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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

The Effects of Shockwave Pressures on Ultrafast Vibrational Energy Transfer in BNFF, a Hydrogen-Free Energetic Material

Energy conversion in energetic materials from shock-wave-induced lattice compression to bond breaking critically depends on vibrational coupling and energy transfer between intra- and intermolecular vibrations, though the details of the mechanisms remain unknown. Herein, we indirectly tune the strength of intermolecular interactions in 3,4-bis(3-nitrofurazan-4-yl)furoxan (BNFF), a hydrogen-free energetic material characterized by van der Waals interactions, by applying high static pressure using a diamond anvil cell and monitoring vibrational energy transfer (VET) with ultrafast broadband infrared pump–probe spectroscopy. As BNFF is compressed from ambient pressure to 9 GPa, we find that VET accelerates by ∼ 0.9 ps/GPa. Density functional theory is applied in tandem with experiments to assign mode character and elucidate VET pathways. In conclusion, we find that furazan ring O–N–O vibrations, which are high-frequency detonation-relevant vibrational modes, experience increased sensitivity to lattice compression under shockwave pressures. These findings provide new mechanistic insight into how intermolecular interactions govern the rate and selectivity of VET.

Energy transfer↗

Vibrational Quantum-State-Controlled Reactivity in the O 2 + + C 3 H 4 Reaction

Quantum-state-controlled reactivity is a long-standing goal in the field of physical chemistry. In this work, we explore the vibrational-state-dependent behavior of the ion–molecule reaction between O 2 + in distinct vibrational states and two isomers of C 3 H 4 , allene (H 2 C 3 H 2 ) and propyne (H 3 C 3 H). While most products are formed regardless of the vibrational state of O 2 + , the branching ratios are influenced by vibrational excitation, and a new product, C 2 O + , appears exclusively in the excited-state reactions. This selective formation of C 2 O + demonstrates that vibrational excitation can effectively activate a reaction pathway, providing direct evidence of quantum-state control in the reactivity. These results represent an important step toward the goal of quantum-state-controlled chemistry in molecular systems.

Chemical reactions↗

Preliminary vibration design and test criteria considerations for the space shuttle

This paper presents some Marshall Space Flight Center preliminary vibration design and test criteria considerations for the space shuttle. The discussion is primarily concerned with the formulation of vibration criteria for the design and testing of the equipment installations on the shuttle. A recommended criteria format is presented with a discussion of when the vibration environment has to be considered in design and testing. A semiempirical method of predicting the vibration criteria for the shuttle from vibroacoustic structural data banks is presented. Some preliminary vibration criteria predictions are presented for the orbiter and booster equipment bays and for the main shuttle engine. A research testing program to determine the vibroacoustic transfer through a typical shuttle thermal protection system (TPS) panel configuration is described.

Harry J. Bandgren↗

Vibration and aerodynamic buckling experiments for blunt truncated conical shells with ring-supported edges

The vibration and buckling characteristics of a series of 140 deg ring-supported conical shells have been investigated experimentally and analytically. Experimental results were obtained from 14 conical shells, each attached to a solid nose cap at the small end. The large (base) end was either free or attached to a solid ring of rectangular cross section. The size of the solid base rings of rectangular cross section was systematically varied to provide a wide range of edge restraint. Shell buckling was induced by aerodynamic loading at a Mach number of 3; the vibration data were obtained prior to the wind tunnel tests. The experimental vibration data indicated that the size of the base rings had a pronounced effect on the magnitude of the frequencies and on the frequency spectrum. For vibration modes having less than two circumferential waves, the frequencies descreased with increasing ring size; whereas, for modes with several circumferential waves, the frequencies initially increased rapidly with ring size and then became relatively insensitive to further increases in ring size. This latter behavior was similar to the trend exhibited by the variation of buckling pressure with ring size. The experimental results were in excellent qualitative agreement with theoretical results and indicated that current shell-of-revolution analyses are adequate for predicting the vibration and buckling behavior of ring-supported shells, at least for the simple isotropic shells considered in this investigation.

