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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

, Experimental Investigation of Electrically Charged Water Droplets Two-Phase Cross-Flow Interactions with Humid

Electrically charged water droplets can capture water vapor molecules in surrounding moist air and promote vapor condensation. This concept unfolds an alternative to mechanical cooling-based air dehumidification systems that separate sensible and latent cooling loads in HVAC applications. The effect of dielectrophoresis, electro-hydrodynamic, and micro-diffusive flows due to highly electrically charged water droplets traveling through moist air were investigated as new methods to reduce the air’s water vapor content. This paper presents new experimental data on humidification and power consumption for a system consisting of highly energized electrosprays in combination with mist eliminators. Electrosprays produced highly charged water spray cones crossing the air perpendicularly and upwardly. The moist air stream was circulated in a horizontal duct at 22C, 80% relative humidity, and 0.24 ms-1 airspeed. Mist eliminators made of stainless wire clothes of 36 and 25 μm pore diameter were used to screen the droplets growing during their flight trajectory. The mist eliminators blocked some of the largest diameter droplets. Still, they could not prevent re-evaporation of the droplets into the bulk air from the droplets deposited on their wire clothes. The equilibrium between the dielectrophoresis condensation from the electrosprays and the droplets’ re-evaporation phenomena resulted in reduced humidification when compared to conventional-type spray evaporative cooling systems. However, to dehumidify the air, the droplets injected by the electrosprays must be separated entirely and promptly removed from the bulk airflow at the end of their flight trajectory.

Electrostatic droplets, Electrospray, humidificati↗
DOE OSTI2022

Quantifying Subsurface Flow and Solute Transport in a Snowmelt‐Recharged Hillslope With Multiyear Water Balance

Abstract Quantifying flow and transport from hillslopes is vital for understanding water quantity and quality in rivers, but remains obscure because of limited subsurface measurements. Using measured hydraulic conductivity K profiles and water balance over a single year to calibrate a transmissivity feedback model for a hillslope in the East River watershed (Colorado) proved unsatisfactory for predicting flow over the subsequent years. Well‐constrained field‐scale K were obtained by optimizing subsurface flux predictions over years having large differences in recharge, and by including estimates of interannual transfer of excess snowmelt recharge. Water and solute exports during high snowmelt recharge occur predominantly via shallow groundwater flow through weathered rock and soil because of their enlarged transmissivities under saturated conditions. Conversely, these shallow pathways are less active in snow drought years when the water table remains deeper within the weathering zone. Hillslope soil water monitoring showed that rainfall does not infiltrate deeply during summer and fall months, and revealed water losses consistent with model ET predictions. By combining water table‐dependent fluxes with pore water chemistry in different zones, time‐dependent rates of solute exports become predictable. As an example, calibrated K were combined with dissolved nitrogen concentrations in pore waters to show the snowmelt‐dependence of reactive nitrogen exported from the hillslope, further supporting the recent finding that the weathering zone is the dominant source of reactive nitrogen at this site. Subsurface export predictions can now be obtained for wide ranges of recharge based on measurements of water table elevation and profiles of pore water chemistry.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Two-Phase Turbulence Statistics from High Fidelity Dispersed Droplet Flow Simulations in a Pressurized Water Reactor (PWR) Sub-Channel with Mixing Vanes

