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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Experimental Replication of Relict "Dusty" Olivine in Type 1B Chondrules

Introduction: Relict "dusty" olivine is considered to be a remnants of previous chondrule forming events based on petrographic and chemical evidence. Dynamic crystallization experiments confirm that dusty olivine can be produced by reduction of FeO-rich olivine in Unequilibrated Ordinary Chondrite (UOC) material. The results of these experiments compliment those of who also produced dusty olivine, but from synthetic starting materials. Techniques: Dynamic crystallization experiments were conducted in which UOC material was reduced in presence of graphite. Starting material was coarsely ground GR095554 or WSG95300 that contained olivine of Fo 65-98. Approximately 75 mg. of UOC material was placed in a graphite crucible and sealed in an evacuated silica tube. The tube was suspended in a gas-mixing furnace operated at 1 log unit below the IW buffer. The experiments were as brief as 1.5 hrs up to 121 hrs. Results: Dusty olivine was produced readily in experiments melted at 1400 C for I hr. and cooled between 5 and 100 C/hr or melted at 1300-1400 C for 24 hours. Fe-rich olivine (dusty olivine precursors) that have been partially reduced were common in the experiments melted at 1400 C and cooled at 1000 C/hr or melted at 1200 C for 24 hrs. Relict olivine is absent in experiments melted at 1400 for 24 hrs, melted above 1400 C, or cooled more slowly than 10 C/hr. Relict olivine in the experiments has minimum Fo value of 83 . Thus even in the shortest experiments the most Fe-rich olivine has been altered significantly. The precursor olivine disappears in a few to many hours depending on temperature. The experiments show Fe-rich olivine in all stages of transition to the new dusty form. The olivine is reduced to form dusty olivine in a matter of a few hours at temperatures less than 1400 C and in minutes at higher temperatures. The reduction appears to proceed from the rim of the crystal inward with time. The reduction appears initially rectilinear as if controlled by crystallography, but with time Fe-metal blebs are randomly distributed throughout the olivine. In a given experiment, dusty olivine can be found in varying stages of development, but in the longest experiments, the Fe-metal blebs are dominant and they appear to be migrating out of the olivine. The composition of the dusty olivine ranges from Fo 94-99. The Cr, Mn, and Ca content of the newly formed, dusty olivine is slightly less on average that the precursor olivine, but is till with the range of type 1 olivine. Chadacrysts in the low Ca pyroxene are most common in the higher temperature, more slowly cooled experiments and range in composition from Fo 90-99. Application to chondrule formation: These experiments place time-temperature limits on the preservation of Fe-rich olivine and the production of dusty olivine during chondrule forming events. The reduction process proceeds in a few hours at temperatures above 1400 C and in 10's of hours at temperature between 1200 and 1300 C. This result further confirms th at chondrules form in a few hours to days as suggested earlier. The experiments also confirm that dusty olivine can form from typical Fe-rich olivine in UOC material during the recycling of such olivine in the chondrule forming process.

Lofgren, Gary E.↗
DOE OSTI2026

Characterizing core and edge turbulence regimes with fluctuation imaging diagnostics in Wendelstein 7-X

Two density fluctuation imaging systems, phase contrast imaging (PCI) and gas puff imaging (GPI) measure spatially resolved density fluctuations with high time resolution throughout the core plasma (PCI) and in the scrape-off layer (GPI) of the Wendelstein 7-X (W7-X) stellarator. Both systems combined give a comprehensive overview of overall fluctuation levels, spectral properties such as their distribution in frequency and wavenumber space as well as their spatial distribution. These tools are used to assess changes in density turbulence in three representative discharges that transition into stable divertor detachment by different strategies (impurity seeding, density ramping and power starvation). Several general trends are identified when the radiated power fraction is systematically increased: In the plasma edge, the line emission observed by GPI shifts radially inward with a drop in electron temperature, and normalized intensity fluctuation profiles follow this inward shift. Skewness and kurtosis of these edge fluctuations are reduced, indicating a reduction of large intermittent transport events, and poloidal phase velocities decrease in magnitude. These observations are consistent with a reduced power input into the plasma edge and a general reduction of turbulent activity. Core density fluctuation levels remain nearly constant in the impurity seeding scenario, indicating that detachment does not significantly impact turbulence there. However, a strong reduction in the dominant outboard fluctuation phase velocity is observed that deviates from the previous interpretation of neoclassical radial electric field changes, showing that the core plasma is not completely unaffected. In the density ramp and power starvation scenarios, undesirable and irregular large-scale events arise clearly in both diagnostic systems as the radiative fraction is increased. Impurity seeding therefore seems to be a promising strategy on W7-X to achieve detachment without significantly altering core turbulence, especially when targeting a specific operating point in core density and heating power.

