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At least 235 records · Page 13

Investigating Si Bonding Environments in Mercurian Melts

Mercury’s low oxygen fugacity results in lavas with extraordinarily high sulfur contents (> 1 wt%). The high S lowers melt viscosity, but why this occurs is unclear (Mouser et al., 2021). The detection of Si-S bonds (using NMR) in such highly reduced basaltic glasses, suggest that the decreased viscosity is due to changes in the Si bonding environment (Pommier et al., 2023). To investigate further, we synthesized a series of Mercurian glasses at 1 GPa, with S contents ranging from 0-6 wt% and oxygen fugacities from IW-4 to IW-6. The experimental glasses were analyzed by Si K-edge X-ray Absorption Near Edge Structure (XANES) spectroscopy and 29Si Nuclear Magnetic Resonance (NMR). Ongoing analyses will include Raman and Fourier Transform Infrared (FTIR). The 29Si NMR analyses suggest the presence of Si-S bonds in the melts, in agreement with Pommier et al. (2023). The Si K-edge XANES spectra show a decrease in K-edge position of 0.4 to 0.6 eV from terrestrial basalts (at ~IW+3) to the experimental melts at IW-4 to IW-6. This shift suggests a moderate (<20 mole %) amount of Si has shifted to lower valence states (Boujibar et al, 2019). The melts contain 0-6 wt% S, so if the K-edge shifts are the results of Si-S bonding, it implies that the majority of the S in the melts is bonded to Si. However, S K-edge XANES analyses indicate that much of the S is also bonded with Mg and Ca at these low oxygen fugacities (Anzures et al, 2020). The implication is that non-bridging Si-S-(Mg,Ca) bonds are prevalent in the reduced melts, consistent with the decrease in viscosity of the melts being due to melt depolymerization. Overall, our results suggest that dissolution of S into the melts at low fO2 is accomplished through bonding with Si, and is accompanied by significant structural changes that lower melt viscosity. Lower melt viscosities will affect many aspects of Mercury’s evolution, from magma ocean dynamics, to melt migration in the mantle, to eruption dynamics and degassing.

Emily L Fischer↗

TRAPPIST-1 d: Exo-Venus, Exo-Earth, or Exo-Dead?

TRAPPIST-1 d is generally assumed to be at the boundary between a Venus-like world and an Earth-like world, although recently published works on TRAPPIST-1 b and c raise concerns that TRAPPIST-1 d may be similarly devoid of a substantial atmosphere. TRAPPIST-1 d is also relatively understudied in comparison with TRAPPIST-1 e. The latter has generally appeared to be within the habitable zone of most atmospheric modeling studies. Assuming that TRAPPIST-1 d still retains a substantial atmosphere, we demonstrate via a series of 3D general circulation model experiments using a dynamic ocean that the planet could reside within the habitable zone in a narrow parameter space. At the same time, it could also be an exo-Venus- or exo-Dead-type world or in transition between between one of these. Studies like this can help distinguish between these types of worlds.

Exoplanets↗

Ocean current surface measurement using dynamic elevations obtained by the GEOS-3 radar altimeter

Remote Sensing of the ocean surface from the GEOS-3 satellite using radar altimeter data has confirmed that the altimeter can detect the dynamic ocean topographic elevations relative to an equipotential surface, thus resulting in a reliable direct measurement of the ocean surface. Maps of the ocean dynamic topography calculated over a one month period and with 20 cm contour interval are prepared for the last half of 1975. The Gulf Stream is observed by the rapid slope change shown by the crowding of contours. Cold eddies associated with the current are seen as roughly circular depressions.

