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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Stability of Y-Ba-Cu-oxide phases in salt flux

The results of an investigation into the possibility of growing YBa2Cu3O7 (or Y123) single crystals from a NaCl-KCl flux (salt flux) are presented. They are compared with results for Y123 crystals grown from a Ba-Cu-oxide flux system. The chosen salt flux composition was 1:1 (NaCl:KCl). The preparation method of the solutes is presented, with particular attention given to the compounds surrounding the Y123 phase, such as Y2BaCuO6 (Y211). Optical microscopy was introduced to study the morphology of the sample; X-ray diffraction was used for phase identification; and a chemical analysis was effected. The Y123, Y211, and BaCuO2 phases were shown to be dissociated in the NaCl-KCl flux, and could not be recrystallized. A small amount of the flux could be added to create large-grain Y123 crystals, but single-crystal growth was not possible in a top-seeded NaCl-KCl solution. This is attributed to significant differences in solubility of the crystal elements, and phase separation caused by CuO crystal formation.

Tao, Y. K.↗
NASA NTRS1991

Chemical characterization of seven Large Area Collector particles by SXRF

Optical microscopy and synchrotron X-ray fluorescence (SXRF) are used to analyze the chemical composition of seven dark-appearing cosmic-dust particles obtained in the stratosphere during NASA Johnson Large Area Collector flights. The experimental setup and procedures are outlined, and the results are presented in extensive tables. Three of the particles had abundances similar to those of chondrites (except for low Ca values in one particle); two had a metallic appearance and spectra dominated by Fe and Zn; one contained Cu and Cr plus small amounts of Fe and Zn; and one had igneous-type abundances of minor and trace elements while containing all of the elements seen in chondritic particles, suggesting it may be of extraterrestrial origin.

Flynn, G. J.↗
NASA NTRS1991

Ammonia-water mixtures at high pressures - Melting curves of ammonia dihydrate and ammonia monohydrate and a revised high-pressure phase diagram for the water-rich region

The phase relations of some mixtures of ammonia and water are investigated to create a phase diagram in pressure-temperature-composition space relevant to the geophysical study of bodies in the outer solar system. The mixtures of NH3(x)H2O(1-x), where x is greater than 0.30 but less than 0.51, are examined at pressures and temperatures ranging from 0-6.5 GPa and 125-400 K, respectively. The ruby luminescence technique monitors the pressure and a diamond-anvil cell compresses the samples, and the phases are identified by means of normal- and polarized-light optical microscopy. The melting curve for NH3H2O(2) is described by the equation T = 176 + 60P - 8.5P squared for the ranges of 0.06-1.4 GPa and 179-243 K. The equation for NH3H2O is T = 194 + 37P - P squared, which represents a minor correction of a previous description by Johnson et al. (1985). Observed phase transitions are consistent with the high-pressure stability limit of NH3H2O(2), and the transition boundary is found to be linear.

Boone, S.↗
NASA NTRS1991

Quantitative nondestructive evaluation of materials and structures

An experimental investigation was undertaken to quantify damage tolerance and resistance in composite materials impacted using the drop-weight method. Tests were conducted on laminates of several different carbon-fiber composite systems, such as epoxies, modified epoxies, and amorphous and semicrystalline thermoplastics. Impacted composite specimens were examined using destructive and non-destructive techniques to establish the characteristic damage states. Specifically, optical microscopy, ultrasonic, and scanning electron microscopy techniques were used to identify impact induced damage mechanisms. Damage propagation during post impact compression was also studied.

Smith, Barry T.↗
NASA NTRS1992

Surface migration and volume diffusion in the AgGaSe2-Ag2Se system

Surface migration and volume diffusion in the Ag2Se-AgGaSe2 system were investigated using reactive diffusion couples which were analyzed by X-ray diffraction, optical microscopy, and electron probe microanalysis. The surface diffusivities of all mobile species are found to be much larger than volume diffusivities. The results of the study suggest that Se moves together with Ag and Ga to maintain binary (Ag2Se and Ga2Se3) stoichiometry and electroneutrality. The dominance of surface migration kinetics can account for the uniform annihilation of second-phase precipitates during heat treatments.

