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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

A reexamination of amino acids in lunar soil

Amino acids in lunar soils provide an important indicator of the level of prebiotic organic compounds on the moon. The results provide insight into the chemistry of amino acid precursors, and furthermore, given the flux of carbonaceous material to the moon, we can evaluate the survival of organics upon impact. The amino acid contents of both hydrolyzed and unhydrolyzed hot-water extracts of Apollo 17 lunar soil were determined using ophthaldialdehyde/N-acetyl cysteine (OPA/NAC) derivatization followed by HPLC analysis. Previous studies of lunar amino acids were inconclusive, as the technique used (derivatization with ninhydrin followed by HPLC analysis) was unable to discriminate between cosmogenic amino acids and terrestrial contaminants. Cosmogenic amino acids are racemic, and many of the amino acids found in carbonaceous meteorites such as Murchison, i.e., alpha-amino-i-butyric acid (aib), are extremely rare on Earth. The ninhydrin method does not distinguish amino acid enantiomers, nor does it detect alpha-alkyl amino acids such as aib, whereas the OPA/NAC technique does both.

Brinton, K. L. F.↗
NASA NTRS1998

Chemically Derived Dense Alumina-Zirconia Composites for Improved Mechanical and Wear Erosion Properties

As a result of this funded project high purity Zirconia-Toughened Alumina (ZTA) ceramic powders with and without yttria were produced using metal alkoxide precursors. ZTA ceramic powders with varying volume percents of zirconia were prepared (7, 15, and 22%). Aluminum tri-sec butoxide, zirconium propoxide, and yttrium isopropoxide were the reagents used. Synthesis conditions were varied to control the hydrolysis and the aging conditions for the sol to gel transition. FTIR analysis and rheological characterization were used to follow the structural evolution during the sol to gel transition. The greater extent of hydrolysis and the build-up of structure measured from viscoelastic properties were consistent. Heat treatment was conducted to produce submicron grain fully crystalline ZTA ceramic powders. This improved materials should have enhanced properties such strength, toughness, and wear resistance for advanced structural applications, for example engine components in high technology aerospace applications.

Source record↗
NASA NTRS1998

Characterization of the Sol-Gel Transition for Zirconia-Toughened Alumina Precursors

High purity ZTA ceramic powders with and without yttria were produced using metal alkoxide precursors. ZTA ceramic powders with varying volume percents of zirconia were prepared (7, 15, and 22%). Aluminum tri-sec butoxide, zirconium propoxide, and yttrium isopropoxide were the reagents used. Synthesis conditions were varied to control the hydrolysis and the aging conditions for the sol to gel transition. FTIR analysis and theological characterization were used to follow the structural evolution during the sol to gel transition. The greater extent of hydrolysis and the build-up of structure measured from viscoelastic properties were consistent. Heat treatment was conducted to produce submicron grain fully crystalline ZTA ceramic powders. In all experimental cases a-alumina and tetragonal zirconia phases were confirmed even in the absence of yttria.

Moeti, I.↗
NASA NTRS2011

NASA's Human Mission to a Near-Earth Asteroid: Landing on a Moving Target

This paper describes a Bayesian approach for comparing the productivity and cost-risk tradeoffs of sending versus not sending one or more robotic surveyor missions prior to a human mission to land on an asteroid. The expected value of sample information based on productivity combined with parametric variations in the prior probability an asteroid might be found suitable for landing were used to assess the optimal number of spacecraft and asteroids to survey. The analysis supports the value of surveyor missions to asteroids and indicates one launch with two spacecraft going simultaneously to two independent asteroids appears optimal.

precursor decision making↗
NASA NTRS2020

The Flexible Lunar Architecture for Exploration (FLARE): Designed for the Artemis-3 Moon 2024 Mission and Beyond

