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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

Intensity of a weak 519-keV γ ray following β decay of the superallowed emitter 34 Ar determined via the 33 S(p,γ) 34 Cl reaction

The predominant branch in the β decay of 34 Ar is the superallowed 0 + → 0 + transition to the ground state of 34 Cl. To determine its important branching ratio one must first establish the ratios for the competing Gamow-Teller branches based on the measured intensities of γ rays subsequently emitted from the excited states they populate in 34 Cl. The strongest of these branches populates the 1 + state at 666 keV in 34 Cl, which has three possible γ-decay paths. Here, we report here a measurement of the decay of this state, which we populated via resonant proton capture in the reaction 33 S(p,γ) 34 Cl. We find that the intensity of the 519-keV γ-ray path is 1.46(19)% relative to that of the 666-keV path. This result is critical to new precise measurements of the superallowed decay of 34 Ar.

20 ≤ A ≤ 38↗

Design Principles for Resonant Wave Energy Converters: Benchmarking Power Capture and Flow

Control co-design (CCD) in Wave Energy Converters (WECs) integrates the controller, power take-off (PTO), and buoy models during system design to optimize power output. Using the bi-conjugate impedance matching principle, this study models the PTO as a two-port network, revealing impedance matching conditions at the input and output ports as a function of the buoy, PTO, and controller. Here, this study examines the pairing of a flywheel-type pitch resonator PTO within a given buoy constrained by limited space and ballast capacity. The results show that physical constraints imposed by the buoy affect PTO performance. While controller tuning achieves optimal output impedance matching and flywheel inertia is maximized within the buoy's limitations, the PTO's input impedance remains smaller than the complex conjugate of the buoy's intrinsic impedance. This mismatch limits the PTO's ability to generate sufficient reaction torque, particularly outside the resonance frequency, resulting in narrow-band power transfer. The findings emphasize the need for PTO design modifications to improve input power transfer. Pendulum-based PTO mechanisms are proposed as alternatives to couple with multiple buoy motion modes and improve wave-to-wire efficiency while respecting system constraints.

Control Co-Design↗

A flash photolysis-resonance fluorescence study of the formation of O/1D/ in the photolysis of water and the reaction of O/1D/ with H2, Ar, and He

The technique employed in the study utilizes the vacuum ultraviolet flash photolysis of H2O combined with time resolved, simultaneous detection of H and O via resonance fluorescence at 121.6 and 130.2 nm respectively. The measurements were made by means of photon counting and multichannel scaling. The sensitivity of the system for H and O is discussed. Experiments are reported in which signals due to H and O were accumulated from the flash photolysis of a mixture of 0.1 torr H2O and 100 torr Ar. Attention is given to the relative importance of two primary processes in the photolysis of water.

Stief, L. J.↗

Gas-phase synthesis of anthracene and phenanthrene via radical-radical reaction induced ring expansions

Unraveling reaction mechanisms of aromatic and resonance-stabilized radicals is critical to understanding molecular mass growth processes to polycyclic aromatic hydrocarbons (PAHs) and carbonaceous nanoparticles in distinct astrophysical environments (molecular clouds, circumstellar envelopes) and combustion systems. Using photoelectron photoion coincidence spectroscopy (PEPICO), we explored the gas-phase reaction of the methyl radical (CH 3 • ) with the aromatic and resonance-stabilized fluorenyl radical (C 13 H 9 • ) under high-temperature conditions in a chemical microreactor. Anthracene and phenanthrene were detected isomer-selectively using photoionization efficiency (PIE) curves and mass-selected threshold photoelectron (ms-TPE) spectra. While phenanthrene is produced through a radical-radical recombination of the carbon-centered radicals, anthracene may plausibly be formed through an unconventional radical addition to a low spin-density fluorenyl carbon. These pathways result in five-membered ring expansion—a critical mechanism crucial to PAH mass growth converting bent PAHs into planar nanostructures.