Miserentino, R.↗

Short term response of insulin, glucose, growth hormone and corticosterone to acute vibration in rats.

Study carried out to obtain some notion of the initial phasing and interactive effects among some hormones known to be responsive to vibration stress. Sprague-Dawley derived rats were exposed to the acute effects of confinement and confinement with lateral (plus or minus G sub y) vibration. The coincident monitoring of glucose, insulin, growth hormone, and corticosterone plasma levels, during and immediately subsequent to exposure to brief low level vibration, exhibits the effects of inhibition of insulin release by epinephrine. The ability of insulin (IRI) to return rapidly to basal levels, from appreciably depressed levels during vibration, in the face of elevated levels of glucose is also shown. Corticosterone responds with almost equal rapidity, but in opposite phase to the IRI. The immuno-assayable growth hormone (IGH) dropped from a basal level of 32 ng/ml to 7.3 ng/ml immediately subsequent to vibration and remained at essentially that level throughout the experiment (60 min). Whether these levels represent a real fall in the rat or whether they merely follow the immuno-logically deficient form is still in question.

Dolkas, C. B.↗

Escape conditioning and low-frequency whole-body vibration - The effects of frequency, amplitude, and controls for noise and activation.

Seven experiments are reported on low-frequency whole-body vibration and rats' escape conditioning in a modified Skinner box. In the first three studies, conditioning was observed but was independent of frequency. In experiment four, the number of escape responses was directly related to vibration amplitude. Experiment five was a control for vibration noise and noise termination; experiments six and seven studied vibration-induced activation. Noise termination did not produce conditioning. In experiment six, subjects made more responses when responding led to termination than when it did not. In experiment seven, subjects preferred a bar which terminated vibration to one which did not.

Wike, E. L.↗

Development and application of vibroacoustic structural data banks in predicting vibration design and test criteria for rocket vehicle structures

A method of predicting broadband random vibration criteria for components on space vehicles is presented. Large amounts of vibration and acoustic data obtained from flights and static firing tests of space vehicle were formulated into vibroacoustic data banks for structural categories of ring frame, skin stringer, and honeycomb. The vibration spectra with their associated acoustic spectra are normalized to a reference acoustic spectrum. The individual normalized spectra are grouped according to definite structural characteristics and statistically analyzed to form the vibroacoustic data banks described in this report. These data banks represent the reference vibration criteria available for determining the new vehicle vibration criteria.

Bandgren, H. J.↗

Fluid dynamic aspects of cardiovascular behavior during low-frequency whole-body vibration

The behavior of the cardiovascular system during low frequency whole-body vibration, such as encountered by astronauts during launch and reentry, is examined from a fluid mechanical viewpoint. The vibration characteristics of typical manned spacecraft and other vibration environments are discussed, and existing results from in vivo studies of the hemodynamic aspects of this problem are reviewed. Recent theoretical solutions to related fluid mechanical problems are then used in the interpretation of these results and in discussing areas of future work. The results are included of studies of the effects of vibration on the work done by the heart and on pulsatile flow in blood vessels. It is shown that important changes in pulse velocity, the instantaneous velocity profile, mass flow rate, and wall shear stress may occur in a pulsatile flow due to the presence of vibration. The significance of this in terms of changes in peripheral vascular resistance and possible damage to the endothelium of blood vessels is discussed.

Nerem, R. M.↗

Vibrational relaxation in expanding N2 and air

New N2 vibrational temperature data, obtained in expanding N2 and air using the electron beam technique, are analyzed permitting the vibrational relaxation times to be determined as a function of temperature. In addition, the effects on N2 vibrational relaxation times of direct vibrational energy transfer between N2 and H2O, between N2 and O2, and between N2 and free electrons introduced from arc contaminants are analyzed. The vibrational relaxation times determined from the present measurements agree with those measured in the expanding flows of shock tunnels and impact tubes. These expanding data also agree with relaxation times observed in acoustical resonant cavities where alternating compressions and expansions take place. The relaxation times in expanding flows (vib-tran exchange process) are found to be approximately 50 times faster than those measured in the compressing flow of shock tubes (tran-vib exchange process). This evidence strongly supports the concept that one relaxation time distribution cannot be applied to both exchange processes.

