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Results for “Mechanically Robust”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Characterization of Rare-earth Doped Thermal Barrier Coatings for Phosphor Thermometry

Thermal Barrier Coatings have been extensively used to protect and insulate the metallic components in turbine engines from extreme environments to achieve higher turbine inlet temperatures, resulting in an increase in combined engine cycle efficiency, lowering NOx emissions and fuel consumption. Additionally, as the major failure mechanisms determining lifetime are thermally activated during engine operation, uncertainty in temperature measurements affects lifetime prediction. Early detection of Thermal Barrier Coatings spallation symptoms, associated with local delamination induced temperature changes, can reduce forced engine outages. Further improvements are envisioned with the development of more reliable measurement techniques. For this purpose, Phosphor Thermometry has been considered a promising method for precision monitoring of turbine blade coatings that contain embedded phosphor dopants. In this work, a modified four-flux Kubelka-Munk model for luminescent rare-earth doped Thermal Barrier Coating configurations supported the design and the fabrication of viable sensing coatings for potential industrial implementation. Phosphor Thermometry instrumentation was developed with the objective of expanding capabilities of the technique, using a synchronized acquisition method on sensing coatings. Experiments on an innovative Erbium-Europium co-doped Yttria-Stabilized Zirconia coating have demonstrated the effectiveness of this advanced Phosphor Thermometry instrument with enhanced sensitivity and extended temperature range. Delamination progression monitoring was achieved for the first time using a Thermal Barrier Coating configuration subjected to indentation that includes a thin luminescent layer deposited on the surface and associating the multi-layer configuration with a predictive model that evaluates the advancement of the degradation of the coatings. To further ensure the integrity of the phosphor doped coatings, synchrotron X-ray diffraction was performed to characterize the specific residual strains and thermal expansion of the materials, determining mechanical robustness and compatibility with state-of-the-art Thermal Barrier Coatings. The outcomes of this work pave the way for in-situ temperature measurements on phosphor-doped turbine blade coatings with increased performance and accuracy.

Fouliard, Quentin↗
DOE OSTI2024

Thin, Highly Selective Polymer Membrane Separators for Advanced Liquid Alkaline Water Electrolysis

Our team will develop novel, dense, polymer electrolyte separators based on polybenzimidazole (PBI) derivatives that will enable tuning of water/KOH uptake in mechanically robust films for advanced liquid alkaline water electrolysis (LAWE). These material advances will enable thinner separators with increased selectivity (hydroxide conductivity/hydrogen permeability), thereby enabling higher operating currents, increased dynamic operating high-temperature stability, and catalyst-coated membranes (zero-gap design advantages) in direct alignment with stated lab call goals.

HYDROGEN↗
DOE OSTI2024

Cellulosic gels, films and composites including the gels, and methods of forming same

Disclosed are cellulose-based 5 flexible aerogels and xerogels containing bacterial cellulose nanorods, ribbons, fibers, and the like, wherein the gels have tunable optical, heat transfer, and stiffness properties. Further disclosed are highly transparent and flexible cellulose nanofiber-polysiloxane composite aerogels featuring enhanced mechanical robustness, tunable optical anisotropy, and low thermal conductivity.

Smalyukh, Ivan I.↗
DOE OSTI2025

High-Nickel Cathodes with Mechanical and Interfacial Robustness via Tailored Concentration Gradients for Stable Li-Ion Batteries

Here, we have developed a versatile mathematical framework integrated with an automated reactor system to design and reify highly customizable full concentration gradient (FCG) in high-nickel cathodes for advanced Li-ion batteries. This method provides precise and independent control of the average composition, slope, and curvature of FCGs, enabling the optimization of structural and mechanical properties of the cathode materials. We have showcased this method with Ni 0.8 Co 0.1 Mn 0.1 (OH) 2 precursors of controlled FCGs, which unlocked an optimized cathode with excellent cycling stability without crack formation after repeated cycles. This work opens up new possibilities for the design and manufacturing of advanced cathode materials, enabling safer, high-performance batteries.