Wendelstein 7-X↗
NASA NTRS1979

Nonlinear Landau damping in the ionosphere

A model which explains the nonresonant waves which produce the diffuse resonance observed near 3/2 f(H) by the Alouette and Isis topside sounders, where f(H) is the ambient electron cyclotron frequency, is presented. These waves are the result of plasma wave instabilities driven by anisotropic electron velocity distributions initiated by the high-power short-duration sounder pulse. Calculations of the nonlinear wave-particle coupling coefficients show that the diffuse resonance wave can be maintained by nonlinear Landau damping of the sounder-stimulated 2f(H) wave which is observed with a time duration longer than that of the diffuse resonance wave. The time duration of the diffuse resonance is determined by the transit time of the instability-generated and nonlinearly maintained diffuse resonance wave from the remote short-lived hot region back to the antenna. The model is consistent with the Alouette/Isis observations and it demonstrates the existence of nonlinear wave-particle interactions in the ionosphere.

Kiwamoto, Y.↗
NASA NTRS1985

Multifrequency observations of dwarf novae outbursts

Studies using EXOSAT and IUE data combined with ground-based optical and IR photometry, spectroscopy and polarimetry of the transition timescales and physical properties of the high accretion rate states of the disks in cataclysmic variables are discussed. Implications for dwarf novae stem from comparison of the timing and amplitude of the optical and IR rise with that of the UV and X-ray; the development of the optical and UV line profile changes as the outburst develops; and the similarity of the outburst flux distributions in different systems and different types of outbursts (standstills and supermaxima). These features of dwarf novae outbursts present interesting comparisons with the outbursts of systems like TV Col and GK Per.

Szkody, P.↗
NASA NTRS1992

Distributed traffic signal control using fuzzy logic

We present a distributed approach to traffic signal control, where the signal timing parameters at a given intersection are adjusted as functions of the local traffic condition and of the signal timing parameters at adjacent intersections. Thus, the signal timing parameters evolve dynamically using only local information to improve traffic flow. This distributed approach provides for a fault-tolerant, highly responsive traffic management system. The signal timing at an intersection is defined by three parameters: cycle time, phase split, and offset. We use fuzzy decision rules to adjust these three parameters based only on local information. The amount of change in the timing parameters during each cycle is limited to a small fraction of the current parameters to ensure smooth transition. We show the effectiveness of this method through simulation of the traffic flow in a network of controlled intersections.

Chiu, Stephen↗
NASA NTRS1999

MOLA-derived Roughness Data Used to Predict Surface Scattering for Mars Subsurface Radar Sounding

The Mars Express orbiter, to be launched by the European Space Agency in 2003, will carry a low-frequency radar sounding instrument, MARSIS (Mars Advanced Radar for Subsurface and Ionospheric Sounding). The primary goal of MARSIS is to map the distribution of water, both solid and (if present) liquid, in the upper several km of the martian crust. Detecting discontinuities in the crust, such as an ice-water transition, presents many challenges for a Mars orbital radar sounder. One challenge that must be overcome is the presence of radar scattering (echoes) from the surface of Mars, expected to be detected by the sounder antennas at the same time as any echoes aris-ing from subsurface interfaces. As the transmitted spherical wavefront spreads within the crust of Mars,. it also interacts with surface topography at off-nadir positions, creating a "clutter" signal that can mask the subsurface echoes. The MARSIS instrument will utilize Doppler filtering to limit the off-nadir clutter in the along-track direction, and a nadir-null secondary antenna to identify strong off-nadir clutter from the cross-track direction. To evaluate the effects of off-nadir surface clutter and the capability of these schemes to reduce the clutter, it is necessary to predict the range of scattering behavior that may be expected from martian surface topography. In this paper, we utilize Mars Orbital Laser Altimeter (MOLA) data from the current Mars Global Surveyor mission to characterize the topographic roughness of a variety of martian terrain types, at scales relevant to the MARSIS clutter problem. Segments of MOLA altimetry profiles are reduced to the topographic parameters rms slope and fractal dimension, which then are used as inputs to a near-nadir radar scattering model to predict the strength of the clutter signal. Additional information is contained in the original extended abstract.