Kim, N.-H.↗
NASA NTRS1992

Failure mechanisms of 3-D woven SiC/SiC composites under tensile and flexural loading at room and elevated temperatures

Nicalon silicon carbide 3D yarn with silicon carbide matrix composites made through a chemical vapor infiltration (CVI) process were investigated under tensile and flexural loading at 23, 1200 and 1550 C in air. The effectiveness of a chemical vapor deposition (CVD) SiC surface coating was also evaluated in severe oxidizing environment. Acoustic emission sensors and in situ optical microscopy were used at room temperature to monitor the failure mechanisms. It is shown that the level of tensile stress at which nonlinear behavior begins is not drastically reduced at 1200 and 1550 C when composites were protected by a SiC surface coating. Extensive fiber pull-out was observed only in the 1550 C specimen. Similar behaviors were also found in flexural specimens.

Chulya, Abhisak↗
NASA NTRS1992

A high-pressure van der Waals compound in solid nitrogen-helium mixtures

A detailed diamond anvil-cell study using synchrotron X-ray diffraction, Raman scattering, and optical microscopy has been conducted for the He-N system, with a view to the weakly-bound van der Waals molecule interactions that can be formed in the gas phase. High pressure is found to stabilize the formation of a stoichiometric, solid van der Waals compound of He(N2)11 composition which may exemplify a novel class of compounds found at high pressures in the interiors of the outer planets and their satellites.

Vos, W. L.↗
NASA NTRS1992

Sudbury project (University of Muenster-Ontario Geological Survey): Petrology, chemistry, and origin of breccia formations

Within the Sudbury Project of the University of Muenster and the Ontario Geological Survey special emphasis was put on the breccia formations exposed at the Sudbury structure (SS) because of their crucial role for the impact hypothesis. They were mapped and sampled in selected areas of the north, east, and south ranges of the SS. The relative stratigraphic positions of these units are summarized. Selected samples were analyzed by optical microscopy, SEM, microprobe, XRF and INAA, Rb-Sr and SM-Nd-isotope geochemistry, and carbon isotope analysis. The results of petrographic and chemical analysis for those stratigraphic units that were considered the main structural elements of a large impact basin are summarized.

Stoeffler, D.↗
NASA NTRS1993

Effects of thermal and mechanical fatigue on the flexural strength of G40-600/PMR-15 cross-ply laminates

The effects of thermal and mechanical fatigue on the flexural strength of G40-600/PMR-15 cross-ply laminates with ply orientation of (0(2),90(2))2S and (90(2),0(2))2S are examined. The relative importance of shear and tensile stresses is examined by varying the span-to-depth ratios of flexural test specimens from 8 to 45. Acoustic emission signals are measured during the flexural tests in order to monitor the initiation and growth of damage. Optical microscopy is used to examine specimens for resin cracking, delamination, and fiber breaks after testing. Transverse matrix cracks and delaminations occur in all specimens, regardless of ply orientation, span-to-depth ratio, or previous exposure of specimens to thermal and mechanical fatigue. A small amount of fiber tensile fracture occurs in the outer 0 deg ply of specimens with high span-to-depth ratios. Because of the complex failure modes, the flexural test results represent the 'apparent' strengths rather than the true flexural or shear strengths for these cross-ply laminates. Thermal cycling of specimens prior to flexural testing does not reduce the apparent flexural strength or change the mode of failure. However, fewer acoustic events are recorded at all strains during flexural testing of specimens exposed to prior thermal cycling. High temperature thermal cycling (32 to 260 C, 100 cycles) causes a greater reduction in acoustic events than low temperature thermal cycling (-85 to +85 C, 500 cycles). Mechanical cycling (0 to 50 percent of the flexural strength, 100 cycles) has a similar effect, except that acoustic events are reduced only at strains less than the maximum strain applied during flexural fatigue.