25 ENERGY STORAGE↗
DOE OSTI2024

Mechanically and Thermally Robust Gel Electrolytes Built from A Charged Double Helical Polymer

Polymer electrolytes have received tremendous interest in the development of solid-state batteries, but often fall short in one or more key properties required for practical applications. Herein, a rigid gel polymer electrolyte prepared by immobilizing a liquid mixture of a lithium salt and poly(ethylene glycol) dimethyl ether with only 8 wt% poly(2,2′-disulfonyl-4,4′-benzidine terephthalamide) (PBDT) is reported. The high charge density and rigid double helical structure of PBDT lead to formation of a nanofibrillar structure that endows this electrolyte with stronger mechanical properties, wider temperature window, and higher battery rate capability compared to all other poly(ethylene oxide) (PEO)-based electrolytes. The ion transport mechanism in this rigid polymer electrolyte is systematically studied using multiple complementary techniques. Li/LiFePO 4 cells show excellent capacity retention over long-term cycling, with thermal cycling reversibility between ambient temperature and elevated temperatures, demonstrating compelling potential for solid-state batteries targeting fast charging at high temperatures and slower discharging at ambient temperature.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Mechanically and thermally robust microporous copolymer separators for lithium ion batteries

Next generation, multifunctional separators can enhance energy storage, power, and safety performance of lithium ion batteries but must be simple to fabricate and incorporate with existing roll-to-roll manufacturing. Here, this study presents a strategy to facilely prepare these separators using UV-initiated polymerization-induced phase separation (PIPS), wherein microporous polymer separators are fabricated directly from constituent monomers and ethylene carbonate (EC) porogen. This enables a wide compositional design space as co-monomers with specific chemical functionality can be readily incorporated into the PIPS precursor mixture. Herein, 1,4-butanediol diacrylate (BDDA) was copolymerized with poly(ethylene glycol) diacrylate (PEGDA) to increase the acrylate conversion in the photopolymerization and improve mechanical properties. By tuning the ratio of PEGDA and EC, separators with high porosity (41.3%) and effective ionic conductivity (2.09 mS cm –1 ) were prepared. Inclusion of PEGDA was essential to increasing the elastic modulus to > 345 MPa, which is required for cell assembly by roll-to-roll manufacturing. All separators prepared were shown to enable reversible cycling of lithium metal/LiNi 0.5 Mn 0.3 Co 0.2 O 2 half-cells for 100 cycles. Unlike conventional polyolefin separators, which were shown to melt at 160 °C and shrink by up to 29.8% at elevated temperatures, the PIPS separators possess exceptional, safety-enhancing thermomechanical properties, undergoing no phase transitions or thermal shrinkage.

25 ENERGY STORAGE↗
DOE OSTI2021

A critical review of 25 years of glomalin research: a better mechanical understanding and robust quantification techniques are required

Arbuscular mycorrhizal fungi (AMF) are important contributors to both plant and soil health. Twenty-five years ago, researchers discovered ‘glomalin’, a soil component potentially produced by AMF, which was unconventionally extracted from soil and bound by a monoclonal antibody raised against Rhizophagus irregularis spores. ‘Glomalin’ can resist boiling, strong acids and bases, and protease treatment. Researchers proposed that ‘glomalin’ is a 60 kDa heat shock protein produced by AMF, while others suggested that it is a mixture of soil organic materials that are not unique to AMF. Despite disagreements on the nature of ‘glomalin’, it has been consistently associated with a long list of plant and soil health benefits, including soil aggregation, soil carbon storage and enhancing growth under abiotic stress. The benefits attributed to ‘glomalin’ have caused much excitement in the plant and soil health community; however, the mechanism(s) for these benefits have yet to be established. This review provides insights into the current understanding of the identity of ‘glomalin’, ‘glomalin’ quantification, and the associated benefits of ‘glomalin’. We invite the community to think more critically about how glomalin-associated benefits are generated. We suggest a series of experiments to test hypotheses regarding the nature of ‘glomalin’ and associated health benefits.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Mechanically and Chemically Robust Lanmodulin-Functionalized Silk Sponges for Rare Earth Element Sequestration

