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Definition and preliminary design of the Laser Atmospheric Wind Sounder (LAWS) phase 1. Volume 2

The steps and engineering trades and analyses used in establishing the initial requirements and in developing a concept and configuration for the laser atmospheric wind sounder (LAWS) instrument. A summary of the performance anticipated from the baseline configuration, and a bibliography are presented. LAWS, which is a facility instrument of the Earth observing system (EOS), is the culmination of over 20 years of effort in the field of laser Doppler wind sensing and will be the first instrument to fly in space capable of providing global-scale tropospheric wind profiles at high spatial resolutions. Global-scale wind profiles are necessary for: (1) more accurate diagnosis of large-scale circulation and climate dynamics; (2) improved numerical weather prediction; (3) improved understanding of mesoscale systems; and (4) improved understanding of global biogeochemical and hydrologic cycles. The objective of phase 1 was to define and perform a preliminary design for the LAWS instrument. The definition phase consisted of identifying realistic concepts for LAWS and analyzing them in sufficient detail to be able to choose the most promising one for the LAWS instrument. Systems and subsystems configurations were then developed for the chosen concept. The concept and subsequent configuration were to be compatible with two prospective platforms: the Japanese polar orbiting platform (JPOP) and as an attached payload on the Space Station Freedom. After a thorough and objective concept selection process, a heterodyne detection Doppler lidar using a CO2 laser transmitter operating a 9.1 micron over a 2.1 micron solid state system was chosen. A configuration for LAWS that meets the performance requirements was designed at the conclusion of phase 1.

Source record↗

Definition and Preliminary Design of the Laser Atmospheric Wind Sounder (LAWS) Phase 1. Volume 1: Executive Summary

The laser atmospheric wind sounder (LAWS) is a facility instrument of the Earth Observing System (EOS) and is the culmination of over 20 years of effort in the field of laser Doppler wind sensing. LAWS will by the first instrument to fly in space with the capability of providing global-scale tropospheric wind profiles at high spatial resolutions. Global-scale wind profiles are necessary for: (1) more accurate diagnostics of large-scale circulation and climate dynamics; (2) improved numerical weather prediction; (3) improved understanding of mesoscale systems; (4) improved understanding of global biogeochemical and hydrologic cycles. The objective of phase 1 of the LAWS study was to evaluate competing concepts and develop a baseline configuration for the LAWS instrument. The first phase of the study consisted of identifying realistic concepts for LAWS and analyzing them in sufficient detail to be able to choose the most promising one for the LAWS application. System configurations were then developed for the chosen concept. The concept and subsequent configuration were to be compatible with two prospective platforms: the Japanese polar orbiting platform (JPOP) and the Space Station Freedom (as an attached payload). After an objective and comprehensive concept selection process, a heterodyne detection Doppler lidar using a CO2 laser transmitter operating at 9.1 microns over a 2.1 micron system with a solid state laser was chosen. The CO2 lidar concept was then analyzed in detail to arrive at a configuration for the instrument and its major subsystems. A configuration for LAWS was arrived at which meets the performance requirements, and this design is presented.

Source record↗

Data management for community research projects: A JGOFS case study

Since the mid 1980s, much of the marine science research effort in the United Kingdom has been focused into large scale collaborative projects involving public sector laboratories and university departments, termed Community Research Projects. Two of these, the Biogeochemical Ocean Flux Study (BOFS) and the North Sea Project incorporated large scale data collection to underpin multidisciplinary modeling efforts. The challenge of providing project data sets to support the science was met by a small team within the British Oceanographic Data Centre (BODC) operating as a topical data center. The role of the data center was to both work up the data from the ship's sensors and to combine these data with sample measurements into online databases. The working up of the data was achieved by a unique symbiosis between data center staff and project scientists. The project management, programming and data processing skills of the data center were combined with the oceanographic experience of the project communities to develop a system which has produced quality controlled, calibrated data sets from 49 research cruises in 3.5 years of operation. The data center resources required to achieve this were modest and far outweighed by the time liberated in the scientific community by the removal of the data processing burden. Two online project databases have been assembled containing a very high proportion of the data collected. As these are under the control of BODC their long term availability as part of the UK national data archive is assured. The success of the topical data center model for UK Community Research Project data management has been founded upon the strong working relationships forged between the data center and project scientists. These can only be established by frequent personal contact and hence the relatively small size of the UK has been a critical factor. However, projects covering a larger, even international scale could be successfully supported by a network of topical data centers managing online databases which are interconnected by object oriented distributed data management systems over wide area networks.