Sebacher, D. I.↗

Experimental forced vibration responses of test houses during the Edwards Air Force Base phase of the national sonic boom test program

Experimental vibration studies were conducted on two houses to determine some of the dynamic response characteristics, resulting from sonic boom. The primary objectives of the vibration tests were to identify the mode shapes associated with the various frequencies determined from the sonic boom response data, and to obtain some basic information about the vibration behavior of buildings in general. The results are presented of forced sinusoidal vibration studies of some components of the test structures. Included are acceleration response data on selected walls, wall surface modal patterns, and vibration induced noise measurements at various locations in the test structures.

Carden, H. D.↗

Vibration simulator studies for the development of passenger ride comfort criteria

A test program to determine the total discomfort associated with vehicle vibration is described. The program utilizes a three-degree-of-freedom vibration simulator to determine the effects of multifrequency and multiaxis vibration inputs. The approach to multifrequency vibration includes a separate consideration of the discomfort associated with each frequency component or band of the total spectrum and a subsequent empirical weighting of the discomfort components of these frequency bands when in various random combinations. The results are in the form of equal discomfort curves that specify the discomfort associated with discrete frequencies between 1 and 30 Hz and different acceleration levels. These results provide detailed information of the human discomfort response to increases in acceleration level for each frequency investigated. More importantly, the results provide a method for adding the discomfort associated with separate frequencies to give a total typification of the discomfort of a random spectrum of vibration.

Dempsey, T. K.↗

Vibration characteristics of 1/8-scale dynamic models of the space-shuttle solid-rocket boosters

Vibration tests and analyses of six 1/8 scale models of the space shuttle solid rocket boosters are reported. Natural vibration frequencies and mode shapes were obtained for these aluminum shell models having internal solid fuel configurations corresponding to launch, midburn (maximum dynamic pressure), and near endburn (burnout) flight conditions. Test results for longitudinal, torsional, bending, and shell vibration frequencies are compared with analytical predictions derived from thin shell theory and from finite element plate and beam theory. The lowest analytical longitudinal, torsional, bending, and shell vibration frequencies were within + or - 10 percent of experimental values. The effects of damping and asymmetric end skirts on natural vibration frequency were also considered. The analytical frequencies of an idealized full scale space shuttle solid rocket boosted structure are computed with and without internal pressure and are compared with the 1/8 scale model results.

Leadbetter, S. A.↗

Concorde noise-induced building vibrations for Sully Plantation, Chantilly, Virginia

A study to assess the noise-induced building vibrations associated with Concorde operations is presented. The approach is to record the levels of induced vibrations and associated indoor/outdoor noise levels in selected homes, historic and other buildings near Dulles and Kennedy International Airports. Presented is a small, representative sample of data recorded at Sully Plantation, Chantilly, Virginia during the period of May 20 through May 28, 1976. Recorded data provide relationships between the vibration levels of walls, floors, windows, and the noise associated with Concorde operations (2 landings and 3 takeoffs), other aircraft, nonaircraft sources, and normal household activities. Results suggest that building vibrations resulting from aircraft operations were proportional to the overall sound pressure levels and relatively insensitive to spectral differences associated with the different types of aircraft. Furthermore, the maximum levels of vibratory response resulting from Concorde operations were higher than those associated with conventional aircraft. The vibrations of nonaircraft events were observed in some cases to exceed the levels resulting from aircraft operations. These nonaircraft events are currently being analyzed in greater detail.

