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At least 235 records · Page 13

Gaseous cometary coronal

Ground-based observations of coma emission line profiles permit direct insight into the composition and kinetic state of a cometary atmosphere and in turn provide much needed constraints in reconstructing a comet's history; the profiles themselves yield information on the mechanisms generating the observed species, while their intensities correspond to overall production rates by the nucleus. Intensities and line profiles at wavelength 6562.1A (H-alpha) and 6300.3A (O(1D) deday) were obtained for Comet Halley in the period March - April 1986 and for Comet Wilson in the period March 1987 using the Fabry-Perot optical facility at Arecibo; the Comet Halley observations have been undergoing careful analysis as the main effort of this project. Attention was centered on O(1D) 6300A observations obtained over four consecutive nights in April 1986. Surprisingly, the sorts of profiles to be expected in coma observations have not been theoretically developed in the past, necessitating a reappraisal of this question. It turns out that coma profiles vary noticeably according to excitation mechanism, and the proper interpretation of a profile requires the use of the appropriate model type. A paper cataloging the basic types and their interpretation will be submitted for publication in a few months. The intensities of the 6300A emission can be used independently to estimate the production rate of H2O by the comet nucleus; indeed, this may be the most reliable way of determining this basic quantity using ground-based facilities. The H2O production rates implied by our observations throughout the period March-April 1986 have been derived and are to be presented at the upcoming COSPAR special session Aeronomy of Comets and Outer Planets.

Atreya, Sushil K.↗

Melting rate correlation with batch properties and melter operating conditions during conversion of nuclear waste melter feeds to glasses

The rate of conversion of nuclear waste melter feed to glass is affected by the selection of melter feed materials and by melter design and operation. The melting rate correlation (MRC) is an equation that relates the glass production rate with two types of variables: (1) feed and melt properties: conversion heat, cold-cap bottom temperature, and glass melt viscosity; and (2) melter design and operation parameters: melter geometry, melter operating temperature, and gas bubbling rate. The MRC shows good agreement for an extended melting-rate data set of high-level waste (HLW) melter feeds and a data set generated for low-activity waste (LAW) melter feeds. Laboratory observation of heated melter feed samples is often used to assess the cold-cap bottom temperature of HLW melter feeds (moderately foaming feeds), but this technique appears inadequate for LAW melter feeds (vigorously foaming feeds). For LAW feeds, an adequate assessment of the cold-cap bottom temperature was achieved using evolved gas analysis, which allows identification of the collapse of primary foam for oxidized feeds. This assessment shows that the cold-cap bottom temperature for vigorously foaming LAW feeds is higher than that for moderately foaming HLW feeds. When the results of MRC are compared, LAW feeds are generally less sensitive to the bubbling rate and melt viscosity, and more sensitive to the cold-cap bottom temperature than HLW feeds. The MRC qualifies as a promising tool to support the selection of melter feed materials and melter operating conditions, which is determined from expensive independent scaled melter experiments, and sophisticated mathematical models.

Lee, Seung Min↗

Observations of the Hydrogen Cyanide in Comet 46P/Wirtanen at a 3.4 mm Wavelength

We searched for rotational lines of H{sup 12}C{sup 14}N in comet 46P/Wirtanen, using the Purple Mountain Observatory 13.7 m radio telescope. The J = 1–0 lines of HCN (3.4 mm wavelength) were unambiguously detected in 46P during the 2018 December 14–15 period, with a beam resolution of 62.″2 and a velocity resolution of ∼0.21 km s{sup −1} per channel. The molecular production rates were computed. The mean HCN(1–0) production rate of 46P was (6.45 ± 1.31) × 10{sup 24} molec s{sup −1} in the above two days. We found possible indications of time variation in the outgassing activity. The average HCN abundance relative to water Q {sub [HCN]}/Q{sub [H{sub 2O]}} of 46P was (0.09 ± 0.01)%. The HCN line shapes gave primary information on the kinematics of the cometary atmosphere. The HCN linewidths provided a direct determination of the coma expansion velocity, which was about 0.5 ± 0.05 km s{sup −1} at post-perihelion (1.056 au).

