The crystal and molecular structure of dichlorodiphenoxytitanium /IV/.
X-ray crystal structural analysis of tetraethyl titanate and monomethyltriethyl titanate, determining reason for difference in color
CHEMICAL PROPERTY↗
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Vacuum thermionic work functions and thermal stability of TaB sub 2, ZrC, Mo sub 2 C, MoSi sub 2, TaSi sub 2, and WSi sub 2.
Vacuum thermionic work function and thermal stability measurements on crystal surfaces, discussing results on carbides, diborides and disilicades
THERMIONIC EMISSION↗
Interaction of hydrogen chloride with alumina
The influence of outgas conditions and temperature on the adsorptive properties of two aluminas Alon-c and Al6sG were studied using adsorption isotherm measurements. Alon-C and Al6SG were characterized using X-ray powder diffraction, thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and BET nitrogen surface areas. Some of these techniques were applied to two other aluminas but no isotherm data was obtained. Isotherm data and techniques applied to each alumina are summarized in tabular form.
Bailey, R. R.↗
Fundamental Effects of Aging on Creep Properties of Solution-Treated Low-Carbon N-155 Alloy
A method is developed whereby the fundamental mechanisms are investigated by which processing, heat treatment, and chemical composition control the properties of alloys at high temperatures. The method used metallographic examination -- both optical and electronic --studies of x-ray diffraction-line widths, intensities, and lattice parameters, and hardness surveys to evaluate fundamental structural conditions. Mechanical properties at high temperatures are then measured and correlated with these measured structural conditions. In accordance with this method, a study was made of the fundamental mechanism by which aging controlled the short-time creep and rupture properties of solution-treated low-carbon n-155 alloy at 1200 degrees F.
Frey, D N↗
The crystal structure of pyridinium dicyanomethylide, C sub 8 H sub 5 N sub 3.
X-ray single crystal diffraction technique determination of structure of pyridinium dicyanomethylide
CYANO COMPOUND↗
High voltage electron microscopy of lunar samples
Lunar pyroxenes from Apollo 11, 12, 14, and 15 were investigated. The iron-rich and magnesium-rich pyroxene specimens were crushed to a grain size of ca. 50 microns and studied by a combination of X-ray and electron diffraction, electron microscopy, 57 Fe Mossbauer spectroscopy and X-ray crystallography techniques. Highly ordered, uniform electron-dense bands, corresponding to exsolution lamellae, with average widths of ca. 230A to 1000A dependent on the source specimen were observed. These were?qr separated by wider, less-dense interband spacings with average widths of ca. 330A to 3100A. In heating experiments, splitting of the dense bands into finer structures, leading finally to obliteration of the exsolution lamellae was recorded. The extensive exsolution is evidence for significantly slower cooling rates, or possibly annealing, at temperatures in the subsolidus range, adding evidence that annealing of rock from the surface of the moon took place at ca. 600 C. Correlation of the band structure with magnetic ordering at low temperatures and iron clustering within the bands was studied.
Fernandez-Moran, H.↗
Changes Found on Run-In and Scuffed Surfaces of Steel Chrome Plate, and Cast Iron
A study was made of run-in and scuffed steel, chrome-plate, and cast-iron surfaces. X-ray and electron diffraction techniques, micro-hardness determinations, and microscopy were used. Surface changes varied and were found to include three classes: chemical reaction, hardening, and crystallite-size alteration. The principal chemical reactions were oxidation and carburization.
IRON, CAST - WEAR RESISTANCE↗
Superconductivity in beta-tungsten films.
Superconductivity of electron beam evaporated tungsten films by X ray and electron diffraction techniques, discussing temperature dependence of energy gap
Basavaiah, S.↗
A liquid radiation detector with high spatial resolution
Detector, using point anode, minimizes problem of oblique tracks by permitting construction of very thin counter. Detector is useful in cosmic ray and high energy physics research and X-ray and neutron diffraction technology.