The Flexible Lunar Architecture for Exploration (FLARE) is a concept to deliver four crew to the lunar surface for 7 to 14 days and then return them safely to Earth by 2024. This meets NASA’s internal 2024 lunar landing deadline directed by President Trump (Trump, 2017) and the “5-year” goal set forth by Vice President Pence (Pence, 2019). FLARE is an alternative to NASA’s Human Landing System reference architecture from the Design Analysis Cycle (DAC) #2 (NASA, 2019b). The minimum FLARE concept uses one Space Launch System launch, one Orion, one European Service Module (ESM), and one human lander to deliver four crew to the Moon for a minimum surface duration of 7 days and return them to Earth. FLARE adds a new capability, called the SpaceTug, based upon the mature and successful United Launch Alliance “Common” Centaur Upper Stage vehicle, with modifications. In FLARE, the SpaceTug provides propulsion needed to return the Orion+ESM from the Moon to Earth. The SpaceTug also provides propulsion to deliver the human lander Descent Element (DE) and Ascent Element (AE) separately to lunar orbit. The Orion+ESM then completes a rendezvous with the mated DE+AE in lunar orbit. FLARE also offers optional phases to the Moon 2024 mission. The SpaceTug can also deliver components of the planned Gateway - including the Power and Propulsion Element and the Habitation and Logistics Outpost - to lunar orbit; however, the planned FLARE destination is a Low Lunar Frozen Polar Orbit unlike the NASA DAC2 plan for a Near Rectilinear Halo Orbit. FLARE also provides an option to deliver precursor equipment - including a habitation module, crew mobility devices and an In-Situ Resource Utilization demonstration - to the lunar surface for enhanced crew exploration and science with the extended 14-day surface mission.

Commercial Launch Vehicles (CLV)↗
NASA NTRS1978

IPS activity observed as a precursor of solar induced terrestrial activity

A radio telescope designed to exploit the interplanetary scintillation (IPS) technique and locate, map, and track solar wind disturbances which result in geomagnetic disturbances, thereby providing a forecast capability, is described. Preliminary results from operation of the telescope include: (1) evidence for a precursor signal in the IPS activity with a 1-2 day lead time with respect to density enhancements which frequently give rise to geomagnetic activity; (2) detection of a spectral broadening signature which also serves as a precursor of geomagnetic activity; (3) out-of-the-ecliptic plasma density enhancements which were not detected by near-Earth, ecliptic plane spacecraft; (4) detection of 12 corotating density enhancements;(5) detection of over 80 sources which give detectable scintillation of which 45 have been used for detailed synoptic analysis and 9 for spectral analysis; and (6) measurement of 0-lag coefficient of 0.56 between density and IPS activity enhancements.

Cronyn, W. M.↗
NASA NTRS2008

Verification of Atmospheric Signals Associated with Major Seismicity by Space and Terrestrial Observations

Observations from the last twenty years suggest the existence of electromagnetic (EM) phenomena during or preceding some earthquakes [Haykawa et a!, 2004; Pulinets at al, 1999,2004, 2006, Ouzounov et all 2007 and Liu et all 20041. Both our previous studies [Pulinets at al, 2005, 2006, Ouzounov et al, 2006, 20071 and the latest review by the Earthquake Remote Precursor Sensing panel [ERPS; 2003- 20051; have shown that there were precursory atmospheric TIR signals observed on the ground and in space associated with several recent earthquakes. [Tramutoli at al, 2005, 2006, Cervone et al, 2006, Ouzounov et all 2004,2006JT.o study these signals, we applied both multi parameter statistical analysis and data mining methods that require systematic measurements from an Integrated Sensor Web of observations of several physical and environmental parameters. These include long wave earth infra-red radiation, ionospheric electrical and magnetic parameters, temperature and humidity of the boundary layer, seismicity and may be associated with major earthquakes. Our goal is to verify the earthquake atmospheric correlation in two cases: (i) backward analysis - 2000-2008 hindcast monitoring of multi atmospheric parameters over the Kamchatka region, Russia ; and (ii) forward real-time alert analysis over different seismo-tectonic regions for California, Turkey, Taiwan and Japan. Our latest results, from several post-earthquake independent analyses of more then 100 major earthquakes, show that joint satellite and some ground measurements, using an integrated web, could provide a capability for observing pre-earthquake atmospheric signals by combining the information from multiple sensors into a common framework. Using our methodology, we evaluated and compared the observed signals preceding the latest M7.9 Sichuan earthquake (0511212008), M8.0 earthquake in Peru (0811512007), M7.6 Kashmir earthquake (1010812005) and M9.0 Sumatra earthquake (1212812004). We found evidence of the systematic appearance of both atmospheric and ionospheric anomalies preceding most of the major events during the period of our analysis 2001 -2008.

Taylor, Patrick↗
NASA NTRS1979

Satellite Power Systems (SPS) concept definition study, exhibit C. Volume 5: Special emphasis studies

Specific areas were analyzed and identified as high priority for more in-depth analysis. These areas were: (1) rectenna constructability; (2) satellite constructability; (3) support systems constructability; (4) space environmental analysis, and (5) special end-to-end analyses. Baseline requirements specified coplanar solar blankets and an end mounted antenna, utilizing either GaAlAs solar cells and employing a CR of 2, or Si cells. Several configurations were analyzed. Utilizing the preferred configuration as a baseline, a satellite construction base was defined, precursor operations incident to establishment of orbital support facilities identified, and the satellite construction sequence and procedures developed. Since the baseline specifies sixty instead of one hundred and twenty satellites to be constructed in a thirty year period, mass flow to orbit requirements were revised and new traffic models established. Launch site requirements (exclusive of actual launch operations) in terms of manpower and building space were defined.

