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At least 235 records · Page 13
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NASA NTRS2021

Physics and Chemistry of Te and HgTe-based Ternary Melts

Historically, the theoretical treatment of the liquid phases has always been more difficult and complicated than that for solid and gas phases. A liquid has no lattice structure as crystalline solids and the atoms/molecules in the liquid can migrate through it relatively rapidly. On the other hand, it is also interacting with many other atoms/molecules so that the simplifications of the kinetic theory of gases cannot be employed. For more complicated liquids, such as the liquids of high ionicity and those containing hydrogen bonds and electric dipoles, the understanding is far from complete. At the same time, accurate information on the physics and chemistry of semiconductor melts is needed for the quantitative descriptions of the process of crystal growth from melt. The pre-crystallization phenomena in the liquid phase are critical because the properties of the grown crystals depend on the state and structure of the melt as well as the thermal history of the melt during solidification process. However, the data on the liquid phase, such as thermophysical properties of semiconductor melts are scarce, especially for the HgTe-based II-VI ternary compound semiconductors because of their high vapor pressure and extreme toxicity. Analysis of the thermophysical properties of the melt can provide information about structural transitions of the melt during the solidification process. From a broader point of view, the structure of liquids is much more complicated than the crystalline solids, especially the relaxation behavior through different thermal histories. The theory of hetero-phase fluctuations of liquids is applicable to any many-body systems including condensed-matter physics, field theory, physics of nuclear-matter, cosmology, biology and even sociology. This book summarizes the physics and chemistry from the experimental measurements and theoretical analyses of phase diagram, thermodynamic properties, density, thermal conductivity, viscosity, and electrical conductivity on the binary, pseudo-binary and ternary melts of the most advanced IR-detector material systems of HgCdTe and HgZnTe as well as the analyses of these results. The main objectives of this study are: (1) to provide the phase diagrams and thermodynamic properties of Hg-Cd-Te and Hg-Zn-Te systems through quantitatively fitting the experimental data by assuming an associated solution model for the liquid phase, (2) to experimentally measure the thermophysical properties of the Hg-Cd-Te and Hg-Zn-Te melts, including density, viscosity, electrical conductivity and thermal conductivity as functions of temperature and composition and (3) to enhance the fundamental knowledge of hetero-phase fluctuations and relaxation phenomena in the melts and extend our understanding of the solidification process in order to interpret the experimental results of crystal growth so as to improve the melt growth processes of the compound semiconductor. The physics and chemistry of Te and HgTe-based ternary melts were explored through the studies of the structural transformation during melting, the supercooling during solidification, the relaxation phenomena after rapid cooling of the melts and the metal-semiconductor transition in the melts through the analyses of electrical conductivity and Lorenz number. An in-depth study on the thermophysical properties and their time-dependent structural dynamic processes taking place in the vicinity of the solid-liquid phase transition of the narrow homogeneity range HgTe-based ternary semiconductors as well as the analysis of the homogenization process in the melt will also be presented.

Thermophysical properties↗
NASA NTRS2004

The Effects of Gravity on the Crystallization Behavior of Heavy Metal Fluoride Glasses

Heavy metal fluoride glasses are used in such applications as fiber lasers and laser amplifiers. ZrF4-BaF2-LaF3-AlF3-NaF (ZBLAN) is one of the more commonly used heavy metal fluoride glasses. ZBLAN is an infrared transmitter and has a theoretical attenuation coefficient of 0.002 db/km. However, due to impurities and small crystallites this attenuation coefficient has not been achieved to date. ZBLAN is a fragile glass which can lead to rapid crystallization, if the glass is not cooled rapidly to below the glass transition temperature or if the glass is reheated near the crystallization temperature for any period of time. Studies carried on at Marshall Space Flight Center and the University of Alabama in Huntsville since 1993 have shown that heating ZBLAN glass at the crystallization temperature in reduced gravity results in a suppression of crystallization when compared to ZBLAN processed in unit gravity. These studies utilized NASA's KC-135 aircraft and the Conquest sounding rocket. In the first series of experiments, short lengths of ZBLAN fiber were heated to the crystallization temperature in reduced gravity on board the KC- 135 and the Conquest sounding rocket and compared with fibers heated in unit gravity. The fibers processed in reduced gravity showed no evidence of crystallization when studied with x-ray diffraction and scanning electron microscopy. However, the fibers processed in unit gravity were completely crystallized. Subsequent experiments included heating small pieces of ZBLAN glass at the crystallization temperature while viewing with a video camera to follow the crystallization phenomenon. In this experiment crystallization was observed in reduced gravity, however, it was suppressed when compared to heating in unit gravity. In the most recent experiment on board the KC-135, rapid thermal analysis of ZBLAN was performed. A mechanism to explain the observations has been proposed. This mechanism is based on shear thinning whereby, the glass undergoes a reduction in viscosity in the 10(exp 5) - 10(exp 7) poise range, allowing more rapid diffusion and thus crystallization. It is proposed that this mechanism is suppressed in reduced gravity. An experiment is presently being conducted to test this theory. With increased knowledge of ZBLAN behavior in reduced gravity, three low earth orbit tiber drawing facilities have been designed. One would be suitable for use on the International Space Station, another while aboard the Space Shuttle and the third system is a fully automated facility which would operate independently of the ISS or Shuttle in a free float mode. The primary benefits of free floating a facility in LEO includes a higher quality of microgravity and reduced safety concerns since it is not in a manned environment.