Lowry, Roy K.↗

Recent Progress on Deep Blue Aerosol Algorithm as Applied TO MODIS, SEA WIFS, and VIIRS, and Their Intercomparisons with Ground Based and Other Satellite Measurements

The impact of natural and anthropogenic sources of aerosols has gained increasing attention from scientific communities in recent years. Indeed, tropospheric aerosols not only perturb radiative energy balance by interacting with solar and terrestrial radiation, but also by changing cloud properties and lifetime. Furthermore, these anthropogenic and natural air particles, once generated over the source regions, can be transported out of the boundary layer into the free troposphere and can travel thousands of kilometers across oceans and continents resulting in important biogeochemical impacts on the ecosystem. With the launch of SeaWiFS in 1997, Terra/MODIS in 1999, and Aqua/MODIS in 2002, high quality comprehensive aerosol climatology is becoming feasible for the first time. As a result of these unprecedented data records, studies of the radiative and biogeochemical effects due to tropospheric aerosols are now possible. In this talk, we will demonstrate how this newly available SeaWiFS/MODIS aerosol climatology can provide an important piece of puzzles in reducing the uncertainty of estimated climatic forcing due to aerosols. We will start with the global distribution of aerosol loading and their variabilities over both land and ocean on short- and long-term temporal scales observed over the last decade. The recent progress made in Deep Blue aerosol algorithm on improving accuracy of these Sea WiFS / MODIS aerosol products in particular over land will be discussed. The impacts on quantifying physical and optical processes of aerosols over source regions of adding the Deep Blue products of aerosol properties over bright-reflecting surfaces into Sea WiFS / MODIS as well as VIIRS data suite will also be addressed. We will also show the intercomparison results of SeaWiFS/MODIS retrieved aerosol optical thickness with data from ground based AERONET sunphotometers over land and ocean as well as with other satellite measurements. The trends observed in global aerosol loadings of both natural and anthropogenic sources based upon more than a decade of combined MODIS/SeaWiFS data (1997-2011) will be discussed. We will also address the importance of various key issues such as differences in spatial-temporal sampling rates and observation time between different satellite measurements could potentially impact these intercomparisons results, especially for using the monthly mean data, and thus on estimates of long-term aerosol trends.

Hsu, N. Christina↗

Interpretable Machine Learning Models for Autonomous Characterization of Analogue Ocean World Seawater Chemistry and Biosignature Potential Using Isotope Ratio Data

Background: Future missions to ocean worlds, such as Enceladus and Europa, will attempt to characterize the subsurface seawater chemistry and assess the potential for life. Such missions will be equipped with capabilities to precisely measure volatile isotopes in plumes, atmospheres, and exospheres. Motivation: While large isotopic fractionations can indicate a biological source, there are signatures resulting from abiotic geochemical processes that mimic isotopic biosignatures. While machine learning (ML) has the potential to disentangle competing effects and biotic mimicry, high-dimensional isotope ratio mass spectrometry (IRMS) data is likely to contain noise/irrelevant features and involve complex statistical interactions that make human inference and interpretation difficult. Further, ML predictions with as far-reaching implications as an extraterrestrial biosignature on an ocean world requires the use of interpretable models (i.e., not “black box” models) with physically and mathematically meaningful feature spaces along with false positive diagnostics. Methods: We use volatile CO2 IRMS data of analogue ocean world seawaters to validate an ML approach to provide biogeochemical context for biosignature detection. We employ a feature selection method called nearest-neighbor projected distance regression (NPDR) that detects statistical interactions and helps elucidate the mechanisms of the Random Forest classification models. Results: We train and validate predictive ML models on volatile CO2 IRMS data of analogue ocean world seawaters to predict major salt components (e.g., MgSO4, NaHCO3), pH, ionic strength, and the presence of biosignatures. Features derived from IRMS measurements are augmented with extracted time-series features. Our results show high test accuracy and interpretability, which is increased by interaction network visualization, sample-wise variable importance scores, and single-sample class probability estimates. We demonstrate an ML mission software solution that triggers autonomous data transmission and biogeochemical sample prediction.