Hanley, G.↗
NASA NTRS1990

A polar orbit for the Mars Global Network Mission

The purpose of the Global Network Mission (GNM) is to deploy simple landers on the Martian surface in late 1998. The objective is to create a globally distributed network of ground stations which will collect environmental data, perhaps for as long as several years. The GNM presents unique mission design challenges, which are addressed by the following essay. The GNM mission concept calls for two carrier spacecraft, each equipped with a number of simple landers. Some of the landers may be deployed from approach, either to reduce carrier mass prior to orbit insertion, or to reach latitudes not available from the carrier orbit. The remaining landers are deployed from orbit. One configuration for the Global Network Mission was proposed in a report from the Exploration Precursors Task Team to the Office of Space Science and Applications. This formed the basis of a previous orbit design for the GNM. This mission scenario is used as a point of reference, but results from the current study are generally applicable to a wide range of GNM mission variants. The analysis concluded that a 1/5 sol, polar orbit with a periapse altitude of 275 km offers the best circumstances for orbital deployment of the Global Network Mission landers. It allows easy polar access at nominal entry angles, and global dispersal of landing sites at lighting angles suitable for descent imaging. The polar orbit allows the option of deploying all the landers from orbit. A wait interval of 160 days after arrival is required before deployment can commence.

Knocke, Philip↗
NASA NTRS2015

Nanoelectric Materials Laboratory Development

The Ultracapacitor Research and Development project is a collaborative effort between the NASA Marshall Space Flight Center's (MSFC's) ES43 Parts, Packaging, and Fabrication Branch and the EM41 Nonmetallic Materials Branch. NASA's Ultracapacitor Research is an effort to develop solid-state energy storage devices through processing of ceramic materials into printable dielectric inks, which can be formed and treated to produce solid state ultracapacitor cells capable of exceeding lithium-ion battery energy density at a fraction of the weight. Research and development efforts into solid state ultracapacitors have highlighted a series of technical challenges such as understanding as-received nature of ceramic powders, treatment and optimization of ceramic powders, dielectric and conductor ink formulation, and firing of printed (green) ultracapacitor cells. Two facilities have been continually developed since project inception: the Additive Electronics Lab in Bldg. 4487 and the Nanoelectric Materials Lab in Bldg. 4602. The Nanoelectric Materials Lab has become a unique facility at MSFC, capable of custom processing a wide range of media for additive electronics. As research has progressed, it was discovered that additional in-house processing was necessary to achieve smaller, more uniform particle diameters. A vibratory mill was obtained that can agitate powder and media in three directions, which has shown to be much more effective than ball milling. However, in order to understand the effects of milling, a particle size analysis system has been installed to characterize as-received and milled materials Continued research into the ultracapacitor technology included advanced milling and optimization of ceramic nanoparticles, fluidized bed treatment of atomic-layer deposition- (ALD-) coated ceramic particles, custom development of dielectric and conductor inks, as well as custom ink precursors such as polyvinylidene diflouride- (PVDF-) loaded vehicles. Experiments with graphene-based inks were also conducted.

Allen, Lee↗
NASA NTRS2018

A Possible Phase-Dependent Absorption Feature in the Transient X-Ray Pulsar SAX J2103.5+4545

We present an X-ray spectral and timing analysis of two Nuclear Spectroscopic Telescope Array (NuSTAR) observations of the transient Be X-ray binary SAX J2103.5+4545 during its 2016 April outburst, which was characterized by the highest flux since NuSTAR's launch. These observations provide detailed hard X-ray spectra of this source during its bright precursor flare and subsequent fainter regular outburst for the first time. In this work, we model the phase-averaged spectra for these observations with a negative and positive power law with an exponential cutoff (NPEX - Negative and Positive power-laws EXponential) model and compare the pulse profiles at different flux states. We found that the broadband pulse profile changes from a three-peaked pulse in the first observation to a two-peaked pulse in the second observation, and that each of the pulse peaks has some energy dependence. We also perform pulse-phase spectroscopy and fit phase-resolved spectra with NPEX to evaluate how spectral parameters change with pulse phase. We find that while the continuum parameters are mostly constant with pulse phase, a weak absorption feature at approximately 12 kiloelectronvolts which might, with further study, be classified as a cyclotron line, does show strong pulse-phase dependence.

