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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Photochemistry of methane and the formation of hydrocyanic acid (HCN) in the earth's early atmosphere

A one-dimensional photochemical model is used to analyze the photochemistries of CH4 and HCN in the primitive terrestrial atmosphere. CH4, N2, and HCN photolysis are examined. The background atmosphere and boundary conditions applied in the analysis are described. The formation of HCN as a by-product of N2 and CH4 photolysis is investigated; the effects of photodissociation and rainfall on HCN is discussed. The low and high CH4 mixing ratios and radical densities are studied.

Zahnle, K. J.↗
NASA NTRS2004

Integrated-Optic Oxygen Sensors

Compact optical oxygen sensors with self-calibration capabilities are undergoing development. A sensor of this type features a single-chip, integrated-optic design implemented by photolithographic fabrication of optical waveguides in a photosensitive porous glass. The porosity serves as both a matrix for retention of an oxygen-sensitive fluorescent indicator chemical and a medium for diffusion of oxygen to the chemical from the ambient air to be monitored. Each sensor includes at least one such waveguide exposed to the atmosphere and at least one covered with metal for isolation from the atmosphere. The covered one serves as a reference channel. In operation, the concentration of oxygen is deduced from the intensity and lifetime of the fluorescence in the exposed channel, with the help of calibration data acquired via the reference channel. Because the sensory chemical is placed directly in and throughout the cross section of the light path, approximately 99 percent of the light in the waveguide is available for interaction with the chemical, in contradistinction to only about 1 percent of the light in an optical sensor that utilizes evanescentwave coupling. Hence, a sensor of this type is significantly more sensitive.

Mendoza, Edgar A.↗
NASA NTRS1979

The seasonal variation of ozone density in the Martian atmosphere

A one-dimensional, time-dependent model has been developed to investigate seasonal variations in ozone density in the Martian atmosphere. The model utilizes data for atmospheric temperature, pressure, and water vapor abundance observed by Viking. The results indicate that a high ozone density is not produced near the winter solstice but is in rather late winter, when the amount of water vapor is still small and the solar radiation can penetrate more deeply. A similar condition met in early winter does not necessarily produce a high ozone density because of the predicted higher HO2 density. Seasonal variations in ozone abundance are discussed in terms of the abundances of H2O and H2 and the seasonal variations in their reaction products H2O2 and HOx. The roles of transport, the effects of ozone loss to the surface, and the differences between northern and southern hemisphere ozone distributions are also discussed.

Shimazaki, T.↗
NASA NTRS1980

Analysis of the solar magnesium lines

The observed quiet-sun profiles for a number of Mg I and II lines are compared with theoretical spectra computed for two upper-photosphere lower-chromosphere models published by Ayres and Linsky (1976). Both the Mg I and the Mg II resonance line wings, observed with the University of Hawaii Echelle Rocket Spectrographs, favor a model with a higher temperature in the upper photosphere than required to match the visible region lines 4571 and 5172. Neither model atmosphere reproduces the observed shapes in the cores of the strong lines or the limb darkening of the 4571 A intercombination line. The wings of the ultraviolet lines in plages can be reproduced either with a mean one-component atmosphere or by a two-component model with an ad hoc filling factor.

Heasley, J. N.↗
NASA NTRS1990

Bolide impacts and the oxidation state of carbon in the earth's early atmosphere

A one-dimensional photochemical model was used to examine the effect of bolide impacts on the oxidation state of earth's primitive atmosphere. The impact rate should have been high prior to 3.8 Ga before present, based on evidence derived from the moon. Impacts of comets or carbonaceous asteroids should have enhanced the atmospheric CO/CO2 ratio by bringing in CO ice and/or organic carbon that can be oxidized to CO in the impact plume. Ordinary chondritic impactors would contain elemental iron that could have reacted with ambient CO2 to give CO. Nitric oxide (NO) should also have been produced by reaction between ambient CO2 and N2 in the hot impact plumes. High NO concentrations increase the atmospheric CO/CO2 ratio by increasing the rainout rate of oxidized gases. According to the model, atmospheric CO/CO2 ratios of unity or greater are possible during the first several hundred million years of earth's history, provided that dissolved CO was not rapidly oxidized to bicarbonate in the ocean.