In the dispersed flow film boiling regime (DFFB), which exists under post-LOCA (loss-of-coolant accident) conditions in pressurized water reactors (PWRs), there is a complex interplay between droplet dynamics and turbulence in the surrounding steam. Experiments have accredited particular significance to droplet collision with the spacer-grids and mixing vane structures and their consequent positive feedback to the heat transfer recorded in the immediate downstream vicinity. Enabled by high-performance computing (HPC) systems and a massively parallel finite element-based flow solver—PHASTA (Parallel Hierarchic Adaptive Stabilized Transient Analysis)—this work presents high fidelity interface capturing, two-phase, adiabatic simulations in a PWR sub-channel with spacer grids and mixing vanes. Selected flow conditions for the simulations are informed by the experimental data found in the literature, including the steam Reynolds number and collision Weber number (Wec={40,80}), and are characteristic of the DFFB regime. Data were collected from the simulations at an unprecedented resolution, which provides detailed insights into the continuous phase turbulence statistics, highlighting the effects of the presence of droplets and the comparative effect of different Weber numbers on turbulence in the surrounding steam. Further, axial evolution of droplet dynamics was analyzed through cross-sectionally averaged quantities, including droplet volume, surface area and Sauter mean diameter (SMD). The downstream SMD values agree well with the existing empirical correlations for the selected range of Wec. The high-resolution data repository from the simulations herein is expected to be of significance to guide model development for system-level thermal hydraulic codes.

Saini, Nadish↗
DOE OSTI2024

Advancing a Watershed Hydro-Biogeochemical Theory: Linking Water Travel Time and Reaction Rates Under Changing Climate

The major goal of the project is to answer the question how and to what degree does a warming climate alter hydrological functioning and (biogeochemical and chemical weathering) reaction rates at the watershed scale? In particular, how does hydrological functioning (water storage, flow paths, and travel time) change responding to a warming climate? What are the corresponding alterations in biogeochemical and chemical weathering rates at the watershed scale? What is the general watershed-scale reaction rate law that causally links reaction rates to metrics of hydrological functioning that are determined by external hydroclimatic conditions and internal watershed structure characteristics? To answer these questions, we have used field measurements and reactive transport modeling. We have found that: 1) stream chemistry has altered tremendously in warmer years; 2) In this water-limited environment, hydrology is the dominant driver for soil respiration and carbon lateral export at the watershed scale; 3) deeper carbon respiration plays an essential role in regulating the patterns of stream carbon in low and high flow conditions, and deeper groundwater will become increasingly important as warming intensifies. This indicates in mountain streams, a warming climate will modify not only the timing and magnitude of streamflow as expected, but also the chemistry and quality of stream water.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Model, data, and code for paper "Modeling of streamflow in a 30-kilometer-long reach spanning 5 years using OpenFOAM 5.x"