Leitao, C. D.↗

Satellite-Derived Dynamics of Southern Ocean Sea Ice

Antarctic ERS-2, RADARSAT Synthetic Aperture Radar and ERS-1/2 Scatterometer images were analyzed with SMMI radiometer image time-series data to investigate seasonal variability in satellite-tracked sea-ice dynamics in the Southern Ocean during 1992. Supporting field data were acquired during 'in-situ' experiments including the winter 1992 Ice Station Weddell and Winter Weddell Gyre studies. A variety of surface measurements were made during these experiments including Argos-buoy deployment and GPS drift measurements. These are used in conjunction with International Program for Antarctic Buoys drift trajectories for ice-motion tracking validation. Comparisons between gridded Special Sensor Microwave Imager (SSMI) ice-motion vectors and European Center for Medium Range Weather Forecasts/National Centers for Environmental Prediction (ECMWF/NCEP) analyses indicate that large-scale drift is forced predominantly by the long-term mean, large-scale synoptic pressure field. Only sub-daily SAR sea-ice tracking can capture high-frequency fluctuations, driven by polar lows or tidal forcing. In these cases, sea-ice drift can respond rapidly to changes in forcing on semi-diurnal time scales depending on the location with respect to the coastline. Seasonality of ice drift, particularly in the Weddell and Ross Seas, is linked to ice extent and compactness, and internal ice stresses transmitted through the pack ice from the coast. Three-monthly seasonal climatologies are presented of austral winter of ice drift in the Southern Ocean. The large Weddell and Ross Sea gyres are clearly resolved along with key seasonal and spatial attributes of their cyclonic circulation. Regional time series of ice dynamics parameters are used to illustrate correlations with meteorological forcing. Persistent divergence such as that occurring in the Ronne-Filchner polynya system results in large fractions of new ice. Similarly, convergence zones produce large fractions of deformed ice and characterize the dynamics of regions where perennial ice is observed. High shear strains also help delineate the axis of the Antarctic divergence in many places in the ice cover. In these regions, the separation between the coastal 'east wind drift'and ACC-dominated drift regimes is characterized by zonally extended regions of intense shear.

Drinkwater, Mark R.↗

Ice-shelf ocean boundary layer dynamics from large-eddy simulations

Abstract. Small-scale turbulent flow below ice shelves is regionally isolated and difficult to measure and simulate. Yet these small-scale processes, which regulate heat and salt transfer between the ocean and ice shelves, can affect sea-level rise by altering the ability of Antarctic ice shelves to “buttress” ice flux to the ocean. In this study, we improve our understanding of turbulence below ice shelves by means of large-eddy simulations at sub-meter resolution, capturing boundary layer mixing at scales intermediate between laboratory experiments or direct numerical simulations and regional or global ocean circulation models. Our simulations feature the development of an ice-shelf ocean boundary layer through dynamic ice melting in a regime with low thermal driving, low ice-shelf basal slope, and strong shear driven by the geostrophic flow. We present a preliminary assessment of existing ice-shelf basal melt parameterizations adopted in single component or coupled ice-sheet and ocean models on the basis of a small parameter study. While the parameterized linear relationship between ice-shelf melt rate and far-field ocean temperature appears to be robust, we point out a little-considered relationship between ice-shelf basal slope and melting worthy of further study.

54 ENVIRONMENTAL SCIENCES↗

Effects of dynamic long-period ocean tides on changes in earth's rotation rate

As a generalization of the zonal response coefficient first introduced by Agnew and Farrell (1978), the zonal response function kappa of the solid earth-ocean system is defined as the ratio, in the frequency domain, of the tidal change in earth's rotation rate to the tide-generating potential. Amplitudes and phases of kappa for the monthly, fortnightly, and nine-day lunar tides are estimated from 2 1/2 years of VLBI UT1 observations, corrected for atmospheric angular momentum effects using NMC wind and pressure series. Using the dynamic ocean tide model of Dickman (1988, 1989), amplitudes and phases of kappa for an elastic earth-ocean system are predicted. The predictions confirm earlier results which found that dynamic effects of the longer-period ocean tides reduce the amplitude of kappa by about 1 percent.

Nam, Young↗

Inference of physical/biological dynamics from synthetic ocean colour images

High resolution numerical experiments with well resolved eddies are performed including advection of a biologically active plankton field. Shelf wave propagation and bottom topographic features are included. The resulting synthetic ocean color fields are examined for sensitivity to the (known) underlying physical dynamics.

Eert, J.↗

Observations of Ocean Radar Backscatter at K and C Bands in the Presence of Large Waves during the surface Wave Dynamics Experiment

Ocean rada backscatter in the presence of large waves is investigated using data acquired with the Jet Propulsion Laboratory NUSCAT radar at K band for horizontal and vertical polarizations and the University of Massachusetts C-SCAT radar at C band for vertical polarization during the Surface Wave Dynamics Experiment. Backscatter data of ocean surfaces was obtained in the presence of large waves with significant wave height up to 5.6m.

