Temperature-Dependent Water Oxidation Kinetics: Implications and Insights
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Abstract High-resolution transmission electron microscopy and atom probe tomography are used to characterize the initial passivation and subsequent intergranular corrosion of degraded grain boundaries in a model Ni-30Cr alloy exposed to 360 °C hydrogenated water. Upon initial exposure for 1000 h, the alloy surface directly above the grain boundary forms a thin passivating film of Cr 2 O 3 , protecting the underlying grain boundary from intergranular corrosion. However, the metal grain boundary experiences severe Cr depletion and grain boundary migration during this initial exposure. To understand how Cr depletion affects further corrosion, the local protective film was sputtered away using a glancing angle focused ion beam. Upon further exposure, the surface fails to repassivate, and intergranular corrosion is observed through the Cr-depleted region. Through this combination of high-resolution microscopy and localized passive film removal, we show that, although high-Cr alloys are resistant to intergranular attack and stress corrosion cracking, degradation-induced changes in the underlying metal at grain boundaries make the material more susceptible once the initial passive film is breached.
This data set reports stream water temperature, specific conductance, pH, dissolved oxygen percent saturation, dissolved oxygen concentration, and turbidity for East Fork Poplar Creek at a location approximately 5.4 kilometers upstream from the mouth of the creek.
This data set reports stream water temperature, specific conductance, pH, dissolved oxygen percent saturation, dissolved oxygen concentration, and turbidity for East Fork Poplar Creek at a location approximately 5.4 kilometers upstream from the mouth of the creek.
The overarching goal of the proposed research is to address SOEC’s degradation problem by advancing a new isostructural highly electrocatalytically active bilayer oxygen evolution reaction (OER) electrode, consisting of a LSCF (La 1-x Sr x Co 1-y Fe y O 3-δ ) core and a SCT (SrCo 0.9 Ta 0.1 O 3-δ ) shell, to achieve high and sustainable rate of oxygen evolution matching operating current densities without encountering delamination. To realize this goal, the project has adopted a combined experimental and theoretical approach to conduct research in the following six areas closely associated with SOPO tasks: 1) Development of electrocatalytically active bilayer oxygen electrodes (SOPO task-1) 2) Development of new symmetric three electrode cell (STEC) methodology to extract electrokinetic data of oxygen electrodes (SOPO task-2) 3) Quantification of electrokinetics of bilayer oxygen electrodes and correlation with degradation and delamination (SOPO task-2) 4) Performances of bilayer oxygen electrodes under fuel cells and electrolyzers modes (SOPO task-3) 5) Microscale modeling of oxygen electrode/electrolyte interface in solid oxide electrolysis cells (SOPO task-4) 6) Prediction of crack growth rate at oxygen electrode/electrolyte interface in solid oxide electrolysis cells (SOPO task-4)
The purpose of this study was to look at the thermodynamic and microphysical evolution the atmosphere during fog events at Summit. These cases were selected due to the presence of fog during a period when additional aerosol sensors where deployed on the colocated tower.
The Water Survey of Canada operates a network of approximately 2400 gauging stations at which water level data are collected. Nine DCPs were installed in isolated areas of northern and western Canada. It was felt that DCPs in these locations would be exposed to climatic conditions severe enough to provide a check on system reliability. Water level data are transmitted from all sites and, also, some of the DCPs are used to transmit ice break-up, water velocity, precipitation, air temperature, water stage recorder clock operation or DCP battery voltage. Consideration is being given to transmitting other parameters that would be of value in flood or flow forecasting. Results of the project have been excellent. There has been no data loss that can be attributed to failure of a DCP although data were lost because of sensor malfunctions. The quality of data collected compares favourably with that of the hard record obtained at the remote sites. Costs of using the ERTS Data Collection System are reasonable.
The author has identified the following significant results. The relationship between the distribution of menhaden and selected oceanographic parameters (water color, turbidity, and possibly chlorophyll concentrations) was established. Similar relationships for thread herring were not established nor were relationships relating to the abundance of either species. Use of aircraft and LANDSAT remote sensing instruments to measure or infer a set of basic oceanographic parameters was evaluated. Parameters which could be accurately inferred included surface water temperature, salinity, and color. Water turbidity (Secchi disk) was evaluated as marginally inferrable from the LANDSAT MSS data and chlorophyll-a concentrations as less than marginal. These evaluations considered the parameters only as experienced in the two test areas using available sensors and statistical techniques.
There are no author-identified significant results in this report.
There are no author-identified significant results in this report.
There are no author-identified significant results in this report.
There are no author-identified significant results in this report.
There are no author-identified significant results in this report.
There are no author-identified significant results in this report.
The considered theoretical model describes the evolution of potential temperature, water vapor content, liquid water content, and horizontal and vertical winds as determined by the processes of vertical turbulent transfer and horizontal advection for momentum, energy, and moisture, as well as radiation cooling, growth of water droplets based on microphysical processes, and drop sedimentation. The mathematical model is two-dimensional in the X-Z plane. The diffusivity coefficient is the same for liquid water droplets as for vapor. The fundamental equations governing the macrophysical processes of the evolution of wind components, water vapor content, liquid water content, and potential temperature under the influences of vertical turbulent diffusion transfer, turbulent momentum transfer, and turbulent energy transfer are expressed by three sets of conservation equations.
Airborne remote sensing systems, as well as those on board Earth orbiting satellites, sample electromagnetic energy in discrete wavelength regions and convert the total energy sampled into data suitable for processing by digital computers. In general, however, the total amount of energy reaching a sensor system located at some distance from the target is composed not only of target related energy, but, in addition, contains a contribution originating from the atmosphere itself. Thus, some method must be devised for removing or at least minimizing the effects of the atmosphere. The LOWTRAN-6 Program was designed to estimate atmospheric transmittance and radiance for a given atmospheric path at moderate spectral resolution over an operational wavelength region from 0.25 to 28.5 microns. In order to compute the Thermal Infrared Multispectral Scanner (TIMS) digital values which were recorded in the absence of the atmosphere, the parameters derived from LOWTRAN-6 are used in a correction equation. The TIMS data were collected at 1:00 a.m. local time on November 21, 1983, over a recirculating cooling pond for a power plant in southeastern Mississippi. The TIMS data were analyzed before and after atmospheric corrections were applied using a band ratioing model to compute the absolute surface temperature of various points on the power plant cooling pond. The summarized results clearly demonstrate the desirability of applying atmospheric corrections.