The data package includes data, model, and code that support the analyses and conclusions in the paper titled “modeling of streamflow in a 30-kilometer-long reach spanning 5 years using OpenFOAM 5.x”. The primary goal of this paper is to demonstrate that key streamflow properties such as water depth, flow velocity, and dynamic pressure in a natural river at 30-kilometer scale over 5 years can be reliably and efficiently modeled using the computational framework presented in this paper. To support the paper, various data types from remote sensing, field observations, and computational models are used. Specific details are described as follows. Firstly, the river bathymetry data was obtained from a Light Detection and Ranging (LiDAR) survey. This data is then converted to a triangulated surface format, STL, for mesh generation in OpenFOAM. The STL data can be found in Model_Setups/BaseCase_2013To2015/constant/triSurface. The OpenFOAM mesh generated using this STL file can be found in constant/polyMesh. Other model setups, boundary and initial conditions can be found in /system and /0.org under folder BaseCase_2013To2015. A similar data structure can also be found in BaseCase_2018To2019 for the simulations during 2018 and 2019. Secondly, the OpenFOAM simulations need the upstream discharge and water depth information at the upstream boundary to drive the model. These data are generated from a one-dimensional hydraulic model and the data can be found under the folder Model_Setups /1D model Mass1 data. The mass1_65.csv and mass1_191.csv files include the results of the 1D model at the model inlet and outlet, respectively. The Matlab source code Mass1ToOFBC20182019.m is used to convert these data into OpenFOAM boundary condition setups.With the above OpenFOAM model, it can generate data for water surface elevation, flow velocity, and dynamic pressure. In this paper, the water surface elevation was measured at 7 locations during different periods between 2011 and 2019. The exact survey locations (see Fig1_SurveyLocations.txt) can be found in folder Fig_1. The variation of water stage over time at the 7 locations can be found in folder /Observation_WSE. The data type include .txt, .csv, .xlsx, and .mat. The .mat data can be loaded by Matlab.We also measured the flow velocities at 12 cross-sections along the river. At each cross-section, we recorded the x, y locations, depth, three velocity components u,v,w. These data are saved to a Matlab format which can be found under folder /Observation_Velocity and /Fig_1. The relative locations of velocity survey locations to the river bathymetry can be found in Figure 1c.The water stage data at the 7 locations from OpenFOAM, 1D, and 2D hydraulic models are also provided to evaluate the long-term performance of 3D models vs 1D/2D models. The water stage data for the 7 locations from OpenFOAM have been saved to .mat format and can be found in /OpenFOAM_WSE. The water stage data from the 1D model are saved in .csv format and can be found in /Mass1_WSE. The water stage from the 2D model is saved as .mat format and can be found in / Mass2_WSEIn addition, the OpenFOAM model outputs the information of hydrostatic and hydrodynamic pressure. They are saved as .mat format under folder /Fig_11/2013_1. As the files are too large, we only uploaded the data for January 2013. The area of different ratio of dynamic pressure to static pressure for all simulation range, i.e., 2013-2015, are saved to .mat format. They can be found in /Fig_11/PA. Further, the data of wall clock time versus the solution time of the OpenFOAM modeling are also saved to .mat format under folder /Fig_13/LogsMat. In summary, the data package contains seven data types, including .txt, .csv, .xlsx, .dat, .stl, .m, and .mat. The former 4 types can be directly open using a text editor or Microsoft Office. The .mat format needs to be read by Matlab. The Matlab source code .m files need to be run with Matlab. The OpenFOAM setups can be visualized in ParaView. The .stl file can be opened in ParaView or Blender. The data in subfolders Fig_1 to Fig_10 and Fig_12 are copied from the aforementioned data folders to generate specific figures for the paper. A readME.txt file is included in each subfolder to further describe how the data in each folder are generated and used to support the paper.Please use the data package's DOI to cite the data package. Please contact yunxiang.chen@pnnl.gov if you need more data related to the paper.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Integrating a Water Tracer Model Into WRF‐Hydro for Characterizing the Effect of Lateral Flow in Hydrologic Simulations

Abstract Most current land models approximate terrestrial hydrological processes as one‐dimensional vertical flow, neglecting lateral water movement from ridges to valleys. Such lateral flow is fundamental at catchment scales and becomes crucial for finer‐scale land models. To test the effect of incorporating lateral flow toward three‐dimensional representations of hydrological processes in the next generation land models, we integrate a water tracer model into the WRF‐Hydro framework to track water movement from precipitation to discharge and evapotranspiration. This hydrologic‐tracer integrated system allows us to identify the key mechanisms by which lateral flow affects the flow paths and transit times in WRF‐Hydro. By comparing modeling experiments with and without lateral routing in two contrasting catchments, we determine the impacts of lateral flow on the transit times of precipitation event‐water. Results show that with limited hydrologic connectivity, lateral flow extends the transit times by reducing (increasing) event‐water drainage loss (accumulation) in ridges (valleys) and allowing reinfiltration of infiltration‐excess flow, which is missing in most land models. On the contrary with high hydrologic connectivity, lateral flow can effectively accelerate the water release to streams and reduce the transit time. However, the transit times are substantially underestimated by the model compared with isotope‐derived estimates, indicating model limitations in representing flow paths and transit times. This study provides some insights on the fundamental differences in terrestrial hydrology simulated by land models with and without lateral flow representation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Numerical algorithms for water waves with background flow over obstacles and topography

