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At least 235 records · Page 13

Shock tube measurements of the optical absorption of triatomic carbon, C3

The spectral absorption of C3 has been measured in a shock tube using a test gas mixture of acetylene diluted with argon. The absorption of a pulsed xenon light source was measured by means of eight photomultiplier channels to a spectrograph and an accompanying drum camera. The postshock test gas temperature and pressure were varied over the range 3300-4300 K and 0.36 to 2.13 atmospheres, respectively. The results showed appreciable absorption from C3 for the wavelength range 300 to 540 nanometers. The computed electronic oscillator strength varied from 0.12 to 0.06 as a function of temperature.

Jones, J. J.↗

Numerical simulations of a nonequilibrium argon plasma in a shock-tube experiment

A code developed for the numerical modeling of nonequilibrium radiative plasmas is applied to the simulation of the propagation of strong ionizing shock waves in argon gas. The simulations attempt to reproduce a series of shock-tube experiments which will be used to validate the numerical models and procedures. The ability to perform unsteady simulations makes it possible to observe some fluctuations in the shock propagation, coupled to the kinetic processes. A coupling mechanism by pressure waves, reminiscent of oscillation mechanisms observed in detonation waves, is described. The effect of upper atomic levels is also briefly discussed.

Cambier, Jean-Luc↗

Pulse-burst spontaneous Raman thermometry of unsteady wave phenomena in a shock tube

A high-speed temperature diagnostic based on spontaneous Raman scattering (SRS) was demonstrated using a pulse-burst laser. The technique was first benchmarked in near-adiabatic H 2 -air flames at a data-acquisition rate of 5 kHz using an integrated pulse energy of 1.0 J per realization. Both the measurement precision and accuracy in the flame were within 3% of adiabatic predictions. Furthermore, this technique was then evaluated in a challenging free-piston shock tube environment operated at a shock Mach number of 3.5. SRS thermometry resolved the temperature in post-incident and post-reflected shock flows at a repetition rate of 3 kHz and clearly showed cooling associated with driver expansion waves. Collectively, this Letter represents a major advancement for SRS in impulsive facilities, which had previously been limited to steady state regions or single-shot acquisition.

47 OTHER INSTRUMENTATION↗

A shock-tube measurement of the SiO/E 1 Sigma + - X 1 Sigma +/ transition moment

The sum of the squares of the electronic transition moments for the (E 1 Sigma +) - (X 1 Sigma +) band system of SiO has been determined from absorption measurements conducted in the reflected-shock region of a shock tube. The test gas produced by shock-heating a mixture of SiCl4, N2O, and Ar, and the spectra were recorded photographically in the 150-230-nm wavelength range. The values of the sum of the squares were determined by comparing the measured absorption spectra with those produced by a line-by-line synthetic spectrum calculation. The value so deduced at an r-centroid value of 3.0 bohr was 0.86 + or - 0.10 atomic unit.

Park, C.↗

Nonlinear problem of a shock-tube interaction-region boundary layer.

Description of a numerical method that dispenses with the recourse to linearization or 'momentum-integral-correction' schemes in solving nonlinear problems of boundary layer flow in the interaction region of a shock tube or of similar singular parabolic problems of shock-induced unsteady boundary layers. The accuracy of the numerical results obtainable is shown to be satisfactory.

Gupta, R. N.↗

A shock-tube determination of the SiO /A 1 Pi - X 1 Sigma +/ transition moment

The sum of the squares of the electronic transition moments for the A 1 Pi - X 1 Sigma + band system of SiO has been determined from absorption measurements conducted in the reflected-shock region of a shock tube. The test gas was produced by shock-heating a mixture of N2O, SiCl4, and Ar, and the spectra were recorded photographically in the 260-290-nm wavelength range. The values of the sum as a function of internuclear distance between 2.8 and 3.3 Bohr were determined by comparing the measured absorption spectrum with that produced by a line-by-line synthetic-spectrum calculation which accounted for instrumental broadening. The value of the sum so deduced at an internuclear distance of 3.0 Bohr was 1.0 + or - 0.3 atomic units.

Park, C.↗

Numerical simulation of transient inviscid gas flows in a shock tube

Time-dependent upwind high resolution schemes for solving the Euler equations were developed and applied to simulate 1-D and 2-D transient inviscid gas flows in a shock tube. Using obstacles of different geometries, a series of calculations were carried out to investigate the transient complex shock-wave diffraction phenomena. Shock-wave and objects interactions with shock Mach-number Ms ranging from 2 to 20 were considered. Comparison with analytical and available experimental results indicate good agreement. Display of detailed flow structures including multiple Mach shocks, slip surfaces, and vortex are also given.