geochemistry↗

Validating spatial structure in canopy water content using geostatistics

Heterogeneity in ecological phenomena are scale dependent and affect the hierarchical structure of image data. AVIRIS pixels average reflectance produced by complex absorption and scattering interactions between biogeochemical composition, canopy architecture, view and illumination angles, species distributions, and plant cover as well as other factors. These scales affect validation of pixel reflectance, typically performed by relating pixel spectra to ground measurements acquired at scales of 1m(exp 2) or less (e.g., field spectra, foilage and soil samples, etc.). As image analysis becomes more sophisticated, such as those for detection of canopy chemistry, better validation becomes a critical problem. This paper presents a methodology for bridging between point measurements and pixels using geostatistics. Geostatistics have been extensively used in geological or hydrogeolocial studies but have received little application in ecological studies. The key criteria for kriging estimation is that the phenomena varies in space and that an underlying controlling process produces spatial correlation between the measured data points. Ecological variation meets this requirement because communities vary along environmental gradients like soil moisture, nutrient availability, or topography.

Sanderson, E. W.↗

Precambrian evolution of the climate system

This paper presents a new examination of the biogeochemical cycles of carbon as they may have changed between an Archean Earth deficient in land, sedimentary rocks, and biological activity, and a Proterozoic Earth much like the modern Earth, but lacking terrestrial life and carbonate-secreting plankton. Results of a numerical simulation of this transition show how increasing biological activity could have drawn down atmospheric carbon dioxide by extracting sedimentary organic carbon from the system. Increasing area of continents could further have drawn down carbon dioxide by encouraging the accumulation of carbonate sediments. An attempt to develop a numerical simulation of the carbon cycles of the Precambrian raises questions about sources and sinks of marine carbon and alkalinity on a world without continents. More information is needed about sea-floor weathering processes.

Walker, James C. G.↗

The ACCP Inclined Orbit Project: Enabling New and Synergistic Aerosol Remote Sensing Inversions

Atmospheric aerosols have high spatiotemporal variations due to their diverse sources including windblown dust, wildfires, volcanic eruptions, and anthropogenic emissions. These aerosols also have strong diurnal emission characteristics that influence long-range transport, air quality, Earth’s radiation budget, biogeochemical cycles, and weather forecasting. While current sensors can measure the steady-state of global 3D cloud and aerosol properties, we lack the observational datasets to discover the diurnal variability of aerosols, even at seasonal and regional scales, because these missions utilize sun synchronous orbits. An Aerosols and Clouds, Convection and Precipitation (ACCP) observing system has been established as part of NASA’s new Earth System Observatory (ESO) to fulfill the science needs presented in the 2017 Earth Science Decadal Survey. The selected ACCP architecture encompasses sensors in two orbit planes, one of which utilizes an inclined orbit (nominally ~55 degrees at a 407 km altitude) to advance our understanding of aerosol and cloud properties and target the dynamics of the cloud and aerosol processes on sub-daily time scales. The anticipated instrumentation suite for the ACCP Inclined Orbit Project is a Stereo Camera System, Polarimeter, Microwave Radiometer, Two-Frequency Radar, and Backscatter Lidar. The polarimeter is expected to have multiple wavelength bands and viewing angles to enable accurate retrievals of aerosol microphysical and optical properties. The backscatter lidar will provide vertical profiles of attenuated backscatter and depolarization ratio at two wavelengths, with better daytime signal-to-noise ratio than previous space-based lidar systems to improve aerosol detection/typing and estimates of aerosol optical properties. The stereo camera system, while designed primarily for clouds, will also provide aerosol plume heights and air motions at the plume heights. This invited presentation will provide (1) an overview of the ACCP Inclined Orbit Project, (2) a description of the new sensor capabilities and orbital characteristics, and (3) a preview of the potential for new synergistic aerosol inversion techniques.

