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At least 235 records · Page 13

Hairlike Percutaneous Photochemical Sensors

Instrumentation systems based on hairlike fiber-optic photochemical sensors have been proposed as minimally invasive means of detecting biochemicals associated with cancer and other diseases. The fiber-optic sensors could be mass-produced as inexpensive, disposable components. The sensory tip of a fiber-optic sensor would be injected through the patient's skin into subcutaneous tissue. A biosensing material on the sensory tip would bind or otherwise react with the biochemical(s) of interest [the analyte(s)] to produce a change in optical properties that would be measured by use of an external photonic analyzer. After use, a fiber-optic sensor could be simply removed by plucking it out with tweezers. A fiber-optic sensor according to the proposal would be of the approximate size and shape of a human hair, and its sensory tip would resemble a follicle. Once inserted into a patient's subcutaneous tissue, the sensor would even more closely resemble a hair growing from a follicle (see Figure 1). The biosensing material on the sensory tip could consist of a chemical and/or cells cultured and modified for the purpose. The biosensing material would be contained within a membrane that would cover the tip. If the membrane were not permeable by an analyte, then it would be necessary to create pores in the membrane that would be large enough to allow analyte molecules to diffuse to the biosensing material, but not so large as to allow cells (if present as part of the biosensing material) to diffuse out. The end of the fiber-optic sensor opposite the sensory tip would be inserted in a fiberoptic socket in the photonic analyzer.

George, Thomas↗

Two new methods to increase the contrast of track-etch neutron radiographs

Methods for increasing the (optical density span) of radiographs were evaluated. In one method, fluorescent dye was deposited in the tracks of the radiograph. The radiograph was then examined under ultraviolet light. The second method was a crossed Polaroid filter technique. The radiograph was placed between the filters and then illuminated with a diffuse white-light source. An increase in the optical density span from .10 to .37 was obtained with the dye method. With the Polaroid method, the increase obtained was from .10 to 2.4.

Morley, J.↗

Degradation of MODIS Optics and its Reflective Solar Bands Calibration

The MODerate Resolution Imaging Spectroradiometer (MODIS) has 36 spectral bands with wavelength ranging from 0.41 micron to 14.5 micron and spatial resolution between 0.25, 0.5, and 1.0 km at Nadir. Its ProtoFlight Model (PFM) on the NASA EOS Terra spacecraft has been providing global coverage of the Land, Ocean, and Atmosphere for the science community since the instrument opened its Nadir door on 24 February 2000. The MODIS optical system consists of a 2-sided paddle wheel scan mirror, a fold mirror, a primary mirror, and other aft optics. The sensor's 20 reflective solar bands from 0.41 to 2.1 micron are calibrated on-orbit by a solar diffuser (SD) and a solar diffuser stability monitor (SDSM). In addition to SD, degradation of the MODIS optics in the reflective solar bands has been observed, including variations in degradation between the two sides of the MODIS scan mirror. During MODIS first year of on-orbit operation, the overall degradations at the shortest wavelength (0.41 micron) are about 3% for SD, and in excess of 10% for the MODIS system. In this paper, we will present our degradation analysis results and discuss their impact on the reflective solar bands' on-orbit calibration.

Xiong, X.↗

A Tracking Sun Photometer Without Moving Parts

This innovation is small, lightweight, and consumes very little electricity as it measures the solar energy attenuated by gases and aerosol particles in the atmosphere. A Sun photometer is commonly used on the Earth's surface, as well as on aircraft, to determine the solar energy attenuated by aerosol particles in the atmosphere and their distribution of sizes. This information is used to determine the spatial and temporal distribution of gases and aerosols in the atmosphere, as well as their distribution sizes. The design for this Sun photometer uses a combination of unique optics and a charge coupled device (CCD) array to eliminate moving parts and make the instrument more reliable. It could be selfcalibrating throughout the year. Data products would be down-welling flux, the direct-diffuse flux ratio, column abundance of gas phase constituents, aerosol optical depth at multiple-wavelengths, phase functions, cloud statistics, and an estimate of the representative size of atmospheric particles. These measurements can be used to obtain an estimate of aerosol size distribution, refractive index, and particle shape. Incident light is received at a light-reflecting (inner) surface, which is a truncated paraboloid. Light arriving from a hemispheric field of view (solid angle 2 steradians) enters the reflecting optic at an entrance aperture at, or adjacent to, the focus of the paraboloid, and is captured by the optic. Most of this light is reflected from an inner surface. The light proceeds substantially parallel to the paraboloid axis, and is detected by an array detector located near an exit aperture. Each of the entrance and exit apertures is formed by the intersection of the paraboloid with a plane substantially perpendicular to the paraboloid axis. Incident (non-reflected) light from a source of limited extent (the Sun) illuminates a limited area on the detector array. Both direct and diffuse illumination may be reflected, or not reflected, before being received on the detector array. As the Sun traverses a path in the sky over some time interval, the track of the Sun can be traced on the detector array. A suitably modified Sun photometer might be used to study the dynamics of an environment on another planet or satellite with an atmosphere.