Goettl, Shane J. [University of Hawai‘i at Mānoa, ↗

Photoproduction of Lambda* Resonances using the CLAS Detector

This thesis presents the study of the reaction yp -> K^+Lambda* using the photo production data from the CLAS-g12 experiment performed in Hall B of Jefferson Laboratory. The decay of Lambda* resonances, Lambda(1520), Lambda(1670), and Lambda(1690), into two exclusive channels, Sigma+pi?and Sigma-pi+, is studied from the detected K+,pi+, and pi?particles. This work aims at understanding photoproduction mechanism to excited state baryons, and to facilitate phenomenological model predictions using precision experimental measurements. A good agreement is established for the Lambda(1520) differential cross sections with the previous CLAS measurements. The differential cross sections as a function of CM angle are extended to higher photon energies. Newly added are the differential cross sections as a function of invariant 4-momentum transfer, which is the natural variable to use for a theoretical model based on a Regge-exchange reaction mechanism. No new N* resonances decaying into the K+Lambda(1520) final state are found. The higher mass resonances, Lambda(1670)1/2- and Lambda(1690)3/2-, are studied for the first time using photoproduction. This work provides a model dependent preliminary cross sections for these excited states.

Shrestha, Utsav↗

Near-threshold resonances in C 11 and the B 10 ( p , α ) Be 7 aneutronic reaction

The nucleus 11 C plays an important role in the boron-proton fusion reactor environment as a catalyzer of the 10 B(p,α) 7 Be reaction which, by producing a long-lived isotope of 7 Be, poisons the aneutronic fusion process 11 B(p,2α) 4 He. The low-energy cross section of 10 B(p,α) 7 Be depends on the near-threshold states 7/2$^{+}_{1}$, 5/2$^{+}_{2}$, 5/2$^{+}_{3}$ in 11 C whose properties are primarily known from the indirect measurements. Here we investigate the continuum-coupling induced collectivization of these resonances in the shell model embedded in the continuum. We predict a significant enhancement of the 10 B(p,α) 7 Be cross section at energies accessible to the laser-driven hot plasma facilities.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Low-energy 23 Al β-delayed proton decay and 22 Na destruction in novae

The radionuclide 22 Na is a target of γ-ray astronomy searches, predicted to be produced during thermonuclear runaways driving classical novae. The 22 Na (p, γ) 23 Mg reaction is the main destruction channel of 22 Na during a nova, hence, its rate is needed to accurately predict the 22 Na yield. However, experimental determinations of the resonance strengths have led to inconsistent results. In this Rapid Communication, we report a measurement of the branching ratios of the 23 Al β-delayed protons as a probe of the key 204-keV (center-of-mass) 22 Na (p, γ) 23 Mg resonance strength. We report a factor of 5 lower branching ratio compared to the most recent literature value. The variation in 22 Na yield due to nuclear data inconsistencies was assessed using a series of hydrodynamic nova outburst simulations and has increased to a factor of 3.8, corresponding to a factor of ≈ 2 uncertainty in the maximum detectability distance. Finally, this is the first reported scientific measurement using the Gaseous Detector with Germanium Tagging system.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Absolute rate parameters for the reaction of ground state atomic oxygen with carbonyl sulfide

The rate parameters for the reaction of O(3P) with carbonyl sulfide, O(3P) + OCS yields CO + SO, have been determined directly by monitoring O(3P) using the flash photolysis-resonance fluorescence technique. The value for reaction rate was measured over a temperature range of 263-502 K and the data were fitted to an Arrhenius expression with good linearity. A comparison of the present results with those from previous studies of this reaction is also presented.

Klemm, R. B.↗

Effect of Many Modes on Self-Polarization and Photochemical Suppression in Cavities

The standard description of cavity-modified molecular reactions typically involves a single (resonant) mode, while in reality the quantum cavity supports a range of photon modes. In this work we demonstrate that as more photon modes are accounted for, physico-chemical phenomena can dramatically change, as illustrated by the cavity-induced suppression of the important and ubiquitous process of proton-coupled electron-transfer. Using a multi-trajectory Ehrenfest treatment for the photonmodes, we find that self-polarization effects become essential, and we introduce the concept of selfpolarization- modified Born-Oppenheimer surfaces as a new construct to analyze dynamics. As the number of cavity photon modes increases, the increasing deviation of these surfaces from the cavityfree Born-Oppenheimer surfaces, together with the interplay between photon emission and absorption inside the widening bands of these surfaces, leads to enhanced suppression. The present findings are general and will have implications for the description and control of cavity-driven physical processes of molecules, nanostructures and solids embedded in cavities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A laser flash photolysis kinetics study of the reaction OH + H2O2 yields HO2 + H2O

Absolute rate constants for the reaction are reported as a function of temperature over the range 273-410 K. OH radicals are produced by 266 nm laser photolysis of H2O2 and detected by resonance fluorescence. H2O2 concentrations are determined in situ in the slow flow system by UV photometry. The results confirm the findings of two recent discharge flow-resonance fluorescence studies that the title reaction is considerably faster, particularly at temperatures below 300 K, than all earlier studies had indicated. A table giving kinetic data from the reaction is included.