Tucker, Dennis S.↗
NASA NTRS1972

Theory and design of variable conductance heat pipes

A comprehensive review and analysis of all aspects of heat pipe technology pertinent to the design of self-controlled, variable conductance devices for spacecraft thermal control is presented. Subjects considered include hydrostatics, hydrodynamics, heat transfer into and out of the pipe, fluid selection, materials compatibility and variable conductance control techniques. The report includes a selected bibliography of pertinent literature, analytical formulations of various models and theories describing variable conductance heat pipe behavior, and the results of numerous experiments on the steady state and transient performance of gas controlled variable conductance heat pipes. Also included is a discussion of VCHP design techniques.

Marcus, B. D.↗
NASA NTRS1978

Preliminary investigation of crack arrest in composite laminates containing buffer strips

The mechanical properties of some hybrid buffer strip laminates and the crack arrest potential of laminates containing buffer strips were determined. The hybrid laminates consisted of graphite with either S-glass, E-glass, or Kevlar. Unnotched tensile coupons and center-cracked fracture coupons were tested. Elastic properties, complete stress/strain curves, and critical stress intensity values are given. The measured elastic properties compare well with those calculated by classical lamination theory for laminates with linear stress/strain behavior. The glass hybrids had more delamination and higher fracture toughness than the all-graphite or the Kevlar hybrid.

Goree, J. G.↗
NASA NTRS1978

Laser amplification of incoherent radiation

The amplification of noise in a laser amplifier is treated theoretically. The model for the active medium and its description using density-matrix techniques, are taken from the theory of laser operation. The spectral behavior of the radiation in the nonlinear regime is studied and the formalism is written from the onset in the frequency domain. The statistics of the light are gradually modified by the nonlinear amplification process, and expressions are derived for the rate of change of fluctuations in intensity as a measure of statistical changes. In addition, the range of validity of Litvak's Gaussian-statistics approximation is discussed. In the homogeneous-broadening case, the evolution of initially broadband Gaussian radiation toward quasimonochromatic oscillations with laserlike statistics is explored in several numerical examples. The connections of this study with the time-domain work on self-pulsing in a ring-laser configuration, are established. Finally, spectral-narrowing and -rebroadening effects in Doppler-broadened media are discussed both analytically and with numerical examples. These examples show the distinct contribution of pulsations in the population ('Raman-type terms'), and saturation phenomena.

Menegozzi, L. N.↗
NASA NTRS1978

Crack extension from flaws in a brittle material subjected to compression

The mechanisms by which cracks extend from flaws in brittle materials subjected to compressive loads are presented. Although it is recognized that most geological materials are neither dense nor single-phase, this experimental study and analysis are restricted to single-phase, dense materials in order to provide a model amenable to analysis and experimental confirmation. The flaws which occur in dense, single-phase materials are divided into three types, each type having different characteristics of crack extension. Experimental studies of crack extension from flaws introduced into blocks of polymethylmethacrylate plastic are described. The studies show that crack extension from three dimensional flaws is more complex than two-dimensional theories predict. The extension of secondary cracks may result in more damage than that which would be predicted by considering only the primary crack extension treated by current theories. The importance of the dynamic behavior of flaws which stick and then suddenly slip is shown.

Adams, M.↗
NASA NTRS1977

Evolution of weak disturbances in inert binary mixtures

The evolution of weak disturbances in inert binary mixtures is determined for the one-dimensional piston problem. The interaction of the dissipative and nonlinear mechanisms is described by Burgers' equation. The binary mixture diffusion mechanisms enter as an additive term in an effective diffusivity. Results for the impulsive motion of a piston moving into an ambient medium and the sinusoidally oscillating piston are used to illustrate the results and elucidate the incorrect behavior pertaining to the associated linear theory.

Rasmussen, M. L.↗
NASA NTRS1980

Short beam shear tests of polymeric laminates and unidirectional composites

The application of advanced composite materials in aerospace, ground transportation, and sporting industries are discussed. Failure theories for the design and mechanical behavior of composite materials are emphasized. Methods for detecting specific types of flaws are outlined. The effect of detected flaws on mechanical properties such as stiffness, strength, fatigue lifetime, or residual strength is described.

Stinchcomb, W. W.↗
NASA NTRS1980

Si and GaAs photocapacitive MIS infrared detectors

Improvement of the previously reported photocapacitive MIS infrared detectors has led to the development of exceptional room-temperature devices. Unoptimized peak detectivities on the order of 10 to the 13th cm sq rt Hz/W, a value which exceeds the best obtainable from existing solid-state detectors, have now been consistently obtained in Si and GaAs devices using high-capacitance LaF3 or composite LaF3/native-oxide insulating layers. The measured spectral response of representative samples is presented and discussed in detail together with a simple theory which accounts for the observed behavior. The response of an ideal MIS photocapacitor is also contrasted with that of both a conventional photoconductor and a p-i-n photodiode, and reasons for the superior performance of the MIS detectors are given. Finally, fundamental studies on the electrical, optical, and noise characteristics of the MIS structures are analyzed and discussed in the context of infrared-detector applications.