Strawa, Anthony W.↗

Optical image subtraction techniques, 1975-1985

Real- and nonreal-time optical image subtraction (OIS) techniques are reviewed. Real-time OIS techniques include source encoding, polarization modulation, pseudocolor image difference detection, the holographic shear lens technique, and nonlinear optics. Included in the nonreal-time category are speckle diffuser encoding, speckle-pattern encoding, halftone screen encoding, and polarization-shifted encoding. It is concluded that the most useful techniques are the real-time operations. It is noted that some nonreal-time optical techniques can be applied directly while others may be converted into real-time ones through the use of advance real-time spatial light modulators or electrooptic devices.

Liu, Hua-Kuang↗

Optical properties of carbonaceous chondrites and their relationship to asteroids

Results of diffuse reflectance measurements of nine samples of carbonaceous chondrites (one C1, three C2, four C3, and one C4) and one iron meteorite, Odessa. Measurements were also made of mineral mixtures in an attempt to understand the cause of some features of the meteorite reflectances. The C1 and C2 carbonaceous chondrites have reflectances low enough to match the anomalously low albedos of some asteroids. Some asteroids have spectral reflectances similar to carbonaceous chondrites, whereas others with flat or F-type curves appear to match simulated mineral mixtures with slightly greater amounts of the carbonaceous component than those found in the meteorites. This observation suggests either that surface physical processes such as melting may be enhancing the optical effect of opaque carbonaceous material on some asteroid surfaces and/or that these asteroids contain even more carbonaceous material than the C1 meteorites.

Johnson, T. V.↗

Optical Flow-Field Techniques Used for Measurements in High-Speed Centrifugal Compressors

The overall performance of a centrifugal compressor depends on the performance of the impeller and diffuser as well as on the interactions occurring between these components. Accurate measurements of the flow fields in each component are needed to develop computational models that can be used in compressor design codes. These measurements must be made simultaneously over an area that covers both components so that researchers can understand the interactions occurring between the two components. Optical measurement techniques are being used at the NASA Lewis Research Center to measure the velocity fields present in both the impeller and diffuser of a 4:1 pressure ratio centrifugal compressor operating at several conditions ranging from design flow to surge. Laser Doppler Velocimetry (LDV) was used to measure the intrablade flows present in the impeller, and the results were compared with analyses obtained from two three-dimensional viscous codes. The development of a region of low throughflow velocity fluid within this high-speed impeller was examined and compared with a similar region first observed in a large low-speed centrifugal impeller at Lewis. Particle Image Velocimetry (PIV) is a relatively new technique that has been applied to measuring the diffuser flow fields. PIV can collect data rapidly in the diffuser while avoiding the light-reflection problems that are often encountered when LDV is used. The Particle Image Velocimeter employs a sheet of pulsed laser light that is introduced into the diffuser in a quasi-radial direction through an optical probe inserted near the diffuser discharge. The light sheet is positioned such that its centerline is parallel to the hub and shroud surfaces and such that it is parallel to the diffuser vane, thereby avoiding reflections from the solid surfaces. Seed particles small enough to follow the diffuser flow are introduced into the compressor at an upstream location. A high-speed charge-coupled discharge (CCD) camera is synchronized to the laser pulse rate; this allows it to capture images of seed particle position that are separated by a small increment in time. A crosscorrelation of a particle's position in two consecutive images provides an estimate of flow velocity and direction. Multiple image pairs obtained in rapid succession at a particular flow condition provide enough measurements for statistical significance. PIV provides simultaneous velocity measurements over the entire plane that is illuminated by the light sheet instead of at a single point, as is the case when LDV is used. PIV has a further advantage in that the laser light pulse can be triggered by an external source such as a high-response pressure transducer. This feature will allow PIV to synchronize flow imaging to physical phenomena such as rotating stall or stall precursor waves. We hope that this technique can be used to obtain images of the flow field during and just prior to stall.