Kasting, James F.↗
NASA NTRS1992

Bolide impacts and the oxidation state of carbon in the Earth's early atmosphere

A one-dimensional photochemical model was used to examine the effect of bolide impacts on the oxidation state of Earth's primitive atmosphere. The impact rate should have been high prior to 3.8 Ga before present, based on evidence derived from the Moon. Impacts of comets or carbonaceous asteroids should have enhanced the atmospheric CO/CO2 ratio by bringing in CO ice and/or organic carbon that can be oxidized to CO in the impact plume. Ordinary chondritic impactors would contain elemental iron that could have reacted with ambient CO2 to give CO. Nitric oxide (NO) should also have been produced by reaction between ambient CO2 and N2 in the hot impact plumes. High NO concentrations increase the atmospheric CO/CO2 ratio by increasing the rainout rate of oxidized gases. According to the model, atmospheric CO/CO2 ratios of unity or greater are possible during the first several hundred million years of Earth's history, provided that dissolved CO was not rapidly oxidized to bicarbonate in the ocean. Specifically, high atmospheric CO/CO2 ratios are possible if either: (1) the climate was cool (like today's climate), so that hydration of dissolved CO to formate was slow, or (2) the formate formed from CO was efficiently converted into volatile, reduced carbon compounds, such as methane. A high atmospheric CO/CO2 ratio may have helped to facilitate prebiotic synthesis by enhancing the production rates of hydrogen cyanide and formaldehyde. Formaldehyde may have been produced even more efficiently by photochemical reduction of bicarbonate and formate in Fe(++)-rich surface waters.

Non-NASA Center↗
NASA NTRS2002

Moisture Advection and Fresh Water Flux over Oceans

Moisture transport in the atmosphere is one of the most significant components in the hydrological cycle. Under stationary condition, ocean surface fresh water flux, which is the difference between precipitation (P) and evaporation (E), is balanced by the divergence of column-integrated moisture transport (IMT) in the atmosphere. Characterizing accurately a global picture of IMT from observation is a difficult task. It requires measurements of vertical profiles for wind vector and humidity. More specifically, IMT can be defined as the integration in pressure coordinates the product of specific humidity q and wind vector u, where g is the gravitational acceleration, and p, is the atmospheric pressure at ocean surface.In this study, a statistical relationship is derived between u, and u(sub)s using data from numerical weather prediction model. The relationship is then validated using surface and vertical profile from radiosonde data, before applied to spacebased measurements.

scatterometers↗
NASA NTRS1985

Does the ocean-atmosphere system have more than one stable mode of operation?

The climate record obtained from two long Greenland ice cores reveals several brief climate oscillations during glacial time. The most recent of these oscillations, also found in continental pollen records, has greatest impact in the area under the meteorological influence of the northern Atlantic, but none in the United States. This suggests that these oscillations are caused by fluctuations in the formation rate of deep water in the northern Atlantic. As the present production of deep water in this area is driven by an excess of evaporation over precipitation and continental runoff, atmospheric water transport may be an important element in climate change. Changes in the production rate of deep water in this sector of the ocean may push the climate system from one quasi-stable mode of operation to another.

Broecker, W. S.↗
NASA NTRSDate not supplied

Observations of the Age of Air from the Northern Hemisphere Midlatitude Surface

Understanding and modeling the interhemispheric transport (IHT) of trace gases and aerosols is important for interpreting past (and projecting future) changes in atmospheric composition. One IHT measure -- the mean age since air was last at the Northern Hemisphere (NH) midlatitude surface – represents a fundamental property of tropospheric transport that can be estimated from measurements of sulfur hexafluoride (SF6). Here we use SF6 measurements obtained from the recent NASA Atmospheric Tomography Mission (ATom) to construct observational estimates of the mean age throughout the troposphere. We compare the ATom based ages, which span all four seasons during the period 2016-2018 over both the Pacific and Atlantic Oceans, with previous in situ-based estimates obtained from the HIAPER Pole‐to‐Pole Observations (HIPPO) project, which are available only for the Pacific. In order to interpret the observed variations in mean age and their relationship with the large-scale flow we use simulations of the Goddard Earth Observing System (GEOS) general circulation model, constrained with meteorological fields derived from the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2), performed over the entire MERRA-2 period (including ATom). We confirm results from previous studies showing that the model ages are biased old compared to the observational estimates. However, we also show that this model bias is reduced in more recent years, which we interpret in terms of changes in the latitudinal distribution of SF6 emissions over the 2000s.