Alvarez, L.↗
The nature of dark-etching rims in meteoritic taenite.
Taenite fields when etched develop a cloudy brown rim with approximate compositional limits of 25 and 40% Ni. In iron meteorites this cloudy zone is only a few microns wide, with a sharp, high-Ni edge about 1 micron from the kamacite interface and a diffuse edge several microns from the central plessite. It is always present in irons unless the meteorite has been cosmically or terrestrially reheated. X-ray and electron diffraction of grains scratched from exceptionally larger areas of cloudy taenite in the mesosiderite Estherville show that this etching zone contains a fine exsolution of kamacite. Detailed electron-probe investigations of taenite in Estherville show that there is a step in the M-shaped Ni profile at the sharp, high-Ni edge of the cloudy region, the Ni dropping suddenly from approximately 45 to 42%. It is proposed that exsolution in the cloudy region effectively froze in the Ni profile at that temperature. On subsequent cooling only the clear outer taenite continued to equilibrate with the kamacite matrix, producing the kink in the M profile. Cloudy taenite is therefore a variety of plessite differing from the usual varieties in that it forms at lower temperatures in areas much richer in Ni, and the morphology is not crystallographically oriented. Its absence can provide a sensitive indication of reheating.
Scott, E. R. D.↗
The preparation and properties of aluminum nitride films
Aluminum nitride films have been deposited on silicon substrates at 800-1200 C by the pyrolysis of an aluminum trichloride-ammonia complex, AlCl3.3NH3, in a gas flow system. The deposit was transparent, tightly adherent to the substrate, and was confirmed to be aluminum nitride by X-ray and electron diffraction techniques. The deposited aluminum nitride films were found to be polycrystalline with the crystallite size increasing with increasing temperature of deposition. Other properties of aluminum nitride films relevant to device applications, including density, refractive index, dissolution rate, dielectric constant, and masking ability, have been determined. These properties indicate that aluminum nitride films have potential as a dielectric in electronic devices.
Chu, T. L.↗
Ternary compound thin film solar cells
A group of ternary compound semiconductor (I-III-VI2) thin films for future applications in photovoltaic devices is proposed. The consideration of these materials (CuInSe2, CuInTe2 and especially CuInS2) for long range device development is emphasized. Much of the activity to date has been concerned with the growth and properties of CuInX2 films. X-ray and electron diffraction analyses, Hall mobility and coefficient, resistivity and carrier concentration variations with substrate and film temperature as well as grain size data have been determined. Both p- and n-type films of CuInS2 and CuInSe2 have been produced. Single and double source deposition techniques have been utilized. Some data have been recorded for annealed films.
Kazmerski, L. L.↗
Relative cooling rates of mare basalts at the Apollo 12 and 15 sites as estimated from pyroxene exsolution data
X-ray single-crystal diffraction studies, supplemented by electron microprobe analyses of core pigeonites and rim augites from rocks 12031, 15085, 15475, and 15495, have been used to suggest cooling rates for these and other Apollo 12 and 15 rocks studied by similar methods. The extent of subsolidus phase separation of pyroxenes is used as a measure of the cooling rate. The results were interpreted in terms of model cooling histories of a lava flow whose thickness was estimated from the absolute cooling rates obtained by cooling rate experiments and by temperature-time variation through an extrusive flow computed by employing simplified theory of Jaeger. All available data on the exsolution and cation distributions of pyroxenes from Apollo 12 and 15 samples at present are consistent with the hypothesis that these rocks were derived from the top and interior of lava flows with thicknesses of 4-10 m. A process for exsolution of augite from a host pigeonite on (100) has been related to its low-calcium content.
Takeda, H.↗
Analyzer crystals for x-ray spectroscopy in the region 25-100 angstrom units.