Skoch, Gary J.↗

Computational and Experimental Study of Energetic Material in a Counterflow Microgravity Environment

Ground based (normal gravity) combustion studies can provide important information on the processes by which monopropellants and composite systems burn. The effects of gravitational forces, however, can often complicate the interpretation of the models and the implementation of experiments designed to help elucidate complex issues. We propose to utilize a combined computational/experimental approach in a microgravity environment to understand the interaction of oxidizer-binder diffusion flames in composite propellants. By operating under microgravity conditions we will be able to increase the length scales and suppress the gravitational forces on melting binders such that increased resolution of both major and minor species will be possible thus reducing the demands placed on both the computational and diagnostic tools. Results of a detailed transport/finite rate chemistry model will be compared with nonintrusive optical diagnostic measurements of the structure and extinction of diffusion flames in which oxidizers such as ammonium perchlorate (AP) and ammonium dinitramide (ADN) are counterflowed against realistic binders such as hydroxyl-terminated polybutadiene (HTPB) and 3,3-bis(azidomethyl)oxetane (BAMO). The work proposed herein represents a collaborative effort among the research groups at Yale University, Princeton University and the Combustion Diagnostics Laboratory at the Naval Air Warfare Center in China Lake, CA.

Smooke, Mitchell D.↗

Surface and Atmospheric Shortwave Radiative Fluxes From ISCCP Data and Fu-Liou Algorithm at Higher Spatial and Vertical Resolution

NASA/GEWEX Surface Radiation Budget (SRB) has provided surface and TOA shortwave and longwave radiative fluxes using International Satellite Cloud Climatology data as the primary input. Release 4.0 came out in 2019, with data from July 1983 through June 2017, and improved validation stats relative to Release 3.0 (Stackhouse et al., 2012). Release 4.0 used the newly reprocessed ISCCP H data set. The shortwave algorithm for versions 3 and 4 has been based on the Pinker and Laszlo (1992) algorithm, which relies on the satellite-measured shortwave radiance to produce a TOA albedo. This background TOA albedo is made utilizing the background clear-sky visible radiance (called clear-sky composite radiance in the ISCCP data) and applying narrowband-to-broadband angular distribution models. Using a climatological aerosol assumption, the surface albedo is estimated using radiative transfer based (i.e., Fu/Liou radiative transfer model; Fu and Liou, 1993) look-up tables. Using this surface albedo and an instantaneous TOA albedo, the look-up tables are used to adjust both the aerosol optical depth (for clear sky) and cloud optical depth (for cloudy sky) for each scene. These properties and look up tables are then used to generate surface fluxes. While this has worked well to provide useful fluxes, it has occasionally resulted in inaccurate direct and diffuse surface SW fluxes due to the overreliance on aerosol optical depth. With increased computational power and storage now available, a more direct approach is now possible. Here we present a different approach for a future high resolution SRB Release 5.0. We replace the Pinker-Laszlo lookup table approach with a forward call to the Fu-Liou radiative transfer model as modified by the CERES team (Rose et al., 2006). In addition to being a proven radiation code, Fu-Liou allows the calculation of fluxes at different atmospheric levels and spectral bands, which will provide more insight into the surface radiation budget, its variability and attribution. It is expected that horizontal resolution will increase to at least 0.5°x0.5° from the current 1°x1°. Here we demonstrate a preliminary look at the next SRB, and show comparisons with the current release.

Earth Radiation Budget↗

Macro-level mechanical interlocking: A rapid joining approach for additively manufactured compression molded composite panels

Composite joining typically involves multiple steps, such as drilling and surface treatment, as part of the manufacturing process, which leads to low throughput and long cycle times. In the present study, we demonstrated a macro-level mechanical interlocking (MI) based, rapid joining technique to assemble additively manufactured compression molded (AMCM) panels, enabling the production of parts larger than the mold dimensions. Composite panels made of 20 wt% short carbon fiber reinforced acrylonitrile butadiene styrene (CF/ABS) were joined using MI features of various geometries, namely tree (TR), dovetail (Dov), rectangle 2 (Rect2), and rectangle 1 (Rect1), and their in-plane strength was evaluated. The resultant strength of the tested MI joints reached up to 74 % of the baseline tensile strength (i.e., the ‘no joint’ case). Observations from optical and scanning electron microscopy revealed inadequate polymer diffusion between the adherends, indicating that the joint strength was primarily derived from mechanical interlocking. Additionally, the fracture surfaces exhibited stress-whitening marks, which were characterized using differential scanning calorimetry (DSC). The increase in melting enthalpy suggested local stretching of polymer chains due to MI. Finite element analysis (FEA) indicated that the Rect1 MI feature, which generated the lowest stress concentration, outperformed the others in terms of joint strength, achieving 42 MPa. As a demonstration of the MI joining method, a battery box tray measuring 108 cm × 34 cm using a mold with an effective dimension of 36 cm × 34 cm successfully manufactured, resulting in a part with an area three times larger than the mold. In conclusion, this study presents a promising approach to improving composite joining techniques while minimizing production complexities.