Brumback, M.C.↗
NASA NTRS1978

A fundamental approach to adhesion: Synthesis, surface analysis, thermodynamics and mechanics

Various surface preparations for titanium 6-4 alloy were studied. An anodizing method was investigated, and compared with the results of other chemical treatments, namely, phosphate/fluoride, Pasa-Jell and Turco. The relative durability of the different surface treatments was assessed by monitoring changes in surface chemistry and morphology occasioned by aging at 505 K (450 F). Basic electron spectroscopic data were collected for polyimide and polyphenylquinoxaline adhesives and synthetic precursors. Fractographic studies were completed for several combinations of adherend, adhesive, and testing conditions.

Chen, W.↗
NASA NTRS2003

An Overview of the NASA Aviation Safety Program (AVSP) Systemwide Accident Prevention (SWAP) Human Performance Modeling (HPM) Element

An overview is provided of the Human Performance Modeling (HPM) element within the NASA Aviation Safety Program (AvSP). Two separate model development tracks for performance modeling of real-world aviation environments are described: the first focuses on the advancement of cognitive modeling tools for system design, while the second centers on a prescriptive engineering model of activity tracking for error detection and analysis. A progressive implementation strategy for both tracks is discussed in which increasingly more complex, safety-relevant applications are undertaken to extend the state-of-the-art, as well as to reveal potential human-system vulnerabilities in the aviation domain. Of particular interest is the ability to predict the precursors to error and to assess potential mitigation strategies associated with the operational use of future flight deck technologies.

Foyle, David C.↗
NASA NTRS1990

Determination of lunar ilmentite abundances from remotely sensed data

The mapping of ilmenite on the surface of the moon is a necessary precursor to the investigation of prospective lunar base sites. Telescopic observations of the moon using a variety of narrow bandpass optical interference filters are being performed as a preliminary means of achieving this goal. Specifically, ratios of images obtained using filters centered at 0.40 and 0.56 microns provide quantitative estimates of TiO2 abundances. Analysis of preliminary distribution maps of TiO2 concentrations allows identification of specific high-Ti areas. Investigations of these areas using slit spectra in the range 0.03 to 0.85 microns are underway to search for discrete spectral signatures attributable to ilmenite.

Johnson, J. R.↗
NASA NTRS1996

Sulfur and Hydrogen Isotope Anomalies in Organic Compounds from the Murchison Meteorite

Isotopic measurements have been made on organic sulfur and phosphorus compounds recently discovered in the Murchison meteorite. Carbon, hydrogen and sulfur measurements were performed on individual members of the organic sulfur compounds, alkyl sulfonates; and carbon and hydrogen measurements were made on bulk alkyl phosphonates. Cooper and Chang reported the first carbon isotopic measurements of Murchison organic sulfonates, providing insight into the potential synthetic mechanisms of these and, possibly, other organic species. Hydrogen isotopic measurements of the sulforiates now reveal deuterium excesses ranging from +660 to +2730 %. The deuterium enrichments indicate formation of the hydrocarbon portion of these compounds in a low temperature astrophysical environment consistent with that of dense molecular clouds. Measurements of the sulfur isotopes provide further constraints on the origin and mechanism of formation of these organic molecules. Recently, there has been growing documentation of sulfur isotopic anomalies in meteoritic material. Thiemens and Jackson have shown that some bulk ureilites possess excess S-33 and Thiemens et al. have reported excess S-33 in an oldhamite separate from the Norton County meteorite. Rees and Thode reported a large S-33 excess in an Allende acid residue, however, attempts to verify this measurements have been unsuccessful, possibly due to the heterogeneous nature of the carrier phase. With the recognition that sulfur isotopes may reflect chemistry in the protosolar nebula or the precursor molecular cloud, identification of potential carriers is of considerable interest. In the present study, the stable isotopes of sulfur were measured in methane sulfonic acid extracted from the Murchison meteorite. The isotopic composition was found to be: (delta)S-33 = 2.48 %, (delta)S-34 = 2.49 % and (delta)S-36 = 6.76 %. Based upon analysis of more than 60 meteoritic and numerous terrestrial samples, the mass fractionation lines are defined by Delta-33 = (delta)S-33 -0.50(delta)S-34 and Delta-36 = (delta)s-36 - 1.97 (delta)S-34. From these relationships Delta-33 = 1.24 % and Delta-36 = 0.89 % are observed. These anomalies, particularly the Delta-33, lie well outside the range of analytical uncertainty. They are the largest observed in any meteoritic component and the first found in an organosulfur compound. As discussed by Thiemens and Jackson, due to it's position on the periodic chart, sulfur undergoes chemically induced mass independent isotopic fractionations as does oxygen. Experiments by Mauersberger et. al. show that in such processes, the magnitude of fractionation for the different isotopically substituted species varies with mass and angular momentum; thus, anomalies are expected for both S-33 and S-36, but not necessarily of the same magnitude. Laboratory experiments have also confirmed that chemically produced, mass independent fractionations are mediated by molecular symmetry factors. A chemical source of fractionation requires that the sulfur isotopic anomaly was established in the gas phase, probably in reactions involving symmetric CS2. The discovery of an anomalous sulfur isotopic composition in a specific molecule containing excess deuterium is an important advance in the understanding of the cosmochemistry of sulfur. This evidence suggests that methanesulfonic acid was synthesized by interstellar processes. Further measurements and details of possible synthesis and fractionation mechanisms will be presented.