John E Yorks↗

An Integrated Use of Experimental, Modeling and Remote Sensing Techniques to Investigate Carbon and Phosphorus Dynamics in the Humid Tropics

Moist tropical forests comprise one of the world's largest and most diverse biomes, and exchange more carbon, water, and energy with the atmosphere than any other ecosystem. In recent decades, tropical forests have also become one of the globe's most threatened biomes, subjected to exceptionally high rates of deforestation and land degradation. Thus, the importance of and threats to tropical forests are undeniable, yet our understanding of basic ecosystem processes in both intact and disturbed portions of the moist tropics remains poorer than for almost any other major biome. Our approach in this project was to take a multi-scale, multi-tool approach to address two different problems. First, we wanted to test if land-use driven changes in the cycles of probable limiting nutrients in forest systems were a key driver in the frequently observed pattern of declining pasture productivity and carbon stocks. Given the enormous complexity of land use change in the tropics, in which one finds a myriad of different land use types and intensities overlain on varying climates and soil types, we also wanted to see if new remote sensing techniques would allow some novel links between parameters which could be sensed remotely, and key biogeochemical variables which cannot. Second, we addressed to general questions about the role of tropical forests in the global carbon cycle. First, we used a new approach for quantifying and minimizing non-biological artifacts in the NOAA/NASA AVHRR Pathfinder time series of surface reflectance data so that we could address potential links between Amazonian forest dynamics and ENSO cycles. Second, we showed that the disequilibrium in C-13 exchanged between land and atmosphere following tropical deforestation probably has a significant impact on the use of 13-CO2 data to predict regional fluxes in the global carbon cycle.

Townsend, Alan R.↗

Towards the Development of a Global Precipitation Measurement (GPM) Mission Concept

The scientific success of the Tropical Rainfall Measuring Mission (TRMM) and additional satellite-focused precipitation retrieval projects have paved the way for a more advanced global precipitation mission. A comprehensive global measuring strategy is currently under study - Global Precipitation Measurement (GPM). The GPM study could ultimately lead to the development of the Global Precipitation Mission. The intent of GPM is to address looming scientific questions arising in the context of global climate-water cycle interactions, hydrometeorology, weather prediction and prediction of freshwater resources, the global carbon cycle, and biogeochemical cycles. This talk overviews the status and scientific agenda of this proposed mission currently planned for launch in the 2007-2008 time frame. GPM is planning to expand the scope of precipitation measurement through the use of a constellation of 6-10 satellites, one of which will be an advanced TRMM-like "core" satellite carry dual-frequency Ku-Ka band radar and a microwave radiometer (e.g. TMI-like). The other constellation members will likely include new lightweight satellites and co-existing operational/research satellites carrying passive microwave radiometers. The goal behind the constellation is to achieve no worse than 3-hour sampling at any spot on the globe. The constellation's orbit architecture will consist of a mix of sun-synchronous and non-su n -synchronous satellites with the "core" satellite providing measurement of cloud-precipitation microphysical processes plus "training calibrating" information to be used with the retrieval algorithms for the constellation satellite measurements. The GPM is organized internationally, currently involving a partnership between NASA in the US, NASDA in Japan, and ESA in Europe (representing the European community). The program is expected to involve additional international partners, other federal agencies, and a diverse collection of scientists from academia, government, and the private sector.