Roberts, Gary D.↗
NASA NTRS1992

Heat pipe fatigue test specimen: Metallurgical evaluation

An innovative creep/fatigue test was run to simulate the temperature, mechanical load, and sodium corrosion conditions expected in a heat pipe designed to supply thermal energy to a Stirling cycle power converter. A sodium-charged Inconel 718 heat pipe with a Nickel 200 screen wick was operated for 1090 hr at temperatures between 950 K (1250 F) and 1050 K (1430 F) while being subjected to creep and fatigue loads in a servo-hydraulic testing machine. After testing, the heat pipe was sectioned and examined using optical microscopy, scanning electron microscopy, and electron microprobe analysis with wavelength dispersive x-ray spectroscopy. The analysis concentrated on evaluating topographic, microstructural, and chemical changes in the sodium exposed surfaces of the heat pipe wall and wick. Surface changes in the evaporator, condenser, and adiabatic sections of the heat pipe were examined in an effort to correlate the changes with the expected sodium environment in the heat pipe. This report describes the setup, operating conditions, and analytical results of the sodium heat pipe fatigue test.

Walak, Steven E.↗
NASA NTRS1992

Beneficiation of ilmenite from lumar analog

The results reported were obtained on a meteoric eucrite sample called Millbillillie Sample no. 173. Optical microscopy studies of the sample showed it to consist of ilmenite, troilite, and transparent gangue. The transparent gangue consisted of feldspar (anorthite), pyroxenes, olivines, and opaques. Troilite was present in minor quantities. Screen assay analyses of the 30, 100, 200, and 400 US mesh screen fractions showed that minor concentration of titanium occurred in the 200 x 400 and -400 mesh screen fractions. Scanning electron microscopy (SEM) studies of the bulk sample showed the presence of a variety of ilmenite grains, ranging from 50 microns down to less than 1 micron without any evidence of liberation. Electron Diffraction Scans (EDS) confirmed the ratio of Fe to Ti in the ilmenite grains. Dry magnetic separation in a Frantz Isodynamic Separator was found to be effective only at sizes finer than 150 microns (100 US mesh) and more so at 200 mesh (74 microns). In each case, dedusting of the sample to remove -400 mesh (-0.037 microns) fines was required. Liberation size was determined to be 200 mesh and finer. The highest grade concentrate assaying 3.45 percent Ti was produced by magnetic separation of the -200 + 400 mesh screen fraction assaying 0.44 Ti (from a -30 mesh sample) at a current setting of 0.35 AMP. This concentrate contained 21.2 percent of the Ti values in the screen fraction with 2.72 weight percent of feed to test. The results can be projected to a sample stage ground to -200 mesh. Magnetic separation of the 200 + 400 mesh (-0.074 + 0.037 microns) should produce a concentrate accounting for 1.41 weight percent of the feed. This concentrate will analyze 3.45 percent Ti and contain 10.3 percent of the Ti values in the feed. By changing the Frantz Magnetic Separator settings, a lower grade concentrate analyzing 0.98 percent Ti can be produced at an increased recovery of 25.4 percent. The concentrate weight will be 11.7 percent of the feed. It must be emphasized that improved grades and recoveries can be obtained with the -400 mesh fines. However, beneficiation of these extremely fine materials is not possible in a practical process scheme.

Ramadorai, G.↗
NASA NTRS1993

Hot Hydrogen Testing of Refractory Metals and Ceramics

The objective of this investigation is to develop a technique with which refractory metal carbide samples can be exposed to hydrogen containing gases at high temperatures, and to use various microstructural and analytical techniques to determine the chemical and rate processes involved in hydrogen degradation in these materials. Five types of carbides were examined including WC, NbC, HfC, ZrC, and TaC. The ceramics were purchased and were all monolithic in nature. The temperature range investigated was from 850 to 1600 C with a hydrogen pressure of one atmosphere. Control experiments, in vacuum, were also conducted for comparison so that the net effects due to hydrogen could be isolated. The samples were analyzed prior to and after exposure. Gas samples were collected in selected experiments and analyzed using gas chromography. Characterization of the resulting microstructure after exposure to hydrogen was conducted using optical microscopy, x-ray diffraction, scanning electron microscopy, and weight change. The ceramics were purchased and were all monolithic in nature. It was found that all samples lost weight after exposure, both in hydrogen and vacuum. Results from the microstructure analyses show that the degradation processes are different among the five types of ceramics involved. In addition, the apparent activation energy for the degradation process is a function of temperature even within the same material. This indicates that there are more than one mechanism involved in each material, and that the mechanisms are temperature dependent.