79 ASTRONOMY AND ASTROPHYSICS↗

Another look at abundance correlations among comets

Abundance correlations among comets are examined using three different data sets. The C2 and C3 production rates prove to be well correlated with CN production rates, but large scatter exists. It is concluded that a 'normal' comet is one for which Q(C3)/Q(CN) = 0.19 + or - 0.13 and Q(C2)/Q(CN) = 1.46 + or 0.68.

Cochran, Anita L.↗

Study of Material Consolidation at Higher Throughput Parameters in Selective Laser Melting of Inconel 718

Selective Laser Melting (SLM) is a powder bed fusion additive manufacturing process used increasingly in the aerospace industry to reduce the cost, weight, and fabrication time for complex propulsion components. SLM stands poised to revolutionize propulsion manufacturing, but there are a number of technical questions that must be addressed in order to achieve rapid, efficient fabrication and ensure adequate performance of parts manufactured using this process in safety-critical flight applications. Previous optimization studies for SLM using the Concept Laser M1 and M2 machines at NASA Marshall Space Flight Center have centered on machine default parameters. The objective of this work is to characterize the impact of higher throughput parameters (a previously unexplored region of the manufacturing operating envelope for this application) on material consolidation. In phase I of this work, density blocks were analyzed to explore the relationship between build parameters (laser power, scan speed, hatch spacing, and layer thickness) and material consolidation (assessed in terms of as-built density and porosity). Phase II additionally considers the impact of post-processing, specifically hot isostatic pressing and heat treatment, as well as deposition pattern on material consolidation in the same higher energy parameter regime considered in the phase I work. Density and microstructure represent the "first-gate" metrics for determining the adequacy of the SLM process in this parameter range and, as a critical initial indicator of material quality, will factor into a follow-on DOE that assesses the impact of these parameters on mechanical properties. This work will contribute to creating a knowledge base (understanding material behavior in all ranges of the AM equipment operating envelope) that is critical to transitioning AM from the custom low rate production sphere it currently occupies to the world of mass high rate production, where parts are fabricated at a rapid rate with confidence that they will meet or exceed all stringent functional requirements for spaceflight hardware. These studies will also provide important data on the sensitivity of material consolidation to process parameters that will inform the design and development of future flight articles using SLM.

Prater, Tracie↗

Study of Material Densification of In718 in the Higher Throughput Parameter Regime

Selective Laser Melting (SLM) is a powder bed fusion additive manufacturing process used increasingly in the aerospace industry to reduce the cost, weight, and fabrication time for complex propulsion components. Previous optimization studies for SLM using the Concept Laser M1 and M2 machines at NASA Marshall Space Flight Center have centered on machine default parameters. The objective of this project is to characterize how heat treatment affects density and porosity from a microscopic point of view. This is performs using higher throughput parameters (a previously unexplored region of the manufacturing operating envelope for this application) on material consolidation. Density blocks were analyzed to explore the relationship between build parameters (laser power, scan speed, and hatch spacing) and material consolidation (assessed in terms of density and porosity). The study also considers the impact of post-processing, specifically hot isostatic pressing and heat treatment, as well as deposition pattern on material consolidation in the higher energy parameter regime. Metallurgical evaluation of specimens will also be presented. This work will contribute to creating a knowledge base (understanding material behavior in all ranges of the AM equipment operating envelope) that is critical to transitioning AM from the custom low rate production sphere it currently occupies to the world of mass high rate production, where parts are fabricated at a rapid rate with confidence that they will meet or exceed all stringent functional requirements for spaceflight hardware. These studies will also provide important data on the sensitivity of material consolidation to process parameters that will inform the design and development of future flight articles using SLM.