Shepherd, Marshall↗

Fungal Exposure to Meteorite Thin Sections: Developing an Experimental to Observe Biogeochemical Changes

The Astromaterials Acquisition & Curation Office maintains collections of meteorite samples collected as part of the Antarctic Search for Meteorites (ANSMET) program. The chief goal of the curation department is to maintain these meteorites in pristine condition. The Astromaterials Research and Exploration Science (ARES) Directorate has implemented a microbial monitoring program for the meteorite collections that has resulted in the isolation of >100 fungal isolates [1], however it is currently unknown if these isolates could present danger to the collections through bioweathering or secretion of organic compounds. We grew a strain of Fusarium oxysporium isolated from nitrogen gas filters feeding the Meteorite Lab nitrogen gas in the presence of a H5 meteorite thin section to determine if this fungus has the capability of altering the mineral structure of this common meteorite. This first trial was to determine and understand the effects of Fusarium oxysporum growth on the iron content within H5 chondrites and evaluate what additional components are needed in the development of future trial runs. This experiment determined new considerations for handling samples, the nature of microscopic scans before and after the incubation period, and the quality of the samples utilized for the experiment. The results of this experiment were promising and warrant further investigation with a more refined process and timeline.

Barbre, K. S. R.↗

Anthropogenic Nitrogen Inputs and Impacts on Oceanic N2O Fluxes in the Northern Indian Ocean: the Need for an Integrated Observation and Modelling Approach

Anthropogenically-derived nitrogen input to the northern Indian Ocean has increased significantly in recent decades, based on both observational and model derived estimates This external nutrient source is supplied by atmospheric deposition and riverine fluxes, and has the potential to affect the vulnerable biogeochemical systems of the Arabian Sea and Bay of Bengal, influencing productivity and oceanic production of the greenhouse-gas nitrous-oxide (N2O). We summarize current estimates of this external nitrogen source to the northern Indian Ocean from observations and models, highlight implications for regional marine N2O emissions using model-based analyses, and make recommendations for measurement and model needs to improve current estimates and future predictions of this impact. Current observationally-derived estimates of deposition and riverine nitrogen inputs are limited by sparse measurements and uncertainties on accurate characterization of nitrogen species composition. Ocean model assessments of the impact of external nitrogen sources on regional marine N2O production in the northern Indian Ocean estimate potentially significant changes but also have large associated uncertainties. We recommend an integrated program of basin-wide measurements combined with high-resolution modeling and more detailed characterization of nitrogen-cycle process to address these uncertainties and improve current estimates and predictions.

Parvadha Suntharalingam↗

A LEO Hyperspectral Mission Implementation for Global Carbon Cycle Observations

For both terrestrial and ocean carbon cycle science objectives, high resolution (less than l0 nm) imaging spectrometers capable of acquiring multiple regional to global scale observations per day should enable the development of new remote sensing measurements for important but as yet unobservable variables, with the overall goal of linking both terrestrial and ocean carbon cycle processes to climate variability. For terrestrial research, accurate estimates of carbon, water and energy (CWE) exchange between the terrestrial biosphere and atmosphere a needed to id- the geographical locations and temporal dynamics of carbon sources/sinks and to improve regional climate models and climate change assessments. It is an enormous challenge to estimate CWE exchange from the infrequent temporal coverage and sparse spectral information provided by most single polar-orbiting, earth-looking satellite. The available satellite observations lack a sufficient number of well-placed narrow bands from which to derive spectral indices that capture vegetation responses to stress conditions associated with down-regulation of photosynthesis. Physiological status can best be assessed with spectral indices based on continuous, narrow bands in the visible/near infrared spectra, as can seasonal and annual terrestrial productivity. For coastal and ocean constituents, narrow-band observations in the ultraviolet and visible are essential to investigate the variability, dynamics and biogeochemical cycles of the world's coastal and open ocean regions, which will in turn help in measuring ocean productivity and predicting the variability of ocean carbon uptake and its role in climate change.

