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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Entropy Splitting for High Order Numerical Simulation of Compressible Turbulence

A stable high-order numerical scheme for direct numerical simulation (DNS) of shock-free compressible turbulence is presented. The method is applicable to general geometries. It contains no upwinding, artificial dissipation, or filtering. Instead the method relies on the stabilizing mechanisms of an appropriate conditioning of the governing equations and the use of compatible spatial difference operators for the interior points (interior scheme) as well as the boundary points (boundary scheme). An entropy-splitting approach splits the inviscid flux derivatives into conservative and nonconservative portions. The spatial difference operators satisfy a summation-by-parts condition, leading to a stable scheme (combined interior and boundary schemes) for the initial boundary value problem using a generalized energy estimate. A Laplacian formulation of the viscous and heat conduction terms on the right hand side of the Navier–Stokes equations is used to ensure that any tendency to odd–even decoupling associated with central schemes can be countered by the fluid viscosity. The resulting methods are able to minimize the spurious high-frequency oscillations associated with pure central schemes, especially for long time integration applications such as DNS. For validation purposes, the methods are tested in a DNS of compressible turbulent plane channel flow at low values of friction Mach number, where reference turbulence data bases exist. It is demonstrated that the methods are robust in terms of grid resolution, and in good agreement with published channel data. Accurate turbulence statistics can be obtained with moderate grid sizes. Stability limits on the range of the splitting parameter are determined from numerical tests.

N.D. Sandham↗
NASA NTRS1947

Tank Tests of a 1/7-Size Dynamic Model of the Grumman XJR2F-1 Amphibian to Determine the Effect of Slotted- and Split-Type Flaps on Take-Off Stability - NACA Model 212, TED No. NACA 2378

Additional tests of a 1/7-size model of the Grumman XJR2F-1 amphibian were made in Langley tank no. 1 to compare the behavior during take-off of the model equipped with split- and slotted-type flaps. The slotted flag had a large effect on locating the forward center-of-gravity limits for stable take-offs. Stable take-offs within the normal operating range of positions of the center of gravity could be made with the split flaps deflected 45deg or with the slotted flaps deflected less than 20deg. At flap deflections required for similar take-off stability, the use of split-flaps resulted lower take-off speeds than the use of slotted flaps. An increase in forward acceleration from 1.1 to 4.8 feet per second per second moved the center-of-gravity limit forward approximately 3-percent mean aerodynamic chord.

Land, Norman S.↗
NASA NTRS1995

Code to Optimize Load Sharing of Split-Torque Transmissions Applied to the Comanche Helicopter

Most helicopters now in service have a transmission with a planetary design. Studies have shown that some helicopters would be lighter and more reliable if they had a transmission with a split-torque design instead. However, a split-torque design has never been used by a U.S. helicopter manufacturer because there has been no proven method to ensure equal sharing of the load among the multiple load paths. The Sikorsky/Boeing team has chosen to use a split-torque transmission for the U.S. Army's Comanche helicopter, and Sikorsky Aircraft is designing and manufacturing the transmission. To help reduce the technical risk of fielding this helicopter, NASA and the Army have done the research jointly in cooperation with Sikorsky Aircraft. A theory was developed that equal load sharing could be achieved by proper configuration of the geartrain, and a computer code was completed in-house at the NASA Lewis Research Center to calculate this optimal configuration.

Source record↗
NASA NTRS2007

Unbalanced and Minimal Point Equivalent Estimation Second-Order Split-Plot Designs

Restricting the randomization of hard-to-change factors in industrial experiments is often performed by employing a split-plot design structure. From an economic perspective, these designs minimize the experimental cost by reducing the number of resets of the hard-to- change factors. In this paper, unbalanced designs are considered for cases where the subplots are relatively expensive and the experimental apparatus accommodates an unequal number of runs per whole-plot. We provide construction methods for unbalanced second-order split- plot designs that possess the equivalence estimation optimality property, providing best linear unbiased estimates of the parameters; independent of the variance components. Unbalanced versions of the central composite and Box-Behnken designs are developed. For cases where the subplot cost approaches the whole-plot cost, minimal point designs are proposed and illustrated with a split-plot Notz design.