In-plane joining↗

Electrode Modification by Laser Ablation to Overcome Mechanical and Scalability Limitations of Solid-State Prealkylation of Electrode Architectures

In this work, laser ablation of Si electrode surfaces is utilized to provide localized strain relief during the Solid State Prealkylation of Electrode Architectures (SPEAR) process, in addition to volumetric expansion relief in the form of free volume channels across the electrode. A hexagonal mesh patterning was employed via laser ablation, where the hexagonal diameter (pitch) was varied from 250 to 1000 µm. It was demonstrated that these channels serve as expansion voids, accommodating the increase in electrode thickness observed during SPEAR and preventing cracking at the electrode surface. Optical microscopy and Raman mapping confirm that Li diffusion is the rate-limiting solid-state process, requiring a 24 h rest period to achieve homogeneous LixSi alloying through the electrode bulk. Electrochemical evaluations in full cells show that a 1000 μm pitch pattern yields a high initial discharge capacity of 2485 mA h g–1 and 86.4% capacity retention after 80 cycles, whereas smaller pitches (<500 μm) result in lithium plating at 4.1 V in full cells paired with NMC 811 due to excessive current collector exposure from the ablation process. XPS analysis reveals that the laser treatment modifies the electrode surface by increasing the Si–O and C–O species, changing the SEI composition observed via an increase in fluorophosphates upon cycling.

Musgrove, Amanda [ORNL] (ORCID:0009000220910389)↗

Absorption of energetic protons by Saturn's Ring G

A reexamination of Pioneer 11 data for the distribution of energetic protons in Saturn's inner magnetosphere has yielded an improved value for the ratio of the cosmic ray albedo neutron decay source strength to the radial diffusion coefficient, and the use of the Blake et al. (1983) lower limit on the source strength is used to find an upper limit on the mean residence time against diffusion. By means of Voyager data on normal optical opacity and radial width, it is found that the particulates in Saturn's Ring G have an efective radius of more than about 0.035 cm, an areal mass density of 1.4 x 10 to the -6th g/sq cm, and an areal number density of 0.008/sq cm. It is reasonably certain that there are no satellites having a radius of the order of 1 km or larger associated with Ring G.

Van Allen, J. A.↗

Infrared observations of the Uranian rings

Maps of the Uranian rings at 2.2 microns and spectrophotometric observations covering 2.0 to 2.4 and 2.9 to 3.9 microns are discussed. The maps reveal a 2:1 azimuthal brightness variation whose amplitude and phase are consistent with the width variation and apsidal precession of the epsilon ring. Comparison with models based on stellar occultation data leads to an upper limit of 0.01 on the normal optical depth of any broad (5000 km wide), diffuse component of the ring system. A significant east-west asymmetry, corresponding to a brightening of the near side of the rings relative to the far side, is unexplained. The spectrum of the rings is flat over the range 2.1 to 3.9 microns. There is no spectroscopic evidence for the presence of H2O.

Nicholson, P. D.↗

Mass and energy balance of the cold Io torus

A new model of the cold Io torus is described. Ions and energy are injected into the system by independent processes so that the mass balance is isolated from the energy balance. The primary source of energy is local ionization and acceleration of hot pickup ions resulting from charge exchange between thermal ions and an extended cloud of Iogenic sulfur and oxygen atoms. The primary energy loss mechanism of the plasma is collisionally excited line emission at optical wavelengths. The primary ion source is radial diffusion inward from the hot torus on a time scale of 140-710 days. The primary ion loss mechanism is a novel two-step enhanced recombination mechanism involving charge exchange between thermal ions and an extended cloud of neutral SO2 molecules, followed by rapid dissociative recombination of the resultant molecular ion. The model provides a self-consistent solution which reconciles a number of diverse observations with known physical processes.

