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At least 235 records · Page 13
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NASA NTRS2003

Soot Surface Growth in Laminar Hydrocarbon/Air Diffusion Flames

The structure and soot surface growth properties of round laminar jet diffusion flames were studied experimentally. Measurements were made along the axes of ethylene-, propylene-propane- and acetylene-benzene-fueled flames burning in coflowing air at atmospheric pressure with the reactants at normal temperature. The measurements included soot structure, soot concentrations, soot temperatures, major gas species concentrations, some radial species (H, OH and 0) concentrations, and gas velocities. These measurements yielded the local flame properties that are thought to affect soot surface growth as well as local soot surface growth rates. When present results were combined with similar earlier observations of acetylene-fueled laminar jet diffusion flames, the results suggested that soot surface growth involved decomposition of the original fuel to form acetylene and H, which were the main reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. Thus, as the distance increased along the axes of the flames, soot formation (which was dominated by soot surface growth) began near the cool core of the flow once acetylene and H appeared together and ended near the flame sheet when acetylene disappeared. Species mainly responsible for soot oxidation - OH and 02 were present throughout the soot formation region so that soot surface growth and oxidation proceeded at the same time. Present measurements of soot surface growth rates (corrected for soot surface oxidation) in laminar jet diffusion flames were consistent with earlier measurements of soot surface growth rates in laminar premixed flames and exhibited good agreement with existing Hydrogen-Abstraction/Carbon-Addition (HACA) soot surface growth mechanisms in the literature with steric factors in these mechanisms having values on the order of unity, as anticipated.

El-Leathy, A. M.↗
NASA NTRS1979

Determination of the ground albedo and the index of absorption of atmospheric particulates by remote sensing. I - Theory

A statistical technique is developed for inferring the optimum values of the ground albedo and the effective imaginary term of the complex refractive index of atmospheric particulates. The procedure compares measurements of the ratio of the hemispheric diffuse to directly transmitted solar flux density at the earth's surface with radiative transfer computations of the same as suggested by Herman et al. (1975). A detailed study is presented which shows the extent to which the ratio of diffuse to direct solar radiation is sensitive to many of the radiative transfer parameters. Results indicate that the optical depth and size distribution of atmospheric aerosol particles are the two parameters which uniquely specify the radiation field to the point where ground albedo and index of absorption can be inferred. Varying the real part of the complex refractive index of atmospheric particulates as well as their vertical distribution is found to have a negligible effect on the diffuse-direct ratio. The statistical procedure utilizes a semi-analytic gradient search method from least-squares theory and includes a detailed error analysis.

King, M. D.↗
NASA NTRS1989

Atmospheric correction of high resolution land surface images

Algorithms to correct for atmospheric-scattering effects in high-spatial resolution land-surface images require the ability to perform rapid and accurate computations of the top-of-atmosphere diffuse radiance field for arbitrarily general surface reflectance distributions (which may be both heterogeneous and non-Lambertian) and atmospheric models. Using three-dimensional radiative transfer (3DRT) theory algorithms are being developed. The methodology used to perform the 3DRT calculations is described. It is shown how these calculations are used to perform atmospheric corrections, and the sensitivity of the retrieved surface reflectances to atmospheric structural parameters is illustrated.

Diner, D. J.↗
NASA NTRS1990

Lead-ruthenium pyrochlores as oxygen electrocatalysts

An investigation of lead-ruthenium pyrochlores of the structure Pb2(Ru/2-x/Pb/x/) O7-y for use as oxygen electrocatalysts in alkaline media is discussed. Lead-ruthenium pyrochlore mixed metal oxides were prepared and characterized by X-ray diffraction, BET surface area, dry powder conductivity, and chemical stability. Gas diffusion electrodes were developed specifically for the lead-ruthenium pyrochlore materials. Also investigated were the effects of varying electrode fabrication parameters on the oxygen reduction performance of the lead-ruthenium pyrochlore electrocatalyst. Long-term stability performance was also evaluated. The oxygen reduction performance of the pyrochlore electrocatalyst is considerably higher than that of the state-of-the-art gold-platinum alloy electrocatalyst currently used by NASA. Furthermore, the pyrochlore electrocatalysts are attractive candidates for high-performance pressurized alkaline fuel cells.