Plaut, J. J.↗
NASA NTRS2006

Uses of the ICRF and implications for future VLBI

Since its inception on 1 Jan 1998, the fundamental ICRF has been set by the VLBI positions of 212 "defining" extragalactic radio sources. In all there are approx.3000 sources with usefully accurate (< few mas) positions consistent with the ICRF. The uses of the ICRF include fundamental astrometry, monitoring of Earth orientation, and spacecraft navigation. For fundamental astrometry, stability and accuracy are most important, and realizations at different frequencies must be in proper registration. However, there is no preferred frequency, and the GAIA mission has the potential for an optical ICRF with 500,000 objects at the 50 microarcsec level some time after the planned 2011 launch. The radio ICRF should be properly prepared for a transition to assure long term stability and consistency. Earth orientation monitoring requires objects attached to the solid Earth, and VLBI will continue to be the fundamental technique. For this purpose it is essential that the new VLBI stations contemplated in the VLBI20l0 report be capable of observing a sufficiently large and well-distributed set of stable sources, and identifying these sources is an on-going effort. Spacecraft navigation by differential VLBI is planned using the Ka-band telemetry signal, and work has begun towards an ICRF realization suitable for this purpose. The balancing of different needs related to the VLBI ICRF will be discussed.

Ma, Chopo↗
NASA NTRS2010

Role of the Russell-McPherron Effect in the Acceleration of Relativistic Electrons

While it is well known that high fluxes of relativistic electrons in the Earth's radiation belts are associated with high-speed solar wind and its heightened geoeffectiveness,less known is the fact that the Russell McPherron(R M) effect strongly controls whether or not a given high-speed stream is geoffective. To test whether it then follows that the R M effect also strongly controls fluxes of relativistic electrons, we perform a superposed epoch analysis across corotating interaction regions (CIR) keyed on the interfaces between slow and fast wind. A total of 394 stream interfaces were identified in the years 1994-2006. Equinoctial interfaces were separated into four classes based on the R-M effect,that is, whether the solar wind on either side of the interface was either(geo)effective (E) or ineffective (I) depending on season and the polarity of the interplanetary magnetic field (IMF). Four classes of interface identified as II, IE, EI,and EE are possible. The classes IE and EI correspond to CIRs with polarity changes indicating passage through the heliospheric current sheet. To characterize the behavior of solar wind and magnetospheric variables, we produced maps of dynamic cumulative probability distribution functions (cdfs) as a function of time over 10-day intervals centered on the interfaces. These reveal that effective high-speed streams have geomagnetic activity nearly twice as strong as ineffective streams and electron fluxes a factor of 12 higher. In addition they show that an effective low-speed stream increases the flux of relativistic electrons before the interface so that an effective to ineffective transition results in lower fluxes after the interface.We conclude that the R-M effect plays a major role in organizing and sustaining a sequence of physical processes responsible for the acceleration of relativistic electrons.

