Late succession undergoing a gradual change in species composition and structure over time). Both Reduced input and Biologically based systems included winter cover crops. Neither SOC nor SON changed significantly in the Conventional or Late successional systems over 25 years. All other systems gained SOC and SON to different degrees. SOC accrual was fastest in the Early successional system (0.8 ± 0.1 Mg C ha –1 y –1 ) followed by Alfalfa and Conifer (avg. 0.7 ± 0.1 Mg C ha –1 y –1 ), Poplar, Reduced input, and Biologically based systems (avg. 0.4 ± 0.1 Mg C ha –1 y –1 ), and Mid-successional and No-till systems (0.3 and 0.2 Mg C ha –1 y –1 , respectively). Over the most recent 12 years, rates of SOC accrual slowed in all systems except Reduced input and Mid-successional. There was no evidence of SOC loss at depth in any system, including No-till. Rates of SON accrual ranged from 64.7 to 0.8 kg N ha –1 y –1 in the order Alfalfa ≥ Early successional > Reduced input and Biologically based ≥ Poplar > No-till and Conifer > Mid-successional systems. Pyrogenic C levels in the Conventional, Early, and Late successional systems were similar despite 17 years of annual burning in the Early successional system (~ 15 % of SOC to 50 cm, on average, and ~40 % of SOC from 50 to 100 cm). Results underscore the importance of cover crops, perennial crops, and no-till options for sequestering whole profile C in intensively managed croplands.

60 APPLIED LIFE SCIENCES↗

Holistic energy analysis method for thermal management architectures of data centers

Modern high-performance computing (HPC) data centers (DCs), particularly those supporting energy-intensive artificial intelligence (AI) workloads, face escalating thermal management challenges that degrade performance through thermal throttling and drive up cooling power consumption and operational costs. To address this challenge, many have developed a wide variety of thermal management solutions (single-phase, two-phase, direct, indirect, hybrid, and more) which attempt to cool HPC DCs effectively while attempting to minimize overall system power consumption. However, the analysis of these solutions and methods to effectively compare one with another is lacking. Overall power usage effectiveness (PUE) and total-power usage effectiveness (TUE) provide a metric to quantify power consumption but fail to identify components in the system which require further optimization. To address this, we propose a holistic analytical framework – the waterfall diagram (WFD) – which leverages a waterfall chart methodology, offering a comprehensive visualization of both the thermal management system loop and heat flow pathways from individual server components to the outdoor ambient. Use of the WFD enables graphical estimations of power efficiency and cooling performance across each component of a DC cooling system and complements Sankey-style energy flow visualizations by additionally resolving stage-wise temperature changes and incremental TUE contributions. The framework is used in conjunction with simulation-based approaches, to conduct a detailed pressure drop and flow distribution analysis aimed at identifying the optimal coolant distribution architecture for a single-phase direct-to-chip water-cooled DC, which serves as the baseline for subsequent WFD analysis. Among the evaluated architectures, the 3 U modular coolant distribution architecture is found to demonstrate the best performance, considering minimal pressure drop and uniform flow distribution. In addition, TUE is calculated for each cooling loop component based on its associated pressure drop and corresponding pumping power, which are integrated into the WFD. This correlation between TUE and local temperature offers immediate insight into the power efficiency and thermal performance contributions of individual components, facilitating further development and optimization. Examples of WFD applications are presented under varying thermal loads and ambient conditions, demonstrating reasonable cooling strategies. Notably, the 3 U modular architecture maintains a consistent chip case temperature of 85°C, achieving a TUE of 1.016 at ambient temperature of 47°C, and a TUE of 1.026 at ambient temperature of 52°C. The WFD methodology provides an efficient, holistic, and streamlined framework for DC thermal management architecture assessment and enables design optimization which is important for addressing the thermal-fluidic energy challenges of current and next-generation DCs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A generic scenario analysis of end-of-life plastic management: Chemical additives