The extraction of rare-earth elements (REEs) from low-grade sources like electronic waste (E-waste) could supplement current unsustainable mining practices. REEs are crucial for various industries, but supply struggles to meet growing demand. Herein, we present an environmentally friendly method for REE extraction using silk protein sponges functionalized with lanmodulin (LanM), a protein that selectively binds REEs. These sponges are relatively facile to fabricate and scale, while offering highly selective REE binding. The REEs can then be recovered via simple acid leaching, allowing sponge reuse for multiple cycles as well as specific desorption of different REEs by changing the pH of the desorption buffer. Finally, this method avoids harmful solvents used in traditional extraction and enables recycling of REEs from industrial and E-waste.

REEs↗
DOE OSTI2022

Mechanically-, Thermally, and Chemically-Robust High-Temperature Ceramic Composites

In an effort to lower the levelized cost of electricity generated by Concentrated Solar Power (CSP) plants, the heat-to-electricity conversion efficiency may be increased by operating such plants with higher turbine inlet temperatures using closed Brayton cycles with high-pressure, supercritical carbon dioxide (sCO 2 ) as the working fluid. For example, if the turbine inlet temperature is raised to ≥750°C, in combination with sCO2 closed Brayton cycles, the relative heat-to-electricity efficiency may be raised by more than 20% (compared to subcritical steam Rankine cycles operating with turbine inlet temperatures ≤550°C). The associated reduction in the cost of dispatchable electricity from such CSP plants (utilizing high-temperature thermal energy storage) would be an important breakthrough on the path towards direct competition with fossil-fuel-based plants. A key barrier to achieve such high-temperature efficient operation has been the limited thermomechanical performance of metal alloys used in compact, primary printed circuit- type heat exchangers (PCHEXs) for heat transfer to high-pressure sCO 2 . The maximum allowed stresses for the use of conventional stainless steels and nickel-based superalloys at high sCO 2 pressures (≥20 MPa) decline rapidly at temperatures ≥550°C. This project has been focused on demonstrating the desired high-temperature properties and attractive manufacturing characteristics of mechanically-, thermally-, and chemically-robust ceramic/metal composites (cermets), in order to allow for the use of such composites in primary PCHEXs for heat transfer to sCO 2 at ≥750°C and ≥20 MPa in CSP plants. Prior work with high-temperature, co-continuous carbide/refractory metal cermets, such as ZrC/W composites, has already demonstrated: i) the attractive combination of high-temperature properties exhibited by such materials (e.g., high values of stiffness, failure strength, and thermal conductivity at 800°C), and ii) cost-effective processes for manufacturing PCHEX plates comprised of such cermets with tailorable channel patterns. However, ZrC/W cermets were not found to be inherently corrosion resistant in sCO 2 at 750°C and 20 MPa. While the application of a Cu coating to ZrC/W surfaces, along with a modest addition (50 ppm) of CO to CO 2 , rendered such composites resistant to corrosion for 1000 h in such sCO 2 -based fluids at 750°C, such additional steps would increase the design complexity of such cermet-based components. An alternative approach (the focus of this project) is to develop mechanically-robust, cost- effective cermets that are inherently resistant to high-temperature oxidation in air and CO 2 . The overall goals of this project have been to demonstrate: i) the oxidation resistance of at least one cermet at 750°C in air and in CO 2 (i.e., with a projected annual corrosion ≤30 μm), ii) the mechanically robust nature of at least one cermet at 750°C (i.e., with an average failure strength ≥200 MPa), and iii) that the selected cermet can be manufactured via low-cost forming techniques.