McPherron, R. L.↗
NASA NTRS2019

Airspace Technology Demonstration 3 (ATD-3): Dynamic Routes for Arrivals in Weather (DRAW) Technology Transfer Document Summary Version 2.0

Airspace Technology Demonstration – 3 (ATD-3) is part of NASA’s Airspace Operations and Safety Program (AOSP) – specifically, its Airspace Technology Demonstrations (ATD) Project. ATD-3 is a multi-year research and development effort which proposes to develop and demonstrate automation technologies and operating concepts that enable air navigation service providers and airspace users to continuously assess weather, winds, traffic, and other information to identify, evaluate, and implement workable opportunities for flight plan route corrections that can result in significant flight time and fuel savings in en route airspace. In order to ensure that the products of this tech-transfer are relevant and useful, NASA has created strong partnerships with the FAA and key industry stakeholders. This summary document and accompanying technology artifacts satisfy the third Research Transition Product (RTP) defined in the Applied Traffic Flow Management (ATFM) Research Transition Team (RTT) Plan, which is Dynamic Routes for Arrivals in Weather (DRAW). This technology transfer consists of artifacts for DRAW Arrival Metering (AM) Operations delivered in June 2018, DRAW AM updates, and DRAW Extended Metering (XM) Operations. Blue highlighting indicates the new or modified deliverables. Some of the artifacts in this technology transfer have distribution restrictions that need to be followed. Distribution information is noted in each section. DRAW is a trajectory-based system that combines the legacy Dynamic Weather Routes (DWR) weather avoidance technology with an arrival-specific rerouting algorithm and arrival scheduler to improve traffic flows on weather-impacted arrival routes into major airports. First, DRAW identifies flights that could be rerouted to more efficient Standard Terminal Arrival Routes (STARs) that may have previously been impacted by weather. Second, when weather is impacting the arrival routing, DRAW proposes simple arrival route corrections that enable aircraft to stay on their flight plan while avoiding weather. The DRAW system proposes reroutes early enough to allow Time Based Flow Management (TBFM) to make the necessary schedule adjustments. As a result, metering operations can be sustained longer and more consistently in the presence of weather because the arrival schedule accounts for the dynamic routing intent of arrival flights to deviate around weather. The first DRAW tech transfer in June 2018 focused on arrival metering operations with the DRAW algorithm implemented in the NASA Center TRACON Automation System (CTAS) automation software. This tech transfer delivery includes updates for DRAW implemented in FAA’s TBFM 4.7 automation software and preliminary research into DRAW for XM operations.

Isaacson, Douglas R.↗
DOE OSTI2025

The evidence of N = 16 shell closure and β -delayed neutron emission from 25 F

We measured the β -delayed neutron emission from 25 F for the first time at the Facility for Rare Isotope Beams (FRIB). Using combined neutron and γ -ray detector systems of the FRIB Decay Station Initiator (FDSi), we observed β -decay transitions populating neutron unbound states between 4.2 and 8 MeV in 25 Ne. The experimental results led to the revision of the β -decay half-life and β -delayed neutron-emission probability of 25 F. The β -decay strength distribution of 25 F extracted from the data agrees with the shell-model predictions using the USDB and SDPF-M effective interactions. This result indicates that the spherical neutron shell gap persists in 25 F and 25 Ne.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1957

Free-Flight Skin Temperature and Pressure Measurements on a Slightly Blunted 25 Deg Cone-Cylinder-Flare Configuration to a Mach Number of 9.89

Skin temperatures and surface pressures have been measured on a slightly blunted cone-cylinder-flare configuration to a maximum Mach number of 9.89 with a rocket-propelled model. The cone had a t o t a l angle of 25 deg and the flare had a 10 deg half-angle. Temperature data were obtained at eight cone locations, four cylinder locations, and seven flare locations; pressures were measured at one cone location, one cylinder location, and three flare locations. Four stages of propulsion were utilized and a reentry type of trajectory was employed in which the high-speed portion of flight was obtained by firing the last two stages during the descent of the model from a peak altitude of 99,400 feet. The Reynolds number at peak Mach number was 1.2 x 10(exp 6) per foot of model length. The model length was 6.68 feet. During the higher speed portions of flight, temperature measurements along one element of the nose cone indicated that the boundary layer was probably laminar, whereas on the opposite side of the nose the measurements indicated transitional or turbulent flow. Temperature distributions along one meridian of the model showed the flare to have the highest temperatures and the cylinder generally to have the lowest. A maximum temperature of 970 F was measured on the cone element showing the transitional or turbulent flow; along the opposite side of the model, the maximum temperatures of the cone, cylinder, and flare were 545 F, 340 F, and 680 F, respectively, at the corresponding time.