Anderson, E. B.↗
NASA NTRS1993

The implementation and validation of improved land-surface hydrology in an atmospheric general circulation model

New land-surface hydrologic parameterizations are implemented into the NASA Goddard Institute for Space Studies (GISS) General Circulation Model (GCM). These parameterizations are: 1) runoff and evapotranspiration functions that include the effects of subgrid-scale spatial variability and use physically based equations of hydrologic flux at the soil surface and 2) a realistic soil moisture diffusion scheme for the movement of water and root sink in the soil column. A one-dimensional climate model with a complete hydrologic cycle is used to screen the basic sensitivities of the hydrological parameterizations before implementation into the full three-dimensional GCM. Results of the final simulation with the GISS GCM and the new land-surface hydrology indicate that the runoff rate, especially in the tropics, is significantly improved. As a result, the remaining components of the heat and moisture balance show similar improvements when compared to observations. The validation of model results is carried from the large global (ocean and land-surface) scale to the zonal, continental, and finally the regional river basin scales.

Johnson, Kevin D.↗
NASA NTRS1994

The viability of photovoltaics on the Martian surface

The viability of photovoltaics (PV) on the Martian surface may be determined by their ability to withstand significant degradation in the Martian environment. Probably the greatest threat is posed by fine dust particles which are continually blown about the surface of the planet. In an effort to determine the extent of the threat, and to investigate some abatement strategies, a series of experiments were conducted in the Martian Surface Wind Tunnel (MARSWIT) at NASA Ames Research Center. The effects of dust composition, particle size, wind velocity, angle of attack, and protective coatings on the transmittance of light through PV coverglass were determined. Both initially clear and initially dusted samples were subjected both to clear winds and simulated dust storms in the MARSWIT. It was found that wind velocity, particle size, and angle of attack are important parameters affecting occlusion of PV surfaces, while dust composition and protective coatings were not. Neither induced turbulence nor direct current biasing up to 200 volts were effective abatement techniques. Abrasion diffused the light impinging on the PV cells, but did not reduce total coverglass transmittance by more than a few percent.

Gaier, James R.↗
NASA NTRS1999

Ocean Wave Studies with Applications to Ocean Modeling and Improvement of Satellite Altimeter Measurements

Combining analysis of satellite data (altimeter, scatterometer, high-resolution visible and infrared images, etc.) with mathematical modeling of non-linear wave processes, we investigate various ocean wave fields (on scales from capillary to planetary), their role in ocean dynamics and turbulent transport (of heat and biogeochemical quantities), and their effects on satellite altimeter measuring accuracy. In 1998 my attention was focused on long internal gravity waves (10 to 1000 km), known also as baroclinic inertia-gravity (BIG) waves. We found these waves to be a major factor of altimeter measurements "noise," resulting in a greater uncertainty [up to 10 cm in terms of sea surface height (SSH) amplitude] in the measured SSH signal than that caused by the sea state bias variations (up to 5 cm or so). This effect still remains largely overlooked by the satellite altimeter community. Our studies of BIG waves address not only their influence on altimeter measurements but also their role in global ocean dynamics and in transport and turbulent diffusion of biogeochemical quantities. In particular, in collaboration with Prof Peter Weichman, Caltech, we developed a theory of turbulent diffusion caused by wave motions of most general nature. Applied to the problem of horizontal turbulent diffusion in the ocean, the theory yielded the effective diffusion coefficient as a function of BIG wave parameters obtainable from satellite altimeter data. This effort, begun in 1997, has been successfully completed in 1998. We also developed a theory that relates spatial fluctuations of scalar fields (such as sea surface temperature, chlorophyll concentration, drifting ice concentration, etc.) to statistical characteristics of BIG waves obtainable from altimeter measurements. A manuscript is in the final stages of preparation. In order to verify the theoretical predictions and apply them to observations, we are now analyzing Sea-viewing Wide Field of view Sensor (SeaWiFS) and Field of view Sensor (SeaWiFS) and Advanced Very High-Resolution Radiometer (AVHRR) data on sea surface temperature (SST) and chlorophyll concentration jointly with TOPEX/POSEIDON data on SSH variations.