Gervin, Janette C.↗

Statistical Considerations of Data Processing in Giovanni Online Tool

The GES DISC Interactive Online Visualization and Analysis Infrastructure (Giovanni) is a web-based interface for the rapid visualization and analysis of gridded data from a number of remote sensing instruments. The GES DISC currently employs several Giovanni instances to analyze various products, such as Ocean-Giovanni for ocean products from SeaWiFS and MODIS-Aqua; TOMS & OM1 Giovanni for atmospheric chemical trace gases from TOMS and OMI, and MOVAS for aerosols from MODIS, etc. (http://giovanni.gsfc.nasa.gov) Foremost among the Giovanni statistical functions is data averaging. Two aspects of this function are addressed here. The first deals with the accuracy of averaging gridded mapped products vs. averaging from the ungridded Level 2 data. Some mapped products contain mean values only; others contain additional statistics, such as number of pixels (NP) for each grid, standard deviation, etc. Since NP varies spatially and temporally, averaging with or without weighting by NP will be different. In this paper, we address differences of various weighting algorithms for some datasets utilized in Giovanni. The second aspect is related to different averaging methods affecting data quality and interpretation for data with non-normal distribution. The present study demonstrates results of different spatial averaging methods using gridded SeaWiFS Level 3 mapped monthly chlorophyll a data. Spatial averages were calculated using three different methods: arithmetic mean (AVG), geometric mean (GEO), and maximum likelihood estimator (MLE). Biogeochemical data, such as chlorophyll a, are usually considered to have a log-normal distribution. The study determined that differences between methods tend to increase with increasing size of a selected coastal area, with no significant differences in most open oceans. The GEO method consistently produces values lower than AVG and MLE. The AVG method produces values larger than MLE in some cases, but smaller in other cases. Further studies indicated that significant differences between AVG and MLE methods occurred in coastal areas where data have large spatial variations and a log-bimodal distribution instead of log-normal distribution.

Suhung, Shen↗

Further Studies on the Physical and Biogeochemical Causes for Large Interannual Changes in the Patagonian Shelf Spring-Summer Phytoplankton Bloom Biomass

A very strong and persistent phytoplankton bloom was observed by ocean color satellites during September - December 2003 along the northern Patagonian shelf. The 2003 bloom had the highest extent and chlorophyll a (Chl-a) concentrations of the entire Sea-viewing Wide Field-of-view Sensor (SeaWiFS) period (1997 to present). SeaWiFS-derived Chl-a exceeded 20 mg/cu m in November at the bloom center. The bloom was most extensive in December when it spanned more than 300 km across the shelf and nearly 900 km north-south (35degS to 43degS). The northward reach and the deep penetration on the shelf of the 2003 bloom were quite anomalous when compared with other years, which showed the bloom more confined to the Patagonian shelf break (PSB). The PSB bloom is a conspicuous austral spring-summer feature detected by ocean color satellites and its timing can be explained using the Sverdrup critical depth theory. Based on high-resolution numerical simulations, in situ and remote sensing data, we provide some suggestions for the probable mechanisms responsible for that large interannual change of biomass as seen by ocean color satellites. Potential sources of macro and micro (e.g., Fe) nutrients that sustain the high phytoplankton productivity of the Patagonian shelf waters are identified, and the most likely physical processes that maintain the nutrient balance in the region are discussed.

Signorini, Sergio R.↗

Quantifying Structural Relationships of Metal-Binding Sites Suggests Origins of Biological Electron Transfer

Biological redox reactions drive planetary biogeochemical cycles. Using a novel, structure-guided sequence analysis of proteins, we explored the patterns of evolution of enzymes responsible for these reactions. Our analysis reveals that the folds that bind transition metal–containing ligands have similar structural geometry and amino acid sequences across the full diversity of proteins. Similarity across folds reflects the availability of key transition metals over geological time and strongly suggests that transition metal–ligand binding had a small number of common peptide origins. We observe that structures central to our similarity network come primarily from oxidoreductases, suggesting that ancestral peptides may have also facilitated electron transfer reactions. Last, our results reveal that the earliest biologically functional peptides were likely available before the assembly of fully functional protein domains over 3.8 billion years ago. Thus, life is a special, very complex form of motion of matter, but this form did not always exist, and it is not separated from inorganic nature by an impassable abyss; rather, it arose from inorganic nature as a new property in the process of evolution of the world. We must study the history of this evolution if we want to solve the problem of the origin of life.