Bond, Aleck C.↗
NASA NTRS1992

CELIAS: Charge, Element and Isotope Analysis System for the SOHO mission

The status and further development as well as first calibration of the CELIAS experiment on SOHO is presented. CELIAS is designed to measure the mass, ionic charge, and energy of low and high speed solar wind of suprathermal ions and of low energy flare particles. Through analysis of the elemental and isotopic abundances (the ionic charge state and velocity distributions of ions originating on the solar atmosphere), the investigation focuses on studying the plasma processes in various temporal and spatial scales in the solar chromosphere, transition zone, and corona. Additionally, the CELIAS experiment includes the Solar EUV Monitor (SEM). This unit, which consists of an EUV transmission grating spectrometer and three isolated silicon photodiodes as detectors, is described. The three mass and charge discriminating sensors based on the time of flight technique are also described.

Hovestadt, D.↗
NASA NTRS2021

Generation of High-frequency Whistler Waves in the Earth's Quasi-Perpendicular Bow Shock

We use observations from the Magnetospheric Multiscale spacecraft to identify a free energy source for high-frequency whistler waves in the Earth's quasi-perpendicular bow shock. In the considered measurements, whistlers propagate both parallel and antiparallel to the background magnetic field B0 with frequencies around 100 Hz (0.15 fce, where fce is the electron cyclotron frequency) and amplitudes between 0.1 and 1 nT. Their growth can be attributed to localized pitch angle anisotropy in the electron velocity distribution function that cannot be precisely described by macroscopic parameters like heat flux or temperature anisotropy. However, the presence of heat flux along −B0 does create preferential conditions for the high-frequency whistler waves that propagate in this direction. These waves are directed partially toward the shock, meaning they can scatter electrons that are streaming from the shock. This prolongs the time the electrons spend in the shock transition region and thereby promotes electron energization.

Brent Page↗
DOE OSTI2024

Transitions To Two-Hadron States From Quantum Chromodynamics

The rich spectrum of hadrons reflects the complexity of interactions between the quarks and gluons confined within them. Most of these hadrons are extremely short-lived and are called resonances. Experimentally, they are observed indirectly through their effects on the energy distribution in scattering experiments. Additionally, the non-perturbative nature of Quantum Chromodynamics (QCD), which governs the dynamics of quarks and gluons, prevents the implementation of known analytical techniques for calculating transition and interaction rates between hadrons. Lattice QCD (LQCD), a numerical implementation of QCD, provides a non-perturbative approach to studying the spectrum, as long as we understand how to account for finite-volume and imaginary-time effects in our calculations. In this dissertation, we present two main results. First, the formalism for extracting the elastic form factors of resonances from LQCD, which is necessary to understand their internal structure. Second, we perform the first numerical calculation of a coupled-channel transition, the timelike form factor of the pion, extending into the inelastic region above the kaon-antikaon threshold, as well as its connection to the spacelike region. These developments open the door for future calculations that explore the non-trivial internal structure of QCD resonances.

Gama, Felipe Ortega↗
DOE OSTI2026

Microchannel-based Membrane-less Extraction of Li from Unconventional Lithium Sources & the Separation of REE

