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At least 235 records · Page 13

Recent Development on O(+) - O Collision Frequency and Ionosphere-Thermosphere Coupling

The collision frequency between an oxygen atom and its singly charged ion controls the momentum transfer between the ionosphere and the thermosphere. There has been a long standing discrepancy, extending over a decade, between the theoretical and empirical determination of this frequency: the empirical value of this frequency exceeded the theoretical value by a factor of 1.7. Recent improvements in theory were obtained by using accurate oxygen ion-oxygen atom potential energy curves, and partial wave quantum mechanical calculations. We now have applied three independent statistical methods to the observational data, obtained at the MIT/Millstone Hill Observatory, consisting of two sets A and B. These methods give results consistent with each other, and together with the recent theoretical improvements, bring the ratio close to unity, as it should be. The three statistical methods lead to an average for the ratio of the empirical to the theoretical values equal to 0.98, with an uncertainty of +/-8%, resolving the old discrepancy between theory and observation. The Hines statistics, and the lognormal distribution statistics, both give lower and upper bounds for the Set A equal to 0.89 and 1.02, respectively. The related bounds for the Set B are 1.06 and 1.17. The average values of these bounds thus bracket the ideal value of the ratio which should be equal to unity. The main source of uncertainties are errors in the profile of the oxygen atom density, which is of the order of 11%. An alternative method to find the oxygen atom density is being suggested.

Omidvar, K.↗

Fundamental Processes of Atomization in Fluid-Fluid Flows

This paper discusses our proposed experimental and theoretical study of atomization in gas-liquid and liquid-liquid flows. While atomization is a very important process in these flows, the fundamental mechanism is not understood and there is no predictive theory. Previous photographic studies in (turbulent) gas-liquid flows have shown that liquid is atomized when it is removed by the gas flow from the crest of large solitary or roll waves. Our preliminary studies in liquid-liquid laminar flows exhibit the same mechanism. The two-liquid system is easier to study than gas-liquid systems because the time scales are much slower, the length scales much larger, and there is no turbulence. The proposed work is intended to obtain information about the mechanism of formation, rate of occurrence and the evolving shape of solitary waves; and quantitative aspects of the detailed events of the liquid removal process that can be used to verify a general predictive theory.

Gallagher, Christopher↗

Cross Sections for Electron Impact Excitation of Ions Relevant to Planetary Atmospheres Observation

The goal of this research grant was to calculate accurate oscillator strengths and electron collisional excitation strengths for inelastic transitions in atomic species of relevance to Planetary Atmospheres. Large scale configuration-interaction atomic structure calculations have been performed to obtain oscillator strengths and transition probabilities for transitions among the fine-structure levels and R-matrix method has been used in the calculations of electron-ion collision cross sections of C II, S I, S II, S III, and Ar II. A number of strong features due to ions of sulfur have been detected in the spectra of Jupiter satellite Io. The electron excitation cross sections for the C II and S II transitions are studied in collaboration with the experimental atomic physics group at the Jet Propulsion Laboratory. There is excellent agreement between experiment and theory which provide an accurate and broad-base test of the ability of theoretical methods used in the calculation of atomic processes. Specifically, research problems have been investigated for: electron impact excitation cross sections of C II: electron impact excitation cross sections of S III; energy levels and oscillator strengths for transitions in S III; collision strengths for electron collisional excitation of S II; electron impact excitation of inelastic transitions in Ar II; oscillator strengths of fine-structure transitions in neutral sulfur; cross sections for inelastic scattering of electrons from atomic nitrogen; and excitation of atomic ions by electron impact.

Tayal, Swaraj S.↗

Theoretical investigations of plasma processes in the ion bombardment thruster

A physical model for a thruster discharge was developed, consisting of a spatially diverging plasma sustained electrically between a small ring cathode and a larger ring anode in a cylindrical chamber with an axial magnetic field. The associated boundary-value problem for the coupled partial differential equations with mixed boundary conditions, which describe the electric potential and the plasma velocity fields, was solved in closed form. By means of quantum-mechanical perturbation theory, a formula for the number S(E) of atoms sputtered on the average by an ion of energy E was derived from first principles. The boundary-value problem describing the diffusion of the sputtered atoms through the surrounding rarefied electron-ion plasma to the system surfaces of ion propulsion systems was formulated and treated analytically. It is shown that outer boundary-value problems of this type lead to a complex integral equation, which requires numerical resolution.

Wilhelm, H. E.↗

Mass fractionation of the lunar surface by solar wind sputtering

The sputtering of the lunar surface by the solar wind is examined as a possible mechanism of mass fractionation. Simple arguments based on current theories of sputtering and the ballistics of the sputtered atoms suggest that most ejected atoms will have sufficiently high energy to escape lunar gravity. However, the fraction of atoms which falls back to the surface is enriched in the heavier atomic components relative to the lighter ones. This material is incorporated into the heavily radiation-damaged outer surfaces of grains where it is subject to resputtering. Over the course of several hundred years an equilibrium surface layer, enriched in heavier atoms, is found to form. The dependence of the calculated results upon the sputtering rate and on the details of the energy spectrum of sputtered particles is investigated. It is concluded that mass fractionation by solar wind sputtering is likely to be an important phenomenon on the lunar surface.

