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Synthesis and Reactivity of Zr MOFs Assembled from P[superscript N]N[supercriptN]P-Ru Pincer Complexes
Abstract not provided
Composition Tuning of Ru-Based Phosphide for Enhanced Propane Selective Dehydrogenation
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Multifunctional Electrocatalysts: Ru–M (M = Co, Ni, Fe) for Alkaline Fuel Cells and Electrolyzers
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Triggering and Stabilizing Oxygen Redox Chemistry in Layered Li[Na[subscript 1/3]Ru[subscript 2/3]]O
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Heterogeneous Electrochemical Ammonia Oxidation with a Ru-bda Oligomer Anchored on Graphitic Electrodes via CH−π Interactions
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Mo 2 TiC 2 MXene-Supported Ru Clusters for Efficient Photothermal Reverse Water–Gas Shift
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Development of Half-Sandwich Ru, Os, Rh, and Ir Complexes Bearing the Pyridine-2-ylmethanimine Bidentate Ligand Derived from 7-Chloroquinazolin-4(3H)-one with Enhanced Antiproliferative Activity
Kinesin spindle protein (KSP) inhibitors are one of the most promising anticancer agents developed in recent years. Herein, we report the synthesis of ispinesib-core pyridine derivative conjugates, which are potent KSP inhibitors, with half-sandwich complexes of ruthenium, osmium, rhodium, and iridium. Conjugation of 7-chloroquinazolin-4(3H)-one with the pyridine-2-ylmethylimine group and the organometallic moiety resulted in up to a 36-fold increased cytotoxicity with IC 50 values in the micromolar and nanomolar range also toward drug-resistant cells. All studied conjugates increased the percentage of cells in the G 2 /M phase, simultaneously decreasing the number of cells in the G 1 /G 0 phase, suggesting mitotic arrest. Additionally, ruthenium derivatives were able to generate reactive oxygen species (ROS); however, no significant influence of the organometallic moiety on KSP inhibition was observed, which suggests that conjugation of a KSP inhibitor with the organometallic moiety modulates its mechanism of action.
Surface-Promoted Evolution of Ru-bda Coordination Oligomers Boosts the Efficiency of Water Oxidation Molecular Anodes
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Elucidating the Role of Reduction Kinetics in the Phase-Controlled Growth on Preformed Nanocrystal Seeds: A Case Study of Ru
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Ru-Catalyzed Polyethylene Hydrogenolysis under Quasi-Supercritical Conditions
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Effect of Pt and Ru-based catalysts on the electrochemical hydrodeoxygenation of phenol to cyclohexane
PtRuC offers the opportunity to electrochemically convert bio-oils to drop-in biofuels and platform chemicals. Here we demonstrate the concept using phenol to cyclohexane as a model reaction.