Sher, A.↗
NASA NTRS1982

Pressure concentrations due to plastic deformation of thin films or gaskets between anvils

Plastic deformation of either a sample or a gasket between diamond anvils leads to large pressure concentrations, i.e., the maximum pressure can be many times the average pressure. This behavior is discussed using elementary plasticity theory for the case where the pressures are sufficiently low that the yield stress can be assumed not to vary with pressure. It is then shown that the pressure concentration factor can be even much larger when the yield stress of the sample at the highest pressure is much greater than the yield stress at the lowest pressure. This is illustrated with solid xenon where it is shown that the assumption that Nelson and Ruoff made about the pressure distribution in their xenon samples is incorrect. The pressure distribution is shown to be much steeper than assumed. Thus, the pressure they observed electrical conduction in xenon was above 1 Mbar.

Chan, K. S.↗
NASA NTRS1983

Injection molding ceramics to high green densities

The injection molding behavior of a concentrated suspension of Si powder in wax was studied. It was found that the injection molding behavior was a function of the processing techniques used to generate the powder. Dry ball-milled powders had the best molding behavior, while air classified and impact-milled powders demonstrated poorer injection moldability. The relative viscosity of these molding batches was studied as a function of powder properties: distribution shape, surface area, packing density, and particle morphology. The experimental behavior, in all cases, followed existing theories. The relative viscosity of an injection molding composition composed of dry ball-milled powders could be expressed using Farris' relation.

Mangels, J. A.↗
NASA NTRS1983

Theory of hydromagnetic waves in the magnetosphere

A survey of theoretical and experimental research on the origin and characteristics of low-frequency hydromagnetic (HM) waves in the magnetosphere is presented, with a focus on advances in theory made in the last ten years. Basic wave theory and a collisionless plasma theory are applied to the magnetosphere as a HM system. Continuous energy sources are considered, such as the Kelvin-Helmholtz instability, the ring-current plasma, and drift instabilities. Other topics discussed include the theory of inhomogeneous HM waves, signal behavior in atmosphere and ionosphere, Alfven waves and ionosphere-magnetosphere coupling, Pi2 signals, damping, pulsating aurora, heavy-ion scattering, and standing waves in high-speed flows (like the wake phenomena caused on Jupiter by the passing of Io, observed by Voyager 1).

Southwood, D. J.↗
NASA NTRS1982

Unsymmetrically laminated composites

Classical lamination theory predicts that the room-temperature shapes of all elevated-temperature cure, unsymmetrically laminated composites are saddles. However, experimental observation indicates that the shapes are often cylindrical. In addition, a second cylindrical can sometimes be obtained from the first by a simple snap-through action. A geometrically nonlinear extension to classical lamination theory is used to explain this behavior. Approximate solutions to the nonlinear extension are obtained by using a Rayleigh-Ritz minimization of the laminate's total potential energy. A stability analysis explains the dual cylindrical shapes.

Hyer, M. W.↗
NASA NTRS1983

Milgrom's revision of cosmic dynamics: Amending Newton's laws or Keplers?

Milgrom's recent revision of Newtonian dynamics was introduced to eliminate the inference that large quantities of invisible mass exist in galaxies. Simple examples show that a Milgrom acceleration, in the form presented so far, imply other far-reaching changes in dynamics. The momentum of an isolated system is not conserved, and the usual theorem for center-of-mass motion of any system does not hold. Naive applications require extreme caution. The model fails to provide a complete description of particle dynamics and should be thought of as a revision of Kepler's laws rather than Newton's. The Milgrom acceleration also implies fundamental changes in cosmology. A quasi-Newtonian calculation adapted from Newtonian cosmology suggests that a Milgrom universe will recollapse even if the classical closure parameter theta is less than 1. The solution, however, fails to satisfy the cosmological principle. Reasons for the breakdown of this calculation are examined. A theory of gravitation needed before the behavior of a Milgrom universe can be predicted.

Felten, J. E.↗
NASA NTRS1990

Structure of turbulence at high shear rate

The structure of homogeneous turbulence subject to high shear rate has been investigated by using three-dimensional, time-dependent numerical simulations of the Navier-Stokes equations. This study indicates that high shear rate alone is sufficient for generation of the streaky structures, and that the presence of a solid boundary is not necessary. Evolution of the statistical correlations is examined to determine the effect of high shear rate on the development of anisotropy in turbulence. It is shown that the streamwise fluctuating motions are enhanced so profoundly that a highly anisotropic turbulence state with a 'one-component' velocity field and 'two-component' vorticity field develops asymptotically as total shear increases. Because of high-shear rate, rapid distortion theory predicts remarkably well the anisotropic behavior of the structural quantities.

Lee, Moon Joo↗