Switkowski, Z. E.↗

Scale covariance and G-varying cosmology. II - Thermodynamics, radiation, and the 3 K background

Within the framework of a scale-covariant theory of gravitation, a semiclassical description of particles and photons is given. Thermodynamic relations consistent with the modified conservation equations are derived. Application to a system of radiation shows that the observed 3-K background radiation can be interpreted, within the present framework, as a remnant of equilibrium radiation in the past. As the theory postulates a nonstandard coupling between gravitation and electrodynamics, the assumption that Einstein's theory of gravitation is unchanged forces modifications at the atomic level. The use of Minkowskian spacetime in atomic physics is found to be adequate only over small, but not large, time scales compared with the age of the universe. As a result, a relation between energy and the frequency of a free photon is demonstrated. Possible observational consequences of this relation are discussed.

Canuto, V. M.↗

Autoionization: Recent developments and applications

Among the topics discussed are: theory of resonance and autoionization of two-electron atoms and ions; projection and quasi-projection operators for electron impact resonances on many-electron atomic targets; and hole projection methods for calculating Feshbach resonances and inner-shell vacancies. Consideration is also given to: complex stabilization methods; complex coordinate and complex basis function calculations; and the variational principle. The application of autoionization calculations to solar and astrophysical plasma diagnostics is also discussed in detail.

Temkin, A.↗

The vibrational frequencies of ozone

The singles and doubles coupled-cluster (CCSD) method is used, together with the recently proposed CCSD(T) and CCSDT-1 methods, to determine the equilibrium structure and harmonic frequencies of ozone at various levels, on the basis of large one-particle basis sets. It is demonstrated that f-type functions are required in order to obtain quantitative accuracy for the equilibrium structure and harmonic frequencies. The CCSD(T) level of theory, in conjunction with a (4s 3p 2d 1f) atomic natural orbital set, yields an equilibrium geometry and harmonic frequencies that are in excellent agreement with experimental results; an effort has accordingly been made to determine the cubic and quartic force constants, and evaluate the anharmonic corrections to the fundamental vibrational frequencies.

Lee, Timothy J.↗

Nonlinear acoustics and the thermal expansivity of glass

The paper shows the intrinsic relationship between acoustical nonlinearity and the thermal expansivity of crystalline solids (a thermal measure of anharmonicity) from consideration of the 'static' radiation field generated by the vibrating lattice (atomic) sources of the crystal. A modification of the theory to account for long-range structural disorder in glass is proposed and applied to an explanation of the zero thermal expansivity at the cross-over temperature in silicate and titanium silicate glasses. Experimental evidence which validates the essential features of the theory is presented. An application of nonlinearity measurement, based on these results, to the processing of ULE glass, where the addition of titanium in various amounts is used to establish the temperature at which the zero thermal expansivity occurs, is suggested.

Cantrell, John H.↗

Measurements of Excitation Functions and Line Polarizations for Electron Impact Excitation of the n = 2, 3 States of Atomic Hydrogen in the Energy Range 11 - 2000 eV

The electron-atomic hydrogen scattering system is an important testing ground for theoretical models and has received a great deal of attention from experimentalists and theoreticians alike over the years. A complete description of the excitation process requires a knowledge of many different parameters, and experimental measurements of these parameters have been performed in various laboratories around the world. As far as total cross section data are concerned it has been noted that the discrepancy between the data of Long et al. and Williams for n = 2 excitations needs to be resolved in the interests of any further refinement of theory. We report new measurements of total cross sections and atomic line polarizations for both n=2 and n=3 excitations at energies from threshold to 2000 eV...

James, G. K.↗

Ultraviolet continuum absorption /less than about 1000 A/ above the quiet sun transition region

Lyman continuum absorption shortward of 912 A in the quiet sun solar transition region is investigated by combining spectra obtained from the Apollo Telescope Mount experiments on Skylab. The most recent atomic data are used to compute line intensities for lines that fall on both sides of the Lyman limit. Lines of O III, O IV, O V, and S IV are considered. The computed intensity ratios of most lines from O IV, O V, and S IV agree with the experimental ratios to within a factor of 2. However, the discrepancies show no apparent wavelength dependence. From this fact, it is concluded that at least part of the discrepancy between theory and observation for lines of these ions can be accounted for by uncertainties in instrumental calibration and atomic data. However, difficulties remain in reconciling observation and theory, particularly for lines of O III, and one line of S IV. The other recent results of Schmahl and Orrall (1979) are also discussed in terms of newer atomic data.

Doschek, G. A.↗

Meteor research program

An overview of research on radio and radar meteors accomplished during the past decade is presented, and the work of the past year is highlighted. Velocity distribution and mass flux data are obtained for meteors in the range 10 to 0.0001 g, the size believed to be the principal hazard to space missions. The physical characteristics of mass, structure and density, luminosity, and ablation are briefly described, and the formulation of a theory for interactions of ionization and excitation during collision of atomic particles is mentioned. Five classes of meteoroids are identified, including the two of iron and stone meteorites. Stream meteors associated with known comets are Classes A or C, and parent comets of Class B streams are not observed. Class A meteoroids are identified with the core of a cometary nucleus, Class C with less dense surface of the nucleus after sublimation of ices, and Class B with less dense cores of smaller cometary nuclei. Atmospheric meteor phenomena associated with winds and gravity waves, density and temperature, atomic oxygen, and meteor rate changes are mentioned.

Southworth, R. B.↗