Abstract We present two accurate and efficient algorithms for solving the incompressible, irrotational Euler equations with a free surface in two dimensions with background flow over a periodic, multiply connected fluid domain that includes stationary obstacles and variable bottom topography. One approach is formulated in terms of the surface velocity potential while the other evolves the vortex sheet strength. Both methods employ layer potentials in the form of periodized Cauchy integrals to compute the normal velocity of the free surface, are compatible with arbitrary parameterizations of the free surface and boundaries, and allow for circulation around each obstacle, which leads to multiple-valued velocity potentials but single-valued stream functions. We prove that the resulting second-kind Fredholm integral equations are invertible, possibly after a physically motivated finite-rank correction. In an angle-arclength setting, we show how to avoid curve reconstruction errors that are incompatible with spatial periodicity. We use the proposed methods to study gravity-capillary waves generated by flow around several elliptical obstacles above a flat or variable bottom boundary. In each case, the free surface eventually self-intersects in a splash singularity or collides with a boundary. We also show how to evaluate the velocity and pressure with spectral accuracy throughout the fluid, including near the free surface and solid boundaries. To assess the accuracy of the time evolution, we monitor energy conservation and the decay of Fourier modes and compare the numerical results of the two methods to each other. We implement several solvers for the discretized linear systems and compare their performance. The fastest approach employs a graphics processing unit (GPU) to construct the matrices and carry out iterations of the generalized minimal residual method (GMRES).

Ambrose, David M.↗
DOE OSTI2023

Characterization of local parameters of inclined upward air–water bubbly two-phase flows in a round pipe

The present work seeks to develop a detailed experimental database and characterize the local effects of inclination on horizontal and upward bubbly air–water two-phase flows. Experimental conditions are selected to investigate bubbly flows at a variety of orientations while reducing the influence of flow regime transition. Detailed time-averaged data is collected using state-of-the-art four-sensor conductivity probes for measurements across the flow area for five flow conditions at five inclination orientations in a 25.4 mm inner diameter pipe. Using the newly established database, effects of inclination on bubbly flows are analyzed, as are changes in liquid and gas flow rate at different orientations. The observations include (1) bubble migration and agglomeration at the top pipe wall as orientation changes from vertical to horizontal; (2) reducing the angle from vertical reduces the local gas velocity, and correspondingly reduces the global slip from greater than unity at 90° to less than unity for 60° and lower; (3) changes in the bubble size distribution are primarily at the interface between the bubble cluster and the liquid region of the pipe, not coalescence within the bubble cluster. In conclusion, physical mechanisms for these observations are proposed, and the present trends at different orientations support previous experiments in horizontal two-phase flows.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Apparatus and method for recovering an amine solvent from an acid gas stream

A method and apparatus are provided for recovering an amine solvent from an acid gas stream. The apparatus includes a water wash recovery column, a nozzle for spraying water wash and an amine nucleation agent into the water wash recovery column and an inlet port for introducing acid gas into the water wash recovery column adjacent the lower end thereof. The method includes the steps of treating the acid gas stream in the water wash recovery column with a counter-current flow of water wash in an amine nucleation agent, discharging treated acid gas from an upper end of the water wash recovery column and collecting water wash, amine nucleation agent and entrained amine solvent from the acid gas stream and a sump at a lower end of the water wash recovery column.