Rada Backscatter Waves Ocean↗

Mean Dynamic Topography of the Arctic Ocean

ICESat and Envisat altimetry data provide measurements of the instantaneous sea surface height (SSH) across the Arctic Ocean, using lead and open water elevation within the sea ice pack. First, these data were used to derive two independent mean sea surface (MSS) models by stacking and averaging along-track SSH profiles gathered between 2003 and 2009. The ICESat and Envisat MSS data were combined to construct the high-resolution ICEn MSS. Second, we estimate the 5.5-year mean dynamic topography (MDT) of the Arctic Ocean by differencing the ICEn MSS with the new GOCO02S geoid model, derived from GRACE and GOCE gravity. Using these satellite-only data we map the major features of Arctic Ocean dynamical height that are consistent with in situ observations, including the topographical highs and lows of the Beaufort and Greenland Gyres, respectively. Smaller-scale MDT structures remain largely unresolved due to uncertainties in the geoid at short wavelengths.

Arctic Ocean↗

Power output of turbines mounted on tension-leg platforms subjected to fully developed ocean gravity waves

A concern in the deployment of large wind turbines on ocean floating platforms is the effect of floating-platform motions on their electrical power generation. Further, it is not clear how floating motions influence waking, which might affect the combined power generation of collections of turbines. We examine the average power output of a single and a collection of NREL 5 MW wind turbines mounted on a tension-leg platform (TLP) under the action of fully developed ocean wave motions, coupling floating motions with the large-eddy simulation (LES) of atmospheric and rotor dynamics. The ocean dynamics enter as fully developed waves derived from the Pierson–Moskowitz spectrum. To assess the influence of ocean motions, we performed simulations over the full range of wind speeds in the operational range of the turbine, reporting comparisons of average power output when the platforms are allowed to move to when they are held rigidly in place. In all simulations, we find that the effects of the TLP floating-platform's induced motions have a minor effect on single and multiple turbine power production and wake deficits. Even when using coherent and large amplitude harmonic-floating-induced perturbations, any significant wake modifications from floating motions are confined to the near-wake region, where downstream turbines are unlikely to be located. The relatively small amplitude of TLP motions relative to pre-existing turbulent fluctuations are the primary reason for low wake and power modifications downstream.

Restrepo, Juan [ORNL] (ORCID:0000000326092882)↗

The seasonal response of the Held-Suarez climate model to prescribed ocean temperature anomalies. II - Dynamical analysis

The heating associated with equatorial, subtropical, and midlatitude ocean temperature anamolies in the Held-Suarez climate model is analyzed. The local and downstream response to the anomalies is analyzed, first by examining the seasonal variation in heating associated with each ocean temperature anomaly, and then by combining knowledge of the heating with linear dynamical theory in order to develop a more comprehensive explanation of the seasonal variation in local and downstream atmospheric response to each anomaly. The extent to which the linear theory of propagating waves can assist the interpretation of the remote cross-latitudinal response of the model to the ocean temperature anomalies is considered. Alternative hypotheses that attempt to avoid the contradictions inherent in a strict application of linear theory are investigated, and the impact of sampling errors on the assessment of statistical significance is also examined.

Phillips, T. J.↗

Observations of Radar Backscatter at Ku and C Bands in the Presence of Large Waves during the Surface Wave Dynamics Experiment

Ocean radar backscatter in the presence of large waves is investigated using data acquired with the Jet Propulsion Laboratory NUSCAT radar at Ku band for horizontal and vertical polarizations and the University of Massachusetts CSCAT radar at C band for vertical polarization during the Surface Wave Dynamics Experiment. Off-nadir backscatter data of ocean surfaces were obtained in the presence of large waves with significant wave height up to 5.6 m. In moderate-wind cases, effects of large waves are not detectable within the measurement uncertainty and no noticeable correlation between backscatter coefficients and wave height is found. Under high-wave light-wind conditions, backscatter is enhanced significantly at large incidence angles with a weaker effect at small incidence angles. Backscatter coefficients in the wind speed range under consideration are compared with SASS-2 (Ku band), CMOD3-H1 (C band), and Plant's model results which confirm the experimental observations. Variations of the friction velocity, which can give rise to the observed backscatter behaviors in the presence of large waves, are presented.