Parker, Peter A.↗
NASA NTRS2006

Classes of Split-Plot Response Surface Designs for Equivalent Estimation

When planning an experimental investigation, we are frequently faced with factors that are difficult or time consuming to manipulate, thereby making complete randomization impractical. A split-plot structure differentiates between the experimental units associated with these hard-to-change factors and others that are relatively easy-to-change and provides an efficient strategy that integrates the restrictions imposed by the experimental apparatus. Several industrial and scientific examples are presented to illustrate design considerations encountered in the restricted randomization context. In this paper, we propose classes of split-plot response designs that provide an intuitive and natural extension from the completely randomized context. For these designs, the ordinary least squares estimates of the model are equivalent to the generalized least squares estimates. This property provides best linear unbiased estimators and simplifies model estimation. The design conditions that allow for equivalent estimation are presented enabling design construction strategies to transform completely randomized Box-Behnken, equiradial, and small composite designs into a split-plot structure.

Parker, Peter A.↗
NASA NTRS2007

Optically Transparent Split-Ring Antennas for 1 to 10 GHz

Split-ring antennas made from optically transparent, electrically conductive films have been invented for applications in which there are requirements for compact antennas capable of operation over much or all of the frequency band from 1 to 10 GHz. Primary examples of such applications include wireless local-area networks and industrial, scientific, and medical (ISM) applications. These antennas can be conveniently located on such surfaces as those of automobile windows and display screens of diverse hand-held electronic units. They are fabricated by conventional printed-circuit techniques and can easily be integrated with solid-state amplifier circuits to enhance gain. The structure of an antenna of this type includes an antenna/feed layer supported on the top or outer face of a dielectric (e.g., glass) and, optionally, a ground layer on the bottom or inner face of the substrate. The ring can be in the form of either a conductive strip or a slot in the antenna/feed layer. The ring can be of rectangular, square, circular, elliptical, or other suitable shape and can be excited by means of a microstrip, slot line, or coplanar waveguide. For example, the antenna shown in the figure features a square conductive-strip split ring with a microstrip feed. In general, an antenna fed at its external boundary in the manner of this invention presents very high impedance, thereby creating an impedance-matching problem. Splitting the ring . that is, cutting a notch through the ring . offers a solution to the problem in that the notch fixes the location of maximum electric field, which location is directly related to the impedance. Thus, an excellent impedance match can be achieved through proper choice of the location of the notch. In geometric layout, such a ring antenna structure is typically between 1.4 and 1.3 the size of a patch antenna capable of operating in the same frequency range. This miniaturization of the antenna is desirable, not only because it contributes to overall miniaturization of equipment, but also because minimization of the extent of the optically transparent, electrically conductive film helps to minimize the electrical loss associated with the surface resistance ( 5 ohms per square) of the transparent, electrically conductive film material. Incidentally, even at 5 ohms per square, this surface resistance is significantly less than that of indium tin oxide film (typically > 25 ohms per square), which, heretofore has been the transparent, electrically conductive film material of choice. At the time of writing this article, information on the composition of the lower-resistance film used in the antennas of this invention was not available.

Lee, Richard Q.↗
NASA NTRS2013

Silicon/Carbon Nanotube Photocathode for Splitting Water

A proof-of-concept device is being developed for hydrogen gas production based on water-splitting redox reactions facilitated by cobalt tetra-aryl porphyrins (Co[TArP]) catalysts stacked on carbon nanotubes (CNTs) that are grown on n-doped silicon substrates. The operational principle of the proposed device is based on conversion of photoelectron energy from sunlight into chemical energy, which at a later point, can be turned into electrical and mechanical power. The proposed device will consist of a degenerately n-doped silicon substrate with Si posts covering the surface of a 4-in. (approximately equal to 10cm) wafer. The substrate will absorb radiation, and electrons will move radially out of Si to CNT. Si posts are designed such that the diameters are small enough to allow considerable numbers of electrons to transport across to the CNT layer. CNTs will be grown on top of Si using conformal catalyst (Fe/Ni) deposition over a thin alumina barrier layer. Both metallic and semiconducting CNT will be used in this investigation, thus allowing for additional charge generation from CNT in the IR region. Si post top surfaces will be masked from catalyst deposition so as to prevent CNT growth on the top surface. A typical unit cell will then consist of a Si post covered with CNT, providing enhanced surface area for the catalyst. The device will then be dipped into a solution of Co[TArP] to enable coating of CNT with Co(P). The Si/CNT/Co [TArP] assembly then will provide electrons for water splitting and hydrogen gas production. A potential of 1.23 V is needed to split water, and near ideal band gap is approximately 1.4 eV. The combination of doped Si/CNT/Co [TArP] will enable this redox reaction to be more efficient.

