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At least 235 records · Page 13

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NASA NTRS1978

Identification of the nu-2 vibration-rotation band of ammonia in ground level solar spectra

Comparison of infrared solar spectra in the 750 to 950 kayser region obtained during sunrise and sunset shows that a number of features due to the nu-2 NH3 band are present on the sunset spectra but are indicated by only a trace on the sunrise spectra. The sunset path shows approximately 0.007 atm-cm NH3, and the reason for the discrepancy between sunrise and sunset spectra is not known. The ground-based measurements at Denver were obtained with a 0.06 kayser resolution.

Murcray, D. G.↗

NASA NTRS1978

Jupiter's atmosphere - Observations and interpretation of the microwave spectrum near 1.25-cm wavelength

Measurements of Jupiter's disk-temperature spectrum in the 20- to 24-GHz (1.5 cm less than lambda less than 1.25 cm) region are reported. These data are combined with previously published data to produce a uniformly calibrated thermal spectrum of Jupiter in the wavelength interval 0.85 to 2.1 cm. Model studies are carried out to determine optimum pressure-temperature profiles for an assumed radiative-convective temperature structure. It is found that the temperature at the 1-bar total effective pressure level is between 140 and 165 K, with a most probable value of 153 K, provided that NH3 is uniformly saturated in the clouds on a global scale. We show that the temperature profile for the microwave model is approximately 20 K cooler than the profiles derived from infrared data. An explanation of this discrepancy is discussed in terms of a model which invokes different NH3 distributions in the belts and zones.

Klein, M. J.↗

NASA NTRS1978

Saturn's atmosphere: Results of recent investigations

Saturn apparently has a high clear layer of H2 under which lies a comparable layer rich in dusty material. Beneath this is a thicker layer consisting mostly of H2 mixed with haze particles. An NH3 cloud deck probably lies below this layer. Evidence for seasonal variations is presented in the form of changes in the NH3, CH4 and H2 absorptions. Finally, the latest mixing ratios for the gaseous constituents are summarized.

Trafton, L.↗

NASA NTRS1979

High-resolution spectra of Jupiter in the 744-980 inverse centimeter spectral range

Spectra of the central 5 in region of Jupiter in the 744 to 980 kayser spectral range are presented at 0.05 and 0.28 kayser resolution. The gases (N-14)H3, (N-15)H3, and PH3 are observed in absorption, and C2H2 and C2H6 observed in emission. A synthetic spectrum which included the opacity from the H2, (N-14)H3, (N-15)H3, and PH3 is compared with observations. It is concluded that: (1) the (N-14)H3 line profiles are best fitted with a NH3 density in the troposphere which is 0.5 times the saturated vapor pressure density and an opaque cloud at the 0.56 bar pressure level, (2) the best fit (N-15)H3/(N-14)H3 ratio is 0.006, (3) the PH3/H2 abundance ratios of NH3 and PH3 must be highly subsaturated above the tropopause or the temperature inversion is cooler than model predictions.

Tokunaga, A. T.↗

NASA NTRS1979

Heterogeneous atmospheric reactions - Sulfuric acid aerosols as tropospheric sinks

The reaction probabilities of various atmospheric species incident on a bulk sulfuric acid surface are measured in order to determine the role of sulfuric acid aerosols as pollutant sinks. Reaction products and unreacted starting materials leaving a Knudsen cell flow reactor after collision at 300 K with a H2SO4 surface or a soot surface were detected by mass spectrometry. Significant collision reaction probabilities are observed on a H2SO4 surface for H2O2, HNO3, HO2NO2, ClONO2, N2O5, H2O and NH3, and on soot for NH3. Estimates of the contribution of heterogeneous reactions to pollutant removal under atmospheric conditions indicate that while aerosol removal in the stratosphere is insignificant (loss rate constants approximately 10 to the -10th/sec), heterogeneous reactions may be the dominant loss process for several tropospheric species (loss rate constant approximately 10 to the -5th/sec, comparable to photolysis rate constants).