Glazman, Roman E.↗
NASA NTRS2011

Effects of Solar Wind Conditions on the Plasma Wake Within a Polar Crater: Preliminary Results

As the solar wind sweeps horizontally past a shadowed lunar crater it simultaneously diffuses toward the surface through an ambipolar process, forming a plasma wake (e.g., Figure 1). Importantly, the resulting electric field structure diverts solar wind protons toward the cold crater floor where they may represent a source of surficial hydrogen. We present a handful of two-dimensional kinetic simulations exploring the range of wake structures and surface particle fluxes possible under various background plasma conditions.

Zimmerman, M. I.↗
NASA NTRS2000

A New Fast Algorithm to Completely Account for Non-Lambertian Surface Reflection of The Earth

Surface bidirectional reflectance distribution function (BRDF) influences not only radiance just about the surface, but that emerging from the top of the atmosphere (TOA). In this study we propose a new, fast and accurate, algorithm CASBIR (correction for anisotropic surface bidirectional reflection) to account for such influences on radiance measured above TOA. This new algorithm is based on a 4-stream theory that separates the radiation field into direct and diffuse components in both upwelling and downwelling directions. This is important because the direct component accounts for a substantial portion of incident radiation under a clear sky, and the BRDF effect is strongest in the reflection of the direct radiation reaching the surface. The model is validated by comparison with a full-scale, vector radiation transfer model for the atmosphere-surface system. The result demonstrates that CASBIR performs very well (with overall relative difference of less than one percent) for all solar and viewing zenith and azimuth angles considered in wavelengths from ultraviolet to near-infrared over three typical, but very different surface types. Application of this algorithm includes both accounting for non-Lambertian surface scattering on the emergent radiation above TOA and a potential approach for surface BRDF retrieval from satellite measured radiance.

Qin, Wen-Han↗
NASA NTRS1994

Effects of vibration (G-jitters) on convection in micro-gravity

To obtain high quality crystals, it is desirable to maintain a diffusion-limited transport process in a planar solidification surface between the solid and the melt during the crystal growth process. Due to the presence of buoyancy-driven convection, however, this situation is difficult to maintain on Earth. The microgravity environment of an orbiting space laboratory presents an alternative worth pursuing. With reduced gravity, convections very much suppressed in a space laboratory, making the environment more conducive for growing crystals with better quality. However, a space laboratory is not immune from any undesirable disturbances. Nonuniform and transient accelerations such as vibrations, g-jitters, and impulsive accelerations exist as a result of crew activities, space maneuvering, and the operations of on-board equipment. Measurements conducted on-board a U.S. Spacelab mission showed the existence of vibrations in the frequency range of 1 to 100 Hz. It was reported that a dominant mode of 17 Hz and harmonics of 54 Hz were observed and these were attributed to antenna operations. The vibration is not limited to any single plane but exists in all directions. Some data from the Russian MIR space station indicates the existence of vibration also at this frequency range.

Wang, Francis C.↗
NASA NTRS1973

Diffusion across the modified polyethylene separator GX in the heat-sterilizable AgO-Zn battery

Models of diffusion across an inert membrane have been studied using the computer program CINDA. The models were constructed to simulate various conditions obtained in the consideration of the diffusion of Ag (OH)2 ions in the AgO-Zn battery. The effects on concentrations across the membrane at the steady state and on the fluxout as a function of time were used to examine the consequences of stepwise reducing the number of sources of ions, of stepwise blocking the source and sink surfaces, of varying the magnitude of the diffusion coefficient for a uniform membrane, of varying the diffusion coefficient across the membrane, and of excluding volumes to diffusion.