14 SOLAR ENERGY↗
DOE OSTI2022

On large-scale dynamos with stable stratification and the application to stellar radiative zones

Our understanding of large-scale magnetic fields in stellar radiative zones remains fragmented and incomplete. Such magnetic fields, which must be produced by some form of dynamo mechanism, are thought to dominate angular-momentum transport, making them crucial to stellar evolution. A major difficulty is the effect of stable stratification, which generally suppresses dynamo action. We explore the effects of stable stratification on mean-field dynamo theory with a particular focus on a non-helical large-scale dynamo (LSD) mechanism known as the magnetic shear-current effect. We find that the mechanism is robust to increasing stable stratification as long as the original requirements for its operation are met: a source of shear and non-helical magnetic fluctuations (e.g. from a small-scale dynamo). Both are plausibly sourced in the presence of differential rotation. Our idealized direct numerical simulations, supported by mean-field theory, demonstrate the generation of near equipartition large-scale toroidal fields. Additionally, a scan over magnetic Reynolds number shows no change in the growth or saturation of the LSD, providing good numerical evidence of a dynamo mechanism resilient to catastrophic quenching, which has been an issue for helical dynamos. These properties – the absence of catastrophic quenching and robustness to stable stratification – make the mechanism a plausible candidate for generating in situ large-scale magnetic fields in stellar radiative zones.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Controllable branching of robust response patterns in nonlinear mechanical resonators

In lieu of continuous time active feedback control in complex systems, nonlinear dynamics offers a means to generate desired long-term responses using short-time control signals. This type of control has been proposed for use in resonators that exhibit a plethora of complex dynamic behaviors resulting from energy exchange between modes. However, the dynamic response and, ultimately, the ability to control the response of these systems remains poorly understood. Here, we show that a micromechanical resonator can generate diverse, robust dynamical responses that occur on a timescale five orders of magnitude larger than the external harmonic driving and these responses can be selected by inserting small pulses at specific branching points. We develop a theoretical model and experimentally show the ability to control these response patterns. Hence, these mechanical resonators may represent a simple physical platform for the development of springboard concepts for nonlinear, flexible, yet robust dynamics found in other areas of physics, chemistry, and biology.

42 ENGINEERING↗
DOE OSTI2024

Cybersecurity Certification Requirements for Distributed Energy Resources: A Survey of SunSpec Alliance Standards

This survey paper explores the cybersecurity certification requirements defined by the SunSpec Alliance for Distributed Energy Resource (DER) devices, focusing on aspects such as software updates, device communications, authentication mechanisms, device security, logging, and test procedures. The SunSpec cybersecurity standards mandate support for remote and automated software updates, secure communication protocols, stringent authentication practices, and robust logging mechanisms to ensure operational integrity. Furthermore, the paper discusses the implementation of the SAE J3072 standard using the IEEE 2030.5 protocol, emphasizing the secure interactions between electric vehicle supply equipment (EVSE) and plug-in electric vehicles (PEVs) for functionalities like vehicle-to-grid (V2G) capabilities. This research also examines the SunSpec Modbus standard, which enhances the interoperability among DER system components, facilitating compliance with grid interconnection standards. This paper also analyzes the existing SunSpec Device Information Models, which standardize data exchange formats for DER systems across communication interfaces. Finally, this paper concludes with a detailed discussion of the energy storage cybersecurity specification and the blockchain cybersecurity requirements as proposed by SunSpec Alliance.

Tsikteris, Sean (ORCID:0009000524202250)↗
DOE OSTI2026

Carbon source–driven metabolic and regulatory remodeling defines phenomic states in Lipomyces starkeyi

Lipomyces is a genus of oleaginous yeasts with potential for contributing to reliable biomanufacturing supply chains. However, progress in advanced strain designs and engineering efforts are still constrained by a lack of understanding of the underlying molecular drivers of Lipomyces phenotypes. To address this gap, we collected a suite of multi-omic data to dissect how carbon source availability reshapes the metabolic network, lipid allocation, and regulatory architecture of Lipomyces starkeyi. We observed that glucose promotes biosynthetic and proliferative processes supported by abundant energy and carbon intermediates, xylose enhances redox-balancing mechanisms centered on the pentose phosphate pathway, and glycerol activates respiratory metabolism, ß-oxidation, and the glyoxylate cycle. Lipid species distributions remained consistent in both nitrogen replete and depleted conditions across the carbon sources, indicating robust production mechanisms. Regulatory protein identification and network analysis revealed glycerol-driven respiratory growth favors regulatory programs integrating stress tolerance, redox balance, and lipid-associated metabolism, whereas xylose growth activates compensatory transcriptional responses aimed at maintaining mitochondrial function. Nitrogen limitation modulates the strength of these responses but does not fundamentally alter their direction, reinforcing carbon source as the dominant driver of regulatory architecture. Taken together, this data enhances the understanding of Lipomyces molecular rearrangements and provides a foundation for further development of predictive phenotypic tools in this genus.