interhemispheric transport (IHT)↗
NASA NTRS1993

Solitary waves in the atmosphere

The weakly nonlinear theory for internal solitary waves is reviewed, and theoretical results of the vertical and horizontal structure of temperature, vertical displacements, and vertical and horizontal perturbations to the wind field associated with steadily propagating solitary waves are presented in two idealized atmospheric configurations. One configuration is representative of solitary waves observed in the lower troposphere and the other of solitary waves that occupy the entire troposphere. The important results of the theory are presented in a form that can be readily used by observationalists. The results obtained are then analyzed using actual rawinsonde data for two well-documented observations of atmospheric solitary waves, which are analogous to the two idealized configurations. The importance and difficulties of properly identifying the waveguide within which the solitary wave is confined are discussed. The fundamental role of a critical level in ducting the disturbances and thus in defining the thickness of the waveguide is illustrated in the example dealing with the solitary wave occupying the entire troposphere. Together, these two examples illustrate the decisions and compromises that must be made in applying the theory to the real atmosphere.

Rottman, James W.↗
NASA NTRS1971

Analysis of solar ultraviolet lines

The formation of the strongest ultra-violet emission lines of Mg II, O I, C II, and C III in the solar atmosphere is studied in detail. The equations of statistical equilibrium and radiative transfer for each ion are solved using a general computer program that is capable of solving non-LTE line-formation problems for arbitrary atmospheric and atomic models. Interpreting the results in terms of the structure of the solar atmosphere, it is concluded that the HSRA atmosphere has a temperature too low by about 500 K near h = 1100 km and that a temperature plateau with T sub e approximately = 18,000 K and width close to 60 km exists in the upper chromosphere. The structure of the solar atmosphere in the range 20,000 to 100,000 K and the effects of microturbulence on the formation of lines are also investigated. Approximate analytic line-formation problems are solved, and more exact solutions are derived later. An attempt is made to make the best possible fit to the Ca II K line center-to-limb profiles with a one-component atmosphere, with an assumed source function and microturbulent velocity.

Chipman, E.↗
NASA NTRS1984

Multiple-pass trajectories for an aeroassisted orbital transfer vehicle

This paper investigates the use of multiple-pass trajectories for aeroassisted orbital transfer vehicles (AOTV) as a means of reducing the severe aeroheating environment and the extreme sensitivity to off-nominal trajectory and atmospheric conditions. One-, two-, and three-pass trajectories were calculated for AOTV's with ballistic coefficients ranging from 5 to 150 psf. Compared to the single-pass case, the maximum heat rate was reduced by 30 percent for two passes and 45 percent for three passes, while the maximum acceleration was reduced by 40 percent and 55 percent, respectively. The sensitivity of the trajectories to variations in atmospheric and orbital parameters was not significantly reduced.

Rehder, J. J.↗
NASA NTRS1986

The upper atmosphere of Venus: A tentative explanation of its rotation

The upper atmosphere of Venus seems to revolve every 4 days, while the planet rotates in 243 days. Mariner 10 UV data on the changing positions of dark spots in the upper Venusian clouds have supported estimations of speeds ranging from 120-240 m/s. High rates of acceleration and deceleration occur on the night side, the former between -110 to -90 deg and the latter continuing to -50 deg. Arch and Y formations have been seen repeatedly between -110 to -70 deg. The highest are seen at about -90 deg and the lowest at about -30 deg. The temperature of the cloud layer at 60 km altitude is about 20 C, the pressure is nearly one earth atmosphere, and complex molecules, including O, C, H, N and S and combinations of these are present in abundance.

Boyer, C.↗
NASA NTRS2022

3-D Atmospheric Modeling of the Global Budget of N2O and its Isotopologues for 1980-2019: The Impact of Anthropogenic Emissions