Nghiem, S. V.↗

Dynamic sea surface topography, gravity, and improved orbit accuracies from the direct evaluation of Seasat altimeter data

A gravitational model incorporating Seasat altimetry, surface gravimetry, and satellite tracking data has been determined in terms of global spherical harmonics complete to degree and order 50. This model, PGS-3337, uses altimeter data as a dynamic observation of the satellite's height above the sea surface. A solution for the ocean's dynamic topography is recovered simultaneously with the orbit parameters, gravity, and ocean tidal terms. The recovered dynamic topography reveals the global long wavelength circulation of the oceans with a resolution of 2000 km and is very similar to the mean upper ocean dynamic height derived from historical ship observations. The PGS-3337 geoid has an uncertainty of 60 cm rms globally but 25 cm rms over the ocean because of the altimeter measurements. Seasat orbits determined in this solution have an estimated accuracy for the radial position of 20 cm rms. The difference between the altimeter observed sea height and the geoid plus dynamic topography model is 30 cm rms. Contained in these residuals are the sea height variability, as well as errors from the geoid, orbits, tidal models, and altimeter range measurement. This performance level is 2 to 3 times better than that achieved with previous Goddard gravitational models.

Marsh, J. G.↗

Results of Airborne Backscatter Measurements During the Surface Wave Dynamics Experiment

Ocean backscatter data over a wide variety of oceanic and atmospheric conditions were obtained by the Jet Propulsion Laboratory NUSCAT Ku-band scatterometer during the Surface Wave Dynamics Experiment (SWADE). Thirty hours of backscatter data were collected in ten flights by NUSCAT on the NASA Ames C130 aircraft during an intensive observation period (IOP) of SWADE in the winter of 1991. The SWADE experimental area, off the coast of Virginia and Maryland, was deployed with an array of buoys providing appropriate in-situ measurements to correlate with the radar backscatter for incidence angles from 10ø to 60ø at both horizontal and vertical polarizations.

Airborne↗

An Assessment of Antarctic Circumpolar Current and Southern Ocean Meridional Overturning Circulation During 1958-2007 in a Suite of Interannual CORE-2 Simulations

In the framework of the second phase of the Coordinated Ocean-ice Reference Experiments (CORE-II), we present an analysis of the representation of the Antarctic Circumpolar Current (ACC) and Southern Ocean Meridional Overturning Circulation (MOC) in a suite of seventeen global ocean-sea ice models. We focus on the mean, variability and trends of both the ACC and MOC over the 19582007 period, and discuss their relationship with the surface forcing. We aim to quantify the degree of eddy saturation and eddy compensation in the models participating in CORE-II, and compare our results with available observations, previous fine-resolution numerical studies and theoretical constraints. Most models show weak ACC transport sensitivity to changes in forcing during the past five decades, and they can be considered to be in an eddy saturated regime. Larger contrasts arise when considering MOC trends, with a majority of models exhibiting significant strengthening of the MOC during the late 20th and early 21st century. Only a few models show a relatively small sensitivity to forcing changes, responding with an intensified eddy-induced circulation that provides some degree of eddy compensation, while still showing considerable decadal trends. Both ACC and MOC interannual variability are largely controlled by the Southern Annular Mode (SAM). Based on these results, models are clustered into two groups. Models with constant or two-dimensional (horizontal) specification of the eddy-induced advection coefficient show larger ocean interior decadal trends, larger ACC transport decadal trends and no eddy compensation in the MOC. Eddy-permitting models or models with a three-dimensional time varying show smaller changes in isopycnal slopes and associated ACC trends, and partial eddy compensation. As previously argued, a constant in time or space is responsible for a poor representation of mesoscale eddy effects and cannot properly simulate the sensitivity of the ACC and MOC to changing surface forcing. Evidence is given for a larger sensitivity of the MOC as compared to the ACC transport, even when approaching eddy saturation. Future process studies designed for disentangling the role of momentum and buoyancy forcing in driving the ACC and MOC are proposed.

Southern Ocean dynamics↗