Plastic growing demand and the increment in global plastics production have raised the number of spent plastics, out of which over 90% are either landfilled or incinerated. Both methods for handling spent plastics are susceptible to releasing toxic substances, damaging air, water, soil, organisms, and public health. Improvements to the existing infrastructure for plastics management are needed to limit chemical additive release and exposure resulting from the end-of-life (EoL) stage. This article analyzes the current plastic waste management infrastructure and identifies chemical additive releases through a material flow analysis. Additionally, we performed a facility-level generic scenario analysis of the current U.S. EoL stage of plastic additives to track and estimate their potential migration, releases, and occupational exposure. Potential scenarios were analyzed through sensitivity analysis to examine the merit of increasing recycling rates, using chemical recycling, and implementing additive extraction post-recycling. Our analyses identified that the current state of plastic EoL management possesses high mass flow intensity toward incineration and landfilling. Although maximizing the plastic recycling rate is a reasonably straightforward goal for enhancing material circularity, the conventional mechanical recycling method requires improvement because major chemical additive release and contamination routes act as obstacles to achieving high-quality plastics for future reuse and should be mitigated through chemical recycling and additive extraction. In conclusion, the potential hazards and risks identified in this research create an opportunity to design a safer closed-loop plastic recycling infrastructure to handle additives strategically and support sustainable materials management efforts to transform the US plastic economy from linear to circular.

54 ENVIRONMENTAL SCIENCES↗

Hydrologic applicability of satellite-based precipitation estimates for irrigation water management in the data-scarce region

Reliable precipitation estimates are crucial for planning and managing water resources, monitoring hydrologic extremes, and fulfilling irrigation water requirements. Accurate precipitation estimates are particularly challenging in complex mountain terrains, where monitoring gauges are often sparsely distributed due to their remote locations, and high installation and long-term operation costs. Recent advances in satellite-based precipitation estimates offer promising opportunities to improve our understanding of hydrologic processes and their applications for irrigation water management. Several datasets are available varying considerably in terms of their data sources, quality control methods, estimation procedure, and spatiotemporal resolutions. Choosing the most suitable dataset for a particular application is a complex task. In this study, we (1) evaluate the performance of six satellite-based precipitation estimates (SPEs): i) CHIRPS v2.0, ii) CMORPH v1.0, iii) ERA5, iv) IMERG v6, v) MSWEP v2.8, and vi) PERSIANN-CDR against the gauge precipitation using continuous statistical and categorical indices, (2) integrate SPEs with a calibrated semi-distributed hydrologic model to predict streamflow, and (3) demonstrate practical implications of improved streamflow prediction for irrigation water management in the central Himalayan region, Nepal. Our results illustrate that satellite-based precipitation estimates have competitive performance in capturing a wide range of rainfall characteristics, with demonstrated variability across river basins and time scales. Further, there are no significant discrepancies observed in satellite-based precipitation estimates for estimating irrigation water requirements for the three major crops (maize, wheat, and paddy) during the cropping period across the selected river basins, showing a greater promise for irrigation water management planning and decision making.

54 ENVIRONMENTAL SCIENCES↗

Waste management strategies for military-generated waste in the United States

Sustainable and energy efficient municipal solid waste (MSW) management is vital for the health and performance of deployed soldiers, as they play an important role in the safety and dignity of a country. As the United States targets net-zero carbon-free emission goals, research and development are essential to surpassing current practices for management of MSW at military installations, both at home and abroad. To achieve this, it is important to act upon and implement the policies and instructions set by government agencies such as the Environmental Protection Agency (EPA), the Department of Energy (DOE), and the Department of Defense (DoD). Understanding the composition of waste and disposal methods that are in use at military installations is a crucial step to success. Here, the authors show this through analyzed data from trusted sources, such as government agencies, reports, magazines, journals, and other publications on MSW management techniques. By defining these challenges, possible solutions can be better understood for improved management of MSW at military installations in the United States. Finally, an integrated approach with deployable units capable of waste-to-energy technology using waste reduction, diversion, and recycling strategies shows to be an effective pathway for MSW conversion into energy and other useful products.