Irvin, Bradley David↗
DOE OSTI2024

Field Study of 120-volt Heat Pump Water Heaters in the Big Easy

To meet long-term goals for reducing carbon emissions and lessen the impacts of climate change, the U.S. plans to decarbonize its building stock, which includes the replacement of fossil fuel-burning end uses with energy efficient electric alternatives. As part of this strategy, the replacement of fossil fuel water heaters with heat pump water heaters (HPWH) has the potential to avoid substantial carbon emissions. An estimated 10-15 million single-family homes with fossil fuel water heaters do not have the electrical panel capacity to install a 240-volt, 30-amp HPWH. For these homes, a technology recently introduced to the market, the 120-volt plug-in HPWH, can provide energy efficient electrification of water heating without an expensive panel and wiring retrofit. This paper presents the results of an ongoing 120-volt HPWH field study conducted in 17 homes in New Orleans, LA. Key installation scenarios are profiled for retrofitting from gas-fired water heaters to 120-volt HPWHs, accounting for space, air volume, air temperature, condensate drainage, and electrical. Each HPWH had its surrounding air temperature, relative humidity, inlet and outlet water temperature, flow, and energy consumption monitored. Using these data, hot water delivery and energy efficiency performance were analyzed based on home characteristics. Hot water run outs were investigated to understand how hot water usage, inlet water temperature, and surrounding air temperature impact the HPWH’s ability to meet load. From these results, best practices for 120-volt HPWH siting, sizing, and installation were developed. In addition, results are explored further to add insight for electrification policies and product development.

heat pump water heater, 120-volt, Residential buil↗
DOE OSTI2022

Full Length Assembly Testing in PELICAN (Final Report)

In support of the development of the U.S. Department of Energy (DOE) Versatile Test Reactor (VTR), a thermal hydraulics test facility was constructed to generate experimental measurement of the pressure drop across a single full-scale assembly containing prototypic axial reflectors, fuel, and plena components. Constructed and operated at Argonne National Laboratory, the Pressure drop Experimental Loop for Investigations of Core Assemblies in Nuclear reactors (PELICAN) facility was designed to achieve hydraulic conditions identical to those anticipated for a full-scale fuel assembly located in the VTR core in the region with the highest flow rate. Using water as surrogate for liquid sodium, the flow loop was operated at elevated temperatures and pressures to match the thermophysical properties of liquid sodium and ensure matching Reynolds and Euler numbers. The measurement objectives for data generated from this test facility was driven primarily by the validation needs for code calculations and simulations of the reference VTR core. These objectives focused on the need to validate pressure drop results across the various segments of the fuel assembly as they relate directly to the pumping power and safety of the reactor. Presented in this report are experimental results and analytical comparisons based on testing of a full-length assembly in PELICAN. Housed within a hexagonal test section extending 3.4 m in length, the tested assembly features a prototypic lower reflector, grid plates, wire-wrapped rod bundle, upper reflector, and exit region. The rod bundle extends over 1.5 m in length and contains 217 individual wire-wrapped rods with dimensions that best reflect the reference VTR design. The as-tested bundle assembly was fabricated using 316 stainless steel 0.25-inch (6.35-mm) diameter rods wrapped with 0.04-inch (1.016-mm) diameter wire at a helical pitch of 10.51 inch (26.6 cm). Details of the method for in-house wire-wrapping, assembly, and installation are provided later in this report. Experimental measurements of pressure drop at 19 positions along the test assembly were recorded for a range of flow conditions, with special attention paid to key locations within the assembly, including component inlet and outlet, transition, and wire-wrapped rod bundle regions. Testing conditions were based on 110°C water with flow rates ranging from 50 to 450 GPM (3 to 27 kg/s) at the inlet of the test assembly generating Reynolds numbers and velocities up to ~8.0×10 4 and ~7.8 m/s, respectively, within the rod bundle region. Non-dimensional values for the friction factor were then calculated based on these experimental measurements and compared against those predicted by various analytical correlations available from open literature. Predictions by the upgraded Cheng and Todreas, Rehme, and Novendstern correlations fell within 4% to those values measured experimentally.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2020

Gambusia holbrooki Survive Shear Stress, Pressurization and Avoid Blade Strike in a Simulated Pumped Hydroelectric Scheme