Amashukeli, Xenia↗
NASA NTRS2013

Stacked Transformer for Driver Gain and Receive Signal Splitting

In a high-speed signal transmission system that uses transformer coupling, there is a need to provide increased transmitted signal strength without adding active components. This invention uses additional transformers to achieve the needed gain. The prior art uses stronger drivers (which require an IC redesign and a higher power supply voltage), or the addition of another active component (which can decrease reliability, increase power consumption, reduce the beneficial effect of serializer/deserializer preemphasis or deemphasis, and/or interfere with fault containment mechanisms), or uses a different transformer winding ratio (which requires redesign of the transformer and may not be feasible with high-speed signals that require a 1:1 winding ratio). This invention achieves the required gain by connecting the secondaries of multiple transformers in series. The primaries of these transformers are currently either connected in parallel or are connected to multiple drivers. There is also a need to split a receive signal to multiple destinations with minimal signal loss. Additional transformers can achieve the split. The prior art uses impedance-matching series resistors that cause a loss of signal. Instead of causing a loss, most instantiations of this invention would actually provide gain. Multiple transformers are used instead of multiple windings on a single transformer because multiple windings on the same transformer would require a redesign of the transformer, and may not be feasible with high-speed transformers that usually require a bifilar winding with a 1:1 ratio. This invention creates the split by connecting the primaries of multiple transformers in series. The secondary of each transformer is connected to one of the intended destinations without the use of impedance-matching series resistors.

Driscoll, Kevin R.↗
DOE OSTI2020

Multi-mode power split hybrid transmission with two planetary gear mechanisms

A multi-mode, power-split hybrid transmission system having two planetary gear (PG) sets connected to one engine, two electric motors, one output shaft, and each other by several clutches, brakes, and direct connection elements. Depending on the specific location and actuation of the various clutch and brake elements, the multi-mode, power-split hybrid transmission system can be run in one of several modes (e.g. electric drive, power-split, parallel hybrid, series hybrid, electronic continuously variable transmission (eCVT), generator, neutral, and the like).

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2021

Enhanced Integer Permutation based Genetic Algorithm for Optimization of Tube-Fin Heat Exchanger Circuitry with Splits and Merges

Tube-fin heat exchangers (HXs) are widely used in air-conditioning and heat pump applications. The performance of these heat exchangers is strongly influenced by the refrigerant circuitry. Studies have proved that by optimizing the refrigerant circuitry, the performance of HXs can be significantly improved. In our previous research, an Integer Permutation based Genetic Algorithm (IPGA) was developed to obtain the optimal circuitry designs. Our previous research showed that IPGA demonstrates superior capability to obtain better refrigerant circuitries with lower computational cost than the other methods in literature. And the optimal circuitry designs obtained from IPGA are manufacturable with the available tooling. However, the IPGA developed previously cannot generate designs with splitting and merging of circuits. To remedy this limitation, a new chromosome which can represent circuitry with splitting and merging of circuits is developed. In addition to the six genetic operators implemented previously, two new genetic operators are developed to generate splits and merges. As a result, the enhanced IPGA can explore the solution space more thoroughly than the previous IPGA. A case study using an evaporator from an A-type indoor unit shows that, given the similar capacity improvements obtained from the enhanced IPGA compared with the previous IPGA, the refrigerant pressure drop reduction obtained from the enhanced IPGA is 26.5% compared against 1.0% pressure drop reduction from the previous IPGA. The benchmark of the enhanced IPGA with other methods in literature demonstrates that the enhanced IPGA can generate circuitry designs with performance superior to those obtained from other methods.

LI, Zhenning↗
DOE OSTI2024

Gas-phase activation of holmium tetranitrato complexes likely leads to formation of hydroxylated species through the loss of nitric acid, not water splitting

It has been observed that water can react with activated gas-phase lanthanide tetranitrato complexes ([Ln(NO3)4]-) to form a hydroxylated species. These reactions, which are proposed to involve water splitting, are observed for most -- but not all -- of the lanthanides. Thus, study of this system could yield insight into how small changes in electronic structure (through variation of the lanthanide species) influences water-splitting reactions, help guide development of new materials used to convert water to hydrogen using electricity. The mechanism proposed in the literature is: (Step 1) [Ln(NO3)4]- ? [LnO(NO3)3]- + ?NO2 (Step 2) [LnO(NO3)3]- + H2O ? [LnOH(NO3)3]- + ?OH The purpose of this study is to determine if the reaction mechanism really does involve splitting of water or proceeds through an alternative pathway.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Organometal Halide Perovskite‐Based Photoelectrochemical Module Systems for Scalable Unassisted Solar Water Splitting