Mayes, W. H.↗

Sound radiation from randomly vibrating beams of finite circular cross section

The radiation of sound from vibrating cylindrical beams is analyzed based on the frequency of the beam vibrations and the physical characteristics of the beam and its surroundings. A statistical analysis of random beam vibrations allows this result to be independent of the boundary conditions at the ends of the beam. The acoustic power radiated by the beam can be determined from a knowledge of the frequency band vibration data without a knowledge of the individual modal vibration amplitudes. A practical example of the usefulness of this technique is provided by the application of the theoretical calculations to the prediction of the octave band acoustic power output of the picking sticks of an automatic textile loom. Calculations are made of the expected octave band sound pressure levels based on measured acceleration data. These theoretical levels are subsequently compared with actual sound pressure level measurements of loom noise.

Sutterlin, M. W.↗

Vibration testing of the JE-M-604-4-IUE rocket motor (Thiokol P/N E 28639-03)

The NASA International Ultraviolet Explorer (IUE) rocket motor (TE-M-604-4), a solid fuel, spherical rocket motor, was vibration tested in the Impact, Vibration, and Acceleration (IVA) Test Unit of the von Karman Gas Dynamics Facility (VKF). The objective of the test program was to subject the motor to qualification levels of sinusoidal and random vibration prior to the altitude firing of the motor in the Propulsion Development Test Cell (T-3), Engine Test Facility (ETF), AEDC. The vibration testing consisted of a low level sine survey from 5 to 2,000 Hz, followed by a qualification level sine sweep and qualification level random vibration. A second low level sine survey followed the qualification level testing. This sequence of testing was accomplished in each of three orthogonal axes. No motor problems were observed due to the imposition of these dynamic environments.

Alt, R. E.↗

Absolute intensity measurement of the 4-0 vibration-rotation band of carbon monoxide

The absolute intensity of the 4-0 vibration band of CO is measured in spectra obtained using a 25-m base-path multiple-traversal absorption cell and a 5-m scanning spectrometer. The intensities of individual vibration-rotation lines in this band are determined from measurements of their equivalent widths, and absolute values for the rotationless transition moment and the vibration-rotation interaction factor are derived from the measured line strengths. The experimentally obtained vibration-rotation function is compared with a theoretical curve; agreement between theory and experiment is found to be good for the P-branch but poor for the R-branch. It is noted that numerical solutions to the radial Schroedinger equation lead to vibration-rotation function values that are in good agreement with the experiment.

Chackerian, C., Jr.↗

The influence of molecular rotation on vibration-translation energy transfer

A three-dimensional vibration-rotation collision model is formulated within a semiclassical framework to study the effect of coupled rotational motion on the rate of vibrational energy transfer for collisions between anharmonic diatomic molecules and structureless atoms. Emphasis is on the net rates of vibrational energy transfer summed over all final rotational states rather than those for individual vibration-rotation transitions. The corresponding three-dimensional rate parameters are cast into forms that may be identified with equivalent parameters associated with the collinear approximation. Their comparisons allow the validity of a collinear model to be evaluated and some constraints on its application to be implied. The mechanisms of vibrational energy transfer including rotational transitions are shown to be separable into three classes which are identified and discussed

Mckenzie, R. L.↗

Noise-Induced Building Vibrations Caused by Concorde and Conventional Aircraft Operations at Dulles and Kennedy International Airports

Outdoor and indoor noise levels resulting from aircraft flyovers and certain nonaircraft events were recorded, as were the associated vibration levels in the walls, windows, and floors at building test sites. In addition, limited subjective tests were conducted to examine the human detection and annoyance thresholds for building vibration and rattle caused by aircraft noise. Representative peak levels of aircraft noise-induced building vibrations are reported and comparisons are made with structural damage criteria and with vibration levels induced by common domestic events. In addition, results of a pilot study are reported which indicate the human detection threshold for noise-induced floor vibrations.

Mayes, W. H.↗