Wine, P. H.↗

Observation of the Exotic Isotope 13 F Located Four Neutrons beyond the Proton Drip Line

A 13 F resonance was observed following a charge-exchange reaction between a fast 13 O beam and a 9 Be target. The resonance was found in the invariant-mass distribution of 3p+ 10 C events and probably corresponds to a 5/2 + excited state. The ground state was also expected to be populated, but was not resolved from the background. The observed level decays via initial proton emissions to both the ground and first 2 + state of 12 O, which subsequently undergo 2p decay. In addition there may also be a significant proton decay branch to the second 2+ level in 12 O. The wavefunction associated with the observed level may be collectivized due to coupling to the continuum as is it located just above the threshold for proton decay to the second $2^{+}_{2}$ state of 12 O.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

$$\pi ^-p\rightarrow \eta ^{(\prime )}\, \pi ^- p$$ in the double-Regge region: Joint Physics Analysis Center

Abstract The production of $$\eta ^{(\prime )}\pi $$ η ( ′ ) π pairs constitutes one of the golden channels to search for hybrid exotics, with explicit gluonic degrees of freedom. Understanding the dynamics and backgrounds associated to $$\eta ^{(\prime )}\pi $$ η ( ′ ) π production above the resonance region is required to impose additional constraints to the resonance extraction. We consider the reaction $$\pi ^-p\rightarrow \eta ^{(\prime )} \pi ^- \,p$$ π - p → η ( ′ ) π - p measured by COMPASS. We show that the data in $$2.4< m_{\eta ^{(\prime )}\pi } < 3.0{\mathrm {\,GeV}} $$ 2.4 < m η ( ′ ) π < 3.0 GeV can be described by amplitudes based on double-Regge exchanges. The angular distribution of the meson pairs, in particular in the $$\eta ' \pi $$ η ′ π channel, can be attributed to flavor singlet exchanges, suggesting the presence of a large gluon content that couples strongly to the produced mesons.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

ESR Analysis of Polymer Photo-Oxidation

Electron-spin resonance identifies polymer-degradation reactions and their kinetics. New technique enables derivation of kinetic model of specific chemical reactions involved in degradation of particular polymer. Detailed information provided by new method enables prediction of aging characteristics long before manifestation of macroscopic mechanical properties.

Kim, Soon Sam↗

Kinetics of the Reaction of O((sup 3)P) with CF3NO

A laser flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the reaction of O((sup 3)P) with CF3NO (k(2)) as a function of temperature. Our results are described by the Arrhenius expression k(2)(T) = (4.54 +/- 0.70) x 10(exp -l2)exp[(-560 +/- 46)/T] cu cm/molecule.s (243 K is less than or equal to T is less than or equal to 424 K); errors are 2 sigma and represent precision only. The O((sup 3)P) + CF3NO reaction is sufficiently rapid that CF3NO cannot be employed as a selective quencher for O2(alpha(1) Delta-g) in laboratory systems where O((sup 3)P) and O2(alpha 1 Delta g) coexist, and where O((sup 3)P) kinetics are being investigated.

Thorn, R. P.↗

Investigation of 31 P levels near the proton threshold with nuclear resonance fluorescence and the impact on the 30 Si (𝑝,𝛾)⁢ 31 P thermonuclear rate

We investigated the nuclear structure of 31 P near the proton threshold using nuclear resonance fluorescence (NRF) to refine the properties of key resonances in the 30 Si (𝑝,𝛾)⁢ 31 P reaction, which is critical for nucleosynthesis in stellar environments. Excitation energies and spin-parities were determined for several states, including two unobserved resonances at 𝐸 𝑟 = 18.7keV and 𝐸 𝑟 = 50.5keV. The angular correlation analysis enabled the first unambiguous determination of the orbital angular momentum transfer for these states. These results provide a significant update to the 30 Si (𝑝,𝛾)⁢ 31 P thermonuclear reaction rate, with direct implications for models of nucleosynthesis in globular clusters and other astrophysical sites. The revised rate is substantially lower than previous estimates at temperatures below 200 MK, affecting predictions for silicon isotopic abundances in stellar environments. Furthermore, our work demonstrates the power of NRF in constraining nuclear properties, and provides a framework for future studies of low-energy resonances relevant to astrophysical reaction rates.

20 ≤ A ≤ 38↗