Baldwin, A. C.↗

NASA NTRS1979

Gaseous NH4Cl revisited - A computational investigation of the potential surface and properties

An investigation of the potential surface and properties of the ground state of gaseous NH4Cl is presented. The calculations, which utilize a good basis set and include investigation of the valence correlation effects, result in a description of gaseous NH4Cl as a weakly bound complex with NH3 and HCl structures essentially equivalent to those of the isolated fragments. The charge distributions within the fragments are modifed in the complex, however, and there is a small amount of charge transfer. The results are in reasonable agreement with estimate of D sub 0, super 0 from high temperature mass spectroscopic investigations and vibrational frequencies from matrix experiments. The equilibrium constant for the reversible reaction NH4Cl yields NH3 + HCl indicates that the homogeneous formation of NH4Cl does not represent a significant chemical sink for HCl in the upper atmosphere

Raffenetti, R. C.↗

NASA NTRS1980

A model for hypokinesia: Effects on muscle atrophy in the rat

Hypokinesia in the hindlimbs of rats was induced by suspension; a newly developed harness system was used. The animal was able to use its forelimbs to maneuver, within a 140 deg arc, to obtain food and water and to permit limited grooming of the forequarters. The hindlimbs were nonload bearing for 7 days; following a 7-day period of hypodynamia, selected animals were placed in metabolic cages for 7 days to study recovery from hypokinesia. During the 7-day period of hypokinesia there was evidence of muscle atrophy. Gastrocnemius weight decreased, renal papillary urea content increased, and daily urinary losses of NH3 and 3-methylhistidine increased. During the 7-day recovery period muscle mass and excretion rate of urea, NH3 and 3-methylhistidine returned to control levels. Calcium balance was positive throughout the 7-day period of hypokinesia. Hypertrophy of the adrenals suggested the occurrence of some level of stress despite the apparent behavioral adjustment to the suspension harness. It was concluded that significant muscle atrophy and parallel changes in nitrogen metabolism occur in suspended rats and these changes are readily reversible.

Musacchia, X. J.↗

NASA NTRS1980

Ammonia in the atmospheres of Saturn and Jupiter

A profile and equivalent width for the 6451.1-A feature of the 6450-A band of ammonia at the equator and south pole of Saturn have been measured. Estimates for the NH3 abundance at the center of the disk which vary from 0.4 to 5 m-am, depending upon the atmospheric model used, lead to uncertainties in the NH3/H2 ratio which are greater than a factor of 10. Half-widths for theoretical line profiles computed from models in which the NH3 absorption occurs at a pressure level of 1.0 atm agree with the observed profiles. NH3/H2 ratios have been obtained which range from 0.00001 to 0.00002 for Jupiter.

Smith, W. H.↗

NASA NTRS1981

Response of selected microorganisms to experimental planetary environments

Anaerobic and aerobic sporeformers and non-sporeformers were cultivated anaerobically in nutrient media under various pressures (up to 1800 psi) of pure H2, CH4, NH3, and H2S. Viability assays were performed periodically to determine growth, survival, or spore survival. Hydrogen up to 1800 psi demonstrated little or no suppression of growth with the possible exception of Bacillus coagulans at 1800 psi. The obligate anaerobes grew very well. Under CH4 the obligate anaerobes again exhibited the most prolific growth, whereas the facultative anaerobes grew well except under higher pressures. Ammonia at low pressure was extremely toxic to all test organisms. At 100 psi all populations were killed within 24 hours except Staphylococcus aureus which survived for 72 hours and the Bacillus spp. which produced a surviving population of approximately 10,000 spores/ml. All populations in H2S were killed within 24 to 48 hours except Proteus mirabilis which decreased to 100 cells/ml and the Bacillus spp. Spore survival studies of two months duration demonstrated that B. coagulans and B. pumilus survived under all experimental conditions. Clostridium novyi type B and C. sporogenes were killed rapidly in NH3 and H2S and demonstrated no sporulation.