Moreno, M. A.↗

The split-cross-bridge resistor for measuring the sheet resistance, linewidth, and line spacing of conducting layers

A new test structure was developed for evaluating the line spacing between conductors on the same layer using an electrical measurement technique. This compact structure can also be used to measure the sheet resistance, linewidth, and line pitch of the conducting layer. Using an integrated-circuit fabrication process, this structure was fabricated in diffused polycrystalline silicon and metal layers and measured optically and electrically. For the techniques used, the optical measurements were typically one-quarter micron greater than the electrical measurements. Most electrically measured line pitch values were within 2 percent of the designed value. A small difference between the measured and designed line pitch is used to validate sheet resistance, linewidth, and line spacing values.

Buehler, M. G.↗

Muon motion in titanium hydride

Motional narrowing of the transverse-field muon spin rotation signal was observed in gamma-TiH(x) for x = 1.83, 1.97, and 1.99. An analysis of the data for TiH1.99 near room temperature indicates that the mechanism responsible for the motion of the muon out of the octahedral site is thermally activated diffusion with an attempt frequency comparable to the optical vibrations of the lattice. Monte Carlo calculations to simulate the effect of muon and proton motion upon the muon field-correlation time were used to interpret the motional narrowing in TiH1.97 near 500 K. The interpretation is dependent upon whether the Bloembergen, Purcell, and Pound (BPP) theory or an independent spin-pair relaxation model is used to obtain the vacancy jump rate from proton NMR T1 measurements. Use of BPP theory shows that the field-correction time can be obtained if the rate of motion of the muon with respect to the rate of the motion for the protons is decreased. An independent spin-pair relaxation model indicates that the field-correlation time can be obtained if the rate of motion for the nearest-neighbor protons is decreased.

Kempton, J. R.↗

Fiber-optic projected-fringe digital interferometry

A phase-stepped projected-fringe interferometer was developed which uses a closed-loop fiber-optic phase-control system to make very accurate surface profile measurements. The closed-loop phase-control system greatly reduces phase-stepping error, which is frequently the dominant source of error in digital interferometers. Two beams emitted from a fiber-optic coupler are combined to form an interference fringe pattern on a diffusely reflecting object. Reflections off of the fibers' output faces are used to create a phase-indicating signal for the closed-loop optical phase controller. The controller steps the phase difference between the two beams by pi/2 radians in order to determine the object's surface profile using a solid-state camera and a computer. The system combines the ease of alignment and automated data reduction of phase-stepping projected-fringe interferometry with the greatly improved phase-stepping accuracy of our closed-loop phase-controller. The system is demonstrated by measuring the profile of a plate containing several convex surfaces whose heights range from 15 to 25 micron high.

Mercer, Carolyn R.↗

FIRE extended time/limited area observations at Palisades, New York

Downwelling shortwave and longwave irradiation are being continuously monitored at Palisades, New York as part of the First International Satellite Cloud Climatology Project (ISCCP) Regional Experiment (FIRE) Extended Time/Limited Area Initiative. In addition, fisheye (180 degree) sky photographs are taken at the times of NOAA 9 and LANDSAT satellite overpasses on select days, particularly when cirrus clouds are present. Measurements of incoming shortwave (0.28 to 2.80 microns) hemispheric and diffuse, hemispheric near infrared (0.7 to 2.80 microns), and downwelling hemispheric infrared (4.0 to 50.0 microns) irradiation have been made from a rooftop location on the grounds of the Lamont-Doherty Geological Observatory since December 1986. The three Eppley Precision Spectral Pyranometers and the Eppley Pyrgeometer used to measure these variables were calibrated with Colorado State University instruments at Madison, Wisconsin as part of the FIRE Intensive Laboratory. Pyrgeometer output contains an adjustment for body temperature but not for dome temperature. Data are transmitted to a Campbell CR-21 Digital Recorder, where one minute averages of ten second samples are stored and subsequently dumped to a cassette recorder. Using a Campbell C-20 Cassette Interface, these data are transferred to an Apple Macintosh computer for analysis and for archiving on floppy disks. In addition to the raw irradiances collected, variables derived from these data are generated and stored. These include: the ratio of near infrared irradiation to visible irradiation and the fraction of the full shortwave irradiation which is diffuse; and will soon include: shortwave transmissivity and optical depth in the shortwave. Sky photographs are taken with an Olympus OM2-N 35 mm camera and are timed to be coincident with overpassing NOAA and LANDSAT satellites. Palisades is within the field of view of the NOAA 9 daily in the middle to late afternoon. The satellite viewing angle is within 45 degrees of nadir over Palisades on approximately half of the passes.

Robinson, David A.↗