Cordner, Samuel↗

High-Resolution Infrared Spectroscopic Measurements of Comet 2PlEncke: Unusual Organic Composition and Low Rotational Temperatures

We present high-resolution infrared spectroscopic measurements of the ecliptic comet 2P/Encke, observed on 4-6 Nov. 2003 during its close approach to the Earth, using the Near Infrared Echelle Spectrograph on the Keck II telescope. We present flux-calibrated spectra, production rates, and mixing ratios for H2O, CH3OH, HCN, H2CO, C2H2, C2H6, CH4 and CO. Comet 2P/Encke is a dynamical end-member among comets because of its short period of 3.3 years. Relative to "organics-normal" comets, we determined that 2PlEncke is depleted in HCN, H2CO, C2H2, C2H6, CH4 and CO, but it is enriched in CH3OH. We compared mixing ratios of these organic species measured on separate dates, and we see no evidence of macroscopic chemical heterogeneity in the nucleus of 2P/Encke, however, this conclusion is limited by sparse temporal sampling. The depleted abundances of most measured species suggest that 2P/Encke may have formed closer to the young Sun, before its insertion to the Kuiper belt, compared with "organics-normal" comets - as was previously suggested for other depleted comets (e.g. C/1999 S4 (LINEAR)). We measured very low rotational temperatures of 20 - 30 K for H2O, CH3OH and HCN in the near nucleus region of 2P/Encke, which correlate with one of the lowest cometary gas production rates (approx. 2.6 x 10(exp 27) molecules/s) measured thus far in the infrared. This suggests that we are seeing the effects of more efficient radiative cooling, insufficient collisional excitation, and/or inefficient heating by fast H-atoms (and icy grains) in the observed region of the coma. Its extremely short orbital period, very low gas production rate, and classification as an ecliptic comet, make 2PlEncke an important addition to our growing database, and contribute significantly to the establishment of a chemical taxonomy of comets.

Radeva, Yana L.↗

Importance of formaldehyde in cloud chemistry

A physical-chemical model which is an extension of that of Hong and Carmichael (1983) is used to investigate the role of formaldehyde in cloud chemistry. This model takes into account the mass transfer of SO2, O3, NH3, HNO3, H2O2, CO2, HCl, HCHO, O2, OH and HO2 into cloud droplets and their subsequent chemical reactions. The model is used to assess the importance of S(IV)-HCHO adduct formation, the reduction of H2O2 by HCHO, HCHO-free radical interactions, and the formation of HCOOH in the presence of HCHO in cloud droplets. Illustrative calculations indicate that the presence of HCHO inhibits sulfate production rate in cloud droplets. The direct inhibition of sulfate production rate in cloudwater due to nucleophilic addition of HSO3(-) to HCHO(aq) to form hydroxymethanesulfonate is generally low for concentrations of HCHO typical of ambient air. However, inhibition of sulfate production due to formaldehyde-free radical interactions in solution can be important. These formaldehyde-free radical reactions can also generate appreciable quantities of formic acid.

Adewuyi, Y. G.↗

Electron loss coefficients for the D-region of the ionosphere from rocket measurements during the eclipses of March 1970 and November 1966.

Observation that recombination-like electron loss coefficients measured during the March 1970 eclipse coincide with those from the November 1966 eclipse and range from 2 x 10 to the minus 7th power cu cm/sec at Z sub zero + 6 km to 0.00005 cu cm/sec at Z sub zero -2 km, where Z sub zero is the altitude of the steep gradient of electron concentration. During totality, Z sub zero was 82.5 km in 1970, and 86.8 km in 1966. For full-sun conditions, Z sub zero was 84 km on both eclipse days. Attachment-like electron loss coefficients from both eclipses are in good agreement below Z sub zero, and have a nearly constant value of about 0.008 per sec. Below Z sub zero, attachment-like loss rates agree with production rates - i.e., electron concentration is proportional to electron production.

Mechtly, E. A.↗

Diurnal observations of basal stem CO2 efflux in three canopy dominant trees in the central Amazon