Yang, J. Y.↗

Hook-method measurements of gf-values for ultraviolet Fe I and Fe II lines on a shock tube

Transition probabilities for 14 lines of Fe II and 12 lines of Fe I in the wavelength region 2560-2737 A were measured by use of a shock tube and the hook method. Absolute oscillator strengths for resonance lines of Fe I reported by Banfield and Huber were used to determine the number density of neutral iron in the shock-heated gas. With the assumption of thermal equilibrium, the density of singly ionized iron atoms in this gas was then computed from the measured temperature and pressure with the aid of the Saha equation. Our results on the 12 strongest of the 13 lines belonging to the first ultraviolet multiplet of Fe II indicate that the multiplet f-value is larger by a factor of 2 than that derived from lifetime measurements by Assousa and Smith.

Huber, M. C. E.↗

Shock tube technique for measuring opacities at high pressures for gaseous-core nuclear rockets.

A new method of opacity determination is described that uses an improved shock tube design and is applicable to measurements of Planck and Rosseland mean opacities in hydrogen or seeded hydrogen at hydrogen partial pressures of 500 atm, at temperatures from 2300 to 8000 K. The selection of seed materials to be added to the gases to make them semiopaque is discussed. Currently favored seeds are silicon and carbon or graphite for reactive seeds, and depleted uranium and tungsten 184 for nonreactive seeds.

Patch, R. W.↗

Shock tube study of the reaction H plus O2 plus Ar yields HO2 plus Ar

Rate coefficient data for the recombination reaction H + 02 + Ar yields H02 + Ar have been determined from studies of lean hydrogen-oxygen mixtures behind incident shock waves over the temperature range of 948 to 1125 K. Hydroxyl radical concentration profiles were measured by ultraviolet absorption spectroscopy, and rate data were obtained through analysis of induction time and exponential growth parameter data. Analysis of the data yielded a rate coefficient which was generally lower than most of the more recent values obtained from shock tube studies. The effect of boundary layer formation on the conditions behind the shock was also examined and found to be negligible.

Jachimowski, C. J.↗

An improved thin-film gauge for shock-tube thermal studies.

An improved type of thin-film heat gauge has been developed and used to measure heat-transfer rates from a shock-heated plasma to the end wall of a shock tube. The gauge is a resistance thermometer consisting of a triple-layered sensor coated by a moderately thick film of SiO2. It was used to measure heat transfer from nonionized argon at temperatures of up to 16000 K. A marked increase in heat transfer at the onset of ionization near the wall indicates that the gauge can be used to obtain the contribution of free electrons to the thermal transport.

Willeke, K.↗

Shock-tube pyrolysis of chlorinated hydrocarbons - Formation of soot

Soot formation in pyrolysis of chlorinated methanes, their mixtures with methane, and chlorinated ethylenes were studied behind reflected shock waves by monitoring the attenuation of an He-Ne laser beam. An additional single-pulse shock-tube study was conducted for the pyrolysis of methane, methyl chloride, and dichloromethane. The experiments were performed at temperatures 1300-3000 K, pressures of 0.4-3.6 bar, and total carbon atom concentrations of 1-5 x 10 to the 17th atoms cu cm. The amounts of soot produced in the pyrolysis of chlorinated hydrocarbons are larger than that of their nonchlorinated counterparts. The sooting behavior and product distribution can be generally explained in terms of chlorine-catalyzed chemical reaction mechanisms. The pathway to soot from chlorinated methanes and ethylenes with high H:Cl ratio proceeds via the formation of C2H, C2H2, and C2H3 species. For chlorinated hydrocarbons with low H:Cl ratio, the formation of C2 and its contribution to soot formation at high temperatures becomes significant. There is evidence for the importance of CHCl radical and its reactions in the pyrolysis of dichloromethane.

Frenklach, M.↗

Meteor Entry Characterization in the Electric Arc Shock Tube

This poster summarizes potential test opportunities in Ames' EAST facility that would benefit studies of meteor and asteroid entry into Earth's atmosphere. The Electric Arc Shock Tube (EAST) facility produces high speed (up to Mach 50) shockwaves at prescribed velocities, densities and atmospheric compositions.

Cruden, B. A.↗