This final report provides an overview of the Project's entire duration, covering July 1, 2021 to December 31, 2023. It primarily focuses on the achievements, technological developments, and unique challenges the team faced while working on separating and extracting Lithium from produced waters. The project's primary aim was to create an integrated, high-throughput, membrane-less, and modular microfluidic platform that could extract Lithium from unconventional sources. We have successfully met all goals and milestones envisioned in the SOPO document. The most critical primary milestones, including the Go-No-Go milestone (refer to the Gantt chart in the Appendices), were successfully accomplished. We demonstrated phase separation (>90%) and extraction (>85%) performance in the MPSE using synthetic, and representative produced water composition feed at 50 ml/min total flow through MPSE 36. We have also performed a parametric study of the MPSE operations, beyond the scope of SOPO, exploring operating conditions of current and broader interest. The extended investigation of operational parameters is concurrent with our efforts to seek further development of the MPSE technology beyond the scope of the Project. Along these lines of development, we have made efforts to be responsive to DOE calls for technological developments of other types of resources (beyond PW) for the recovery of Critical Materials and higher TRL development (beyond TRL 4). During the work on this Project, we developed and implemented three innovative technical approaches that emerged from our efforts to successfully meet the Project milestones. The innovative & original technical approaches developed and implemented in this Project are now the contributions to process engineering that could be clearly credited to the Project. First, Convergent Design Approach is a comprehensive feedforward & feedback loop of four design phases: i) design for functionality, ii) design for manufacturing, iii) design for sustainability, and iv) design for market. Next was Process Intensification. A major aim of this Project was to create an innovative phase separation & extraction microscale-based technology for Li separation – thus the words microchannel-based in the Project title. A microscale-based technology is intrinsically in the center of the Process Intensification domain as defined by its unique principles. Therefore, Process Intensification was implicitly envisioned in the Project’s SOPO. Lastly, Time Scale Analysis is a novel tool for discovering the needs and directions of Process Intensification implementations in any process technology. This Project is fully credited for developing and implementing the three novel technical approaches mentioned above. These are general contributions to process engineering that emerged from this Project. Beyond the original SOPO scope, the OSU-U.Pitt research group utilized a Convergent Design methodology, integrating first-principles mathematical modeling with experimental validation on the Minimum Development Vehicle. By creating these Digital Twins, the team rapidly assessed manufacturing iterations to support TEA analysis. This framework further enabled the development of advanced Surface Modification Techniques, where hydrophobic and oleophobic coating strategies were optimized via Digital Twin tools and validated through rigorous 100-hour longevity testing. TEA Analysis: The closing efforts of this Project were focused on the TEA analysis. TEA analysis had two primary functions: i) enabling critical assessments of design variations withing 10 the Concurrent Design Approach, thus enabling evolution of the MPSE design to reach faster- better-cheaper alternatives; and ii) to create a bridge between the accomplishments of this Project and future projects of higher TRL, beyond TRL 6 level. It is important to note that the TEA model created in the Project stirred the technological solutions for the recovery of critical materials toward a vision of a very profitable modular plant that has unique zero-waste water discharge signature. More importantly, thanks to our experimental performance data and conservative assumptions, the TEA model predicts minimal technological and investment risks. Low cost of a modular unit of a nominal capacity of [1000 tons of Li 2 CO 3 /year] positions the MPSE based technology within the reach of community investors, thus offering a paradigm shift in the development of critical technologies. The project successfully navigated two primary challenges: solvent selection and manufacturing adaptation. Restricted by the SOPO to existing literature for lithium recovery, the team identified a critical need for a "material excellence program" to develop next-generation solvents, eventually concluding with a preliminary investigation into promising Ionic Liquids (ILs). Simultaneously, COVID-19 supply chain disruptions forced a pivot from traditional manufacturing to advanced additive methods at ATAMI-OSU. By transitioning from stainless steel to 3D-printed polymer substrates, the team achieved a transformative three-order-of- magnitude reduction in manufacturing costs and compressed prototyping timelines from several months to just two days. The MPSE technology offers significant energy, environmental, and economic advantages by overcoming the traditional bottlenecks of phase-separation hardware and contactor size. Unlike conventional mixer-settlers or membrane-based systems, MPSE operates without moving parts or fouling-prone membranes, achieving robust performance even with challenging, viscous, or particulate-heavy feeds. Key performance metrics include an energy intensity reduction of 5–50x (3–40 kJ/m 3 ) compared to incumbent technologies and a dramatic reduction of processing time to under 60 seconds, which drastically reduces the physical plant footprint. These technical efficiencies translate into superior economic outcomes; for a 100 t/year Li 2 CO 3 facility, implementing MPSE is projected to nearly halve contactor CAPEX (from $\$$6.08M to $\$$3.01M) and significantly increase the project's Net Present Value (NPV), derisking new investment and enabling distributed critical-mineral processing configurations. The commercialization of MPSE technology is being spearheaded by Vigsur Dynamics Inc., which has adopted a structured, parallel approach to technical and business development since its formation in January 2026. Following extensive customer discovery and engagement with the Oregon State University accelerator, Vigsur Dynamics is working to establish a business model that transitions from pilot demonstrations to modular hardware sales, ultimately aiming for a "build-own-operate" service strategy. Current technical milestones—including 100 hours of continuous operation, superior energy efficiency, and successful 6-unit modular scale-up— provide a foundation for this transition. Backed by ongoing IP licensing and a growing network of industrial and venture advisors, the company is actively de-risking the platform to replace conventional mixer-settler systems in the critical minerals market.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Ground state rotational and kinetic temperatures of C 2 molecules in a laser-produced plasma