Nitrous oxide (N2O) is the third most important anthropogenic greenhouse gas (GHG) and a major ozone-depleting substance (ODS). Its main sources include anthropogenic activities (mostly agriculture) and natural emissions from ocean and soils. However, emission estimates for individual sources are highly variable due to uncertainties in N2O lifetime estimates and partitioning among sources. We derive annual global N2O emissions for 1990-2019 using NOAA Global Monitoring Laboratory (GML) surface N2O observations and the N2O lifetime calculated in the NASA GEOS-5 chemistry climate model (CCM). The inferred global mean N2O emissions has gradually increased from ~15.8 TgN/yr in the early 1990s to ~17.8 TgN/yr in the 2010s. This implies that anthropogenic N2O emissions have grown rapidly from ~6.7 TgN/yr in the 1990s to about ~8.7 TgN/yr in the 2010s, a ~30% increase. With specially designed N2O isotopic tracers in 3-D GEOSCCM, we estimate that, on global average, stratospheric enrichment contributes about +7.7‰/yr, +7.6‰/yr, +8.0‰/yr to tropospheric N(sup α)-δ(sup 15), N(sup β)-δ(sup 15), and O-δ(sup 18) budget, respectively. To balance the global mean isotopic signature for pre-industrial terrestrial sources of N(sup α)-δ(sup 15) ~ 6.7‰, N(sup β)-δ(sup 15) ~ -12.6‰, O-δ(sup 18) ~ 35.4‰, our 3-D isotopic budget simulation using the GEOSCCM suggests global mean anthropogenic isotopic signatures in the recent decades are N(sup α)-δ(sup 15) ~ -18‰, N(sup β)-δ(sup 15) ~ -20‰, O-δ(sup 18) ~ 19‰. These anthropogenic isotopic estimates are significantly lighter than results from one-box atmospheric model-based estimates with the largest difference seen for N(sup β)-δ(sup 15). More surface isotopic measurements are needed to better quantify the N2O isotopic signatures.

Nitrous oxide↗
NASA NTRS1973

The effects of an autopilot on airplane responses to turbulence with emphasis on tail loads

An analytical study has been made to assess the loads developed on the horizontal tail of an autopilot-controlled rigid airplane flying in one-dimensional atmospheric turbulence. The root-mean-square values of rigid-airframe responses and tail-load responses were calculated at five flight conditions, and the behavior of these responses was observed in two autopilot modes: pitch-attitude-hold mode and altitude-control mode. It was found that pitch attitude and altitude can be controlled by the simple autopilot with acceptable or no increases in tail loads.

Perry, B., III↗
NASA NTRS1976

Possibilities of efficient high-speed transport airplanes

Comparisons of wing-body combinations may not disclose the full effect of a loss in aerodynamic efficiency. If the thrust needs to be increased at a given altitude then more or larger engines will have to be used and the possibility of concealing them becomes less. In this process the lift drag ratio of the complete airplane may become still more unfavorable than indicated by the comparison. Primarily aerodynamic and structural considerations point toward the development of turbojet engines specifically adapted to operation in an atmosphere of one tenth normal density. In addition to the numerous other technological problems associated with operation at these high altitudes, the problems of safe descent and effective limitation to low speeds at low altitudes seem important.

Jones, R. T.↗
NASA NTRS1976

A search for short-term meteorological effects of solar variability in an atmospheric circulation model

A set of numerical experiments is carried out to test the short-range sensitivity of the Goddard Institute for Space Studies global atmospheric general-circulation model to changes in solar constant and ozone amount. These experiments consist of forecasts initiated with actual atmospheric data. One set of forecasts is made with a standard version of the model; another set uses the model modified by very different values of the solar constant (two-thirds and three-halves of the standard value) and of the ozone amount (zero and twice the standard amount). Twelve-day integrations with these very large variations show such small effects that the effects of realistic variations would almost certainly be insignificant meteorologically on this time scale.

Somerville, R. C. J.↗
NASA NTRS1976

Atmospheric engineering of Mars

The feasibility of creating a breathable atmosphere on Mars was studied. Assuming that indigenous life is absent, and that human habitation will prove economically justifiable, several methods of introducing oxygen were considered. On the basis of energy requirements, photosynthetic oxygen production appears to be reasonable, assuming that the amounts of water, carbon dioxide, and mineral nutrients available on the Martian surface would be adequate for the growth of photosynthetic microorganisms. However, optimum rates of O2 formation could occur only after a significant increase in average temperature and in atmospheric mass. The generation of a runaway greenhouse/advective effect was considered. However, neither the energy requirement nor the time constant for initiation could be calculated. There appear to be no insuperable obstacles to the conversion of the Martian atmosphere to one containing oxygen, but the conversion would require many thousands of years.

Macelroy, R. D.↗