Foster, T. L.↗

NASA NTRS1980

The middle-infrared spectrum of Saturn - Evidence for phosphine and upper limits to other trace atmospheric constituents

Observations of Saturn at high spectral resolution in the middle-IR spectral region (2.5-5.6 microns) were obtained using a Fourier spectrometer at ground-based and airborne observatories. These spectra establish that PH3 exists on Saturn with an abundance at least equal to the solar P/H value, and probably enhanced by about a factor of 2. No evidence is found for gaseous or solid NH3 on Saturn throughout this spectral region, and upper limits to several other molecules (H2O, HCN, SiH4, and GeH4) are determined. Frequent comparisons of the spectral data for Saturn with observations and interpretations of IR studies of Jupiter show that these two planetary atmospheres are chemically similar, with major observational differences accounted for by reduced H2O and NH3 abundances in Saturn's colder atmosphere.

Larson, H. P.↗

NASA NTRS1982

Low NO sub x heavy fuel combustor concept program phase 1A gas tests

The emissions performance of a rich lean combustor (developed for liquid fuels) for combustion of simulated coal gases ranging in heating value from 167 to 244 Btu/scf were assessed. The 244 Btu/scf gas is typical of the product gas from an oxygen blown gasifier, while the 167 Btu/scf gas is similar to that from an air blown gasifier. Although meeting NOx goals for the 167 Btu/scf gas, NOx performance of the rich lean combustor did not meet program goals with the 244 Btu/scf gas because of high thermal NOx, similar to levels expected from conventional lean burning combustors. The NOx emissions are attributed to inadequate fuel air mixing in the rich stage resulting from the design of the large central fuel nozzle delivering 71% of the total gas flow. NOx generation from NH3 was significant at ammonia concentrations significantly less tha 0.5%. These levels occur depending on fuel gas cleanup system design, However, NOx yield from ammonia injected into the fuel gas decreased rapidly with increasing ammonia level, and is projected to be less than 10% at NH3 levels of 0.5% or higher.

Cutrone, M. B.↗

NASA NTRS1981

Solar-wind interactions with the moon - Nature and composition of nitrogen compounds

The direct interaction of the solar wind with the lunar surface results in a complete absorption of the solar wind corpuscles by the lunar surface material, with no upstream bow-shock but a cavity downstream from the lunar body. The active N ions and atoms derived from the solar wind were considered in the calculation of the radicals and compounds of nitrogen in the lunar material atmosphere, where the main species escaping from the surface to the atmosphere are NO and NH3 with near-surface concentrations of 327 and 295/cu cm, respectively. While the calculated concentration of NH3 seems consistent with the sunrise concentration results of the mass spectrometer implanted on the lunar surface, there has been no report of NO detection.

Mukherjee, N. R.↗

NASA NTRS1982

The origin of Uranus - Compositional considerations

Implications of two broad classes of theories for the origin of the solar system for the composition of Uranus are examined as an approach to the testing of alternative hypotheses. Consideration is given to accretional theories of planetary formation, which predict interior structures consisting of a rock core surrounded by an envelope of H2, He, H2O, NH3 and CH4 with different ratios of H2 to ice, and to theories postulating the formation of giant gaseous protoplanets as a result of an encounter with an extended protostar, the condensation of eddies (flocules) in a cloud, with supersonic turbulence and the breakup of a ring formed in a collapsing massive solar nebula. It is shown that whereas accretional theories can easily account for the high density of Uranus relative to Jupiter and Saturn, the apparent absence of NH3, and the observed D/H ratio being about three times the solar ratio, the giant protoplanet theories do not clearly demonstrate how the compositions were achieved.