09 BIOMASS FUELS↗

Microbial Proxies for Anoxic Microsites Vary with Management and Partially Explain Soil Carbon Concentration

Anoxic microsites are potentially important but unresolved contributors to soil organic carbon (C) storage. How anoxic microsites vary with soil management and the degree to which anoxic microsites contribute to soil C stabilization remain unknown. Sampling from four long-term agricultural experiments in the central United States, we examined how anoxic microsites varied with management (e.g., cultivation, tillage, and manure amendments) and whether anoxic microsites determine soil C concentration in surface (0–15 cm) soils. We used a novel approach to track anaerobe habitat space and, hence, anoxic microsites using DNA copies of anaerobic functional genes over a confined volume of soil. No-till practices inconsistently increased anoxic microsite extent compared to conventionally tilled soils, and within one site organic matter amendments increased anaerobe abundance in no-till soils. Across all long-term tillage trials, uncultivated soils had ~2–4 times more copies of anaerobic functional genes than their cropland counterparts. Finally, anaerobe abundance was positively correlated to soil C concentration. Even when accounting for other soil C protection mechanisms, anaerobe abundance, our proxy for anoxic microsites, explained 41% of the variance and 5% of the unique variance in soil C concentration in cropland soils, making anoxic microsites the strongest management-responsive predictor of soil C concentration. Our results suggest that careful management of anoxic microsites may be a promising strategy to increase soil C storage within agricultural soils.

54 ENVIRONMENTAL SCIENCES↗

The iodine-129 paradox in nuclear waste management strategies

Nuclear energy has an important role in the low-carbon energy transition, but the safety of spent nuclear fuel (SNF) management remains a public concern. Here, in this study, we investigate the interplay between waste management strategies and their environmental impacts with a particular focus on a highly mobile and persistent radionuclide, iodine-129 (I-129), which is the dominant risk contributor from SNF disposal and at existing groundwater contamination sites. The results show that the current recycling practice releases more than 90% of I-129 in SNF into the present-day biosphere using an isotropic dilution strategy, whereas the direct disposal of SNF in geological repositories is likely to delay and reduce the release by 8 orders of magnitude. In addition, our data synthesis of surface water concentrations near four nuclear facilities shows that the release-dilution strategy results in lower concentrations than regulatory standards, while insufficient waste isolation in the past has resulted in locally high concentrations within one site. Our analysis suggests that it is essential to consider effluents more explicitly as a part of the waste, that as society moves from dilution to isolation of waste, the potential risks of waste isolation to local regions should be carefully evaluated, and that excessive burdens of proof could hinder or discourage waste isolation. Comprehensive waste management strategies—considering not just volume but also mobility, isolation technologies and ultimate fates—are needed for persistent contaminants. This study offers valuable insights for optimizing the management of SNF and other persistent contaminants.

Wainwright, Haruko M. [Massachusetts Inst. of Tech↗

Determining spatially varying profit‐maximizing management practices for miscanthus and switchgrass production in the rainfed United States

Abstract Determining optimal management practices for the profitable production of perennial energy crops is critical for scaling up production beyond experimental levels. Although many experimental field studies have examined the effects of management practices on the performance of miscanthus and switchgrass, there are no recommendations for economically optimal nitrogen (N) application rates and how they should vary spatially and with the age of the energy crop as well as on optimal rotation age of the energy crop to maximize profits. We develop a modeling framework to determine economically optimal crop management decisions and simulate the variability under various scenarios for miscanthus and switchgrass production across 2287 counties in the rainfed United States. We find that profit‐maximizing N recommendations for these crops vary across maturity stages and regions and can increase the landowner's profits compared with a uniform N rate across ages and regions. We also find that the optimal rotation for these crops is shorter than the productive physical lifespan (15–20 and 10 years for miscanthus and switchgrass, respectively). Specifically, the N rate that maximizes the economic returns is negligible for miscanthus and 111 kg ha −1 for switchgrass production at age 2. The mean profit‐maximizing N rate increases with age for miscanthus, peaking at 151 kg ha −1 at age 11 before declining to 114 kg ha −1 at the optimal rotation age of 13 years while that for switchgrass is 150 kg ha −1 for middle‐aged stands and declines to 114 kg ha −1 at the optimal rotation of 8–9 years. We find that miscanthus is the most profitable energy crop in the northern region of the rainfed United States while switchgrass is most profitable in the south of the rainfed United States. Our findings are useful for improving assessments of the profitability of energy crops and guiding future management decisions by landowners.

54 ENVIRONMENTAL SCIENCES↗