Pumped hydroelectric energy storage (PHES) projects are being considered worldwide as a means of achieving political renewable energy targets in a way that stabilises baseload energy supply from often intermittent renewable energy sources. Unlike a conventional hydroelectric system that only pass water in a downstream direction, a feature of PHES is that it relies on the bi-directional flow of water. In some cases this flow can be across different waterbodies or catchments, posing a risk of inadvertently expanding the range of aquatic animals like fish. The risk of this happening depends on the likelihood of survival of individuals, which remains poorly understood for turbines that are pumping rather than generating. This study quantified the survival of a globally widespread and invasive poeciliid fish, Eastern gambusia (Gambusia holbrooki) when exposed hydraulic stresses characteristic of what would be experienced through a PHES during the pumping phase. A shear flume and hyperbaric chamber were used to expose fish to different strain rates and rapid and sustained pressurisation. A blade strike model was also used to predict survival of fish passing through a Francis dual turbine / pump. The ranges simulated were based on design and operational conditions provided for a PHES scheme being proposed in south-eastern Australia. All gambusia tested survived extremely high (up to 7600 kPa gauge pressure) pressurisation, high levels of shear stress (up to 1853 s -1 ), and the majority (> 93 %) were unlikely to be struck by a turbine blade. Given their tolerance to these extreme simulated stresses, we conclude that gambusia will likely survive passage through a PHES scheme. Therefore, where a new PHES poses the risk of inadvertently expanding the range of gambusia or similar poeciliid species, measures to minimise their spread or mitigate their ecosystem impacts should be considered.

25 ENERGY STORAGE↗
DOE OSTI2022

Quantifying the City-Scale Impacts of Impervious Surfaces on Groundwater Recharge Potential: An Urban Application of WRF–Hydro

Decades of urbanization have created sprawling, complex, and vulnerable cities, half of which are located in water-scarce areas. With the looming effects of climate change, including increasing droughts and water shortages, there is an urgent need to better understand how urbanization impacts the water cycle at city scale. Impervious surfaces disrupt the natural flow of water, affecting groundwater recharge in water-scarce cities, such as Los Angeles, looking to harness local water resources. In the face of growing water demand, informing on opportunities to maximize potential groundwater recharge can help increase cities’ resilience. WRF–Hydro, a physics-based hydrological modeling system, capable of resolving atmospheric, land surface, and hydrological processes at city scale, is adapted to represent urban impervious surfaces. The modified model is used to assess the hydrological implications of historical urbanization. Pre- and post-urban scenarios are used to quantify the impacts of impervious surfaces on the local water budget. Our results show that urbanization in LA has vastly decreased the potential for groundwater recharge, with up to half of the water inflow being redirected from infiltration in highly urbanized watersheds, while doubling surface runoff’s share of the city’s water budget, from ~15% to 30%. This study not only sheds light on the role of imperviousness on groundwater recharge in water-scarce cities, but also offers a robust and transferable tool for the management of urban land and water resources.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Numerical Analysis of Water Harvesting from Saturated Vapor with the Electrospray Water Droplet Injection in The Solar-Driven Desalination Applications

Solar-driven seawater desalination systems provide freshwater through environmentally friendly and carbon-neutral processes. Air humidification and dehumidification desalination (HDD) systems extract water directly from moist air. This paper focuses on a new solar-driven seawater desalination system that shares some common traits with HDD systems but in which the air is eliminated from the process. Seawater is vaporized by solar thermal radiation in high-performance solar panels. Water vapor flows to a new electro-condensation chamber and passes through a series of electrosprays, which inject small nuclei of freshwater droplets into the vapor clouds. Here, due to dielectrophoresis and electrohydrodynamic flows, the vapor molecules are captured by the charged droplets, and vapor is condensed at the droplet surface. The water vapor condensation was modeled by using the multiphase flow numerical model. The CFD model, which was also experimentally validated, used SprayFoam solver modules available in the Open FOAM® CFD open-source software. In preliminary results, 802 grams/(hr-m2) (grams per hour per unit area) of water was harvested directly from moist air at 24C and 90% relative humidity. The simulation results indicated that freshwater productivity could increase up to 4,000 grams/(hr-m2) for fully saturated air conditions. This represents about 5 times the water productivity rate of current conventional HDD systems today. In addition, energy consumption could be reduced by 80 percent compared to conventional HDD systems.