Cooper, G. W.↗
NASA NTRS2005

Space Resource Utilization and Extending Human Presence Across the Solar System

The Presidents Vision for Exploration is not a single mission, but an open ended journey that seeks to answer "How can we live on other worlds?" Using space resources is the only known approach for affordable, sustained, flexible, and self sufficient, human occupation beyond Earth orbit. Earth is a large planet. A simple analysis using the rocket equation shows that if Earth were a bit larger, chemical propulsion as a mechanism to access space would become impractical. Thus, even with the most efficient chemical rocket launch capability, the cost of lifting massive payloads into space will remain very steep (currently about $l00k/lb to the Moon and greater than $500k/lb to Mars). Space resource utilization should begin with an aggressive broad based demonstration program as afforded by the precursor missions implementation of the President's Vision of Exploration. Ion engine upper stages, for example, were studied for over 30 years, but only implemented in design after the Deep Space 1 in space demonstration. These demonstrations should include: extraction of elements from lunar regolith, and Martian soil and atmosphere, demonstration of power break even and growth from lunar or Mars moons derived photovoltaics, oxygen extraction for life support and propellant, and metals and alloys for in space repair and the production of habits and radiation shielding. Space resource utilization yields operational dividends through the subsequent programs including: propellant from lunar oxygen which could cut transportation costs from Earth in half, mega watts per year of power grown from lunar photovoltaics at decreasing cost per kW, decreased cost for human Mars missions by a factor of 10 by using propellant derived from Mars atmosphere for return, and in space manufacturing and food production with space resources yielding safe sustained and eventually self sufficient human presence in space. After the demonstration and implementation, the space resource utilization investment enables commercial and private viability beyond Earth orbit. For example, analysis has shown the lunar oxygen production for propellant becomes commercially viable after the exploration program completes the R&D, and power from lunar derived photovoltaics could, according to past NASA sponsored studies, pay for themselves while supplying most of Earth's electrical energy after about 17 years. Besides the Moon and Mars the resources of the near Earth asteroids enable the building of large space structures and science payloads. Analysis has shown that one of the thousands of these objects (some as easily accessible in space as the Moon and Mars), 2 km dia, the size of a typical open pit mine, would cost the total global financial product of Earth for 30,000 years if we were to launch it from Earth. Beyond Mars, the belt asteroids have been calculated to contain enough materials for habitat and life to support 10 quadrillion people. Thus, the development and use of space resources enables the extension of human life through the solar system allowing humanity to move from a planetary to a solar system society.

Curreri, Peter A.↗
NASA NTRS1981

V/STOL propulsion control technology

Results of a NASA sponsored study of V/STOL Propulsion Control Analysis are presented. The study involved propulsion control requirements, design concepts and procedures, and control designs for supersonic V/STOL. A variable cycle engine with a remote augmented lift system was used as a basis for establishing typical operating requirements and control concepts, and a nonlinear engine model was developed for control development as a precursor to a real-time simulation capability. A simplified aircraft model was also used to investigate transition requirements, and a long-range technology plan was developed to define subsequent program requirements for achieving a real-time piloted simulation capability.

Brown, H.↗
NASA NTRS1994

Raman structural studies of the nickel electrode

The objectives of this investigation have been to define the structures of charged active mass, discharged active mass, and related precursor materials (alpha-phases), with the purpose of better understanding the chemical and electrochemical reactions, including failure mechanisms and cobalt incorporation, so that the nickel electrode may be improved. Although our primary tool has been Raman spectroscopy, the structural conclusions drawn from the Raman data have been supported and augmented by three other analysis methods: infrared spectroscopy, powder X-ray Diffraction (XRD), and x-ray absorption spectroscopy (in particular EXAFS, Extended X-ray Absorption Fine Structure spectroscopy).

Cornilsen, Bahne C.↗