Lutwack, R.↗
NASA NTRS1977

Determination of minority-carrier lifetime and surface recombination velocity with high spacial resolution

Quantitative analysis of the electron beam induced current in conjunction with high-resolution scanning makes it possible to evaluate the minority-carrier lifetime three dimensionally in the bulk and the surface recombination velocity two dimensionally, with a high spacial resolution. The analysis is based on the concept of the effective excitation strength of the carriers which takes into consideration all possible recombination sources. Two-dimensional mapping of the surface recombination velocity of phosphorus-diffused silicon diodes is presented as well as a three-dimensional mapping of the changes in the minority-carrier lifetime in ion-implanted silicon.

Watanabe, M.↗
NASA NTRS1987

Impeller shroud to casing leakage flow simulations in the Space Shuttle Main Engine high pressure fuel pump

Quasi-three-dimensional Navier-Stokes calculations were carried out for the Space Shuttle Main Engine high-pressure fuel pump to simulate the impeller shroud to casing leakage flow. This flow geometry was modeled as an axisymmetric cavity flow with a stationary surface representing the casing, and a rotating surface denoting the impeller. A 63 x 81-node mesh provided sufficient resolution in the regions of greatest flow variations and reduced the effects of numerical diffusion. The turbulence field was closed with the high Reynolds number form of the k-epsilon model supplemented with wall functions in the vicinity of the walls. Finally, a parametric study quantified the effects of through mass flow changes on this leakage flow.

Sindir, Munir M.↗
NASA NTRS1988

Observed variability of the solar luminosity

Data on solar luminosity variations are compiled in graphs and analyzed, with a focus on the SMM satellite bolometric measurements and other observations made since 1983. Consideration is given to total irradiance measurements in integrated light; emission-line variability in the visible, UV, and IR; mechanisms contributing to the solar variability (sunspots, faculae, rotation, oscillations, granulation, and active networks); the role of the solar magnetic cycle; and other observable parameters indicating variability. Also discussed are the effects of solar variations on the earth climate and the implications of the observations for theoretical models of convective-envelope processes (thermal diffusion near the surface and magnetic pressure in the interior).

Hudson, H. S.↗
NASA NTRS2000

Soot Oxidation in Laminar Hydrocarbon/Air Diffusion Flames at Atmospheric Pressure

Soot oxidation was studied experimentally in laminar hydrocarbon/air diffusion flames at atmospheric pressure. Measurements were carried out along the axes of round jets burning in coflowing air considering acetylene, ethylene, proplyene and propane as fuels. Measurements were limited to the initial stages of soot oxidation (carbon consumption less than 70%) where soot oxidation mainly occurs at the surface of primary soot particles. The following properties were measured as a function of distance above the burner exit: soot concentrations by deconvoluted laser extinction, soot temperatures by deconvoluted multiline emission, soot structure by thermophoretic sampling and analysis using Transmission Electron Microscopy (TEM), concentrations of stable major gas species (N2, H2O, H2, 02, CO, CO2, CH4, C2H2, C2H4, C2H6, C3H6, and C3H8) by sampling and gas chromatography, concentrations of some radical species (H, OH, O) by the deconvoluted Li/LiOH atomic absorption technique and flow velocities by laser velocimetry. It was found that soot surface oxidation rates are not particularly affected by fuel type for laminar diffusion flames and are described reasonably well by the OH surface oxidation mechanism with a collision efficiency of 0.10, (standard deviation of 0.07) with no significant effect of fuel type in this behavior; these findings are in good agreement with the classical laminar premixed flame measurements of Neoh et al. Finally, direct rates of surface oxidation by O2 were small compared to OH oxidation for present conditions, based on estimated O2 oxidation rates due to Nagle and Strickland-Constable, because soot oxidation was completed near the flame sheet where O2 concentrations were less than 1.2% by volume.