Despite achievements in the remarkable photoelectrochemical (PEC) performance of photoelectrodes based on organometal halide perovskites (OHPs), the scaling up of small-scale OHP-based PEC systems to large-scale systems remains a great challenge for their practical application in solar water splitting. Significant resistive losses and intrinsic defects are major obstacles to the scaling up of OHP-based PEC systems, leading to the PEC performance degradation of large-scale OHP photoelectrodes. Herein, a scalable design of the OHP-based PEC systems by modularization of the optimized OHP photoelectrodes exhibiting a high solar-to-hydrogen conversion efficiency of 10.4% is suggested. As a proof-of-concept, the OHP-based PEC module achieves an optimal PEC performance by avoiding major obstacles in the scaling up of the OHP photoelectrodes. The constructed OHP module is composed of a total of 16 OHP photoelectrodes, and a photocurrent of 11.52 mA is achieved under natural sunlight without external bias. The successful operation of unassisted solar water splitting using the OHP module without external bias can provide insights into the design of scalable OHP-based PEC systems for future practical application and commercialization.

14 SOLAR ENERGY↗
DOE OSTI2021

Twinning Enhances Efficiencies of Metallic Catalysts toward Electrolytic Water Splitting

Twinning is demonstrated to be an effective way of enhancing efficiencies of metallic catalysts toward electrolytic water splitting. Dendritic Cu possessing dense coherent nanotwin (NT) boundaries (NTCu-5nm) is successfully prepared with an organic-assisted electrodeposition at high pulse current densities. NT boundaries significantly improve electrocatalytic efficiencies and stability of NTCu-5nm over nanocrystalline Cu (NCCu), reducing overpotentials at 10 mA cm -2 for the oxygen evolution reaction (OER) from 378 to 281 mV and from 235 to 88 mV for the hydrogen evolution reaction (HER), with a small chronoamperometric decay of 5% after 100 h continuous overall water splitting at an ultrahigh initial current density of 500 mA cm -2 , largely outperforming the large chronoamperometric decay of 27% for only 1 h operation of the NCCu//NCCu couple. The defective twin boundaries enable formation of active Cu III O 2 - at low overpotentials, thus enhancing OER performance. Furthermore, the synergistic geometric and electronic effects induced by the twin boundaries result in shifts in Gibbs free energies of hydrogen adsorption (ΔG H ) toward the apex of a volcano plot of exchange current density versus ΔG H , leading to the remarkable improvement in HER activity.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2021

Operational Limits of Redox Metal Oxides Performing Thermochemical Water Splitting

Solar thermochemical hydrogen production is an attractive technology that stores intermittent solar energy in the form of chemical bonds. Efficient operation requires the identification of a redox-active metal oxide (MO x ) material that can achieve high conversion of water to hydrogen at minimal energy input. Water splitting occurs by consecutive reduction and reoxidation reactions of MO x . MO x is reduced to MO x-δ and, in the second step, is reoxidized by water recovering the initial MO x and generate H 2 . The material must reduce at temperatures achievable in concentrated solar receiver/reactors, while maintaining a thermodynamic driving force to split water. At equilibrium, extent of reduction depends on temperature and oxygen partial pressure, and in this analysis, a set of thermodynamic properties, namely, enthalpy and entropy of oxygen vacancy formation, is sufficient to represent MO x . Herein, a method to easily classify materials based on these thermodynamic properties under any condition of oxygen partial pressure and temperature is presented. This method is based on fundamental thermodynamic principles and is applicable for any redox material with known thermodynamic properties. Despite the simplicity of the method, it is believed that this analysis will support future research in targeting thermodynamic properties of redox-active metal oxides.

water splitting↗
DOE OSTI2023

Convergence analysis of single rate and multirate fixed stress split iterative coupling schemes in heterogeneous poroelastic media

Recently, the accurate modeling of flow–structure interactions has gained more attention and importance for both petroleum and environmental engineering applications. Of particular interest is the coupling between subsurface flow and reservoir geomechanics. Different single rate and multirate iterative and explicit coupling schemes have been proposed and analyzed in the past. In addition, Banach fixed point contraction results were obtained for iterative coupling schemes, and conditionally stable results were obtained for explicit coupling schemes. In this work, we will consider the mathematical analysis of the single rate and multirate fixed stress split iterative coupling schemes for spatially heterogeneous poroelastic media. We will re–establish the contractivity for both schemes in the localized case, and we will show that heterogeneities come at the expense of imposing more restricted conditions on the number of fine flow time steps that can be taken within one coarse mechanics time step in the multirate case. Our mathematical analysis is supplemented by numerical simulations validating our derived upper bounds. Finally, to the best of our knowledge, this is the first rigorous mathematical analysis of the multirate fixed–stress split iterative coupling scheme in heterogeneous poroelastic media.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2021