Single crystals with long diffracting plane spacings for use as dispersing elements in solar X-ray spectral analyzer
X-RAY SPECTROSCOPY↗
Thermochemical Stability of Ca2Yb8(SiO4)6O2 Apatite in Presence of Molten Calcium-Magnesium-Aluminosilicate (CMAS)
Thermochemical stability of ytterbium silicon oxyapatite Ca 2 Yb 8 (SiO 4 ) 6 O 2 (CYbS) in the presence of molten calcium-magnesium aluminosilicate (CMAS) has been investigated at elevated temperatures for consideration as a thermal and environmental barrier coating (T/EBC) material. CYbS apatite powder was synthesized from the constituent oxides via a solid-state reaction method. Hot-pressed apatite substrates were exposed to molten CMAS at 1200, 1300, and 1400 °C for 1, 10, and 50 h. Development of phases in the interaction region of the heat-treated specimens was monitored using scanning electron microscopy, transmission electron microscopy, high-angle annular dark-field imaging, selected area electron diffraction, and energy dispersive x-ray spectroscopy. Monoclinic cyclosilicate Ca 3 Yb 2 (Si 3 O 9 ) 2 formed from interaction of CYbS apatite with CaO in the CMAS melt at the apatite-CMAS reaction front and continued to nucleate and grow within the residual CMAS in diffusion couples annealed for 1 to 50 h at 1200 °C as well as in those heat treated at 1300 °C for 1 h. Residual CMAS was depleted of Ca when cyclosilicate was present. Dendritic wollastonite (CaSiO3) was observed within the residual CMAS in couples annealed at 1200 and 1300 °C. Ingress of molten CMAS, because of its exponential decrease in viscosity, occurred through open pores and along the grain boundaries of the apatite substrates without any detectable chemical reaction at 1300 and 1400 °C. Results of this study indicate that Ca 2 Yb 8 (SiO 4 ) 6 O 2 apatite has the potential to mitigate the CMAS corrosion up to about 1200 °C but not at higher temperatures.
Narottam P Bansal↗
Development of a position sensitive X-ray detector for use in a light weight X-ray diffractometer
The characteristics of a curved position sensitive X-ray detector are discussed. Emphasis is placed on the analysis of operation in a focusing diffraction geometry. Problems encountered in constructing the sensor are described. Construction drawings of the sensor components are provided.
Semmler, R. A.↗
X-ray evaluation of crystals for stellar spectrometers
The report consists of three parts. The first part is an analysis of the principles involved in X-ray crystal evaluation and how they are applied to a number of crystals. The principles of crystal evaluation analysis as they apply to the special problems of X-ray astronomy are presented. A number of crystals were evaluated, and the energy dependence of the diffraction properties of (002) PET, (111) Ge, (101) ADP, (001) KAP, and (001) RAP are reported. The second part is a compilation of the diffraction properties of a number of crystals as reported by other authors. In the third part some technical details of a triple crystal spectrometer built by the author at Polytechnic Institute of Brooklyn are given. This spectrometer seems to be a most appropriate instrument for evaluation of crystal properties. (Modified author abstract)
Alexandropolos, N. G.↗
Low orthopyroxene from a lunar deep crustal rock - A new pyroxene polymorph of space group P21ca
Bronzite crystals (En86Fs11Wo3) from a slowly-cooled lunar troctolitic granulite, have space group P21ca, a postulated, but previously unreported space group. Diffractions violating the b-glide extinction conditions have been observed in long-exposure X-ray precession photographs from three of these crystals and on an automated X-ray diffractometer. P21ca is a subgroup of the common orthopyroxene space group Pbca, and its cell dimensions (a = 18.235 plus or minus 0.004 A, b = 8.831 plus or minus 0.002 A, c = 5.189 plus or minus 0.001 A) are similar to those of terrestrial bronzites. It is postulated that the lower symmetry space group has developed as a result of very slow cooling at pressures of one to two kilobars deep in the lunar crust.
Smyth, J. R.↗