Determination of iron, nickel, cobalt, calcium, chromium and manganese in stony meteorites by X-ray fluorescence.
Stony meteorite Fe, Ni, Co, Ca, Cr and Mn concentration determined by X-ray fluorescence
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Stony meteorite Fe, Ni, Co, Ca, Cr and Mn concentration determined by X-ray fluorescence
Fabrication of Cr-Mo-Ta-C-Y alloy sheet
New high dispersion, high resolution X ray spectrometer
Ductile metal clads and coatings of silicides, aluminides and noble metals to protect Cr alloys against nitrogen embrittlement and air oxidation
Chondritic Cr and Mn content studied by X ray fluorescence, noting positive correlation in H and L groups and negative correlation in carbonaceous chondrites
H release, pressure and oxide layer formed by reaction during ball milling Cr in water
Silicide, aluminide and boride coatings transition temperature holdability, considering nitridation/ oxidation protection for Cr alloys
Ni-Cr content and variability in Ivory Coast tektites using atomic absorption and X ray emission techniques
Dispersion strengthened Ni-Cr alloys creep properties, investigating temperature, applied stress and thorium dioxide particles effects
Development and fabrication of precipitation hardened TD NiCr structures for use in high temperature environments
Thoria dispersed Ni-Cr alloy hypersonic entry ablation model, accounting for Cr oxidation
Oxidation and nitrogen absorption protection of Cr alloy by Ni alloy claddings applied by gas pressure bonding
Apollo 11 and 12 lunar dust and rocks, determining Be and Cr contents by gas chromatography for comparison with crystalline rocks
TD NiCr was exposed to a Mach 1, 1-atmosphere gas stream at 1204 C for times up to 50 hours. Weight change, metal thickness loss, X-ray diffraction, metallographic, and electron microprobe analyses were made. Neither surface preparation nor thermal cycling had an appreciable effect on the results. Initially, Cr2O3 formed and volatilized, allowing a rapid metal loss rate of 40 microns per hour. After about 1 hour the Cr2O3 broke down, resulting in an NiO overgrowth. The metal loss rate then slowed to 2.5 microns per hour and remained constant to 50 hours.
Various solid-solid diffusion couples were assembled from thoriated and nonthoriated nickel-base alloys, welded, and diffusion annealed at 1260 C. Concentration profiles indicated that a thoria dispersion does not affect diffusion in Cr(alloy):Ni and Ni-4.8Al:Ni types of couples unless a fine grain structure is retained by the thoria particles. Metallography revealed the presence of thoria-free bands in the thoriated-Ni side of the diffusion zone. The bands contained grain boundaries and, in some cases, non-Kirkendall porosity. A mechanism based on the operation of vacancy sources is proposed to explain the thoria-free bands. In addition, a particular DS-NiCr:Ni couple had negligible Kirkendall porosity. This behavior was related to the grain structure of the particular lot of DS-NiCr.
Embedded-alumina-particle aluminide (EAPA) coated and CoCrAlY coated IN-100 and NASA-TRW-VIA specimens were cyclically oxidation tested in a high velocity (approximately Mach 1) gas flame at 1093 C (2000 F). The EAPA coatings on both alloys performed very similarly to commercial pack aluminide coatings with respect to weight change and thermal fatigue cracking. The CoCrAlY coating on IN-100 had weight changes similar to commercial pack aluminide coatings but no thermal fatigue cracks appeared at 300 hours. The CoCrAlY coating on VIA performed significantly better than the commercial aluminide coatings, providing oxidation protection (based on weight change) to 450 hours and thermal fatigue crack prevention to at least 600 hours.
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