We explored mechanisms responsible for disturbance-induced shifts in carbon metabolism in forests north of Manaus, Brazil (S2º 38' 17", W60º 09' 25"), using data from a selective logging experiment (BIONTE). BIONTE (the BIOmass and NuTrient Experiment) selective logging treatments were initiated in the mid-1980s and comprised variable removal of commercial tree (not total) species basal area (T1 =32%, T2 = 42%, T3 = 69%), and control plots with no logging (T0). Raw data including tree base diameter (Db), CO2 concentration versus time inside a static stem chamber, and wood density were used to derive stem respiration rates (Rw), wood production rates (Pw), and wood carbon use efficiency (CUE). Changes in tree base diameter (Db; measured at 1.3 m height, or above the buttresses) was used to calculate wood production for individual trees (Pw). Wood density enabled calculation of stem growth rate in the same units as stem respiration (mmol C m-2 s-1). Four trees were randomly selected from five tree growth rate classes for each treatment block, for a total of 20 trees per treatment block, or 80 trees total from the BIONTE plots. Each of the 80 trees selected for the Rw study were outfitted with dendrometer bands (da Silva et al. 2002). Stem respiration was measured using the method described in Chambers et al. (2004). Briefly, an infra-red gas analyzer (LiCor 820) was operated as a closed dynamic chamber with a flow rate of 1.0 L min-1. Polyvinyl chloride (PVC) semi-cylindrical chambers (250–400 mL) were secured to the tree stem near the dendrometer bands using nylon straps. The measurement interval spanned 1–2 min, and the CO2 flux from the stem of each tree was quantified using the enclosed stem area and slope of the stem CO2 concentration versus time.

54 ENVIRONMENTAL SCIENCES↗

Primary cosmic ray positrons and galactic annihilation radiation

The observation (Leventhal et al, 1978) of positron annihilation radiation at 0.511 MeV from the direction of the Galactic Center is reexamined, suggesting the possibility of a primary positron component of the cosmic rays. The observed 0.511 MeV emission requires a positron production rate nearly two orders of magnitude greater than the production rate of secondary cosmic ray positrons from pion decay produced in cosmic ray interactions. Possible sources of positrons are reviewed with both supernovae and pulsars appearing to be the more likely candidates. If only about 1% of these positrons were accelerated along with the cosmic ray nucleons and electrons to energies not less than 100 MeV, it is believed that these primary positrons would be comparable in intensity to those secondary positrons resulting from pion decay. Some observational evidence for the existence of primary positrons in the cosmic rays is also discussed.

Lingenfelter, R. E.↗

Effect of cold-cap-bottom shear stress on primary foam stability

Here, we analyze the heat transfer between the melt pool and the layer of reacting materials called cold cap, which is the determining factor for the glass production rate in Joule-heated air-bubbled nuclear waste glass melters. We consider the effects of bubbling rate, melt viscosity, melt thermal conductivity, conversion kinetics, and shear rate at the cold-cap bottom, and develop simple relationships for the cold-cap bottom temperature and glass production rate. We show that the melt convection enhances the heat transfer to the cold cap by suppressing the thermal boundary layer and primary foam, while the conversion kinetics opposes these effects. Additionally, we mention how dissolving silica particles affects the primary foam stability and discuss the limitations of the presented approach for vigorously foaming feeds.

36 MATERIALS SCIENCE↗

Massive peatland carbon banks vulnerable to rising temperatures

Peatlands contain one-third of the world’s soil carbon (C). If destabilized, decomposition of this vast C bank could accelerate climate warming; however, the likelihood of this outcome remains unknown. Here, we examine peatland C stability through five years of whole-ecosystem warming and two years of elevated atmospheric carbon dioxide concentrations (eCO 2 ). Warming exponentially increased methane (CH 4 ) emissions and enhanced CH 4 production rates throughout the entire soil profile; although surface CH 4 production rates remain much greater than those at depth. Additionally, older deeper C sources played a larger role in decomposition following prolonged warming. Most troubling, decreases in CO 2 :CH 4 ratios in gas production, porewater concentrations, and emissions, indicate that the peatland is becoming more methanogenic with warming. We observed limited evidence of eCO 2 effects. Our results suggest that ecosystem responses are largely driven by surface peat, but that the vast C bank at depth in peatlands is responsive to prolonged warming.