Biotechnology↗
DOE OSTI2024

How Does Escherichia coli Allocate Proteome?

Microorganisms are shown to actively partition their intracellular resources, such as pro- teins, for growth optimization. Recent experiments have begun to reveal molecular com- ponents unpinning the partition; however, it remains unclear quantitatively how individual parts orchestrate to yield precise resource allocation that is both robust and dynamic. Here we developed a coarse-grained mathematical framework that centers on guanosine pentaphosphate (ppGpp)-mediated regulation, and used it to systematically uncover the design principles of proteome allocation in Escherichia coli. Our results showed that cellular ability of resource partition lies in an ultrasensitive, negative feedback control- ling topology with the ultrasensitivity arising from zero-order amino acid kinetics and the negative feedback from ppGpp-controlled ribosome synthesis. In addition, together with the time-scale separation between slow ribosome kinetics and fast turnovers of ppGpp and amino acids, the network topology confers the organism an optimization mechanism which mimics sliding mode control, a nonlinear optimization strategy that is widely used in man-made systems. We further showed that such a controlling mechanism is robust against parameter variations and molecular fluctuations, and is also efficient for biomass production over time. Furthermore, this work elucidates the fundamental controlling mechanism of E. coli proteome allocation, thereby providing insights into quantitative microbial physiology as well as the design of synthetic gene networks.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

A Deep Learning-Aided Workflow for Decoding the Stress Regime of Southern Nevada

The Rock Valley fault zone in southern Nevada has a notable history of seismic activity and is the site of a future direct comparison experiment of explosion and earthquake sources. This study aims to gain insight into regional tectonic processes by leveraging recent advances in seismic monitoring capabilities to elucidate the local stress regime. A crucial step in this investigation is the accurate determination of P-wave first-motion polarities, which play a vital role in resolving earthquake focal mechanisms of small earthquakes. Here, we deploy a deep learning-based method for automatic determination of first-motion polarities to vastly expand the polarity dataset beyond what has been reviewed by human analysts. By the integrating P-wave polarities with new measurements of S/P amplitude ratios, we obtain robust focal mechanism estimates for 1306 earthquakes with a local magnitude of 1 and above occurring between 2010 and 2023 in southern Nevada. We then use the focal mechanism catalog to examine the regional stress orientation, confirming an overall trans-tensional stress regime with smaller scale complexities illuminated by individual earthquake sequences. These findings demonstrate how detailed analyses of small earthquakes can provide fundamental information for understanding earthquake processes in the region and inform future experiments at the Nevada National Security Site.

58 GEOSCIENCES↗
DOE OSTI2020

Magnetic field generation in a laser-irradiated thin collisionless plasma target by return current electrons carrying orbital angular momentum

Abstract Magnetized high energy density physics offers new opportunities for observing magnetic field-related physics for the first time in the laser–plasma context. We focus on one such phenomenon, which is the ability of a laser-irradiated magnetized plasma to amplify a seed magnetic field. We performed a series of fully kinetic 3D simulations of magnetic field amplification by a picosecond-scale relativistic laser pulse of intensity 4.2 × 10 18 W cm −2 incident on a thin overdense target. We observe axial magnetic field amplification from an initial 0.1 kT seed to 1.5 kT over a volume of several cubic microns, persisting hundreds of femtoseconds longer than the laser pulse duration. The magnetic field amplification is driven by electrons in the return current gaining favorable orbital angular momentum from the seed magnetic field. This mechanism is robust to laser polarization and delivers order-of-magnitude amplification over a range of simulation parameters.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