Xu, F.↗
NASA NTRS2001

Soot Oxidation in Hydrocarbon/Air Diffusion Flames at Atmospheric Pressure

Soot oxidation was studied experimentally in laminar hydrocarbon/air diffusion flames at atmospheric pressure. Measurements were carried out along the axes of round jets burning in coflowing air considering acetylene, ethylene, propylene and propane as fuels. Measurements were limited to the initial stages of soot oxidation (carbon consumption less than 70%) where soot oxidation mainly occurs at the surface of primary soot particles. The following properties were measured as a function of distance above the burner exit: soot concentrations by deconvoluted laser extinction, soot temperatures by deconvoluted multiline emission, soot structure by thermophoretic sampling and analysis using Transmission Electron Microscopy (TEM), concentrations of stable major gas species (N2, H2O, H2, O2, CO, CO2, CH4, C2H2,C2H4, C2H6, C3H6, and C3H8) by sampling and gas chromatography, concentrations of some radical species (H, OH, O) by the deconvoluted Li/LiOH atomic absorption technique and flow velocities by laser velocimetry. It was found that soot surface oxidation rates are not particularly affected by fuel type for laminar diffusion flames and are described reasonably well by the OH surface oxidation mechanism with a collision efficiency of 0.10, (standard deviation of 0.07) with no significant effect of fuel type in this behavior; these findings are in good agreement with the classical laminar premixed flame measurements of Neoh et al. Finally, direct rates of surface oxidation by O2 were small compared to OH oxidation for present conditions, based on estimated O2 oxidation rates due to Nagle and Strickland-Constable (1962), because soot oxidation was completed near the flame sheet where O2 concentrations were less than 1.2% by volume.

Xu, F.↗
NASA NTRS2003

Magnetic Flux Compression Experiments Using Plasma Armatures

Magnetic flux compression reaction chambers offer considerable promise for controlling the plasma flow associated with various micronuclear/chemical pulse propulsion and power schemes, primarily because they avoid thermalization with wall structures and permit multicycle operation modes. The major physical effects of concern are the diffusion of magnetic flux into the rapidly expanding plasma cloud and the development of Rayleigh-Taylor instabilities at the plasma surface, both of which can severely degrade reactor efficiency and lead to plasma-wall impact. A physical parameter of critical importance to these underlying magnetohydrodynamic (MHD) processes is the magnetic Reynolds number (R(sub m), the value of which depends upon the product of plasma electrical conductivity and velocity. Efficient flux compression requires R(sub m) less than 1, and a thorough understanding of MHD phenomena at high magnetic Reynolds numbers is essential to the reliable design and operation of practical reactors. As a means of improving this understanding, a simplified laboratory experiment has been constructed in which the plasma jet ejected from an ablative pulse plasma gun is used to investigate plasma armature interaction with magnetic fields. As a prelude to intensive study, exploratory experiments were carried out to quantify the magnetic Reynolds number characteristics of the plasma jet source. Jet velocity was deduced from time-of-flight measurements using optical probes, and electrical conductivity was measured using an inductive probing technique. Using air at 27-inHg vacuum, measured velocities approached 4.5 km/s and measured conductivities were in the range of 30 to 40 kS/m.

Turner, M. W.↗
NASA NTRS1987

Distortion of the vortex core during blade-vortex interaction

The effect of vortex distortion on the flow arising from the interaction of a convecting vortex and an airfoil is analyzed for two-dimensional, incompressible, inviscid flow. Significant distortion of the vortex structure, owing to interaction with the airfoil, can occur, especially during close interactions. The vorticity field is represented by multiple vortices. Vortex instability and diffusion, resulting from discretization in space and time, are discussed. An integral boundary element method is used to represent the airfoil surface. The body panels are re-distributed on the surface as the vortices are convected past to calculate the effect of the vorticity field more accurately. The method is applied to several cases to examine effects of vortex strength, distribution, initial separation position, and airfoil angle of attack. Calculations of vortex trajectory and distortion, and airfoil surface-pressure distribution, lift, drag, and circulation as functions of time are presented.

Lee, G. J.↗