Podolak, M.↗

NASA NTRS1982

Observation of interstellar ammonia ice

An absorption band probably due to solid ammonia on interstellar grains has been detected in the infrared spectrum at 2.97 microns of the Becklin-Neugebauer object and probably in NGC 2264-IR. An ammonia-water amorphous ice mixture can explain the structure of the new band and of the 3.07 microns interstellar absorption. Laboratory data suggest that a long wavelength wind extending to 3.5 microns in interstellar dust spectra may be absorption by NH3-H2O complexes in the ices. In the molecular cloud obscuring the BN object, about 20 times as much NH3 is frozen in grains as exists in the gas phase, suggesting the gas-grain interactions may be important in the ammonia chemistry of molecular clouds. Arguments are given that interstellar features at 6.0 and 6.8 microns are also ammonia-related absorptions.

Knacke, R. F.↗

NASA NTRS1982

Evaluation of advanced combustion concepts for dry NO sub x suppression with coal-derived, gaseous fuels

The emissions performance of a rich lean combustor (developed for liquid fuels) was determined for combustion of simulated coal gases ranging in heating value from 167 to 244 Btu/scf (7.0 to 10.3 MJ/NCM). The 244 Btu/scf gas is typical of the product gas from an oxygen blown gasifier, while the 167 Btu/scf gas is similar to that from an air blown gasifier. NOx performance of the rich lean combustor did not meet program goals with the 244 Btu/scf gas because of high thermal NOx, similar to levels expected from conventional lean burning combustors. The NOx emissions are attributed to inadequate fuel air mixing in the rich stage resulting from the design of the large central fuel nozzle delivering 71% of the total gas flow. NOx yield from ammonia injected into the fuel gas decreased rapidly with increasing ammonia level, and is projected to be less than 10% at NH3 levels of 0.5% or higher. NOx generation from NH3 is significant at ammonia concentrations significantly less than 0.5%. These levels may occur depending on fuel gas cleanup system design. CO emissions, combustion efficiency, smoke and other operational performance parameters were satisfactory. A test was completed with a catalytic combustor concept with petroleum distillate fuel. Reactor stage NOx emissions were low (1.4g NOx/kg fuel). CO emissions and combustion efficiency were satisfactory. Airflow split instabilities occurred which eventually led to test termination.

Beebe, K. W.↗

NASA NTRS1983

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

The infrared spectra of H2O ice VII and D2O ice VII were studied and techniques were developed for measuring adiabats of phases of NH3-H2O to 5 GPa. A mixing system for pressurized fluids was constructed in which liquid solutions of definite compositions can be prepared and loaded reliably into diamond cells in a project which seeks to determine the properties and boundaries of several high pressure phases of the H2-He-H2O-NH3-CH4 system. These data are needed to constrain theoretical models of the interiors of the major planets.

Nicol, M. F.↗

NASA NTRS1982

The prebiological paleoatmosphere - Stability and composition

In the past, it was generally assumed that the early atmosphere of the earth contained appreciable quantities of methane (CH4) and ammonia (NH3). This was the type of atmosphere believed to be the most suitable environment for chemical evolution, the nonbiological formation of complex organic molecules, the precursors of living systems. Photochemical considerations suggest that a CH4-NH3 dominated early atmosphere was probably very short-lived, if it ever existed at all. Instead, an early atmosphere of carbon dioxide (CO2) and nitrogen (N2) is favored by photochemical as well as geological and geochemical considerations. Photochemical calculations also indicate that the total oxygen column density of the prebiological paleoatmosphere did not exceed 10 to the -7th of the present atmospheric level.

Levine, J. S.↗

NASA NTRS1983

Infrared laser optogalvanic spectroscopy of molecules

Infrared laser optogalvanic spectra of portions of the NH3 nu3 band at 9.5 microns and the NO2 nu3 band at 6.2 microns have been recorded using CW tunable diode lasers to probe dc electrical discharges in pure NH3 and an NO2/He gas mixture. Two contributions to the optogalvanic signal are identified: one which corresponds to an increase in discharge impedance and is seen only for irradiation of the negative glow region; and a second which corresponds to a decrease in discharge impedance and is seen for irradiation of all other discharge regions and the volume outside the interelectrode region. Mechanisms by which infrared laser irradiation may cause impedance changes in the discharge are proposed.

Webster, C. R.↗