This study presents an experimental comparison between rotational and kinetic temperatures of molecular species in a laser-produced plasma, utilizing tunable laser absorption spectroscopy. We analyzed high-resolution and time-resolved absorption spectra of 31 rotational transitions within the Phillips A 1 II u –X 1 Σ g 3-0 band of the C 2 molecule, measured from a laser-produced graphite plasma in ~2 Torr argon, within the 771–781 nm spectral range. Spectral fitting provided quantitative state column densities of C 2 rotational energy levels in the ground electronic and vibrational states. Boltzmann analysis revealed thermalized rotational distributions showing rotational temperatures decreasing from 3000 to 600 K within 5–500 μs following the onset of the laser plasma. The measured kinetic and rotational temperatures of C 2 molecules are comparable, suggesting that collisional processes in the laser-produced plasma are sufficient to maintain thermal equilibrium between the C 2 molecules and the Ar background gas.

Absorption spectroscopy↗
NASA NTRS1976

The waveguide laser - A review

The present article reviews the fundamental physical principles essential to an understanding of waveguide gas and liquid lasers, and the current technological state of these devices. At the present time, waveguide laser transitions span the visible through submillimeter regions of the wavelength spectrum. The introduction discusses the many applications of waveguide lasers and the wide variety of laser configurations that are possible. Section 1 summarizes the properties of modes in hollow dielectric waveguides of circular, rectangular, and planar cross section. Section 2 considers various approaches to optical feedback including internal and external mirror Fabry-Perot type resonators, hollow waveguide distributed feedback structures, and ring-resonant configurations. Section 3 discusses those aspects of molecular kinetic and laser theory pertinent to the design and optimization of waveguide gas lasers.

Degnan, J. J.↗
DOE OSTI2026

Entropy-defect synergy for dual luminescence mechanism in spinel: Time-resolved anti-counterfeiting and fingerprint visualization

Multimodal luminescent materials, while promising for anti-counterfeiting, often lack dynamic time-dependent responses and controllable spatial distribution, limiting their encryption capabilities in the spatiotemporal dimension. Here, this work presents a coordinated control strategy based on entropy and defect engineering, and uses a backpropagation (BP) neural network for material screening to successfully prepare spinel Mg 0.8 (Fe 0.04 Co 0.04 Ni 0.04 Cu 0.04 Zn 0.04 )Cr 2 O 4 (MgA 5 CO) phosphors with time-dependent dynamic luminescence behavior. This phosphor simultaneously activated the d-d transition luminescence (∼618 nm) derived from Co 2+ /Cr 3+ and the defect luminescence (∼398 nm) related to zinc vacancies (V Zn ) in a single-phase solid solution. The phosphor exhibits a time-dependent color evolution from pink to purple under fixed-wavelength excitation, due to the different excited-state dynamics and decay lifetimes associated with the d-d transition and defect luminescence. Structural characterization and spectral analysis confirmed the existence of V Zn and its significant role in defect luminescence process. The fluorescent and dynamic luminescent properties of entropy-based spinel oxide enable its use in advanced anti-counterfeiting applications like fingerprint recognition and color-changing dedicated anti-counterfeiting mark, showing promise in high-end and time-dynamic anti-counterfeiting fields. This research not only developed a new type of fluorescent dynamic anti-counterfeiting material, but also provided a new idea for constructing advanced optical functional materials with multiple luminescence mechanisms.

Defect project↗