54 ENVIRONMENTAL SCIENCES↗

A Kuiper Belt Source for Solar Flare Track-Rich Interplanetary Dust Particles

The presence of solar flare particle tracks in mineral grains within interplanetary dust particles (IDPs) has long been accepted as proof of their extraterrestrial origin [e.g. 1]. The 10-20 micrometers diameter IDPs released by dust producing objects in the solar system (mainly comets and asteroids) spiral in towards the Sun under the influence of Poynting-Robertson (PR) drag forces [2] and accumulate solar flare energetic particle tracks during their journey. The number of IDPs with well-constrained track density measurements is small, owing to the difficulty in the measurements and the lack of appropriatelysized crystals in which to image them. In order to use track densities as a chronometer of space exposure, the track production rate must be known. All previous work relied on track production rates determined by chemical etching techniques [e.g. 3], but tracks in IDPs are measured using TEM imaging. Here we report measurements of track densities in IDPs from both the anhydrous and hydrated IDP groups. Using the track production calibration determined from TEM observations of anorthite and olivine in lunar rock 64455 [4] we estimate space exposure times for these IDPs to constrain their parent body sources.

Keller, L. P.↗

Resource Characterization to Estimate Potential for Electricity Co-Production at Blackburn Oil Field, Nevada

The U.S. Department of Energy estimates that an annual average of 25 billion barrels of hot water are produced from oil and gas wells within the United States. The thermal energy available in the co-produced water stream is usually discarded, as the produced waters are considered an inconvenience by the operators and are disposed of using injection wells. However, utilizing organic Rankine cycle (ORC) generators, a vast amount of thermal energy can be captured and converted into electricity (albeit at relatively low efficiency due to the low temperatures). The National Renewable Energy Laboratory (NREL), in collaboration with Transitional Energy and Grant Canyon Oil & Gas, evaluated the feasibility of geothermal co-production of electricity by utilizing existing oil wells in Blackburn oil field in Nevada. The once prolific Blackburn oil field is located in Pine Valley, approximately 45 miles east-southeast of Elko, Nevada. Currently, the wells targeting the highly fractured Devonian Nevada dolomite reservoir are operating at a water cut ratio of more than 99%, with individual fluid (oil and water) production rates reaching 7.4 L/s (4,021 BBL/day). Analysis of publicly available data showed that the combination of the suitable wells' maximum historical production rates reached 22.90 L/s. The production from these wells occurs naturally and the wells are choked (and even shut down) by the operator to mitigate excessive water production, indicating a strong reservoir recharge and future opportunity to increase the water production for geothermal electricity generation. The main goal of this study was to evaluate the productivity of the existing wells, the performance of the reservoir, the surface network, and the operational constraints in order to achieve 1 MWe of electricity production from the field's water production. Utilizing the GEOPHIRES tool, we have determined that a twofold to threefold increase in the total fluid production, compared to the historical production under artificial restraint (choke), is required to reach a 1-MWe net target output for a low-temperature ORC system with air-cooled condensers. Lower flow rates would be required when utilizing water-based condensers instead of air-cooled condensers. However, that would require a constant supply of cold water, which may be challenging given the arid environment of the project site.

Blackburn↗

The chlorine budget of the present-day atmosphere - A modeling study

The contribution of source gases to the total amount of inorganic chlorine (ClY) is examined analytically with a time-dependent model employing 11 source gases. The source-gas emission data are described, and the modeling methodology is set forth with attention given to the data interpretation. The abundances and distributions are obtained for all 11 source gases with corresponding ClY production rates and mixing ratios. It is shown that the ClY production rate and the ClY mixing ratio for each source gas are spatially dependent, and the change in the relative contributions from 1950 to 1990 is given. Ozone changes in the past decade are characterized by losses in the polar and midlatitude lower stratosphere. The values for CFC-11, CCl4, and CH3CCl3 suggest that they are more evident in the lower stratosphere than is suggested by steady-state estimates based on surface concentrations.

Weisenstein, Debra K.↗

On the Bur Gheluai H5 chondrite and other meteorites with complex exposure histories

Isotopic concentrations and track densities measured in 13 samples of the Bur Gheluai meteorite fall are presented. Experimental methods are described and results are presented for isotopic ratios of noble gases and cosmogenic radionuclide contents. Evidence for complex irradiation is discussed and a model for two-stage exposure histories is presented. The duration of each irradiation stage and possible effects on isotope production rates are considered. Explanations are suggested for the discrepant Ne production rates.

Vogt, S. K.↗