The influence of microstructure on the fracture topography of titanium alloys
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Study resulting in a satisfactory stress corrosion cracking test with extremely consistent results produced six new analytical methods. Methods detect and determine differences in the minor constituent composition of different types of dinitrogen tetroxide.
The Ti-8Al-1Mo-1V alloy was tested in four conditions: mill annealed (70 ppM H), duplex annealed (70 ppM H), vacuum annealed to an intermediate (36 ppM) and a low (9 ppM H) hydrogen level. Material annealed at 650 C (duplex condition) exhibited resistance to hot-salt stress corrosion superior to that exhibited by material in the mill-annealed condition. Reduction of the alloy hydrogen content from 70 to as low as 9 ppM did not influence resistance to hot-salt stress corrosion embrittlement or cracking.
Through- and surface-cracked specimens of two thicknesses were tested in uniaxial tension. Surface-cracked specimens were generally found to be stronger than through-cracked specimens with the same crack length. Apparent surface-crack fracture toughness calculated using the Anderson modified Irwin equation remained relatively constant for cracks as deep as 90 percent of the sheet thickness. Subcritical growth of surface cracks was investigated. Comparison of chamber and open air welds showed chamber welds to be slightly tougher. Both methods produced welds with toughness that compared favorably with that of the parent metal. Weld efficiencies were above 94 percent.
The A-type polyimide adhesive resin P11B was modified by use of mixed diamines (thio-dianiline and meta phenylene diamine) which provided the desired autoclave processability. This new resin was termed P11BA. It was shown that copolymeric blends of P11BA and Amoco AI-1137 amide-imide resin provided improved adhesive properties when autoclave processed over the properties obtained previously by press bonding with P11B based copolymeric blended adhesives. Properties of bonded assemblies are presented for long-term aging at both elevated and low temperatures, and also stress-rupture tests at elevated temperature.
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An investigation of the effect of temperature on the surface hydriding reaction of Ti-5Al-2.5Sn alloy exposed to hydrogen at 250 psig was made. The temperature range studied extended from 160 to -160 F. Reaction conditions were controlled so as to expose a vacuum-cleaned, oxide-free alloy surface to an ultra-pure hydrogen atmosphere. Reaction times up to 1458 hr were studied. The hydriding reaction was extremely sensitive to experimental variables and the reproducibility of reaction behavior was poor. However, it was demonstrated that the reaction proceeded quite rapidly at 160 F; as much as 1 mil surface hydriding was observed after exposure for 162 hr. The amount of hydriding was observed to decrease with decreasing temperature at 75, 36, and -76 F. No surface hydriding was detected either by vacuum fusion analysis or by metallographic examination after exposure for 1458 hr at -110 or -160 F.
Stress corrosion cracking (SCC) experiments were conducted on Ti-8-1-1 wire specimens in hydrochloric and sulfuric acids of variable pH in order to determine the effect of pH on the susceptibility to cracking. The alloy exhibited increasing susceptibility with decreasing pH. By varying the applied potential, it was observed that susceptibility zones exist both in the cathodic and the anodic ranges. In the cathodic range, susceptibility also increased with decreasing applied potential. Corrosion potential-time data in hydrochloric acid (pH 1.7) and sulfuric acid (pH 1.7) indicate that chloride ions lower the corrosion potential of the specimen which, in turn, increases the susceptibility.
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Ti-8 Al-1 Mo-1 V was tested in solvents containing chloride, bromide or iodide ions. It was found that the region II plateau velocity could be correlated with the inverse of the viscosity for several solvents. It seems most likely that this reflects the influence of the viscosity on the diffusion coefficient of some species involved in a mass transfer process which limits the crack growth. Associated tests were performed in which the potential, pH and concentration of Cl- were varied, in some of the same solutions as used for the viscosity tests. It is concluded from these tests that the absence of cathodic protection against cracking in solutions of low pH arises from an ohmic effect which isolates the crack tip from external potential control.
The influence of exposure cycle on the hot-salt stress-corrosion cracking resistance of the Ti-8Al-1Mo-1V alloy was determined. Both temperature and stress were cycled simultaneously to simulate turbine-powered aircraft service cycles. Temperature and stress were also cycled independently to determine their individual effects. Substantial increases in crack threshold stresses were observed for cycles in which both temperature and stress or temperature alone were applied for 1 hour and removed for 3 hours. The crack threshold stresses for these cyclic exposures were twice those determined for continuous exposure for the same total time of 96 hours.
Study suggests ways of reducing chatte, increasing productivity, and reducing tool wear. Report also describes static and dynamic cutting tests and tool materials and finishes.
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Development efforts have been undertaken to improve the processing and structural efficiencies of advanced cold-formable beta Ti alloys, using the standard, hot-formed and rivetted construction of Ti-6Al-4V sheet structures as a basis for comparison. Ti-15V-3Cr-3Al-3Sn (Ti-15-3) beta alloy is formable, brazable and weldable in the solution-treated condition, and after aging displays mechanical properties suitable for postulated service in the -65 to 600 F temperature range. A novel methodology using cold-formed Ti-15-3 stringers and Ti-6Al-4V face sheets that are joined by means of an out-of-furnace isothermal brazing process, followed by low temperature aging, can reduce production costs by as much as 28 per cent. Structural efficiency has been demonstrated in room and elevated temperature crippling tests of small skin-stringer assemblies.
(Previously announced in STAR as N82-20551)
The present investigation is concerned with the mutual influence of creep and fatigue in the case of Ti-6211, which represents a new weldable, stress-corrosion resistant alloy. Attention is given to the effect of creep on fatigue, the effect of fatigue on creep, and microstructural studies. It is found that prior creep in the amounts investigated, from 0.2 percent to 2.7 percent, is beneficial to low-cycle fatigue life. Hold time at peak strain is found to be beneficial to low-cycle fatigue life. Hold time at constant stress has no effect on low-cycle fatigue when specimens are cycled only once between hold times; but increasing fatigue loading for 50 or more cycles between hold times can prolong the fatigue life. There is an acceleration of creep by cyclic loading when comparison of cyclic and static creep is based on mean stress.
Emerging evidence that the sliding between alpha and beta interfaces reported in both Ti-Mn alloys and the Ti-4.5Al-5Mo-1.5Cr ('Corona 5') alloy at room temperature is associated with hydrogen suggests that this may be a general problem contributing to Ti alloys' room-temperature creep. The present evaluation of experimental data indicates that while the hydrogen is concentrated at the Ti-Mn alloys' beta phase, no hydride formation at the alpha/beta interfaces has been reported for either the Ti-Mn alloys or Corona 5. If a hydrogen flux is needed, sliding at the alpha-beta interfaces should be a function of total hydrogen content in the alloy.
The Ti-6Al-4V-constructed retropropulsion-module tanks of the Galileo spacecraft were purged with nitrogen tetroxide in order to wait out a major launch rescheduling; nitric acid is among the residual products of such an operation. A test program was conducted on representative samples to ascertain the fracture toughness and stress corrosion threshold of the tanks' material, in view of Space Shuttle safety and mission-reliability requirements. It was found that the tanks' structural integrity was not degraded by nitric acid exposure.