Zee, Ralph↗
NASA NTRS1992

Characterization of damage modes in impacted thermoset and thermoplastic composites

Composite materials remain extremely vulnerable to out-of-plane impact loads, which may lead to severe losses in strength and stiffness. Impact induced damage is often a complex mixture of transverse cracks, delaminations and fiber failures. An experimental investigation was undertaken to quantify damage tolerance and resistance in composite materials impacted using the drop-weight method. Tests were conducted on laminates of several different carbon-fiber composite systems such as epoxies, modified epoxies, and amorphous and semicrystalline thermoplastics. In this paper, impacted composite specimens have been examined using destructive and nondestructive techniques to establish the characteristic damage states. Specifically, optical microscopy, ultrasonic and scanning electron microscopy techniques have been used to identify impact induced damage mechanisms. Damage propagation during post impact compression was also studied.

Srinivasan, K.↗
NASA NTRS1992

Classification of four ordinary chondrites from the Monnig Meteorite Collection

We classified four ordinary chondrites from the Monnig Meteorite Collection into compositional groups, petrologic types and shock stages, based on optical microscopy in transmitted and reflected light, and electron microprobe and modal analyses. These meteorites are Allen, Texas, H4(S2): May Day, Kansas, H4(S2); Pony Creek, Texas, H4(S3); and Springer, Oklahoma, H5(S3).

Ehlmann, Arthur J.↗
NASA NTRS1992

Mechanisms of compressive failure in 3D composites

The present study of angle-interlock woven polymer matrix composite behavior under uniaxial monotonic compression notes these materials to be macroscopically ductile, with compressive strains in failure that can exceed 15 percent. Some of the tests conducted on stitched laminates indicated brittle behavior. Woven composite failure mechanisms have been studied by a combination of optical microscopy, moire interferometry, stereoscopy, and digital image comparisons; the critical failure event was in all cases a kink band formation in the primary load-bearing axial rows.

Cox, B. N.↗
NASA NTRS1992

Shock metamorphism of carbonaceous chondrites

Shock effects were studied in 69 carbonaceous chondrites, including CM2, CO3, CV3, ungrouped C2-C4, and CK4-6 chondrites, using optical microscopy of thin sections. It is shown that the classification scheme of Stoeffler et al. (1991) for the progressive stages of shock metamorphism in ordinary chondrites is also applicable to carbonaceous chondrites. On the basis of shock effects in olivine, the 69 carbonaceous chondrites could be assigned to four shock stage, S1 to S4. The CM2 and CO3 groups were found to be the least shocked chondrite groups, whereas the CK4-6 and CV3 were the most strongly shocked groups.

Scott, Edward R. D.↗
NASA NTRS1993

Mineralogy of three slightly palagonitized basaltic tephra samples from the summit of Mauna Kea, Hawaii

The paper characterizes the mineralogy and spectral properties of three slightly palagonitized basaltic tephra samples collected near the summit of Mauna Kea in order to contribute to the basis for inferring mineralogy and processes for Martian surface materials. The mineralogy of size fractions of these samples is examined by diffuse reflectance and FIR spectroscopy, optical microscopy, X-ray diffraction, Moessbauer spectroscopy, magnetic analysis, EMPA, TEM, and SEM. For the 20-1000 micron size fraction, sample HWMK11 (red) is essentially completely oxidized and has a hematite (Ti-hematite) pigment dispersed throughout the silicate matrix. Sample HWMK12 (black) has the lowest proportion of ferric-bearing phases and is thus least weathered. For HWMK11, the amount of hematite is essentially constant, and mica is present only in the coarse clay-sized fraction; smectites are low in structural Fe.

Golden, D. C.↗