Electrospray, electro-condensation, solar, droplet↗
DOE OSTI2025

Wellbore Fracture Imaging Using Inflow Detection Measurements

One of the most striking measurements taken during DOE’s EGS Collab project at the 4850-foot depth location was the so-called ‘sewer cam’, which enabled direct visualization of the flow of water into the production well through fractures during the stimulation. The ability to see directly which fractures were flowing and (roughly) how much was a breakthrough in understanding the topology of the created fracture network. Achieving this kind of fracture flow imaging at FORGE would be more challenging because of the 225°C temperature, but equally or even more valuable if it could be achieved. In 2017, a joint project between Sandia and Stanford developed a downhole tool concept to measure the enthalpy of multiphase fluid entering a geothermal well from individual fractures (Gao et al., 2017). For the FORGE project, measuring enthalpy is of less interest because the fluid is expected to be single-phase liquid water. However, the foundation of the device was the measurement of chloride ion concentration, which could form the basis for a direct measurement of inflow from fractures. During the 2017 project, this novel chloride sensing system was implemented into a laboratory test instrument, and we confirmed the capability of the system to measure the ion concentration of fluid entering a model wellbore through a small entry port. The wellbore was a 6-inch diameter model well, and the port was approximately 0.08 inch (2mm) in diameter. The device could measure the chloride concentration accurately even when the well was flowing in a bubbly flow. Given its accuracy, the tool should be able to identify locations of water entering the wellbore even if the ion concentration differs only slightly from that of the water in the well. It is likely that different fractures may flow slightly different chloride concentrations, which would make it feasible to detect individual fractures as well as to estimate the volume of their flow. Ultimately, we could also recognize different fractures flowing back significantly different ion concentrations after fracturing in the FORGE wells. This could be realized by adding different ions in the fracturing fluids in different fractures created at different stages of stimulation (and modifying the tool to include different ion specificity). Sandia’s tool was shown during the study to have the capability to withstand the 225°C temperature, and the electrochemical sensing elements were tested in the laboratory to 225°C at 1500 psia for 24 hours. An early implementation of the fully integrated downhole electrochemical tool, including high-temperature electronics, robust housing, and wireline truck interface, had previously been constructed and tested successfully at Sandia; thus, hardware development tasks focused on advancing the technology readiness level (TRL) of this promising technology for FORGE deployment, rather than on developing a new scientific basis for its operation. The data collection electronics in this tool allowed for several other sensors (pressure, temperature, flow spinner) to be implemented in parallel as well. The research was a new collaboration between Stanford and Sandia to modify and refine the tool for FORGE deployment, to make the downhole measurements, and to characterize the evolving fractures.

15 GEOTHERMAL ENERGY↗
DOE OSTI2023

A Hydrogen Iron Flow Battery with High Current Density and Long Cyclability Enabled Through Circular Water Management

The hydrogen‐iron (HyFe) flow cell has great potential for long‐duration energy storage by capitalizing on the advantages of both electrolyzers and flow batteries. However, its operation at high current density (high power) and over continuous cycling testing has yet to be demonstrated. In this paper, we discuss our design and demonstration of a water management strategy that supports high current and long cycling performance of a HyFe flow cell. Water molecules associated with the movement of protons from the iron electrode to the hydrogen electrode are sufficient to hydrate the membrane and electrode at a low current density of 100 mA cm −2 during the charge process. At higher charge current density, more aggressive measures must be taken to counter back‐diffusion driven by the acid concentration gradient between the iron and hydrogen electrodes. Our water management approach is based on water vapor feeding in the hydrogen electrode, and water evaporation in the iron electrode, thus enabling the high current density operation of 300 mA cm −2 .

25 ENERGY STORAGE↗