Yana Bromberg↗

Current Development of Global Precipitation Mission (GPM)

The scientific success of the Tropical Rainfall Measuring Mission (TRMM) and additional satellite-focused precipitation retrieval projects, particularly those based on use of passive microwave radiometer measurements, have paved the way for a more advanced global precipitation mission. The new mission is motivated by a number of scientific questions that TRMM research has posed over a range of space-time scales and within a variety of scientific disciplines that are becoming more integrated into earth system science modeling. Added to this success is the realization that satellite rainfall datasets are now a foremost tool in understanding global climate variability out to decadal scales and beyond. This progress has motivated a comprehensive global measuring strategy -- leading to the "Global Precipitation Mission" (GPM). GPM is planning to expand the scope of rainfall measurement through use of a satellite constellation. The intent is to address looming scientific questions arising in the context of global climate-water cycle interactions, hydrometeorology, weather prediction & prediction of fresh water resources, the global carbon budget, and biogeochemical cycles. This talk overviews the status and scientific agenda of this mission currently planned for launch in the 2007-2008 time frame. The GPM notional design involves a 10-member satellite constellation, one of which will be an advanced TRMM-like "core" satellite carrying a dual-frequency Ku-Ka band radar (DFPR) and a TMI-like radiometer. The other nine members of the constellation will be considered daughters of the core satellite, each carrying some type of passive microwave radiometer measuring across the 10.7-85 GHz frequency range -- likely to include a combination of lightweight satellites and co-existing operational/experimental satellites carrying passive microwave radiometers (i.e., 2 DMSP/SSMISs, GCOM-B1/AMSR-J, & Megha Tropiques/MADRAS). The goal behind the constellation is to achieve no worse than 3-hour sampling at any spot on the globe. The constellation's orbit architecture will consist of a mix of sun-synchronous and non- sun-synchronous daughter satellites, with the core satellite providing relevant measurements on internal cloud-precipitation microphysical processes plus "training-calibrating" information to be used with the retrieval algorithms for the daughter satellite measurements. The GPM is organized internationally, currently involving a partnership between NASA in the US, NASDA in Japan, and ESA in Europe (representing the European community nations). The mission is expected to involve additional international participants, sister agencies to the mainstream space agencies, and a diverse collection scientists from academia, government, and the private sector.

Smith, Eric A.↗

The carbon isotope biogeochemistry of (epsilon)CO2 production in a methanogenic marine sediment

To investigate the relationship between sigma(CO2) delta(C-13) values and rates of the dominant remineralization processes at the organic-rich field site of Cape Lookout Bight, NC, the isotopic composition of porewater sigma(CO2) was measured on a seasonal basis. The sigma(CO2) delta(C-13) values varies seasonally in response to changes in rates of sulfate reduction and methanogenesis, the dominant remineralization processes at this site. A tube incubation experiment was also performed to determine the isotopic signature of the sigma(CO2) produced by sulfate reduction and methanogenesis. The delta(C-13) of the sigma(CO2) produced in the sulfate reduction zone determined from the tube incubation was -14.3 plus or minus 1.9, a value enriched in C-13 relative to the labile organic fraction. The C-13-enrichment may be caused by low rates of methanogenesis occurring in the sulfate reduction zone. The delta(C-13) of the sigma(CO2) produced in the methanogenic zone was estimated to be +44 per mil, whereas the co-produced methane was -65 per mil. The fractionation factor for CO2 reduction was calculated to be 1.055, a value in agreement with previous estimates at this site. The measured concentration and delta(C-13) of the sigma(CO2) at Cape Lookout was closely reproduced by a diagenetic model using the measured rates of sulfate reduction and sigma(CO2) production, and the isotopic signature of the sigma(CO2) production in the two biogeochemical zones.

Boehme, Susan E.↗