Split representation of adaptively compressed polarizability operator

The polarizability operator plays a central role in density functional perturbation theory and other perturbative treatment of first principle electronic structure theories. The cost of computing the polarizability operator generally scales as O(Ne4) where Ne is the number of electrons in the system. The recently developed adaptively compressed polarizability operator (ACP) formulation [L. Lin, Z. Xu and L. Ying, Multiscale Model. Simul. 2017] reduces such complexity to O(Ne 3 ) in the context of phonon calculations with a large basis set for the first time, and demonstrates its effectiveness for model problems. In this paper, we improve the performance of the ACP formulation by splitting the polarizability into a near singular component that is statically compressed, and a smooth component that is adaptively compressed. The new split representation maintains the O(Ne 3 ) complexity, and accelerates nearly all components of the ACP formulation, including Chebyshev interpolation of energy levels, iterative solution of Sternheimer equations, and convergence of the Dyson equations. For simulation of real materials, we discuss how to incorporate nonlocal pseudopotentials and finite temperature effects. In this work, we demonstrate the effectiveness of our method using one-dimensional model problem in insulating and metallic regimes, as well as its accuracy for real molecules and solids.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

PdPt-TiO 2 nanowires: correlating composition, electronic effects and O-vacancies with activities towards water splitting and oxygen reduction

Here we report the optimization of both the support and the active phase of PdPt NPs supported on TiO 2 nanowires to obtain highly active electro/photocatalysts for the oxygen reduction and water splitting reactions. This system displayed strong metal-support interactions, high concentration of oxygen vacancies, and PdPt NP were ~2 nm in size. By optimizing the loading of PdPt, both the photo- and electrocatalytic activities were improved compared to commercial materials. Interestingly, a volcano plot was obtained from the activity and the PdPt composition, and the Pd 0.22 Pt 0.78 -TiO 2 /C sample afforded the optimal performance. For instance, the amount of hydrogen produced from water splitting was 11.6 mmol/g catalyst . For the ORR, the activity was similar to a commercial Pt catalyst, but a lower E onset (0.87 V RHE vs w 0.95 V RHE ) was detected. The variations in the activities with the composition correlated well with the variations in the electronic effects and the concentration of oxygen vacancies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Investigation of fuel film formation and soot emissions in a GDI engine during cold-start with Split-injection strategies

This study investigates the impact of fuel-film formation on engine-out soot emissions in a gasoline direct injection (GDI) engine under cold-start conditions. Split-injection strategies were applied by varying the number of injections, injection duration, and total fuel quantity to affect wall wetting and control the average in-cylinder equivalence ratio. A combined experimental and numerical approach was employed to analyze fuel-film deposition, combustion efficiency, and engine-out soot and unburnt hydrocarbons (UHC) emissions. In particular, fuel film distribution estimated by means of non-reacting, 3-D, computational fluid dynamics (CFD) simulations, together with experimentally measured soot data, were used to investigate fuel film formation and its role in soot generation. In the experiments, a skip-fired engine control strategy was applied to mimic the transient nature of engine cold-start operation. The results indicate that, under the same total number of injections, increasing the average in-cylinder equivalence ratio through longer injection durations improves combustion stability, as indicated by the decrease of the coefficient of variation of IMEP n (Net Indicated Mean Effective Pressure) from 6.0 % to 0.6 %. However, this strategy leads to higher soot emissions, which increased by nearly an order of magnitude, primarily due to enhanced wall-film formation. In contrast, increasing the number of injections while maintaining a constant equivalence ratio significantly impacts fuel-film deposition and, consequently, soot emissions, with a fivefold reduction of the measured engine-out soot, decreasing from 3.5 mg to 0.7 mg. A soot-film correlation was developed and achieved a high coefficient of determination (r 2 = 0.95) and was further extended to account for spark timing effects. These findings confirm the effectiveness of split-injection for avoiding wall film formation and soot emissions, and the critical role of fuel film in soot generation, supporting the hypothesis that pool fires play a crucial role in contributing to soot formation under these cold-start conditions. In conclusion, the study also indicates the value of a predictive soot-film correlation for developing cold-start emission control strategies.

Engine Cold-start↗